木质素高值化利用最新研究进展
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摘要
因木质素结构复杂且类型繁多,使得木质素一直难以实现高值化利用。本文结合最近五年木质素高值化利用的研究文献报道,综述了木质素在阻燃材料、吸附材料、光电材料及医用材料等方面应用的可行性,以期为木质素制备高附加值产品提供指导。
High-value application of lignin is difficult to realize due to its complicated structure and great variety. Feasibility of lignin application in flame-resistant material, adsorption material, photoelectric material, and medical material was generally introduced in the paper based on the related research in recent five years. And more instructions are expected to be provided in the preparation of high-value products made from lignin.
High-value application of lignin is difficult to realize due to its complicated structure and great variety. Feasibility of lignin application in flame-resistant material, adsorption material, photoelectric material, and medical material was generally introduced in the paper based on the related research in recent five years. And more instructions are expected to be provided in the preparation of high-value products made from lignin.
引文
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[6]Younesi-Kordkheili H.Improving physical and mechanical properties of new lignin-urea-glyoxal resin by nanoclay[J].European Journal of Wood&Wood Products,2017,75:885-891.
[7]Yamamoto K,Hosoya T,Yoshioka K,et al.Tetrabutylammonium hydroxide 30-hydrate,as novel reaction medium for lignin conversion[J].Acs Sustainable Chemistry&Engineering,2017,5(11):10111-10115.
[8]Rahimi A,Ulbrich A,Coon J J,et al.Formic-acid-induced depolymerization of oxidized lignin to aromatics[J].Nature,2014,515(7526):249.
[9]马咏昶,王涛,郭倩,等.木质素磺酸钠改性硬质聚氨酯泡沫阻燃性能研究[J].化学与黏合,2017,39(5):345-347+374
[10]Song K,Ganguly I,Eastin I,et al.Lignin-modified carbon nanotube/graphene hybrid coating as efficient flame retardant[J].International Journal of Molecular Sciences,2017,18(11):2368.
[11]Costes L,Laoutid F,Brohez S,et al.Phytic acid–lignin combination:A simple and efficient route for enhancing thermal and flame retardant properties of polylactide[J].European Polymer Journal,2017,94:270-285.
[12]Bartczak P,Klapiszewski,Wysokowski M,et al.Treatment of model solutions and wastewater containing selected hazardous metal ions using a chitin/lignin hybrid material as an effective sorbant[J].Journal of Environmental Management,2017,204:300-310.
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[14]Ma Y,Ling L,Guo Y,et al.Porous lignin based poly(acrylic acid)/organo-montmorillonite nanocomposites:Swelling behaviors and rapid removal of Pb(II)ions[J].Polymer,2017,128:12-23.
[15]Hu L Q,Dai L,Liu R,et al.Lignin-graft-poly(acrylic acid)for enhancement of heavy metal ion biosorption[J].Journal of Materials Science,2017,52(24):13689-13699.
[16]Yu C,Wang F,Fu S,et al.Laccase-assisted grafting of acrylic acid onto lignin for its recovery from wastewater[J].Journal of Polymers&the Environment,2016,25:1072-1079.
[17]Leskinen T,Witos J,Valledelgado J J,et al.Adsorption of proteins on colloidal lignin particles for advanced biomaterials[J].Biomacromolecules,2017,18(9):2767-2776
[18]Qian Y,Qiu X,Zhong X,et al.Lignin reverse micelles for UVabsorbing and high mechanical performance thermoplastics[J].Industrial&Engineering Chemistry Research,2015,54(48):12025-12030.
[19]Xing Q,Ruch D,Dubois P et al.Biodegradable and highperformance poly(butylene adipate-co-terephthalate)lignin UVblocking films[J].Acs.Sustainable Chemistry&Engineering,2017,5(11):10342-10351.
[20]Wang H,Qiu X,Liu W,et al.A Novel lignin/Zn O hybrid nanocomposite with excellent UV-absorption ability and its application in transparent polyurethane coating[J].Industrial&Engineering Chemistry Research,2017,56(39):11133-11141.
[21]Shankar S,Rhim J W.Preparation and characterization of agar/lignin/silver nanoparticles composite films with ultraviolet light barrier and antibacterial properties[J].Food Hydrocolloids,2017,71:76-84.
