SSZ-13分子筛合成及应用进展
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摘要
对SSZ-13分子筛及SSZ-13分子筛膜的制备进行了综述,介绍了SSZ-13分子筛在应用领域的研究进展,对SSZ-13分子筛的发展趋势做了展望。通过低成本模板剂替代或开发无有机模板剂的高效合成路线,是实现SSZ-13分子筛工业应用的基础。在应用领域,SSZ-13分子筛的未来研发方向应集中于反应机理的研究。
The preparation methods of SSZ-13 molecular sieve and its membrane are reviewed.Research advances in application aspects of SSZ-13 molecular sieve are also introduced and the prospects and future development of SSZ-13 molecular sieve are presented.It is pointed out that before SSZ-13 molecular sieve can be applied commercially,low cost template must be developed or a high-efficient synthesis route without organic templates must be developed. In the applications,the future research and development for SSZ-13 molecular sieve is predicted to focus on the reaction mechanism research.
The preparation methods of SSZ-13 molecular sieve and its membrane are reviewed.Research advances in application aspects of SSZ-13 molecular sieve are also introduced and the prospects and future development of SSZ-13 molecular sieve are presented.It is pointed out that before SSZ-13 molecular sieve can be applied commercially,low cost template must be developed or a high-efficient synthesis route without organic templates must be developed. In the applications,the future research and development for SSZ-13 molecular sieve is predicted to focus on the reaction mechanism research.
引文
[1]Zones S I.Zeolite SSZ-13 and its method of preparation:US,4544538[P].1985-10-01.
[2]Zhu X C,Kosinov N,Kubarev A V,et al.Probing the influence of SSZ-13 zeolite pore hierarchy in methanol-to-olefins catalysis by using nanometer accuracy by stochastic chemical reactionsfluorescencemicroscopy and positron emission profiling[J].Chem Cat Chem,2017,9:3470-3477.
[3]Kwak J H,Tran D,Burton S D,et al.Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites[J].Journal of Catalysis,2012,287:203-209.
[4]Liu Bo,Zhou Rongfei,Bu Na,et al.Room-temperature ionic liquids modified zeolite SSZ-13 membranes for CO2/CH4separation[J].Journal of Membrane Science,2017,524:12-19.
[5]S·J·米勒,L-T·袁.分子筛SSZ-13的制备:CN,101573293[P].2007-12-21.
[6]Wu Leilei,Degirmenci V,Pieter C M M,et al.Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction[J].Chem Commun,2012,48:9492-9494.
[7]韩玉,裴仁彦,张耀日,等.混合模板法低成本合成SSZ-13分子筛的研究[J].无机盐工业,2016,48(9):36-39.
[8]任丽敏,张一波,肖丰收,等.由新型铜胺络合物模板剂设计合成活性优异的Cu-SSZ-13分子筛[J].催化学报,2012,33(1):92-100.
[9]Imai H,Hayashida N,Yokoi T,et al.Direct crystallization of CHAtype zeolite from amorphous aluminosilicate gel by seed-assisted method in the absence of organic-structure-directing agents[J].Microporous and Mesoporous Materials,2014,196:341-348.
[10]Bhadraa B N,Seoa P W,Khana N A,et al.Conversion of Y into SSZ-13 zeolite in the presence of tetraethyammonium hydroxide and ethylene-to-propylene reactions over SSZ-13 zeolites[J].Catalysis Today,2017,298:53-60.
[11]冯晴,裴仁彦,张耀日,等.干胶转化法合成整体式SSZ-13分子筛[J].化工学报,2017,68(3):1231-1238.
[12]孟祥举,吴勤明,肖丰收,等.一种通过固相研磨合成SSZ-13分子筛的方法:CN,10409917A[P].2015-06-17.
[13]Kwak J H,Tonkyn R G,Kim D H,et al.Excellent activity and selectivity of Cu-SSZ-13 in the selectivie catalytic reduction of NOx with NH3[J].Journal of Catalysis,2010,275(2):187-190.
[14]Kovarik L,Washton N M,Kukkadapu R,et al.Transformation of active sites in Fe/SSZ-13 SCR catalysts during hydrothermal aging:A spectroscopic,microscopic,and kinetics study[J].ACS Catslysis,2017,(4):2458-2470.
