质子型离子液体离子率的研究进展
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摘要
质子型离子液体是由布朗斯特酸和布朗斯特碱通过质子转移得到的,质子转移反应的平衡导致大多数PILs中除离子组分外还存在着分子组分. PILs中离子组分的占比即为离子率.本文综述了研究PILs的离子率的定性和定量方法,同时介绍了基于离子率定量测定的热力学研究方法.
Protic ionic liquids(PILs) are formed by proton transfer from Br?nsted acid and Br?nsted base. The balance of proton transfer reaction leads to the presence of molecular components in addition to the ionic components in most PILs. The proportion of ionic components in PILs is ionicity. This paper reviews the qualitative and quantitative methods for studying the ionicity of PILs. In addition, a thermodynamic research method based on the quantitative measurement of ionicity is introduced.
Protic ionic liquids(PILs) are formed by proton transfer from Br?nsted acid and Br?nsted base. The balance of proton transfer reaction leads to the presence of molecular components in addition to the ionic components in most PILs. The proportion of ionic components in PILs is ionicity. This paper reviews the qualitative and quantitative methods for studying the ionicity of PILs. In addition, a thermodynamic research method based on the quantitative measurement of ionicity is introduced.
引文
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2 Seddon KR.J Chem Technol Biotechnol,1997,68:351-356
3 Stoimenovski J,Izgorodina EI,MacFarlane DR.Phys Chem Chem Phys,2010,12:10341-10347
4 Olah GA,Mathew T,Goeppert A,T?r?k B,Bucsi I,Li XY,Wang Q,Marinez ER,Batamack P,Aniszfeld R,Prakash GKS.J Am Chem Soc,2005,127:5964-5969
5 Nakamoto H,Watanabe M.Chem Commun,2007,104:2539-2541
6 Wang C,Luo H,Jiang D,Li H,Dai S.Angew Chem Int Ed,2010,49:5978-5981
7 Greaves TL,Weerawardena A,Fong C,Krodkiewska I,Drummond CJ.J Phys Chem B,2006,110:22479-22487
8 Yoshizawa M,Xu W,Angell CA.J Am Chem Soc,2003,125:15411-15419
9 Greaves TL,Drummond CJ.Chem Rev,2008,108:206-237
10 Greaves TL,Drummond CJ.Chem Rev,2015,115:11379-11448
11 Burrell GL,Burgar IM,Separovic F,Dunlop NF.Phys Chem Chem Phys,2010,12:1571-1577
12 Achinivu EC,Howard RM,Li G,Gracz H,Henderson WA.Green Chem,2014,16:1114-1119
13 Stoimenovski J,Dean PM,Izgorodina EI,Macfarlane DR.Faraday Discuss,2012,154:335-352
14 Stoimenovski J,MacFarlane DR.Chem Commun,2011,47:11429-11431
15 Xu W,Cooper EI,Angell CA.J Phys Chem B,2003,107:6170-6178
16 Belieres JP,Angell CA.J Phys Chem B,2007,111:4926-4937
17 Kanzaki R,Doi H,Song X,Hara S,Ishiguro S,Umebayashi Y.J Phys Chem B,2012,116:14146-14152
18 Berg RW,Canongia Lopes JN,Ferreira R,Rebelo LPN,Seddon KR,Tomaszowska AA.J Phys Chem A,2010,114:10834-10841
19 Cui Y,Yin J,Li C,Li S,Wang A,Yang G,Jia Y.Phys Chem Chem Phys,2016,18:19731-19737
20 Kanzaki R,Uchida K,Hara S,Umebayashi Y,Ishiguro S,Nomura S.Chem Lett,2007,36:684-685
21 Tokuda H,Hayamizu K,Ishii K,Susan MABH,Watanabe M.J Phys Chem B,2004,108:16593-16600
22 Tokuda H,Hayamizu K,Ishii K,Susan MABH,Watanabe M.J Phys Chem B,2005,109:6103-6110
23 Tokuda H,Ishii K,Susan MABH,Tsuzuki S,Hayamizu K,Watanabe M.J Phys Chem B,2006,110:2833-2839
24 Tokuda H,Tsuzuki S,Susan MABH,Hayamizu K,Watanabe M.J Phys Chem B,2006,110:19593-19600
25 Ueno K,Tokuda H,Watanabe M.Phys Chem Chem Phys,2010,12:1649-1658
26 Miran MS,Kinoshita H,Yasuda T,Susan MABH,Watanabe M.Phys Chem Chem Phys,2012,14:5178-5186
27 Yasuda T,Kinoshita H,Miran MS,Tsuzuki S,Watanabe M.J Chem Eng Data,2013,58:2724-2732
28 MacFarlane DR,Forsyth M,Izgorodina EI,Abbott AP,Annat G,Fraser K.Phys Chem Chem Phys,2009,11:4962-4967
29 Giordano AN,Morton SM,Jensen L,Lear BJ.J Phys Chem A,2013,117:2067-2074
30 Shen M,Zhang Y,Chen K,Che S,Yao J,Li H.J Phys Chem B,2017,121:1372-1376
31 Chen K,Wang Y,Yao J,Li H.J Phys Chem B,2018,122:309-315
32 Aparicio S,Atilhan M,Karadas F.Ind Eng Chem Res,2010,49:9580-9595
33 Vitorino J,Bernardes CES,Minas da Piedade ME.Phys Chem Chem Phys,2012,14:4440-4446
34 Ostonen A,Bervas J,Uusi-Kyyny P,Alopaeus V,Zaitsau DH,Emel’yanenko VN,Schick C,King AWT,Helminen J,Kilpel?inen I,Khachatrian AA,Varfolomeev MA,Verevkin SP.Ind Eng Chem Res,2016,55:10445-10454
35 Ribeiro FMS,Lima CFRAC,Vaz ICM,Rodrigues ASMC,Sapei E,Melo A,Silva AMS,Santos LMNBF.Phys Chem Chem Phys,2017,19:16693-16701
36 Dai XZ,Yao T,Tang D,Song H,Peng LC,Yao S.J Mol Liquids,2016,221:1249-1249
37 Fumino K,Fossog V,Stange P,Wittler K,Polet W,Hempelmann R,Ludwig R.ChemPhysChem,2014,15:2604-2609