生态环境中石墨烯/金属复合材料降解三氯乙烯进展
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摘要
介绍石墨烯/金属复合材料的结构及其制备方法,就复合材料中过渡金属的选择进行讨论,得出含铁矿物是制备石墨烯/金属复合材料的最佳选择。分析了石墨烯/金属复合材料降解三氯乙烯的机理性能,对石墨烯/金属复合材料未来的发展趋势提出了展望。
This paper mainly introduces the structures of graphene/metal composite and their preparation method.The selection of transition metal in composite is discussed.It is concluded that iron-containing minerals are the best choice for preparing graphene/metal composite.The mechanism performance of graphene/metal composite material for degradation of three chloroethylene is analyzed.Finally,the future development trend of grapheme/metal composites is prospected.
This paper mainly introduces the structures of graphene/metal composite and their preparation method.The selection of transition metal in composite is discussed.It is concluded that iron-containing minerals are the best choice for preparing graphene/metal composite.The mechanism performance of graphene/metal composite material for degradation of three chloroethylene is analyzed.Finally,the future development trend of grapheme/metal composites is prospected.
引文
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[27]刘芳,樊丰涛,吕玉翠,等.石墨烯/TiO2复合材料光催化降解有机污染物的研究进展[J].化工学报,2016,67(5):1635-1643.
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[29] HUSSAIN I,ZHANG Y,HUANG S.Degradation of aniline with zerovalent iron as an activator of persulfate in aqueous solution[J].RSC Adv.,2014,4:3502-3511.
[30] YAN Jingchun,LEI Min,ZHU Lihua,et al.Degradation of sulfamonomethoxine with Fe3O4 magnetic nanoparticles as heterogeneous activator of persulfate[J].J.Hazard.Mate.r,2011,186(2/3):1398-1404.
[2] KO S,CRIMI M,MARVIN B K,et al.Comparative study on oxidative treatments of NAPL containing chlorinated ethanes and ethenes using hydrogen peroxide and persulfate in soils[J].J.Environ.Manag.,2012,108:42-48.
[3] GAO Yuqiong,GAO Naiyun,DENG Yang,et al.Ultraviolet(UV)light-activated persulfate oxidation of sulfamethazine in water[J].Chem.Eng.J,2012,195/196:248-253.
[4] LIANG C,BRUELL C J,MARLEY M C,et al.Persulfate oxidation for in situ remediation of TCE.II.Activated by chelated ferrous ion[J].Chemosphere,2004,55:1225-1233.
[5] XU Minhui,DU Huizhen,GU Xiaogang,et al.Generation and intensity of active oxygen species in thermally activated persulfate systems for the degradation of trichloroethylene[J].RSC Adv.,2014b,4:40511-40517.
[6] ANIPSITAKIS G P,DIONYSIOU D D,GONZALEZ M A.Cobalt-mediated activation of peroxymonosulfate and sulfate radical attack on phenolic compounds Implications of chloride ions[J].Environ.Sci.Technol.,2006,40:1000-1007.
[7] LIU C S,SHIH K,SUN C X,et al.Oxidative degradation of propachlor by ferrous and copper ion activated persulfate[J].Sci.Total Environ.,2012,416:507-512.
[8] USMAN M,FAURE P,RUBY C,et al.Application of magnetiteactivated persulfate oxidation for the degradation of PAHs in contaminated soils[J].Chemosphere,2012,87:234-240.
[9] ZHEN Guangyin,LU Xueqin,ZHAO Youcai,et al.Enhanced dewaterability of sewage sludge in the presence of Fe(II)-activated persulfate oxidation[J].Bioresour.Technol.,2012,116:259-265.
[10] ZHANG Yongqing,XIE Xiaofang,HUANG Shaobin,et al.Effect of chelating agent on oxidation rate of aniline in ferrous ion activated persulfate system at neutral pH[J].J.Cent.South Univ.,2014,21:1441-1447.
