无溶剂纳米类流体的研究进展
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摘要
纳米结构功能化的实现带来了多种具有新特性的纳米材料,从而促进了纳米科技的快速发展。通过对纳米粒子进行表面改性,即接枝和化学反应在其表面引入长链离子,形成包覆于粒子表层的核-壳结构。这种结构赋予其众多新的功能化特性,进而扩展了纳米材料的应用范围。采用该法制备的无溶剂纳米类流体是一种在接近室温或者室温的条件下,不借助溶剂便可产生流动行为的悬浮液体,具有独特的化学和物理性质,如光致发光、高的电导率、增塑和热稳定性等。本文综合了国内外对于无溶剂纳米类流体的合成方法和结构性能的研究进展,总结了存在的疑点和问题,对无溶剂纳米类流体的发展趋势做出了展望。
Realization of the functionalized nanostructure brings on much new nanomaterial, which promotes the development of nanotechnology rapidly. Surface modification of the nanoparticles involves long-chain anions form a core-shell structure which gives numerous new functionalized characters, and then extend the applied range of nanomaterial. Solvent-free Nano liquid-like fluids prepared in this way are able to flow in the room temperature or approximate the ambient temperature without any solvent.Also they have unique chemical and physical properties, such as photoluminescence properties, high conductivity, softening, and thermo-stabilization and so on. Synthesis and structural characters researches are reviewed in this review.
Realization of the functionalized nanostructure brings on much new nanomaterial, which promotes the development of nanotechnology rapidly. Surface modification of the nanoparticles involves long-chain anions form a core-shell structure which gives numerous new functionalized characters, and then extend the applied range of nanomaterial. Solvent-free Nano liquid-like fluids prepared in this way are able to flow in the room temperature or approximate the ambient temperature without any solvent.Also they have unique chemical and physical properties, such as photoluminescence properties, high conductivity, softening, and thermo-stabilization and so on. Synthesis and structural characters researches are reviewed in this review.
引文
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[23]ZHANG J,ZHENG Y,YU P,et al.The synthesis of functionalized carbon nanotubes by hyperbranched poly(amine-ester)with liquid-like behavior at room temperature[J].Polymer,2009,50(13):2953-2957.
[24]PERRIMAN A W,COELFEN H,HUGHES R H,et al.ChemInform Abstract:Solvent-Free Protein Liquids and Liquid Crystals[J].Cheminform,2010,40(44):6242-6246.
[25]HUANG J,LI Q,WANG Y,et al.Self-suspended polyaniline doped with a protonic acid containing a polyethylene glycol segment.[J].Chemistry-An Asian Journal,2011,6(11):2920-2924.
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[27]VIRJI S,HUANG J,KANER R B,et al.Polyaniline nanofiber gas sensors:Examination of response mechanisms[J].Nano Letters,2016,4(3):491-496.
[2]BOURLINOS A B,CHOWDHURY S R,HERRERA R,et al.Functionalized Nanostructures with Liquid-Like Behavior:Expanding the Gallery of Available Nanostructures[J].Advanced Functional Materials,2010,15(8):1285-1290.
[3]BOURLINOS A B,HERRERA R,CHALKIAS N,et al.Surface-Functionalized Nanoparticles with Liquid-Like Behavior[J].Advanced Materials,2010,17(2):234-237.
[4]BOURLINOS A B,CHOWDHURY S R,JIANG D D,et al.Layered organosilicate nanoparticles with liquidlike behavior[J].Small,2010,1(1):80-82.
[5]BOURLINOS A B,GIANNELIS E P,ZHANG Q,et al.Surface-functionalized nanoparticles with liquid-like behavior:The role of the constituent components[J].European Physical Journal E,2006,20(1):109-117.
[6]李琦,吴晓彦,董丽杰,等.SiO2纳米类流体及其复合材料的电性能研究[J].武汉理工大学学报,2011(1):22-27.LI Qi,WU Xiao-yan,DONG Li-jie,et al.Solvent-free SiO2Nanofluid and Electrical Properties of Its Composite[J].Journal of Wuhan University of Technology,2011(1):22-27.
[7]兰岚,郑亚萍,张娇霞,等.无溶剂SiO2纳米流体的制备及其导电性能研究[J].功能材料与器件学报,2011,17(3):279-285.LAN Lan,ZHENG Ya-ping,ZHANG Jiao-xia,et al.The Preparation of Solvent-Free SiO2 Nanofluids and the Study of Their Conductivity[J].Journal of Functional Materials and Devices,2011,17(3):279-285.
[8]檀雨默,郑亚萍,兰岚.无溶剂Fe3O4纳米流体的制备及表征[J].高等学校化学学报,2012,33(1):206-209.TAN Yu-Mo,ZHENG Ya-Ping,LAN Lan.Preparation and Characterization of Solvent-free Fe3O4 Nanofluids[J].Chemical Journal of Chinese Universities,2012,33(1):206-209.
