鄂尔多斯盆地上古生界灰岩烃源岩生烃潜力评价
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摘要
对于鄂尔多斯盆地上古生界海陆过渡相灰岩能否生烃及生烃潜力有多大,目前研究较少.通过岩石热解、总有机碳测定、干酪根碳同位素及有机显微组分的测定实验,同时结合镜质体反射率的测定,综合评价了灰岩烃源岩,并分析了其生排烃特征.结果显示:从有机质丰度角度,本溪组为差的烃源岩,山西组为差-一般的烃源岩、太原组为一般-好的烃源岩;从有机质类型角度,本溪组为Ⅲ型,山西组以Ⅲ型为主同时混有少量Ⅱ2型,太原组为Ⅱ2-Ⅲ型;从有机质成熟度角度,本溪组处于成熟-高成熟阶段,太原组及山西组均处于高成熟阶段.根据排烃门限理论,认为Ro为1.6%时,天然气大量生成.考虑到灰岩烃源岩的特殊性、成熟度及其排烃特征,综合认为太原组灰岩可以成为天然气的有效烃源岩.
There is little research on whether hydrocarbon generation from limestone in the transitional phase of the Upper Paleozoic in the Ordos basin can be made,and on how much the hydrocarbon can be.Using rock pyrolysis,determination of TOC,carbon isotope of kerogen,organic maceral and Roexperiment,we analyzed the limestone source rocks and characteristics of hydrocarbon generation and expulsion.The results show that:(1)The source rocks from Benxi Formation,Shanxi Formation and Taiyuan Formation is poor,poor-fair,and fair-good respectively according to organic matter abundance.(2)The organic matter type of Benxi Formation,Taiyuan Formation and Shanxi Formation isⅢ,Ⅱ2-ⅢandⅢ mixed with a small quantity ofⅡ2 respectively.(3)The maturity of source rocks from Benxi Formation is mature-high mature stage,and Taiyuan Formation and Shanxi Formation is high mature stage.According to hydrocarbon expulsion threshold theory,we consider large amount of natural gas generated when Rois above 1.6%.Considering the particularity of limestone source rocks,maturity and characteristics of hydrocarbon expulsion,we comprehensively consider that the limestone of Taiyuan Formation can be the effective source rocks of natural gas.
There is little research on whether hydrocarbon generation from limestone in the transitional phase of the Upper Paleozoic in the Ordos basin can be made,and on how much the hydrocarbon can be.Using rock pyrolysis,determination of TOC,carbon isotope of kerogen,organic maceral and Roexperiment,we analyzed the limestone source rocks and characteristics of hydrocarbon generation and expulsion.The results show that:(1)The source rocks from Benxi Formation,Shanxi Formation and Taiyuan Formation is poor,poor-fair,and fair-good respectively according to organic matter abundance.(2)The organic matter type of Benxi Formation,Taiyuan Formation and Shanxi Formation isⅢ,Ⅱ2-ⅢandⅢ mixed with a small quantity ofⅡ2 respectively.(3)The maturity of source rocks from Benxi Formation is mature-high mature stage,and Taiyuan Formation and Shanxi Formation is high mature stage.According to hydrocarbon expulsion threshold theory,we consider large amount of natural gas generated when Rois above 1.6%.Considering the particularity of limestone source rocks,maturity and characteristics of hydrocarbon expulsion,we comprehensively consider that the limestone of Taiyuan Formation can be the effective source rocks of natural gas.
引文
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Han,X.T.,Bao,Z.Y.,Xie,S.Y.,2016.Origin and Geochemical Characteristics of Dolomites in the Middle Permian Formation,SW Sichuan Basin,China.Earth Science,41(1):167-176(in Chinese with English abstract).https://doi.org/10.3799/dqkx.2016.013
Hao,S.S.,1984.Richness of Organic Matter and its Evolutional Characteristics in Carbonate Source Rocks.Petroleum Geology&Experiment,6(1):67-70(in Chinese with English abstract).
Huang,D.F.,Li,J.C.,1982.X-Diagram of Kerogen Classification and the Characters of Kerogen of Standard Humic Type.Geochimica,11(1):21-30(in Chinese with English abstract).
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Huo,Z.P.,Jiang,T.,Pang,X.Q.,et al.,2016.Evaluation of Deep Carbonate Source Rocks with Low TOC and Contribution to Oil-Gas Accumulation in Tazhong Area,Tarim Basin.Earth Science,41(12):2061-2074.https://doi.org/10.3799/dqkx.2016.143
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Li,J.C.,Ma,Y.S.,Zhang,D.J.,et al.,1998.Some Important Scientific Problems on Petroleum Exploration in Marine Formations of China.Petroleum Exploration and Development,25(5):1-2(in Chinese with English abstract).
Liu,D.,Yu,C.,Huang,S.P.,et al.,2015.Using Light Hydrocarbons to Identify the Depositional Environment of Source Rocks in the Ordos Basin,Central China.Energy,Exploration&Exploitation,33(6):869-890.https://doi.org/10.1260/0144-5987.33.6.869
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Liu,Y.T.,Yang,S.Y.,Hu,K.,et al.,2007.Organic Geochemical Features of Mudstone Source Rock from Member 7Strata of Middle Jurassic Age in the Northern Margin of Qaidam Basin and Its Hydrocarbon-Generation Potential.Geological Journal of China Universities,13(4):703-713(in Chinese with English abstract).
Ma,C.S.,Xu,H.Z.,Gong,C.H.,et al.,2011.Paleo-Oil Reservoir and Jingbian Natural Gasfield of Ordovician Weathering Crust in Ordos Basin.Natural Gas Geoscience,22(2):280-286.
Ma,Y.S.,2006.Marine Oil and Gas Exploration in China.Geological Publishing House,Beijing(in Chinese).
Ning,N.,Chen,M.J.,Sun,F.J.,et al.,2007.Determination and its Significance of Ancient Oil Pools in Ordovician Weathering Crust,Ordos Basin.Oil&Gas Geology,28(2):280-286(in Chinese with English abstract).
Pang,X.Q.,1995.Principle of Controlling Oil and Gas with Hydrocarbon-Expulsion Threshold and its Application.Petroleum Industry Press,Beijing(in Chinese).
Peters,K.E.,1986.Guidelines for Evaluating Petroleum Source Rock Using Programmed Pyrolysis.AAPG Bulletin,70(3):318-329.
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Qin,J.Z.,Liu,B.Q.,Zheng,L.J.,et al.,2006.Study on Capability of Hydrocarbon Generation and Expulsion from Marine Carbonate Source Rocks.Oil&GasGeology,27(3):348-355(in Chinese with English abstract).
Qin,J.Z.,Tenger,Fu,X.D.,2009.Study of Forming Condition on Marine Excellent Source Rocks and Its Evaluation.Petroleum Geology and Experiment,31(4):366-372,378(in Chinese with English abstract).
Qin,J.Z.,Zheng,L.J.,Tenger,2007.Study on the Restitution Coefficient of Original Total Organic Carbon for High Mature Marine Hydrocarbon Source Rocks.Earth Science,32(6):853-860(in Chinese with English abstract).
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