微区电化学测量技术及其在腐蚀中的应用
摘要
综述了近几年来用于研究金属腐蚀的几种微区电化学测量技术,重点介绍了扫描电化学显微镜技术及其应用,并对它未来的发展趋势进行阐述。
引文
[1]单国忠,肖桂兰.论输油管道的腐蚀与防护[J].大众科技,2005,(4):82
[2]陈群尧,曹晓燕.中国管道腐蚀与防护技术综述[J].防腐保温技术,2007,(1):1
[3]王力伟,李晓刚,杜翠藏等.微区电化学测量技术进展及在腐独领域的应用[J].中国腐蚀与防护学报,2010,30:498
[4]Vignal V,Krawiec H,Heintz O,et al.The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels[J].Electrochim.Acta,2007,52:4994
[5]Vuillemin B,Philippe X,Oltra R,et al.SVET,AFM and AES study of pitting corrosion initiated on Mn S inclusions by microinjection[J].Corros.Sci.,2003,45:1143
[6]Yan M C,Gelling V J,Hinderliter B R,et al.SVET method for characterizing anti-corrosion performance of metal-rich coatings[J].Corros.Sci.,2010,52(8):636
[7]Vooys A,Weijde H.Investigating cracks and crazes on coated steel with simultaneous SVET and EIS[J].Prog.Org.Coat.,2011,71(3):250
[8]Deshpande K B.Experimental investigation of galvanic corrosion:comparison between SVET and immersion techniques[J].Corros.Sci.,2010,52(9):2819
[9]Sim?es A M,Fernandes J C S.Studying phosphate corrosion inhibition at the cut edge of coil coated galvanized steel using the SVET and EIS[J].Prog.Org.Coat.,2010,69(2):219
[10]Tang X,Cheng Y F.Localized dissolution electrochemistry at surface irregularities of pipeline steel[J].Appl.Surf.Sci.,2008,254(16):5199
[11]Neema S,Selvara M,Raguraman J,et al.Investigating the self healing process on coated steel by SVET and EIS techniques[J].J.Appl.Polym.Sci.,2012,127(1):740
[12]Izquierdo J,Nagy L,Souto R M,et al.Resolution of the apparent experimental discrepancies observed between SVET and SECM for the characterization of galvanic corrosion reactions[J].Electrochem.Commun.,2013,27:50
[13]Stratmann M,Leng A,Fiirbeth W.The scanning Kelvin probe:A new technique for the in situs analysis of the delamination of organic coatings[J].Prog.Org.Coat.,1996,27(4):261
[14]张建新,刘景柱.6063铝型材表面斑点腐蚀的成因与机理探讨[J].铝加工,2003,(6):35
[15]叶威,李瑛,王福会.单相和双相不锈钢纳米涂层的电化学腐蚀行为[J].中国腐蚀与防护学报,2008,28(3):129
[16]骆鸿,肖葵,董超芳等.金属腐蚀微区电化学研究进展[J].腐蚀与防护,2009,(8):511
[17]Jorcin J B,Aragon E,Merlatti C,et al.Delaminated areas beneath organic coating:A local electrochemical impedance approach[J].Corros.Sci.,2006,48(7):1779
[18]Yanson Y I,Schenkel F,Rost M J.Design of a high-speed electrochemical scanning tunneling microscope[J].Rev.Sci.Instr.,2013,84(2):023702
[19]Schlaup C,Spaenig A,Broekmann P,et al.Sulfide anion interaction with Cu(1 0 0)and Cu modified Au(1 0 0):An electrochemical STM study[J].Phys.Status Solidi,2010,207A:254
[20]黄仁忠,刘柳,杨文静.扫描隧道显微镜针尖调制的薄膜表面的原子扩散[J].物理学报,2011,60(11):116803
[21]Williford R E,Windisch C F,Jones R H.In-situ observations of the early stages of localized corrosion in type 304 SS using the electrochemical atomic force microscope[J].Mater.Sci.Eng.,2000,A288(1):54
[22]Li J,Meier D J.An AFM study of the properties of passive films on iron surfaces[J].J.Electroanal.Chem.,1998,454(1):53
[23]Luong T,Nishikata A,Tsuru T.Scanning electrochemical microscope study on pitting corrosion of iron[J].Electrochemistry,2003,1(7):555
[24]Volker E,Inchauspe C G,Calvo E.Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion steel[J].Electrochem.Commun.,2006,8(l):179
[25]Lister T E,Pinhero P J.Microelectrode array microscopy:Investigation of dynamic behavior of localized corrosion at type 304stainless steel surfaces[J].Anal.Chem.,2005,77(8):2601
[26]Rajendran L,Ananthi S P.Analysis of positive feedback currents at the scanning electrochemical microscope[J].J.Electroanal.Chem.,2003,561:113
[27]Wang W,Zhang J,Han L H,et al.Generation/collection mode of SECM with combined probe[J].Chin.Chem.Lett.,2011,23(1):86
[28]Mandler D,Meltzer S.Micro electrochemistry on surfaces with the scanning electrochemical microscope(SECM).[J].Isr.J.Chem.,2013,36(1):73
[29]Janin M,Ghilane J,Lacroix J C.Scanning electrochemical microscopy for the fabrication of copper nanowires:Atomic contacts with quantized conductance,and molecular adsorption effect[J].Electrochim.Acta,2012,83:7