[22]Chaleawlertumpon S,Liedel C.More sustainable energy storage:lignin based electrodes with glyoxal crosslinking[J].Journal of Materials Chemistry A,2017,5:24344-24352.
[23]Chen T,Hu J,Zhang L,et al.High performance binderfree Si Ox/C composite LIB electrode made of Si Ox and lignin[J].Journal of Power Sources,2017,362:236-242.
[24]He Zhang,Dandan Jia,Zewen Yang,et al.Alkaline lignin derived porous carbon as an efficient scaffold for lithium-seleniumbattery cathode[J].Carbon,2017,122:547-555.
[25]Klapiszewski,Szalaty T J,Kurc B,et al.Functional hybrid materials based on manganese dioxide and lignin activated by ionic liquids and their application in the production of lithium ion batteries[J].International Journal of Molecular Sciences,2017,18(7):1509.
[26]Yang B S,Kang K Y,Jeong M J.Preparation of lignin-based carbon aerogels as biomaterials for nano-supercapacitor[J].Journal of the Korean Physical Society,2017,71(8):478-482.
[27]Farhat W,Venditti R,Mignard N,et al.Polysaccharides and lignin based hydrogels with potential pharmaceutical use as a drug delivery system produced by a reactive extrusion process[J].International Journal of Biological Macromolecules,2017,104:564-575.
[28]姚奋尖,向育君,冯伟,等.改性木质素磺酸钠水凝胶对阿魏酸哌嗪的缓释作用研究[J].离子交换与吸附,2016(2):134-140.
[29]Marulasiddeshwara M B,Dakshayani S S,Sharath M K,et al.Facile-one pot-green synthesis,antibacterial,antifungal,antioxidant and antiplatelet activities of lignin capped silver nanoparticles:A promising therapeutic agent[J].Materials Science&Engineering Materials for Biological Applications,2017,81:182.
[30]Figueiredo P,Ferro C,Kemell M,et al.Functionalization of carboxylated lignin nanoparticles for targeted and p H-responsive delivery of anticancer drugs[J].Nanomedicine,2017,12(21):2581-2596.
[2]Ghaffar S H,Fan M.Structural analysis for lignin characteristics in biomass straw[J].Biomass&Bioenergy,2013,57(10):264-279.
[3]Rahimi A,Ulbrich A,Coon J J,et al.Formic-acid-induced depolymerization of oxidized lignin to aromatics[J].Nature,2014,515(7526):249.
[4]Qin J,Woloctt M,Zhang J.Use of Polycarboxylic acid derived from partially depolymerized lignin as a curing agent for epoxy application[J].Acs Sustainable Chemistry&Engineering,2013,2(2):188-193.
[5]Dong T,Hu J,Bao J,et al.Lignin valorization:lignin nanoparticles as high-value bio-additive for multifunctional nanocomposites[J].Biotechnology for Biofuels,2017,10(1):192.
[6]Younesi-Kordkheili H.Improving physical and mechanical properties of new lignin-urea-glyoxal resin by nanoclay[J].European Journal of Wood&Wood Products,2017,75:885-891.
[7]Yamamoto K,Hosoya T,Yoshioka K,et al.Tetrabutylammonium hydroxide 30-hydrate,as novel reaction medium for lignin conversion[J].Acs Sustainable Chemistry&Engineering,2017,5(11):10111-10115.
[8]Rahimi A,Ulbrich A,Coon J J,et al.Formic-acid-induced depolymerization of oxidized lignin to aromatics[J].Nature,2014,515(7526):249.
[9]马咏昶,王涛,郭倩,等.木质素磺酸钠改性硬质聚氨酯泡沫阻燃性能研究[J].化学与黏合,2017,39(5):345-347+374
[10]Song K,Ganguly I,Eastin I,et al.Lignin-modified carbon nanotube/graphene hybrid coating as efficient flame retardant[J].International Journal of Molecular Sciences,2017,18(11):2368.
[11]Costes L,Laoutid F,Brohez S,et al.Phytic acid–lignin combination:A simple and efficient route for enhancing thermal and flame retardant properties of polylactide[J].European Polymer Journal,2017,94:270-285.
[12]Bartczak P,Klapiszewski,Wysokowski M,et al.Treatment of model solutions and wastewater containing selected hazardous metal ions using a chitin/lignin hybrid material as an effective sorbant[J].Journal of Environmental Management,2017,204:300-310.
