氢化丁腈橡胶的补强技术研究进展
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摘要
氢化丁腈橡胶(HNBR)是由丁腈橡胶(NBR)经催化选择性加氢制得的弹性体,具有优异的力学性能和耐热、耐候等性能,有着广泛的应用。重点介绍了HNBR传统的补强体系炭黑和白炭黑的应用研究进展,并介绍了甲基丙烯酸锌、蒙脱土以及不同填料并用的研究进展,指出目前国内对HNBR的研究多集中在后加工与填料补强方面,但是没有相对稳定的原料体系,所以应加强HNBR工艺的开发,加快开发自主知识产权的成套技术和产品,指出低成本、环保化的功能填料是补强填料的研究趋势。
HNBR has excellent mechanical properties and heat resistance,weather resistance and so on,which is made of nitrile rubber elastomer by catalyzed hydrogenation selectively,and it is widely used.The research progress in reinforcing system of HNBR was introduced respectively,such as carbon black,white carbon black,methyl acrylic acid zinc and montmorillonite.And mixed use of fillers was elaborated.The current domestic research concentrated in the processing and reinforcing filler on HNBR has been pointed out,lack of the relative stable material system.So the development of independent intellectual property rights of technology and products should be accelerated.And filler of low cost,environmental protection is the trend of research on reinforcing filler.
HNBR has excellent mechanical properties and heat resistance,weather resistance and so on,which is made of nitrile rubber elastomer by catalyzed hydrogenation selectively,and it is widely used.The research progress in reinforcing system of HNBR was introduced respectively,such as carbon black,white carbon black,methyl acrylic acid zinc and montmorillonite.And mixed use of fillers was elaborated.The current domestic research concentrated in the processing and reinforcing filler on HNBR has been pointed out,lack of the relative stable material system.So the development of independent intellectual property rights of technology and products should be accelerated.And filler of low cost,environmental protection is the trend of research on reinforcing filler.
引文
[1]田帅承,王增林,张福涛,等.防老剂在氢化丁腈橡胶复合材料中的应用研究[J].弹性体,2015,25(2):17-20.
[2]郭建维.高性能氢化丁腈橡胶的研究与应用[J].化工进展,2001,8(1):31-33.
[3]翁国文,刘琼琼,杨慧.氢化丁腈橡胶的回收利用[J].弹性体,2015,25(3):69-73.
[4]GUAN Y,ZHANG L X,ZHANG L Q,et al.Study on ablative properties and mechanisms of hydrogenated nitrile butadiene rubber(HNBR)composites containing different fillers[J].Polymer Degradation and Stability,2011,96(5):808-817.
[5]高磊,龚光碧,魏绪玲,等.功能纳米填料在橡胶中的作用及橡胶纳米复合材料的制备[J].合成橡胶工业,2015,38(1):67-73.
[6]LI Q,ZHAO S,PAN Y.Structure,morphology,and properties of HNBR filled with N550,SiO2,ZDMA,and two of three kinds of fillers[J].Journal of Applied Polymer Science,2010,117(1):421-427.
[7]欧阳春发,施宇涛,高群,等.硫化体系对氢化丁腈胶热氧老化性能的影响[J].弹性体,2011,21(5):26-29.
[8]陈琪,辛振祥.HNBR 4种补强填充体系的研究[J].特种橡胶制品,2013,34(1):17-20.
[9]王增林,李再峰,孙宝全,等.甲基丙烯酸锌/炭黑增强氢化丁腈橡胶的性能[J].合成橡胶工业,2011,34(3):218-222.
[10]梁磊,赵素合,朱伶俐,等.纳米填料填充氢化丁腈橡胶的性能及压缩形态特征[J].合成橡胶工业,2012,35(1):17-21.
[11]WONGWITTHAYAKOOL P,SIRISINHA C,SAEOUI P.Cure and viscoelastic properties of HNBR effects of carbon black loading and characteristics[J].KGK-Kautsch Gummi Kunstst,2010,63(11):506-512.
[12]白华栋,文方岱,周淑芹,等.高性能氢化丁腈橡胶的配方与性能[J].合成橡胶工业,2004,27(6):360-362.
[13]田军涛,许炳才.非炭黑橡胶补强填料的应用研究进展[J].橡胶工业,2010,57(2):69-75.
[14]陈秀霞,李涛,王文艳,等.HNBR补强填充体系的研究[J].弹性体,2013,23(2):30-35.
[15]杨晓东,朱峰,董超峰.补强型氢化丁腈橡胶力学与粘接性能研究[J].火箭推进,2014,40(5):75-79.
[16]杨慧,刘琼琼,候亚合.白炭黑填充氢化丁腈胶的性能研究[J].化工时刊,2013,27(2):10-13.
