低氧TZM合金研究进展
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摘要
钼合金作为一种高温结构材料、功能材料,被广泛应用于冶金工业、航空航天、核工业等诸多领域。近年来,随着相关行业的技术升级,钼合金凭借特有的优势,其应用范围也不断扩大。同时,对钼合金的使用性能也提出了更高的要求。尤其是有色金属、医疗器械材料等加工行业已明确提出对钼合金材料中氧含量的技术要求。详细介绍了目前国内外TZM钼合金低氧制备技术的研究现状,分析了TZM钼合金中氧的来源,明确了钼合金制备过程中起氧化作用的主要因素,讨论了烧结过程中氧含量的变化以及料层厚度对氧含量的影响规律,总结出目前国内外TZM钼合金低氧制备的关键技术。在此基础上,对现在国内外TZM钼合金低氧制备技术的研究未涉及且还需完善之处提出补充意见,并展望了低氧TZM钼合金制备技术的发展前景。
Molybdenum alloys are widely used as a kind of high-temperature structural material and function material in many areas such as metallurgical industry,aerospace,nuclear industry.With the development of relevant technology,molybdenum alloys applied range increased.While,higher usability requirement to molybdenum alloys appeared.The technical requirement of oxygen content in molybdenum alloy has been presented clearly in non-ferrous metals industry,medical apparatus and instruments process industry.The domestic and overseas research status of low oxygen preparation technology of the TZM molybdenum alloy,and the source of oxygen from the TZM molybdenum alloy are introduced.The major factor lead to oxidation in the processing of molybdenum preparation,oxygen content change and the effect of material thickness on oxygen content are discussed.The key technologies on low content molybdenum alloy preparation are summarized.Base on above analysis,additional comments about low oxygen content molybdenum preparation technology which did not involve in previous study and need improving are introduced.And its development prospect is put forward.
Molybdenum alloys are widely used as a kind of high-temperature structural material and function material in many areas such as metallurgical industry,aerospace,nuclear industry.With the development of relevant technology,molybdenum alloys applied range increased.While,higher usability requirement to molybdenum alloys appeared.The technical requirement of oxygen content in molybdenum alloy has been presented clearly in non-ferrous metals industry,medical apparatus and instruments process industry.The domestic and overseas research status of low oxygen preparation technology of the TZM molybdenum alloy,and the source of oxygen from the TZM molybdenum alloy are introduced.The major factor lead to oxidation in the processing of molybdenum preparation,oxygen content change and the effect of material thickness on oxygen content are discussed.The key technologies on low content molybdenum alloy preparation are summarized.Base on above analysis,additional comments about low oxygen content molybdenum preparation technology which did not involve in previous study and need improving are introduced.And its development prospect is put forward.