[15]Oord R,Have I C,Arends J M,et al.Enhanced activity of desilicated Cu-SSZ-13 for the selective catalytic reduction of NOx and its comparison with steamed Cu-SSZ-13[J].Catalysis Science&Technology,2017,7:3851-3862.
[16]由慧玲,程涛,姚远介.介孔SSZ-13催化剂的合成以及在甲醇制烯烃反应中的应用[J].化工中间体,2014,(6):18-22.
[17]王艳悦.SSZ-13分子筛材料合成新路线的探索[D].太原:太原理工大学,2016.
[18]Kosinov N,Auffret C,Borghuis G J,et al.Influence of the Si/Al ratio on the separation properties of SSZ-13 zeolite membranes[J].Journal of Membrane Science,2015,484:140-145.
[19]郑艺鸿,布娜,袁晓蕾,等.SSZ-13分子筛膜在CO2/N2体系中的分离性能研究[J].江西师范大学学报:自然科学版,2015,(4):411-414.
[20]Qian Qingyun,Javier R M,Mohamed M,et al.Single-catalyst particle spectroscopy of alcohol-to-olefins conversions:Comparison between SAPO-34 and SSZ-13[J].Catalysis Today,2014,226:14-24.
[21]李渊,李晓庆,王文婷,等.SSZ-13和SAPO-34对乙醇脱水制乙烯反应的对比研究[J].天津工业大学学报,2014,33(5):48-52.
[22]Gao Feng,Mei Donghai,Wang Yilin,et al.Selective catalytic reduction over Cu/SSZ-13:Linking homo-and heterogeneous catalysis[J].Journal of the American Chemical Society,2017,139(13):4935-4942.
[23]Wang Jiancheng,Peng Zhaoliang,Chen Ying,et al.In-situ hydrothermal synthesis of Cu-SSZ-13/cordierite for the catalytic removalof NOxfrom diesel vehicles by NH3[J].Chemical Engineering Journal,2015,263:9-19.
[24]Xie Lijuan,Liu Fudong,Shi Xiaoyan,et al.Effects of post-treatment method and Na co-cation on the hydrothermal stability of Cu-SSZ-13 catalyst for the selective catalystic reduction of NOxwith NH3[J].Applied Catalysis B:Environmental,2015,179:206-212.
[25]Thompson J A.Process for gas seperations using zeolite SSZ-13:US,4544538[P].2017-04-04.
[26]Hudson M R,Queen W L,Fickel D W,et al.Unconventional highly selective CO2adsorption in zeolite SSZ-13[J].J Am Chem Soc,2012,134:1970-1973.
[27]Kida K,Maeta Yasushi,Yogo Katsunori.Preparation and gas permeation properties on pure silica CHA-type zeolite membranes[J].Journal of Membrane Science,2017,522:363-370.
[2]Zhu X C,Kosinov N,Kubarev A V,et al.Probing the influence of SSZ-13 zeolite pore hierarchy in methanol-to-olefins catalysis by using nanometer accuracy by stochastic chemical reactionsfluorescencemicroscopy and positron emission profiling[J].Chem Cat Chem,2017,9:3470-3477.
[3]Kwak J H,Tran D,Burton S D,et al.Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites[J].Journal of Catalysis,2012,287:203-209.
[4]Liu Bo,Zhou Rongfei,Bu Na,et al.Room-temperature ionic liquids modified zeolite SSZ-13 membranes for CO2/CH4separation[J].Journal of Membrane Science,2017,524:12-19.
[5]S·J·米勒,L-T·袁.分子筛SSZ-13的制备:CN,101573293[P].2007-12-21.
[6]Wu Leilei,Degirmenci V,Pieter C M M,et al.Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction[J].Chem Commun,2012,48:9492-9494.
[7]韩玉,裴仁彦,张耀日,等.混合模板法低成本合成SSZ-13分子筛的研究[J].无机盐工业,2016,48(9):36-39.
[8]任丽敏,张一波,肖丰收,等.由新型铜胺络合物模板剂设计合成活性优异的Cu-SSZ-13分子筛[J].催化学报,2012,33(1):92-100.