[17]杨玲,孙士飞,刘洪伟,等.炭黑类填充料对氢化丁腈橡胶的导电性能的影响[J].渤海大学学报(自然科学版),2012,33(3):234-238.
[18]KLINGENDER R C,OYAMA M,SATIO Y.Metallic highstrength compound of highly saturated nitrile and its applications[J].Rubber World,1990,202(3):26-31.
[19]WEI Z,LU Y,YAN S,et al.Dramatic influence of curing temperature on micro–nano structure transform of HNBR filled with zinc dimethacrylate[J].Journal of Applied Polymer Science,2012,124(1):288-295.
[20]朱伶俐,赵素合,姚楚,等.ZSC/氢化丁腈橡胶并用的性能研究[J].橡胶工业,2010,57(7):389-394.
[21]赵明明,孙爱玲,李超芹.甲基丙烯酸锌补强氢化丁腈橡胶耐老化性能的研究[J].橡胶工业,2013,60(10):588-592.
[22]WEI Z,LU Y L,MENG Y,et al.Improved understanding of insitu polymerization of zinc dimethacrylate:The solid bulk polymerization[J].Polymer,2012,53(6):1409-1417.
[23]LU Y L,LIU L,YANG C,et al.The morphology of zinc dimethacrylate reinforced elastomers investigated by SEM and TEM[J].European Polymer Journal,2005,41(3):577-588.
[24]武守鹏,王婷,纪彦玲,等.硫化时间对HNBR/ZMMA复合材料形态结构及性能的影响[J].特种橡胶制品,2013,34(3):1-4.
[25]武守鹏,王增林,田帅承,等.甲基丙烯酸锌增强氢化丁腈橡胶复合材料的性能[J].合成橡胶工业,2014,37(5):376-379.
[26]王冠中,田帅承,刘红天,等.单甲基丙烯酸锌增强丁腈及氢化丁腈橡胶复合材料的热氧老化研究[J].化学工程师,2015(7):1-5.
[27]ALI Z,LE H H,IIISCH S,et al.Morphology development and compatibilization effect in nanoclay filled rubber blends[J].Polymer,2010,51(20):4580-4588.
[28]Gatos K G,Karger-Kocsis J.Effect of the aspect ratio of silicate platelets on the mechanical and barrier properties of hy-drogenated acrylonitrile butadiene rubber(HNBR)/layered silicate nanocomposites[J].European Polymer Journal,2007,43(4):1097-1104.
[29]张继华,吴福迪,皂伟涛,等.低温耐油蒙脱土/氢化丁腈的制备和性能研究[J].宇航材料工艺,2013(1):66-71.
[30]高鑑明,谷正,宋国君,等.氢化丁腈橡胶/有机蒙脱土纳米复合材料的结构与性能[J].特种橡胶制品,2007,28(6):23-26.
[31]张春梅,杜华太,庞明磊,等.有机蒙脱土/氢化丁腈橡胶纳米复合材料的结构和性能[J].航空材料学报,2013,33(5):66-71.
[32]孟晓宇,刘旭,丛川波,等.超临界CO2方法制备纳米蒙脱土/氢化丁腈橡胶复合材料[J].复合材料学报,2014,31(3):604-609.
[33]WANG X P,JIA D M,HUANG A M.Structure and properties of hydrogenated nitrile-butadiene rubber/organo montmorillonite nanocomposites[C]//2nd International Conference on Mechanical and Aerospace Engineering(ICMAE 2011).Applied Mechanics and Materials.Bangkok:Trans Tech publications Ltd,2011:3818-3824.
[34]GATOS K G,SAWANIS N S,APSTOLOV A A,et al.Nanocomposite formation in hydrogenated nitrile rubber(HNBR)/organo-montmorillonite as a function of the intercalant type[J].Macromolecular Materials and Engineering,2004,289(12):1079-1086.
[35]潘岩,赵素合,李颀.增强氢化丁腈橡胶的结构与性能[J].合成橡胶工业,2009,32(3):232-237.
[36]黄安民,王丹丹,王小萍,等.补强剂填充HNBR胶料的结构和性能[J].橡胶工业,2008,55(2):69-74.
[37]黄安民,王小萍,贾德民.氢化丁腈橡胶/聚甲基丙烯酸镁/有机蒙脱土纳米复合材料制备及其耐介质老化性能[J].高分子学报,2012(6):660-665.
[38]王增林,田帅承,李再峰.OMMT/ZDMA协同增强HNBR复合材料的性能研究[J].特种橡胶制品,2014,35(3):1-4.
[39]李颀,赵素合,朱伶俐,等.ZDMA/白炭黑填充HNBR的结构与性能[J].橡胶工业,2010,57(2):69-75.
