电镀污泥处理现状及进展
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摘要
电镀污泥性质复杂、危害性大,然而其中蕴藏的重金属资源丰富。在天然矿产资源日益枯竭和环境保护深入人心的背景下,科学处理电镀污泥成为研究热点。从电镀污泥的危害性和资源性出发,对国内外电镀污泥无害处置和重金属回收现状进行综述,讨论了电镀污泥处理的方向。
Electroplating sludge has a very complex and dangerous composition,while the heavy metal resources in electroplating sludge are also abundant.Under the background that the natural mineral resources are exhausted and environmental protection is more popular,scientific treatment of electroplating sludge has become a hot research topic.Based on the dangers and resources of electroplating sludge,this paper reviews the electroplating sludge treatment situation of harmless disposal and recovery of heavy metals both in home and abroad,and discusses the direction of electroplating sludge treatment.
Electroplating sludge has a very complex and dangerous composition,while the heavy metal resources in electroplating sludge are also abundant.Under the background that the natural mineral resources are exhausted and environmental protection is more popular,scientific treatment of electroplating sludge has become a hot research topic.Based on the dangers and resources of electroplating sludge,this paper reviews the electroplating sludge treatment situation of harmless disposal and recovery of heavy metals both in home and abroad,and discusses the direction of electroplating sludge treatment.
引文
[1]陈永松,周少奇.电镀污泥的基本理化特性研究[J].中国资源综合利用,2007,25(5):2-6.
[2]M ag觔lhaes J M,Silva J E,Castro F P,et al.Physical and chemical characterisation of metal finishing industrial w astes[J].Journal of Environmental M anagement,2005,75(2):157-166.
[3]石太宏,陈可.电镀重金属污泥的无害化处置和资源化利用[J].污染防治技术,2007(2):48-52.
[4]易龙生,冯泽平,汪洲,等.电镀污泥资源化处理技术综述[J].电镀与精饰,2014(12):16-20.
[5]张焕然,王俊娥.电镀污泥资源化利用及处置技术进展[J].矿产保护与利用,2016(3):73-78.
[6]苗远,王尚芝,张超,等.剩余污泥中重金属处理技术研究进展[J].四川环境,2014(4):135-139.
[7]Ayd1n A A,Ayd1n A.Development of an immobilization process for heavy metal containing galvanic solid w astes by use of sodium silicate and sodium tetraborate[J].Journal of Hazardous M aterials,2014,270:35-44.
[8]Silva A C,M ello-Castanho S R H.Vitrified galvanic w aste chemical stability[J].Journal of the European Ceramic Society,2007,27(2-3):565-570.
[9]Cioffi R,Lavorgna M,Santoro L.Environmental and technological effectiveness of a process for the stabilization of a galvanic sludge[J].Journal of Hazardous M aterials,2002.
[10]王继元.电镀重金属污泥的水泥固化处理试验研究[J].化工时刊,2006(1):44-47.
[11]涂洁,侯浩波.HAS土壤固化剂对电镀污泥处理效果的研究[J].环境工程,2003(4):44-47.
[12]LUZ C,ROCHA J,CHERIAF M,et al.Use of sulfoaluminate cement and bottom ash in the solidification/stabilization of galvanic sludge[J].Journal of Hazardous M aterials,2006,136(3):837-845.
[13]M ymrine V,Ponte M J J S,Ponte H A,et al.Oily diatomite and galvanic w astes as raw materials for red ceramics fabrication[J].Construction and Building M aterials,2013,41:360-364.
[14]张静文,徐淑红,姜佩华.电镀污泥制备陶粒的正交试验分析[J].砖瓦,2008(8):12-15.
[15]Andreola F,Barbieri L,Bondioli F,et al.Synthesis of chromium containing pigments from chromium galvanic sludges[J].Journal of Hazardous M aterials,2008,156(1-3):466-471.
[16]沈瑾.铁氧体法稳定污泥中重金属的实验研究[D].兰州:兰州交通大学,2013.
