无铅化低温封接玻璃研究发展概况
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摘要
本文简要介绍了铅玻璃对环境和人类的危害,论述了无铅低温封接玻璃的研究发展概况,主要包括铋酸盐、磷酸盐、钒酸盐三大体系。对各玻璃体系中的结构特点、性能和研究现状做了简要分析。并指出铋酸盐具有良好的化学稳定性以及简单的制备工艺,拥有很好的发展前景。
The harm of lead glass to environment and human was briefly introduced.The research and development of lead-free low-melting point sealing glass which including bismuthate glass,phosphate glass and vanadate glass was discussed.The structural features,properties and research status of various glass systems are briefly analyzed.It is pointed out that bismuthate glass has good chemical stability and simple preparation process,and has good prospects for development.
The harm of lead glass to environment and human was briefly introduced.The research and development of lead-free low-melting point sealing glass which including bismuthate glass,phosphate glass and vanadate glass was discussed.The structural features,properties and research status of various glass systems are briefly analyzed.It is pointed out that bismuthate glass has good chemical stability and simple preparation process,and has good prospects for development.
引文
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[2]李长久,黄幼榕,崔竹,等.环境友好型无铅低温封接玻璃最新进展[J].玻璃,2007,34(6):17-23.
[3]肖卓豪,卢安贤,李岐新,等.电真空玻璃的研究现状及进展[J].硅酸盐通报,2005,24(1):81-84.
[4]Morena R.Phosphate glasses as alternatives to Pb-based sealing frits[J].Journal of Non-Crystalline Solids,2000,s 263–264:382-387.
[5]Wu C M L,Yu D Q,Law C M T,et al.Properties of lead-free solder alloys with rare earth element additions[J].Materials Science&Engineering R,2004,44(1):1-44.
[6]Wood E P,Nimmo K L.In search of new lead-free electronic solders[J].Journal of Electronic Materials,1994,23(8):709-713.
[7]江涛宏.以铋代铅前景广阔[J].中国金属通报,2005(6):45-45.
[8]何鹏,郭伟,林铁松,等.绿色无铅低熔点封接玻璃研究进展[J].材料工程,2016,44(6):123-130.
[9]隋普辉,陆雷,武相萍,等.电子封接用微晶玻璃的研究进展[J].材料开发与应用,2008,23(2):72-76.
[10]陈培,王海风,李浩业.掺杂氧化物对氧化锌系封接玻璃烧结特性的影响[J].玻璃与搪瓷,2014,42(6):8-13.
[11]刘远平.低熔点铋酸盐封接玻璃的研究[D].中国计量学院,2013.
[12]李胜春.Zn O-B2O3-P2O5低熔封接玻璃结构与性能的表征[D].东华大学,2008.
[13]Brow R K.Review:the structure of simple phosphate glasses[J].Journal of Non-Crystalline Solids,2000,s 263–264(1):1-28.
[14]刘新年,高档妮,郭宏伟,等.磷酸盐在低熔封接玻璃中的应用[J].无机盐工业,2005,37(7):45-47.
[15]董福惠.铋系低熔点电子玻璃结构与性能的表征[D].东华大学,2009.
[16]Morena R.Phosphate glasses as alternatives to Pb-based sealing frits[J].Journal of Non-Crystalline Solids,2000,s 263–264:382-387.
[17]沈健,李启甲,殷海荣,等.Sn O-Zn O-P2O5三元系统封接玻璃的研究[J].陕西科技大学学报,2003,21(6):30-33.
[18]Ide,Akira.Lead-free sealing glass and sealing compositions containing same for display panels[P].JP Patent2004035316,2004-02-05.
[19]马占锋,李启甲,赵彦钊,等.Sn O-Zn O-P2O5玻璃部分热性质的研究[J].玻璃与搪瓷,2005,33(5):5-9.
[20]李春丽,田英良,孙诗兵.R2O3对Sn O-Zn O-P2O5无铅玻璃系统性能的影响[C]//电子玻璃技术交流会.2006.
[21]Shyu J J,Yeh C H.Influence of sintering atmosphere on the microstructure and water durability of Sn O–Mg O–P2O5,glass[J].Journal of Materials Science,2011,46(4):999-1006.
