摘要
用一个简单的方法将Fe与ZnO掺杂,并研究了它的光催化性能。通过球磨机制备出高效率降解甲基橙的光催化剂,一部分归因于ZnO掺杂了Fe,一部分则是由于在高速研磨下样品颗粒尺寸变小,氧化锌纳米颗粒的反应速度约为普通氧化锌颗粒100~1000倍,尺寸越小光催化效果越明显[1]。而且通过球磨机掺杂制备的光催化剂可以循环使用。
Fe doped ZnO were prepared by a simple method, and studied the photocatalytic properties.Through the simple ball mill grinding, the elemental of Fe doping ZnO catalysts showed the higher degradation rates than that of pure ZnO,which was attributed to the Fe doping effects and due to the ball mill grinding, the particle size of the samples become smaller. The reaction speed of ZnO nanoparticles is about 100~1000 times of the normal ZnO particles, the size become smaller the effect of the light catalytic become more obvious[1]. And the photocatalyst can be recycled by doping with the ball mill.
引文
[1]李洪杰,杨凤珠,柳闽生,等.铁掺杂氧化锌纳米晶的制备及光催化性能研究[J].化工时刊,2009,23(8):16-19.
[2]林元华,翟俊宜,王海峰,等.机械化学法合成纳米粉体[J].无机材料学报,2003,18(3):673-676.
[3]吴莉莉,吕伟,伦宁,等.纳米氧化锌的制备与光学性能表征[J].山东大学学报:工学版,2005,35(2):1-4.
[4]Roselin L S,Rajarajiswari G R,Selvin R,et al.Sun-light/ZnO mediated photocatalytic degradtion of reactive red 22 using thin film flatbed flow photoreactor[J].Solar Energy,2002,73(4):281-285.
[5]Xu Z Q,Deng H,Li Y,et al.Characteristics of Al-doped C-axis orientation ZnO thin films prepared by the sol-gel method[J].Materials Research Bulletin,2006,41(2):354-358.
[6]Wang Y,Li M.Hydrothermal synthesis of single-crystal-line hexagonal prism ZnO Nanords[J].Materials Letters,2006,60(2):266-269.
[7]吴诗德,李超,方少明,等.铁掺杂氧化锌的制备及其对甲基橙的光催化降解[J].人工晶体学报,2010,39(2):444-448.