引文
1 李洪桂.稀有金属冶金学[M].北京:冶金工业出版社,1990
2 康轩齐,王快社,胡平,等.TZM合金抗氧化性研究进展[J].热加工工艺,2013,42(4):11
3 成会朝,范景莲,刘涛,等.TZM钼合金制备技术及研究进展[J].中国钼业,2008,32(6):40
4 崔超鹏,张国赏,魏世忠,等.TZM合金的研究现状[J].中国钼业,2011,35(1):26
5 黄强,李青,宋尽霞,等.TZM合金的研究进展[J].材料导报:综述篇,2009,23(11):39
6 张启修,赵秦生.钨钼冶金[M].北京:冶金工业出版社,2005:34
7 刘仁智,李晶,安耿,等.层片状二氧化钼还原过程模型化研究[J].中国钼业,2009,33(3):37
8 Mehdi Rouhani,Jonathan Hobley,Gomathy Sandhya Subramanian,et al.The influence of initial stoichiometry on the mechanism of photochromism of molybdenum oxide amorphous films[J].Solar Energy Mater Solar Cells,2014,126(6):26
9 韩强.钼及其合金的氧化、防护与高温应用[J].中国钼业,2002,26(4):32
10 曹冬,朱琦.低氧TZM合金的制备机理研究[J].中国钼业,2011,35(6):57
11 Majumdar S,Sharma I G.Oxidation behavior of MoSi2and Mo(Si,Al)2coated Mo-0.5Ti-0.1Zr-0.02Calloy[J].Intermetallics,2011(19):541
12 Smolik G R,Petti D A,Schuetz S T.Oxidation and volatilization of TZM alloy in air[J].J Nucl Mater,2000,283-287:1458
13 Yang F,Hu P,Wang K S.La doping effect on molybdenum TZM alloy oxidation behavior[J].J Alloys Compd,2014,593:196
14 成会朝,范景莲,李鹏飞,等.难熔钼合金的高温抗氧化和烧蚀行为[J].中国有色金属学报,2011(3):570
15 向铁根,刘海湘.还原工艺对钼粉粒度和氧含量的影响[J].中国钼业,2004,28(2):42
16 黄培云.粉末冶金原理[M].北京:冶金工业出版社,1982
17 王德志,汪异,程仕平,等.料层厚度对还原钼粉性能的影响[J].中国钼业,2007,31(3):20
18 王增民,宋光涛.钼合金坯料烧结过程中氧含量的变化[J].稀有金属材料与工程,2002,31(增2):119
19 马全智.温度变化趋势对还原钼粉的影响[J].中国钨业,2012,27(4):36
20 Hitoshi Aoyama,Shinichi Yamamoto,et al.Microstructure,high temperature strength and Co-gas emission of liquid-phase sintered and forged low oxygen TiC-ZrC-Mo alloy[J].J Soc Mater Sci,2006,55(6):558
21 唐惠庆,郭兴敏,张圣弼,等.CO/CO2气氛下含碳球团还原动力学模型及其应用[J].钢铁研究学报,2000,12(6):1
22 梁静,李来平,奚正平,等.TZM合金真空烧结脱氧的机制分析[J].稀有金属材料与工程,2011,40(6):998
23 林宇霖,陈同云,黄宪法,等.碳还原三氧化钼制取金属钼[J].中国钼业,2012,36(2):43
24 靳广洲,赵如松,罗运强,等.氧化钼在CH4/H2气氛中还原碳化机理研究[J].燃料化学学报,2008(6):738
25 靳广洲,俱虎良,朱建华,等.CH4/H2气氛中Ni-Mo双金属氧化物还原碳化过程的TG-DTA研究[J].石油学报,2006(5):69
26 李文超.冶金与材料物理化学[M].北京:冶金工业出版社,2001:21
27 梁英教,车荫昌.无机物热力学数据手册[M].沈阳:东北大学出版社,1993:3
28 邹洪伟,叶金文,刘颖,等.原料粉末碳、氧含量对无粘结相硬质合金性能的影响[J].功能材料,2010,41(1):90
29 曹欢,温治,刘训良,等.烧结过程碳燃烧模拟研究[J].冶金能源,2014,33(3):36
30 梁静,林小辉,王国栋,等.碳含量对真空烧结钼合金的影响[J].中国钼业,2012,36(5):43