[9]Imai H,Hayashida N,Yokoi T,et al.Direct crystallization of CHAtype zeolite from amorphous aluminosilicate gel by seed-assisted method in the absence of organic-structure-directing agents[J].Microporous and Mesoporous Materials,2014,196:341-348.
[10]Bhadraa B N,Seoa P W,Khana N A,et al.Conversion of Y into SSZ-13 zeolite in the presence of tetraethyammonium hydroxide and ethylene-to-propylene reactions over SSZ-13 zeolites[J].Catalysis Today,2017,298:53-60.
[11]冯晴,裴仁彦,张耀日,等.干胶转化法合成整体式SSZ-13分子筛[J].化工学报,2017,68(3):1231-1238.
[12]孟祥举,吴勤明,肖丰收,等.一种通过固相研磨合成SSZ-13分子筛的方法:CN,10409917A[P].2015-06-17.
[13]Kwak J H,Tonkyn R G,Kim D H,et al.Excellent activity and selectivity of Cu-SSZ-13 in the selectivie catalytic reduction of NOx with NH3[J].Journal of Catalysis,2010,275(2):187-190.
[14]Kovarik L,Washton N M,Kukkadapu R,et al.Transformation of active sites in Fe/SSZ-13 SCR catalysts during hydrothermal aging:A spectroscopic,microscopic,and kinetics study[J].ACS Catslysis,2017,(4):2458-2470.
[15]Oord R,Have I C,Arends J M,et al.Enhanced activity of desilicated Cu-SSZ-13 for the selective catalytic reduction of NOx and its comparison with steamed Cu-SSZ-13[J].Catalysis Science&Technology,2017,7:3851-3862.
[16]由慧玲,程涛,姚远介.介孔SSZ-13催化剂的合成以及在甲醇制烯烃反应中的应用[J].化工中间体,2014,(6):18-22.
[17]王艳悦.SSZ-13分子筛材料合成新路线的探索[D].太原:太原理工大学,2016.
[18]Kosinov N,Auffret C,Borghuis G J,et al.Influence of the Si/Al ratio on the separation properties of SSZ-13 zeolite membranes[J].Journal of Membrane Science,2015,484:140-145.
[19]郑艺鸿,布娜,袁晓蕾,等.SSZ-13分子筛膜在CO2/N2体系中的分离性能研究[J].江西师范大学学报:自然科学版,2015,(4):411-414.
[20]Qian Qingyun,Javier R M,Mohamed M,et al.Single-catalyst particle spectroscopy of alcohol-to-olefins conversions:Comparison between SAPO-34 and SSZ-13[J].Catalysis Today,2014,226:14-24.
[21]李渊,李晓庆,王文婷,等.SSZ-13和SAPO-34对乙醇脱水制乙烯反应的对比研究[J].天津工业大学学报,2014,33(5):48-52.
[22]Gao Feng,Mei Donghai,Wang Yilin,et al.Selective catalytic reduction over Cu/SSZ-13:Linking homo-and heterogeneous catalysis[J].Journal of the American Chemical Society,2017,139(13):4935-4942.
[23]Wang Jiancheng,Peng Zhaoliang,Chen Ying,et al.In-situ hydrothermal synthesis of Cu-SSZ-13/cordierite for the catalytic removalof NOxfrom diesel vehicles by NH3[J].Chemical Engineering Journal,2015,263:9-19.
[24]Xie Lijuan,Liu Fudong,Shi Xiaoyan,et al.Effects of post-treatment method and Na co-cation on the hydrothermal stability of Cu-SSZ-13 catalyst for the selective catalystic reduction of NOxwith NH3[J].Applied Catalysis B:Environmental,2015,179:206-212.
[25]Thompson J A.Process for gas seperations using zeolite SSZ-13:US,4544538[P].2017-04-04.
[26]Hudson M R,Queen W L,Fickel D W,et al.Unconventional highly selective CO2adsorption in zeolite SSZ-13[J].J Am Chem Soc,2012,134:1970-1973.
[27]Kida K,Maeta Yasushi,Yogo Katsunori.Preparation and gas permeation properties on pure silica CHA-type zeolite membranes[J].Journal of Membrane Science,2017,522:363-370.