[13]Wang B,Wen J L,Sun S L,et al.Chemosynthesis and structural characterization of a novel lignin-based bio-sorbent and its strong adsorption for Pb(II)[J].Industrial Crops&Products,2017,108:72-80.
[14]Ma Y,Ling L,Guo Y,et al.Porous lignin based poly(acrylic acid)/organo-montmorillonite nanocomposites:Swelling behaviors and rapid removal of Pb(II)ions[J].Polymer,2017,128:12-23.
[15]Hu L Q,Dai L,Liu R,et al.Lignin-graft-poly(acrylic acid)for enhancement of heavy metal ion biosorption[J].Journal of Materials Science,2017,52(24):13689-13699.
[16]Yu C,Wang F,Fu S,et al.Laccase-assisted grafting of acrylic acid onto lignin for its recovery from wastewater[J].Journal of Polymers&the Environment,2016,25:1072-1079.
[17]Leskinen T,Witos J,Valledelgado J J,et al.Adsorption of proteins on colloidal lignin particles for advanced biomaterials[J].Biomacromolecules,2017,18(9):2767-2776
[18]Qian Y,Qiu X,Zhong X,et al.Lignin reverse micelles for UVabsorbing and high mechanical performance thermoplastics[J].Industrial&Engineering Chemistry Research,2015,54(48):12025-12030.
[19]Xing Q,Ruch D,Dubois P et al.Biodegradable and highperformance poly(butylene adipate-co-terephthalate)lignin UVblocking films[J].Acs.Sustainable Chemistry&Engineering,2017,5(11):10342-10351.
[20]Wang H,Qiu X,Liu W,et al.A Novel lignin/Zn O hybrid nanocomposite with excellent UV-absorption ability and its application in transparent polyurethane coating[J].Industrial&Engineering Chemistry Research,2017,56(39):11133-11141.
[21]Shankar S,Rhim J W.Preparation and characterization of agar/lignin/silver nanoparticles composite films with ultraviolet light barrier and antibacterial properties[J].Food Hydrocolloids,2017,71:76-84.
[22]Chaleawlertumpon S,Liedel C.More sustainable energy storage:lignin based electrodes with glyoxal crosslinking[J].Journal of Materials Chemistry A,2017,5:24344-24352.
[23]Chen T,Hu J,Zhang L,et al.High performance binderfree Si Ox/C composite LIB electrode made of Si Ox and lignin[J].Journal of Power Sources,2017,362:236-242.
[24]He Zhang,Dandan Jia,Zewen Yang,et al.Alkaline lignin derived porous carbon as an efficient scaffold for lithium-seleniumbattery cathode[J].Carbon,2017,122:547-555.
[25]Klapiszewski,Szalaty T J,Kurc B,et al.Functional hybrid materials based on manganese dioxide and lignin activated by ionic liquids and their application in the production of lithium ion batteries[J].International Journal of Molecular Sciences,2017,18(7):1509.
[26]Yang B S,Kang K Y,Jeong M J.Preparation of lignin-based carbon aerogels as biomaterials for nano-supercapacitor[J].Journal of the Korean Physical Society,2017,71(8):478-482.
[27]Farhat W,Venditti R,Mignard N,et al.Polysaccharides and lignin based hydrogels with potential pharmaceutical use as a drug delivery system produced by a reactive extrusion process[J].International Journal of Biological Macromolecules,2017,104:564-575.
[28]姚奋尖,向育君,冯伟,等.改性木质素磺酸钠水凝胶对阿魏酸哌嗪的缓释作用研究[J].离子交换与吸附,2016(2):134-140.
[29]Marulasiddeshwara M B,Dakshayani S S,Sharath M K,et al.Facile-one pot-green synthesis,antibacterial,antifungal,antioxidant and antiplatelet activities of lignin capped silver nanoparticles:A promising therapeutic agent[J].Materials Science&Engineering Materials for Biological Applications,2017,81:182.
[30]Figueiredo P,Ferro C,Kemell M,et al.Functionalization of carboxylated lignin nanoparticles for targeted and p H-responsive delivery of anticancer drugs[J].Nanomedicine,2017,12(21):2581-2596.