酞菁金属配合物的合成及光谱特性研究
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摘要
以4-叔丁基邻苯二甲酸酐、金属(Co~(3+)、Al~(3+)、Zn~(2+))氯化物、尿素、钼酸铵为原料,用固相合成法分别合成系列酞菁类金属配合物(MPc)。通过目标产物的红外谱图和紫外图,确定形成MPc;对合成的MPc的紫外可见吸收、荧光光谱特性进行研究,考察溶剂、浓度、中心金属对MPc化合物的光谱特性的影响,为光谱理论理解和实验教学提供桥梁。
A series of metal phthalocyanine(MPc) were synthesized by solid phase synthesis using 4-tertbutyl phthalic anhydride, ZnCl_2,CoCl_3, AlCl_3, urea and ammonium molybdate. And the target products were confirmed through infrared spectrum; at the same time, the effect of the solvent, concentration, center metal to the UV-Vis spectra and fluorescence spectra of MPc was analyzed.
A series of metal phthalocyanine(MPc) were synthesized by solid phase synthesis using 4-tertbutyl phthalic anhydride, ZnCl_2,CoCl_3, AlCl_3, urea and ammonium molybdate. And the target products were confirmed through infrared spectrum; at the same time, the effect of the solvent, concentration, center metal to the UV-Vis spectra and fluorescence spectra of MPc was analyzed.
引文
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[2] VanSlyke S A, Chen C H, Tang C W. Appl. Phys. Lett., 1996, 69:2160-2162
[3] 殷焕顺,邓建成,周燕. 染料与染色, 2004, 41(3): 150-152
[4] 唐宁莉,彭德贤,范会饮. 桂林冶金地质学院院报, 1994, 14(2):188-192
[5] 白青龙,张春花,夏道成,等.材料导报,2010,24(7):61-65
[6] 黄金陵,彭亦如,陈耐生.光谱学与光谱分析,2001, 21 (1) :1-6
[7] 黄紫洋,黄剑东,陈耐生, 等.光谱学与光谱分析, 2009, 29 (5) :1354-1357
[8] 黄剑东,刘尔生,杨素苓,等. 光谱学与光谱分析, 2000,20 (1) :95-98
[9] Bulovi■ V, Deshpande R, Thompson M E, et al. Chemical Physics Letters, 1999, 308(3/4), 317-322
[10] 胡敏,高培红,向丹,等. 化学教育 2016,37(2):29-31