[30]Fushimi K,Takabatake Y,Nakanishi T,et al.Microelectrode techniques for corrosion research of iron[J].Electrochim.Acta,2013,113:741
[31]Katemann B B,Inchauspe C G,Castro P A.Precursor sites for localized corrosion on lacquered tinplates visualized by means of alternating current scanning electrochemical microscopy[J].Electrochim.Acta,2003,48(9):1115
[32]Phler M,Santana J J,Schuhmann W,et al.Application of ACSECM in corrosion science:Local visualisation of inhibitor films on active metals for corrosion protection[J].Chem.Eur.J.,2011,17(3):905
[33]Bastos A C,Simes A M,Souto R M.Application of the scanning electrochemical microscope to the examination of organic coatings on metallic substrates[J].Prog.Org.Coat.,2005,53(3):177
[34]Souto R M,González-García Y,González S.Characterization of coating systems by scanning electrochemical microscopy:Surface topology and blistering[J].Prog.Org.Coat.,2010,68:40
[35]Souto R M,González-García Y,González S.Evaluation of the corrosion performance of coil-coated steel sheet as studied by scanning electrochemical microscopy[J].Corros.Sci.,2008,50(6):1637
[36]Souto R M,González-García Y,González S.In-situ monitoring of electroactive species by using the scanning electrochemical microscope:Application to the investigation of degradation processes at defective coated metals[J].Corros.Sci.,2005,47(12):3312
[37]Gabrielli C,Joiret S,Keddam M.A SECM assisted EQCM study of iron pitting[J].Electrochim.Acta,2007,52(27):7706
[38]Gonzalez-Garcia Y,Burstein G T,Gonzalez S,et al.Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential[J].Electrochem.Commun.,2004,18(6):637
[39]Fushimi K,Kirsten A L,Habazaki H.Heterogeneous hydrogen evolution on corroding at Fe-3%Si surface observed by scanning electrochemical microscopy[J].Electrochim.Acta,2007,52:4246
[40]Senz C,Maljusch A,Rohwerder M,et al.SECM and SKPFM studies of the local corrosion mechanism of al alloys-A pathway to an integrated SKP-SECM system[J].Electroanalysis,2012,24(2):239
[2]陈群尧,曹晓燕.中国管道腐蚀与防护技术综述[J].防腐保温技术,2007,(1):1
[3]王力伟,李晓刚,杜翠藏等.微区电化学测量技术进展及在腐独领域的应用[J].中国腐蚀与防护学报,2010,30:498
[4]Vignal V,Krawiec H,Heintz O,et al.The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels[J].Electrochim.Acta,2007,52:4994
[5]Vuillemin B,Philippe X,Oltra R,et al.SVET,AFM and AES study of pitting corrosion initiated on Mn S inclusions by microinjection[J].Corros.Sci.,2003,45:1143
[6]Yan M C,Gelling V J,Hinderliter B R,et al.SVET method for characterizing anti-corrosion performance of metal-rich coatings[J].Corros.Sci.,2010,52(8):636
[7]Vooys A,Weijde H.Investigating cracks and crazes on coated steel with simultaneous SVET and EIS[J].Prog.Org.Coat.,2011,71(3):250
[8]Deshpande K B.Experimental investigation of galvanic corrosion:comparison between SVET and immersion techniques[J].Corros.Sci.,2010,52(9):2819
[9]Sim?es A M,Fernandes J C S.Studying phosphate corrosion inhibition at the cut edge of coil coated galvanized steel using the SVET and EIS[J].Prog.Org.Coat.,2010,69(2):219
[10]Tang X,Cheng Y F.Localized dissolution electrochemistry at surface irregularities of pipeline steel[J].Appl.Surf.Sci.,2008,254(16):5199
[11]Neema S,Selvara M,Raguraman J,et al.Investigating the self healing process on coated steel by SVET and EIS techniques[J].J.Appl.Polym.Sci.,2012,127(1):740
[12]Izquierdo J,Nagy L,Souto R M,et al.Resolution of the apparent experimental discrepancies observed between SVET and SECM for the characterization of galvanic corrosion reactions[J].Electrochem.Commun.,2013,27:50
[13]Stratmann M,Leng A,Fiirbeth W.The scanning Kelvin probe:A new technique for the in situs analysis of the delamination of organic coatings[J].Prog.Org.Coat.,1996,27(4):261
[14]张建新,刘景柱.6063铝型材表面斑点腐蚀的成因与机理探讨[J].铝加工,2003,(6):35
[15]叶威,李瑛,王福会.单相和双相不锈钢纳米涂层的电化学腐蚀行为[J].中国腐蚀与防护学报,2008,28(3):129
[16]骆鸿,肖葵,董超芳等.金属腐蚀微区电化学研究进展[J].腐蚀与防护,2009,(8):511
