非金属矿物合成沸石分子筛的研究进展
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摘要
沸石分子筛是一种具有规则孔道结构的硅铝酸盐晶体材料,广泛应用于吸附、催化、离子交换等工业领域。通常采用硅酸钠、铝酸钠等化工原料合成沸石分子筛,其工艺成熟,产品纯度高,但是价格昂贵,来源有限,因此以储量丰富的非金属矿物为原料合成沸石分子筛,将廉价的非金属矿物转化成高附加值的化工产品,具有良好的社会效益和经济效益。在简单介绍非金属矿物的理化性质的基础上,综述了非金属矿物合成沸石分子筛的工艺条件与研究成果,同时指出非金属矿物合成沸石分子筛时存在预处理工序复杂等问题,并展望了其发展趋势。
Zeolite is a kind of aluminosilicate crystal material with regular pore structure,which is widely used in adsorption,catalysis,ion exchange and other industrial fields.Generally,zeolites are synthesized by chemical materials such as sodium silicate and sodium aluminate,which is mature and the products are of high purity,but the chemical materials are expensive and limited.Therefore,it will possess great social and economic benefits to synthesize zeolites with abundant non-metallic minerals.Based on a brief introduction of the physicochemical properties of non-metallic minerals,advances in synthesis of zeolites are reviewed. Meanwhile,the problems such as complex pretreatment are presented in the synthesis of zeolites with non-metallic minerals.In addition,the development trends for the synthesis of zeolites with non-metallic minerals are also prospected.
Zeolite is a kind of aluminosilicate crystal material with regular pore structure,which is widely used in adsorption,catalysis,ion exchange and other industrial fields.Generally,zeolites are synthesized by chemical materials such as sodium silicate and sodium aluminate,which is mature and the products are of high purity,but the chemical materials are expensive and limited.Therefore,it will possess great social and economic benefits to synthesize zeolites with abundant non-metallic minerals.Based on a brief introduction of the physicochemical properties of non-metallic minerals,advances in synthesis of zeolites are reviewed. Meanwhile,the problems such as complex pretreatment are presented in the synthesis of zeolites with non-metallic minerals.In addition,the development trends for the synthesis of zeolites with non-metallic minerals are also prospected.
引文
[1]Abdullahi T,Harun Z,Othman M H D.A review on sustainable synthesis of zeolite from kaolinite resources via hydrothermal process[J].Advanced Powder Technology,2017,28(8):1827-1840.
[2]徐如人,庞文琴,霍启升,等.分子筛与多孔材料化学[M].2版.北京:科学出版社,2015.
[3]傅平丰,杨慧芬.非金属矿深加工[M].北京:科学出版社,2015.
[4]郑水林.非金属矿加工与应用[M].3版.北京:化学工业出版社,2013.
[5]Gougazeh M,Buhl J C.Synthesis and characterization of zeolite A by hydrothermal transformation of natural Jordanian kaolin[J].Journal of the Association of Arab Universities for Basic&Applied Sciences,2014,15(1):35-42.
[6]Ayele L,Pérez-Pariente J,Chebude Y,et al.Synthesis of zeolite A from Ethiopian kaolin[J].Microporous&Mesoporous Materials,2015,215:29-36.
[7]Wang J Q,Huang Y X,Pan Y,et al.Hydrothermal synthesis of high purity zeolite A from natural kaolin without calcination[J].Microporous&Mesoporous Materials,2014,199(20):50-56.
[8]Ma Y,Yan C,Alshameri A,et al.Synthesis and characterization of13X zeolite from low-grade natural kaolin[J].Advanced Powder Technology,2014,25(2):495-499.
[9]孔德顺,宋说讲,王茜,等.基于碱融活化的高岭土水热法制备干燥剂Na P分子筛[J].硅酸盐通报,2017,36(11):3653-3658.
[10]Youssef H,Ibrahim D,Komarneni S.Microwave-assisted versus conventional synthesis of zeolite A from metakaolinite[J].Microporous&Mesoporous Materials,2008,115(3):527-534.
[11]Lafi A A F,Matam S K,Hodali H A.New synthesis of ZSM-5 from high-silica kaolinite and its use in vapor-phase conversion of 1-phenylethanol to styrene[J].Industrial&Engineering Chemistry Research,2015,54(15):3754-3760.
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[13]Faghihian H,Godazandeha N.Synthesis of nano crystalline zeolite Y from bentonite[J].Journal of Porous Materials,2009,16(3):331-335.
[14]Chen C,Park D W,Ahn W S.CO2capture using zeolite 13X prepared from bentonite[J].Applied Surface Science,2014,292(4):63-67.