31 林宇霖,陈同云,黄宪法,等.两段碳还原MoO3反应产物的成分研究[J].稀有金属和硬质合金,2013,40(1):28
32 Aydinyana S V,Gumruyana Z H,Manukyan Kh V,et al.Self-sustaining reduction of MoO3by the Mg-C mixture[J].Mater Sci Eng B,2010,172:267
2 康轩齐,王快社,胡平,等.TZM合金抗氧化性研究进展[J].热加工工艺,2013,42(4):11
3 成会朝,范景莲,刘涛,等.TZM钼合金制备技术及研究进展[J].中国钼业,2008,32(6):40
4 崔超鹏,张国赏,魏世忠,等.TZM合金的研究现状[J].中国钼业,2011,35(1):26
5 黄强,李青,宋尽霞,等.TZM合金的研究进展[J].材料导报:综述篇,2009,23(11):39
6 张启修,赵秦生.钨钼冶金[M].北京:冶金工业出版社,2005:34
7 刘仁智,李晶,安耿,等.层片状二氧化钼还原过程模型化研究[J].中国钼业,2009,33(3):37
8 Mehdi Rouhani,Jonathan Hobley,Gomathy Sandhya Subramanian,et al.The influence of initial stoichiometry on the mechanism of photochromism of molybdenum oxide amorphous films[J].Solar Energy Mater Solar Cells,2014,126(6):26
9 韩强.钼及其合金的氧化、防护与高温应用[J].中国钼业,2002,26(4):32
10 曹冬,朱琦.低氧TZM合金的制备机理研究[J].中国钼业,2011,35(6):57
11 Majumdar S,Sharma I G.Oxidation behavior of MoSi2and Mo(Si,Al)2coated Mo-0.5Ti-0.1Zr-0.02Calloy[J].Intermetallics,2011(19):541
12 Smolik G R,Petti D A,Schuetz S T.Oxidation and volatilization of TZM alloy in air[J].J Nucl Mater,2000,283-287:1458
13 Yang F,Hu P,Wang K S.La doping effect on molybdenum TZM alloy oxidation behavior[J].J Alloys Compd,2014,593:196
14 成会朝,范景莲,李鹏飞,等.难熔钼合金的高温抗氧化和烧蚀行为[J].中国有色金属学报,2011(3):570
15 向铁根,刘海湘.还原工艺对钼粉粒度和氧含量的影响[J].中国钼业,2004,28(2):42
16 黄培云.粉末冶金原理[M].北京:冶金工业出版社,1982
17 王德志,汪异,程仕平,等.料层厚度对还原钼粉性能的影响[J].中国钼业,2007,31(3):20
18 王增民,宋光涛.钼合金坯料烧结过程中氧含量的变化[J].稀有金属材料与工程,2002,31(增2):119
19 马全智.温度变化趋势对还原钼粉的影响[J].中国钨业,2012,27(4):36
20 Hitoshi Aoyama,Shinichi Yamamoto,et al.Microstructure,high temperature strength and Co-gas emission of liquid-phase sintered and forged low oxygen TiC-ZrC-Mo alloy[J].J Soc Mater Sci,2006,55(6):558
21 唐惠庆,郭兴敏,张圣弼,等.CO/CO2气氛下含碳球团还原动力学模型及其应用[J].钢铁研究学报,2000,12(6):1
22 梁静,李来平,奚正平,等.TZM合金真空烧结脱氧的机制分析[J].稀有金属材料与工程,2011,40(6):998
23 林宇霖,陈同云,黄宪法,等.碳还原三氧化钼制取金属钼[J].中国钼业,2012,36(2):43
24 靳广洲,赵如松,罗运强,等.氧化钼在CH4/H2气氛中还原碳化机理研究[J].燃料化学学报,2008(6):738
25 靳广洲,俱虎良,朱建华,等.CH4/H2气氛中Ni-Mo双金属氧化物还原碳化过程的TG-DTA研究[J].石油学报,2006(5):69
26 李文超.冶金与材料物理化学[M].北京:冶金工业出版社,2001:21
27 梁英教,车荫昌.无机物热力学数据手册[M].沈阳:东北大学出版社,1993:3
28 邹洪伟,叶金文,刘颖,等.原料粉末碳、氧含量对无粘结相硬质合金性能的影响[J].功能材料,2010,41(1):90
29 曹欢,温治,刘训良,等.烧结过程碳燃烧模拟研究[J].冶金能源,2014,33(3):36
30 梁静,林小辉,王国栋,等.碳含量对真空烧结钼合金的影响[J].中国钼业,2012,36(5):43
31 林宇霖,陈同云,黄宪法,等.两段碳还原MoO3反应产物的成分研究[J].稀有金属和硬质合金,2013,40(1):28
32 Aydinyana S V,Gumruyana Z H,Manukyan Kh V,et al.Self-sustaining reduction of MoO3by the Mg-C mixture[J].Mater Sci Eng B,2010,172:267