[22]Morinaga K,Fujino S.Preparation and properties of Sn O–Sn Cl2–P2O5,glass[J].Journal of Non-Crystalline Solids,2001,282(1):118-124.
[23]Niida H,Takahashi M,Uchino T,et al.Preparation and structure of organic–inorganic hybrid precursors for new type low-melting glasses[J].Journal of Non-Crystalline Solids,2002,306(3):292-299.
[24]高金飞,何岗,何明中,等.无铅低温封接玻璃研究的进展及其应用前景[J].建材世界,2008,29(5):18-20.
[25]齐济.钒氧化物及其复合玻璃的制备与性质研究[D].大连理工大学,2008.
[26]Garbarczyk J,Wasiucionek M,Jozwiak P,et al.Studies of Li2O–V2O5-P2O5 glasses by DSC,EPR and impedance spectroscopy[J].Solid State Ionics,2002,154(8):367-373.
[27]吴春娥,秦国斌.一种无铅低熔玻璃粉及其制造[P].中国专利:200310103592.2005-05-18.
[28]赵宏生,李艳青,周万城,等.Mo O3-V2O5-P2O5-Fe2O3玻璃的制备及性能研究[J].无机材料学报,2005,20(3):563-569.
[29]万隆,李争,刘小磐,等.V2O5的含量对Zn O-Bi2O3–B2O3系无铅封接玻璃的性能影响[J].湘潭大学自科学报,2015(4):59-63.
[30]李宏彦.V2O5-P2O5-Sb2O3-Bi2O3体系低熔点玻璃的结构及性质研究[D].北京有色金属研究总院,2012.
[31]Werner V.玻璃化学[M].谢于深译.北京:轻工业出版社,1988:221.
[32]Roberts,Gordon J.Bismuth-Lead-Free Glass Enamels and Glazes of Low Silica Content[P].美国专利:5252521,1993-10-12.
[33]Toshi F,Tatsuo M.Electrode material dielectric material and plasma display panel using them[P].USP:6787239.2004-12-07.
[34]Saritha D,Markandeya Y,Salagram M,et al.Effect of Bi2O3,on physical,optical and structural studies of Zn O–Bi2O3–B2O3,glasses[J].Journal of Non-Crystalline Solids,2008,354(52–54):5573-5579.
[35]邓大伟.Bi2O3-B2O3-Zn O系低熔点无铅封接玻璃结构与熔体性质研究[D].武汉理工大学,2011.
[36]周洪萍,曾人杰.Cu O对Zn O-Bi2O3-B2O3系玻璃结构及热处理结果影响[J].陶瓷学报,2010,31(4):568-575.
[37]常明.Bi2O3-B2O3-Zn O低温无铅封接玻璃结构及性能研究[D].中国建筑材料科学研究总院,2014.
[2]李长久,黄幼榕,崔竹,等.环境友好型无铅低温封接玻璃最新进展[J].玻璃,2007,34(6):17-23.
[3]肖卓豪,卢安贤,李岐新,等.电真空玻璃的研究现状及进展[J].硅酸盐通报,2005,24(1):81-84.
[4]Morena R.Phosphate glasses as alternatives to Pb-based sealing frits[J].Journal of Non-Crystalline Solids,2000,s 263–264:382-387.
[5]Wu C M L,Yu D Q,Law C M T,et al.Properties of lead-free solder alloys with rare earth element additions[J].Materials Science&Engineering R,2004,44(1):1-44.
[6]Wood E P,Nimmo K L.In search of new lead-free electronic solders[J].Journal of Electronic Materials,1994,23(8):709-713.
[7]江涛宏.以铋代铅前景广阔[J].中国金属通报,2005(6):45-45.
[8]何鹏,郭伟,林铁松,等.绿色无铅低熔点封接玻璃研究进展[J].材料工程,2016,44(6):123-130.
[9]隋普辉,陆雷,武相萍,等.电子封接用微晶玻璃的研究进展[J].材料开发与应用,2008,23(2):72-76.
[10]陈培,王海风,李浩业.掺杂氧化物对氧化锌系封接玻璃烧结特性的影响[J].玻璃与搪瓷,2014,42(6):8-13.
[11]刘远平.低熔点铋酸盐封接玻璃的研究[D].中国计量学院,2013.
[12]李胜春.Zn O-B2O3-P2O5低熔封接玻璃结构与性能的表征[D].东华大学,2008.