[9]BOURLINOS A B,STASSINOPOULOS A,ANGLOS D,et al.Functionalized ZnO nanoparticles with liquidlike behavior and their photoluminescence properties.[J].Small,2010,2(4):513-516.
[10]ZHANG J X,ZHENG Y P,LAN L,et al.Direct synthesis of solvent-free multiwall carbon nanotubes/silica nonionic nanofluid hybrid material[J].Acs Nano,2009,3(8):2185-2190.
[11]袁望章,赵辉,徐海鹏,等.用带不同侧链的双取代聚乙炔衍生物增溶多壁碳纳米管[J].高分子学报,2007,1(10):901-904.YUAN Wang-zhang,ZHAO Hui,XU Hai-peng.Improvement of the Solubility of Multiwalled Carbon Nanotubes with Disubstituted polyacetylenes Bearing Different Side-chains[J].Acta Polymerica Sinica,2007,1(10):901-904.
[12]邱军,王国建,尚婧.聚乙烯基吡咯烷酮修饰多壁碳纳米管的研究[J].高分子学报,2007,1(4):327-331.QIU Jun WANG Guojian SHANG Jing.Multi-walled Carbon Nanotubes Modified by Poly(Vinyl Pyrrolidone)[J].Acta Polymerica Sinica,2007,1(4):327-331.
[13]HAMON M A,CHEN J,HU H,et al.Dissolution of Single-Walled Carbon Nanotubes[J].Advanced Materials,2010,11(10):834-840.
[14]李博,连永福,施祖进,等.单层碳纳米管的化学修饰[J].高等学校化学学报,2000,21(11):1633-1635.LI Bo LIAN Yong-Fu SHI Zu-Jin GU Zhen-Nan.Chemical Modification of Single-wall Carbon Nanotube[J].Chemical Journal of Chinese Universities,2000,21(11):1633-1635.
[15]LIU Z,SHEN Z,TAO Z,et al.Organizing Single-Walled Carbon Nanotubes on Gold Using a Wet Chemical Self-Assembling Technique[J].Langmuir,2000,16(8):3569-3573.
[16]WU B,JIN Z,ZHONG W,et al.Chemical Alignment of Oxidatively Shortened Single-Walled Carbon Nanotubes on Silver Surface[J].Journal of Physical Chemistry B,2001,105(22):5075-5078.
[17]KANG Y J,TATON T A.Micelle-encapsulated carbon nanotubes:A route to nanotube composites[J].Journal of the American Chemical Society,2003,125(19):5650-5651
[18]RIGGS J E,GUO Z X,CARROLL D L,et al.Strong luminescence of solubilized carbon nanotubes[J].Journal of the American Chemical Society,2000,122(24):5879-5880.
[19]BOURLINOS A B,GEORGAKILAS V,BOUKOS N,et al.Silicone-functionalized carbon nanotubes for the production of new carbon-based fluids[J].Carbon,2007,45(7):1583-1585.
[20]BOURLINOS A,GEORGAKILAS V,TZITZIOS V,et al.Functionalized Carbon Nanotubes:Synthesis of Meltable and Amphiphilic Derivatives[J].Small,2006,2(10):1188-1191.
[21]张娇霞,郑亚萍,杨晓东,等.一种含碳纳米管的第二代纳米流体的制备[J].高分子学报,2008,1(12):1209-1213.ZHANG,Jiao-xia,ZHENG Ya-ping,YANG Xiao-dong,et al.The Synthesis of a Second Generation of Nanofluids Based on Carbon Nanotubes[J].Acta Polymerica Sinica,2008,1(12):1209-1213.
[22]LAN L,ZHENG Y P,ZHANG A B,et al.Study of ionic solvent-free carbon nanotube nanofluids and its composites with epoxy matrix[J].Journal of Nanoparticle Research,2012,14(3):1-10.
[23]ZHANG J,ZHENG Y,YU P,et al.The synthesis of functionalized carbon nanotubes by hyperbranched poly(amine-ester)with liquid-like behavior at room temperature[J].Polymer,2009,50(13):2953-2957.
[24]PERRIMAN A W,COELFEN H,HUGHES R H,et al.ChemInform Abstract:Solvent-Free Protein Liquids and Liquid Crystals[J].Cheminform,2010,40(44):6242-6246.
[25]HUANG J,LI Q,WANG Y,et al.Self-suspended polyaniline doped with a protonic acid containing a polyethylene glycol segment.[J].Chemistry-An Asian Journal,2011,6(11):2920-2924.
[26]MACDIARMID A G.“Synthetic Metals”:A Novel Role for Organic Polymers(Nobel Lecture)[J].Angew.Chem.Int.Ed,2001,40:2581-2590.
[27]VIRJI S,HUANG J,KANER R B,et al.Polyaniline nanofiber gas sensors:Examination of response mechanisms[J].Nano Letters,2016,4(3):491-496.