[15]Mezni M,Hamzaoui A,Hamdi N,et al.Synthesis of zeolites from the low-grade Tunisian natural illite by two different methods[J].Applied Clay Science,2011,52(3):209-218.
[16]郑淑琴,韩勇,黄石,等.海泡石原位晶化合成Na Y分子筛的研究[J].化学学报,2010,68(4):329-333.
[17]Chen L,Wang Y W,He M Y,et al.Facile synthesis of 5A zeolite from attapulgite clay for adsorption of n-paraffins[J].Adsorption:Journal of the International Adsorption Society,2016,22(3):309-314.
[18]Liu X,Wang R.Effective removal of hydrogen sulfide using 4A molecular sieve zeolite synthesized from attapulgite[J].Journal of Hazardous Materials,2017,326:157-164.
[19]Zhou X Z,Liu Y,Meng X J,et al.Synthesis and catalytic cracking performance of Fe/Ti-ZSM-5 zeolite from attapulgite mineral[J].Chinese Journal of Catalysis,2013,34(8):1504-1512.
[20]Li X Y,Jiang Y,Liu X Q,et al.Direct synthesis of zeolites from a natural clay,attapulgite[J].Acs Sustainable Chemistry&Engineering,2017,5(7):6124-6130.
[21]张洁清,曹吉林,刘秀伍,等.钾长石碱熔活化合成4A沸石研究[J].人工晶体学报,2013,42(5):953-958.
[22]Su S,Ma H,Chuan X.Hydrothermal synthesis of zeolite A from Kfeldspar and its crystallization mechanism[J].Advanced Powder Technology,2016,27(1):139-144.
[23]刘昶江,苏双青,杨静,等.钾长石粉体合成L型分子筛[J].硅酸盐学报,2013,41(8):1151-1157.
[24]王静洁,赵斌,李琳,等.钾长石水热合成K-ZSM-5分子筛[J].硅酸盐学报,2014,42(3):340-348.
[25]杜翠华,赵斌,郭宏飞,等.KOH碱熔活化钾长石制取全钾W型分子筛[J].人工晶体学报,2014,43(1):153-162.
[26]Jamshid B,Hossein K,Sohrab R.Sonochemical synthesis of zeolite Na P from clinoptilolite[J].Ultrasonics Sonochemistry,2016,28:400-408.
[27]Garcia G,Cardenas E,Cabrera S,et al.Synthesis of zeolite Y from diatomite as silica source[J].Microporous&Mesoporous Materials,2016,219:29-37.
[28]雷晶晶,张晓雨,姚光远,等.硅藻土水热合成X型分子筛[J].非金属矿,2018,41(3):20-23.
[29]Li Y,Sun H,Feng R,et al.Synthesis of ZSM-5 zeolite from diatomite for fluid catalytic cracking(FCC)application[J].Applied Petrochemical Research,2015,5(4):347-353.
[30]Zhang S,Cui M,Zhang Y,et al.Synthesis of zeolite Y from diatomite and its modification by dimethylglyoxime for the removal of Ni(Ⅱ)from aqueous solution[J].Journal of Sol-Gel Science and Technology,2016,80(1):215-225.
[31]Wang P,Shen B,Gao J.Synthesis of ZSM-5 zeolite from expanded perlite and its catalytic performance in FCC gasoline aromatization[J].Catalysis Today,2007,125(3/4):155-162.
[2]徐如人,庞文琴,霍启升,等.分子筛与多孔材料化学[M].2版.北京:科学出版社,2015.
[3]傅平丰,杨慧芬.非金属矿深加工[M].北京:科学出版社,2015.
[4]郑水林.非金属矿加工与应用[M].3版.北京:化学工业出版社,2013.
[5]Gougazeh M,Buhl J C.Synthesis and characterization of zeolite A by hydrothermal transformation of natural Jordanian kaolin[J].Journal of the Association of Arab Universities for Basic&Applied Sciences,2014,15(1):35-42.
[6]Ayele L,Pérez-Pariente J,Chebude Y,et al.Synthesis of zeolite A from Ethiopian kaolin[J].Microporous&Mesoporous Materials,2015,215:29-36.
[7]Wang J Q,Huang Y X,Pan Y,et al.Hydrothermal synthesis of high purity zeolite A from natural kaolin without calcination[J].Microporous&Mesoporous Materials,2014,199(20):50-56.
[8]Ma Y,Yan C,Alshameri A,et al.Synthesis and characterization of13X zeolite from low-grade natural kaolin[J].Advanced Powder Technology,2014,25(2):495-499.