[40]武守鹏,纪彦玲,徐文龙,等.氢氧化甲基丙烯酸锌/炭黑协同增强氢化丁腈橡胶硫化过程中的形态演变及性能[J].高分子材料科学与工程,2013,29(11):54-57.
[41]WANG G,LI Z,TIAN S,et al.Morphology and properties of hydrogenated nitrile rubber/poly hydroxyl zinc monomethacrylate composites by curing with peroxide[J].Journal of Research Updates in Polymer Science,2015,4(1):24-30.
[42]沙青娥,岳红,赵建勇.不同补强剂对氢化丁腈橡胶硫化胶性能的影响[J].中国胶粘剂,2013,22(8):14-18.
[43]玉树,赵素合,杨伟锦.高性能氢化丁腈橡胶密封胶料的制备及性能[J].合成橡胶工业,2013,6(2):132-137.
[44]朱永康.蒙脱土/氢化丁腈橡胶纳米复合材料之分析[J].世界橡胶工业,2008,35(4):1-6.
[45]禹权,黄承亚,叶素娟.氢化丁腈橡胶的研究进展[J].特种橡胶制品,2006,27(2):56-62.
[2]郭建维.高性能氢化丁腈橡胶的研究与应用[J].化工进展,2001,8(1):31-33.
[3]翁国文,刘琼琼,杨慧.氢化丁腈橡胶的回收利用[J].弹性体,2015,25(3):69-73.
[4]GUAN Y,ZHANG L X,ZHANG L Q,et al.Study on ablative properties and mechanisms of hydrogenated nitrile butadiene rubber(HNBR)composites containing different fillers[J].Polymer Degradation and Stability,2011,96(5):808-817.
[5]高磊,龚光碧,魏绪玲,等.功能纳米填料在橡胶中的作用及橡胶纳米复合材料的制备[J].合成橡胶工业,2015,38(1):67-73.
[6]LI Q,ZHAO S,PAN Y.Structure,morphology,and properties of HNBR filled with N550,SiO2,ZDMA,and two of three kinds of fillers[J].Journal of Applied Polymer Science,2010,117(1):421-427.
[7]欧阳春发,施宇涛,高群,等.硫化体系对氢化丁腈胶热氧老化性能的影响[J].弹性体,2011,21(5):26-29.
[8]陈琪,辛振祥.HNBR 4种补强填充体系的研究[J].特种橡胶制品,2013,34(1):17-20.
[9]王增林,李再峰,孙宝全,等.甲基丙烯酸锌/炭黑增强氢化丁腈橡胶的性能[J].合成橡胶工业,2011,34(3):218-222.
[10]梁磊,赵素合,朱伶俐,等.纳米填料填充氢化丁腈橡胶的性能及压缩形态特征[J].合成橡胶工业,2012,35(1):17-21.
[11]WONGWITTHAYAKOOL P,SIRISINHA C,SAEOUI P.Cure and viscoelastic properties of HNBR effects of carbon black loading and characteristics[J].KGK-Kautsch Gummi Kunstst,2010,63(11):506-512.
[12]白华栋,文方岱,周淑芹,等.高性能氢化丁腈橡胶的配方与性能[J].合成橡胶工业,2004,27(6):360-362.
[13]田军涛,许炳才.非炭黑橡胶补强填料的应用研究进展[J].橡胶工业,2010,57(2):69-75.
[14]陈秀霞,李涛,王文艳,等.HNBR补强填充体系的研究[J].弹性体,2013,23(2):30-35.
[15]杨晓东,朱峰,董超峰.补强型氢化丁腈橡胶力学与粘接性能研究[J].火箭推进,2014,40(5):75-79.
[16]杨慧,刘琼琼,候亚合.白炭黑填充氢化丁腈胶的性能研究[J].化工时刊,2013,27(2):10-13.
[17]杨玲,孙士飞,刘洪伟,等.炭黑类填充料对氢化丁腈橡胶的导电性能的影响[J].渤海大学学报(自然科学版),2012,33(3):234-238.
[18]KLINGENDER R C,OYAMA M,SATIO Y.Metallic highstrength compound of highly saturated nitrile and its applications[J].Rubber World,1990,202(3):26-31.
[19]WEI Z,LU Y,YAN S,et al.Dramatic influence of curing temperature on micro–nano structure transform of HNBR filled with zinc dimethacrylate[J].Journal of Applied Polymer Science,2012,124(1):288-295.
[20]朱伶俐,赵素合,姚楚,等.ZSC/氢化丁腈橡胶并用的性能研究[J].橡胶工业,2010,57(7):389-394.
[21]赵明明,孙爱玲,李超芹.甲基丙烯酸锌补强氢化丁腈橡胶耐老化性能的研究[J].橡胶工业,2013,60(10):588-592.
[22]WEI Z,LU Y L,MENG Y,et al.Improved understanding of insitu polymerization of zinc dimethacrylate:The solid bulk polymerization[J].Polymer,2012,53(6):1409-1417.