[17]Jorcin J B,Aragon E,Merlatti C,et al.Delaminated areas beneath organic coating:A local electrochemical impedance approach[J].Corros.Sci.,2006,48(7):1779
[18]Yanson Y I,Schenkel F,Rost M J.Design of a high-speed electrochemical scanning tunneling microscope[J].Rev.Sci.Instr.,2013,84(2):023702
[19]Schlaup C,Spaenig A,Broekmann P,et al.Sulfide anion interaction with Cu(1 0 0)and Cu modified Au(1 0 0):An electrochemical STM study[J].Phys.Status Solidi,2010,207A:254
[20]黄仁忠,刘柳,杨文静.扫描隧道显微镜针尖调制的薄膜表面的原子扩散[J].物理学报,2011,60(11):116803
[21]Williford R E,Windisch C F,Jones R H.In-situ observations of the early stages of localized corrosion in type 304 SS using the electrochemical atomic force microscope[J].Mater.Sci.Eng.,2000,A288(1):54
[22]Li J,Meier D J.An AFM study of the properties of passive films on iron surfaces[J].J.Electroanal.Chem.,1998,454(1):53
[23]Luong T,Nishikata A,Tsuru T.Scanning electrochemical microscope study on pitting corrosion of iron[J].Electrochemistry,2003,1(7):555
[24]Volker E,Inchauspe C G,Calvo E.Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion steel[J].Electrochem.Commun.,2006,8(l):179
[25]Lister T E,Pinhero P J.Microelectrode array microscopy:Investigation of dynamic behavior of localized corrosion at type 304stainless steel surfaces[J].Anal.Chem.,2005,77(8):2601
[26]Rajendran L,Ananthi S P.Analysis of positive feedback currents at the scanning electrochemical microscope[J].J.Electroanal.Chem.,2003,561:113
[27]Wang W,Zhang J,Han L H,et al.Generation/collection mode of SECM with combined probe[J].Chin.Chem.Lett.,2011,23(1):86
[28]Mandler D,Meltzer S.Micro electrochemistry on surfaces with the scanning electrochemical microscope(SECM).[J].Isr.J.Chem.,2013,36(1):73
[29]Janin M,Ghilane J,Lacroix J C.Scanning electrochemical microscopy for the fabrication of copper nanowires:Atomic contacts with quantized conductance,and molecular adsorption effect[J].Electrochim.Acta,2012,83:7
[30]Fushimi K,Takabatake Y,Nakanishi T,et al.Microelectrode techniques for corrosion research of iron[J].Electrochim.Acta,2013,113:741
[31]Katemann B B,Inchauspe C G,Castro P A.Precursor sites for localized corrosion on lacquered tinplates visualized by means of alternating current scanning electrochemical microscopy[J].Electrochim.Acta,2003,48(9):1115
[32]Phler M,Santana J J,Schuhmann W,et al.Application of ACSECM in corrosion science:Local visualisation of inhibitor films on active metals for corrosion protection[J].Chem.Eur.J.,2011,17(3):905
[33]Bastos A C,Simes A M,Souto R M.Application of the scanning electrochemical microscope to the examination of organic coatings on metallic substrates[J].Prog.Org.Coat.,2005,53(3):177
[34]Souto R M,González-García Y,González S.Characterization of coating systems by scanning electrochemical microscopy:Surface topology and blistering[J].Prog.Org.Coat.,2010,68:40
[35]Souto R M,González-García Y,González S.Evaluation of the corrosion performance of coil-coated steel sheet as studied by scanning electrochemical microscopy[J].Corros.Sci.,2008,50(6):1637
[36]Souto R M,González-García Y,González S.In-situ monitoring of electroactive species by using the scanning electrochemical microscope:Application to the investigation of degradation processes at defective coated metals[J].Corros.Sci.,2005,47(12):3312
[37]Gabrielli C,Joiret S,Keddam M.A SECM assisted EQCM study of iron pitting[J].Electrochim.Acta,2007,52(27):7706
[38]Gonzalez-Garcia Y,Burstein G T,Gonzalez S,et al.Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential[J].Electrochem.Commun.,2004,18(6):637
[39]Fushimi K,Kirsten A L,Habazaki H.Heterogeneous hydrogen evolution on corroding at Fe-3%Si surface observed by scanning electrochemical microscopy[J].Electrochim.Acta,2007,52:4246
[40]Senz C,Maljusch A,Rohwerder M,et al.SECM and SKPFM studies of the local corrosion mechanism of al alloys-A pathway to an integrated SKP-SECM system[J].Electroanalysis,2012,24(2):239