[9]孔德顺,宋说讲,王茜,等.基于碱融活化的高岭土水热法制备干燥剂Na P分子筛[J].硅酸盐通报,2017,36(11):3653-3658.
[10]Youssef H,Ibrahim D,Komarneni S.Microwave-assisted versus conventional synthesis of zeolite A from metakaolinite[J].Microporous&Mesoporous Materials,2008,115(3):527-534.
[11]Lafi A A F,Matam S K,Hodali H A.New synthesis of ZSM-5 from high-silica kaolinite and its use in vapor-phase conversion of 1-phenylethanol to styrene[J].Industrial&Engineering Chemistry Research,2015,54(15):3754-3760.
[12]Gougazeh M,Buhl J.Conversion of natural Jordanian kaolin into zeolite A without thermal pre-activation[J].Zeitschrift für Anorganische und Allgemeine Chemie,2014,640(8/9):1675-1679.
[13]Faghihian H,Godazandeha N.Synthesis of nano crystalline zeolite Y from bentonite[J].Journal of Porous Materials,2009,16(3):331-335.
[14]Chen C,Park D W,Ahn W S.CO2capture using zeolite 13X prepared from bentonite[J].Applied Surface Science,2014,292(4):63-67.
[15]Mezni M,Hamzaoui A,Hamdi N,et al.Synthesis of zeolites from the low-grade Tunisian natural illite by two different methods[J].Applied Clay Science,2011,52(3):209-218.
[16]郑淑琴,韩勇,黄石,等.海泡石原位晶化合成Na Y分子筛的研究[J].化学学报,2010,68(4):329-333.
[17]Chen L,Wang Y W,He M Y,et al.Facile synthesis of 5A zeolite from attapulgite clay for adsorption of n-paraffins[J].Adsorption:Journal of the International Adsorption Society,2016,22(3):309-314.
[18]Liu X,Wang R.Effective removal of hydrogen sulfide using 4A molecular sieve zeolite synthesized from attapulgite[J].Journal of Hazardous Materials,2017,326:157-164.
[19]Zhou X Z,Liu Y,Meng X J,et al.Synthesis and catalytic cracking performance of Fe/Ti-ZSM-5 zeolite from attapulgite mineral[J].Chinese Journal of Catalysis,2013,34(8):1504-1512.
[20]Li X Y,Jiang Y,Liu X Q,et al.Direct synthesis of zeolites from a natural clay,attapulgite[J].Acs Sustainable Chemistry&Engineering,2017,5(7):6124-6130.
[21]张洁清,曹吉林,刘秀伍,等.钾长石碱熔活化合成4A沸石研究[J].人工晶体学报,2013,42(5):953-958.
[22]Su S,Ma H,Chuan X.Hydrothermal synthesis of zeolite A from Kfeldspar and its crystallization mechanism[J].Advanced Powder Technology,2016,27(1):139-144.
[23]刘昶江,苏双青,杨静,等.钾长石粉体合成L型分子筛[J].硅酸盐学报,2013,41(8):1151-1157.
[24]王静洁,赵斌,李琳,等.钾长石水热合成K-ZSM-5分子筛[J].硅酸盐学报,2014,42(3):340-348.
[25]杜翠华,赵斌,郭宏飞,等.KOH碱熔活化钾长石制取全钾W型分子筛[J].人工晶体学报,2014,43(1):153-162.
[26]Jamshid B,Hossein K,Sohrab R.Sonochemical synthesis of zeolite Na P from clinoptilolite[J].Ultrasonics Sonochemistry,2016,28:400-408.
[27]Garcia G,Cardenas E,Cabrera S,et al.Synthesis of zeolite Y from diatomite as silica source[J].Microporous&Mesoporous Materials,2016,219:29-37.
[28]雷晶晶,张晓雨,姚光远,等.硅藻土水热合成X型分子筛[J].非金属矿,2018,41(3):20-23.
[29]Li Y,Sun H,Feng R,et al.Synthesis of ZSM-5 zeolite from diatomite for fluid catalytic cracking(FCC)application[J].Applied Petrochemical Research,2015,5(4):347-353.
[30]Zhang S,Cui M,Zhang Y,et al.Synthesis of zeolite Y from diatomite and its modification by dimethylglyoxime for the removal of Ni(Ⅱ)from aqueous solution[J].Journal of Sol-Gel Science and Technology,2016,80(1):215-225.
[31]Wang P,Shen B,Gao J.Synthesis of ZSM-5 zeolite from expanded perlite and its catalytic performance in FCC gasoline aromatization[J].Catalysis Today,2007,125(3/4):155-162.