[23]LU Y L,LIU L,YANG C,et al.The morphology of zinc dimethacrylate reinforced elastomers investigated by SEM and TEM[J].European Polymer Journal,2005,41(3):577-588.
[24]武守鹏,王婷,纪彦玲,等.硫化时间对HNBR/ZMMA复合材料形态结构及性能的影响[J].特种橡胶制品,2013,34(3):1-4.
[25]武守鹏,王增林,田帅承,等.甲基丙烯酸锌增强氢化丁腈橡胶复合材料的性能[J].合成橡胶工业,2014,37(5):376-379.
[26]王冠中,田帅承,刘红天,等.单甲基丙烯酸锌增强丁腈及氢化丁腈橡胶复合材料的热氧老化研究[J].化学工程师,2015(7):1-5.
[27]ALI Z,LE H H,IIISCH S,et al.Morphology development and compatibilization effect in nanoclay filled rubber blends[J].Polymer,2010,51(20):4580-4588.
[28]Gatos K G,Karger-Kocsis J.Effect of the aspect ratio of silicate platelets on the mechanical and barrier properties of hy-drogenated acrylonitrile butadiene rubber(HNBR)/layered silicate nanocomposites[J].European Polymer Journal,2007,43(4):1097-1104.
[29]张继华,吴福迪,皂伟涛,等.低温耐油蒙脱土/氢化丁腈的制备和性能研究[J].宇航材料工艺,2013(1):66-71.
[30]高鑑明,谷正,宋国君,等.氢化丁腈橡胶/有机蒙脱土纳米复合材料的结构与性能[J].特种橡胶制品,2007,28(6):23-26.
[31]张春梅,杜华太,庞明磊,等.有机蒙脱土/氢化丁腈橡胶纳米复合材料的结构和性能[J].航空材料学报,2013,33(5):66-71.
[32]孟晓宇,刘旭,丛川波,等.超临界CO2方法制备纳米蒙脱土/氢化丁腈橡胶复合材料[J].复合材料学报,2014,31(3):604-609.
[33]WANG X P,JIA D M,HUANG A M.Structure and properties of hydrogenated nitrile-butadiene rubber/organo montmorillonite nanocomposites[C]//2nd International Conference on Mechanical and Aerospace Engineering(ICMAE 2011).Applied Mechanics and Materials.Bangkok:Trans Tech publications Ltd,2011:3818-3824.
[34]GATOS K G,SAWANIS N S,APSTOLOV A A,et al.Nanocomposite formation in hydrogenated nitrile rubber(HNBR)/organo-montmorillonite as a function of the intercalant type[J].Macromolecular Materials and Engineering,2004,289(12):1079-1086.
[35]潘岩,赵素合,李颀.增强氢化丁腈橡胶的结构与性能[J].合成橡胶工业,2009,32(3):232-237.
[36]黄安民,王丹丹,王小萍,等.补强剂填充HNBR胶料的结构和性能[J].橡胶工业,2008,55(2):69-74.
[37]黄安民,王小萍,贾德民.氢化丁腈橡胶/聚甲基丙烯酸镁/有机蒙脱土纳米复合材料制备及其耐介质老化性能[J].高分子学报,2012(6):660-665.
[38]王增林,田帅承,李再峰.OMMT/ZDMA协同增强HNBR复合材料的性能研究[J].特种橡胶制品,2014,35(3):1-4.
[39]李颀,赵素合,朱伶俐,等.ZDMA/白炭黑填充HNBR的结构与性能[J].橡胶工业,2010,57(2):69-75.
[40]武守鹏,纪彦玲,徐文龙,等.氢氧化甲基丙烯酸锌/炭黑协同增强氢化丁腈橡胶硫化过程中的形态演变及性能[J].高分子材料科学与工程,2013,29(11):54-57.
[41]WANG G,LI Z,TIAN S,et al.Morphology and properties of hydrogenated nitrile rubber/poly hydroxyl zinc monomethacrylate composites by curing with peroxide[J].Journal of Research Updates in Polymer Science,2015,4(1):24-30.
[42]沙青娥,岳红,赵建勇.不同补强剂对氢化丁腈橡胶硫化胶性能的影响[J].中国胶粘剂,2013,22(8):14-18.
[43]玉树,赵素合,杨伟锦.高性能氢化丁腈橡胶密封胶料的制备及性能[J].合成橡胶工业,2013,6(2):132-137.
[44]朱永康.蒙脱土/氢化丁腈橡胶纳米复合材料之分析[J].世界橡胶工业,2008,35(4):1-6.
[45]禹权,黄承亚,叶素娟.氢化丁腈橡胶的研究进展[J].特种橡胶制品,2006,27(2):56-62.