[11]WANG Hua,LI Shuai,SI Yanmei,et al.Recyclable enzyme mimic of cubic Fe3O4nanoparticles loaded on grapheme oxidedispersed carbon nanotubes with enhanced peroxidase-like catalysis and electrocatalysis[J].J.Mater.Chem.B,2014a,2:4442-4448.
[12] WU Yan,LUO Hanjin,WANG Hou.Removal of para-nitrochlorobenzene from aqueous solution on surfactant-modified nanoscale zero-valent iron/graphene nanocomposites[J].Environ.Technol.,2014,35:2698-2707.
[13] HU Maocong,HUI K S,HUI K N.Role of graphene in Mn O2/graphene composite for catalytic ozonation of gaseous toluene[J].Chem.Eng.J.,2014,254:237-244.
[14]WANG Juntao,JI Shujing,MA Ruiyang,et al.Synthesis of magnetic Fe3O4 modified graphene nanocomposite and its application on the adsorption of some dyes from aqueous solution[J].Sep.Sci.Technol.,2014,49:861-867.
[15] YAN Jingchun,GAO Weiguo,DONG Mingang,et al.Degradation of trichloroethylene by activated persulfate using a reduced graphene oxide supported magnetite nanoparticle[J].Chem.Eng.J.,2016,295:309-316.
[16] AHMAD A,GU Xiaogang,LI Li,et al.Efficient degradation of trichloroethylene in water using persulfate activated by reduced graphene oxide-iron nanocomposite[J].Environ.Sci.Pollut.Res.,2015,22:17876-17885.
[17]刘承斌,唐艳红.石墨烯基功能材料在环境中的应用[M].北京:科学出版社,2015.
[18]杨胜韬,赵连勤.石墨烯吸附材料的制备与应用研究进展[J].西南民族大学学报(自然科学版),2014,40(2):203-218.
[19] BONACCORSO F,SUN Z,HASAN,et al.Graphene photonics and optoelectronics[J].Nature Photonics,2010,4:611-612.
[20] SCHWIERZ F.Graphene transistors[J].Nature Nanotechnol.,2010,5:487-496.
[21] WANG Ying,LI Zhaohui,WANG Jun,et al.Graphene and graphene oxide:Bio-functionalization and applications in biotechnology[J].Trends Biotechnol.,2011,29:205-212.
[22] YOUNG R J,KINLOCH I A,GONG L,et al.The mechanics of graphene nanocomposites:a review[J].Compos.Sci.Technol.,2012,72:1459-1476.
[23] ZHAO Guixia,WEN Tao,CHEN Changlun,et al.Synthesis of graphene-based nanomaterials and their application in energyrelated and environmental-related areas[J].RSC Adv.,2012,2:9286-9303.
[24]黄国家,陈志刚,李茂东,等.石墨烯和氧化石墨烯的表面功能化改性[J].化学学报,2016,74(10):789-799.
[25]郭盛.新型Fe2O3/氣化石墨烯催化剂的制备及吸附与可见光Fenton降解有机污染的研究[D].武汉:武汉理工大学,2013.
[26]何大方,吴健,刘战剑,等.面向应用的石墨烯制备研究进展[J].化工学报,2015,66(8):2888-2894.
[27]刘芳,樊丰涛,吕玉翠,等.石墨烯/TiO2复合材料光催化降解有机污染物的研究进展[J].化工学报,2016,67(5):1635-1643.
[28] FURUKAWA Y,KIM J W,WATKINS J,et al.Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron[J].Environ.Sci.Technol.,2002,36:5469-5475.
[29] HUSSAIN I,ZHANG Y,HUANG S.Degradation of aniline with zerovalent iron as an activator of persulfate in aqueous solution[J].RSC Adv.,2014,4:3502-3511.
[30] YAN Jingchun,LEI Min,ZHU Lihua,et al.Degradation of sulfamonomethoxine with Fe3O4 magnetic nanoparticles as heterogeneous activator of persulfate[J].J.Hazard.Mate.r,2011,186(2/3):1398-1404.