[13]Brow R K.Review:the structure of simple phosphate glasses[J].Journal of Non-Crystalline Solids,2000,s 263–264(1):1-28.
[14]刘新年,高档妮,郭宏伟,等.磷酸盐在低熔封接玻璃中的应用[J].无机盐工业,2005,37(7):45-47.
[15]董福惠.铋系低熔点电子玻璃结构与性能的表征[D].东华大学,2009.
[16]Morena R.Phosphate glasses as alternatives to Pb-based sealing frits[J].Journal of Non-Crystalline Solids,2000,s 263–264:382-387.
[17]沈健,李启甲,殷海荣,等.Sn O-Zn O-P2O5三元系统封接玻璃的研究[J].陕西科技大学学报,2003,21(6):30-33.
[18]Ide,Akira.Lead-free sealing glass and sealing compositions containing same for display panels[P].JP Patent2004035316,2004-02-05.
[19]马占锋,李启甲,赵彦钊,等.Sn O-Zn O-P2O5玻璃部分热性质的研究[J].玻璃与搪瓷,2005,33(5):5-9.
[20]李春丽,田英良,孙诗兵.R2O3对Sn O-Zn O-P2O5无铅玻璃系统性能的影响[C]//电子玻璃技术交流会.2006.
[21]Shyu J J,Yeh C H.Influence of sintering atmosphere on the microstructure and water durability of Sn O–Mg O–P2O5,glass[J].Journal of Materials Science,2011,46(4):999-1006.
[22]Morinaga K,Fujino S.Preparation and properties of Sn O–Sn Cl2–P2O5,glass[J].Journal of Non-Crystalline Solids,2001,282(1):118-124.
[23]Niida H,Takahashi M,Uchino T,et al.Preparation and structure of organic–inorganic hybrid precursors for new type low-melting glasses[J].Journal of Non-Crystalline Solids,2002,306(3):292-299.
[24]高金飞,何岗,何明中,等.无铅低温封接玻璃研究的进展及其应用前景[J].建材世界,2008,29(5):18-20.
[25]齐济.钒氧化物及其复合玻璃的制备与性质研究[D].大连理工大学,2008.
[26]Garbarczyk J,Wasiucionek M,Jozwiak P,et al.Studies of Li2O–V2O5-P2O5 glasses by DSC,EPR and impedance spectroscopy[J].Solid State Ionics,2002,154(8):367-373.
[27]吴春娥,秦国斌.一种无铅低熔玻璃粉及其制造[P].中国专利:200310103592.2005-05-18.
[28]赵宏生,李艳青,周万城,等.Mo O3-V2O5-P2O5-Fe2O3玻璃的制备及性能研究[J].无机材料学报,2005,20(3):563-569.
[29]万隆,李争,刘小磐,等.V2O5的含量对Zn O-Bi2O3–B2O3系无铅封接玻璃的性能影响[J].湘潭大学自科学报,2015(4):59-63.
[30]李宏彦.V2O5-P2O5-Sb2O3-Bi2O3体系低熔点玻璃的结构及性质研究[D].北京有色金属研究总院,2012.
[31]Werner V.玻璃化学[M].谢于深译.北京:轻工业出版社,1988:221.
[32]Roberts,Gordon J.Bismuth-Lead-Free Glass Enamels and Glazes of Low Silica Content[P].美国专利:5252521,1993-10-12.
[33]Toshi F,Tatsuo M.Electrode material dielectric material and plasma display panel using them[P].USP:6787239.2004-12-07.
[34]Saritha D,Markandeya Y,Salagram M,et al.Effect of Bi2O3,on physical,optical and structural studies of Zn O–Bi2O3–B2O3,glasses[J].Journal of Non-Crystalline Solids,2008,354(52–54):5573-5579.
[35]邓大伟.Bi2O3-B2O3-Zn O系低熔点无铅封接玻璃结构与熔体性质研究[D].武汉理工大学,2011.
[36]周洪萍,曾人杰.Cu O对Zn O-Bi2O3-B2O3系玻璃结构及热处理结果影响[J].陶瓷学报,2010,31(4):568-575.
[37]常明.Bi2O3-B2O3-Zn O低温无铅封接玻璃结构及性能研究[D].中国建筑材料科学研究总院,2014.