[17]季文佳,黄启飞,王琪,等.电镀污泥资源化与处置方法的研究[J].电镀与环保,2010(1):42-45.
[18]李磊,唐伟,朱渊博,等.电镀污泥的铁氧体化研究[J].现代化工,2013(10):62-65.
[19]陈丹,朱化军,钱光人,等.电镀污泥水热合成复合铁氧体与回收铜试验研究[J].环境科学学报,2007(05):873-879.
[20]黄卫东,张焕然.电镀污泥资源化利用技术及处置工艺现状[J].世界有色金属,2016(2):32-36.
[21]谭中欣,严建华,蒋旭光,等.电镀污泥焚烧过程中的热分析以及重金属的迁移规律[J].环境科学,2006(05):998-1 002.
[22]陈天明,王鑫,陆俊程,等.电镀污泥热处理过程中重金属Cu,Ni的迁移与形态变化[J].环境科学与管理,2016(5):48-50.
[23]廖昌华,孙水裕,张志.焚烧温度对电镀污泥后续处理影响研究[J].再生资源研究,2002(5):34-36.
[24]赵永超.电镀污泥焚烧预处理研究[J].河南化工,2006(9):20-21.
[25]智建辉.电镀重金属污泥综合利用研究[J].天津化工,2009(4):10-13.
[26]Espinosa D C R.Thermal behavior of chromium electroplating sludge[J].Waste M anagement,2000.
[27]党晓娥,周雪,吕军,等.螯合电镀污泥的基本理化特性及燃烧特性[J].环境科学学报,2015(11):3 762-3 768.
[28]裔兆军,严金龙,丁成.电镀污泥焚烧残渣中的Cu,Ni形态分析[J].环境工程,2012(4):80-82.
[29]李红艺,刘伟京,陈勇.电镀污泥中铜和镍的回收和资源化技术[J].中国资源综合利用,2005(12):7-10.
[30]ROSSINI G,BERNARDES A.Galvanic sludge metals recovery by pyrometallurgical and hydrometallurgical treatment[J].Journal of Hazardous M aterials,2006,131(1-3):210-216.
[31]陈娴,程洁红,顾冬梅.还原焙烧-酸浸回收电镀污泥中的铜[J].环境污染与防治,2011(06):48-51.
[32]Amaral F A D,Dos Santos V S,Bernardes A M.M etals recovery from galvanic sludge by sulfate roasting and thiosulfate leaching[J].M inerals Engineering,2014,60:1-7.
[33]郭茂新,沈晓明,楼菊青.中温焙烧/钠化氧化法回收电镀污泥中的铬[J].环境污染与防治,2009(4):21-23.
[34]齐美富,郑园芳.从电镀污泥中回收铜、镍、铬的工艺研究[J].电镀与涂饰,2010(09):43-45.
[35]郑顺.氯盐体系电镀污泥中有价金属选择性提取工艺研究[D].南昌:江西理工大学,2015.
[36]Huang R,Huang K,Lin Z,et al.Recovery of valuable metals from electroplating sludge w ith reducing additives via vitrification[J].Journal of Environmental M anagement,2013,129:586-592.
[37]Chou I,Kuo Y,Lin C,et al.Electroplating sludge metal recovering w ith vitrification using mineral pow der additive[J].Resources,Conservation and Recycling,2012,58:45-49.
[38]王静,叶海明.含铜电镀污泥中铜的资源化回收技术[J].化学工程与装备,2010(8):197-199,205.
[39]全桂香,严金龙.电镀污泥中重金属酸浸条件试验[J].环境工程,2013(2):92-95.
[40]SILVA J,SOARES D,PAIVA A,et al.Leaching behaviour of a galvanic sludge in sulphuric acid and ammoniacal media[J].Journal of Hazardous M aterials,2005,121(1-3):195-202.
[41]JandováJ,TefanováT,NiemczykováR.Recovery of Cu-concentrates from w aste galvanic copper sludges[J].Hydrometallurgy,2000.
[42]安显威,韩伟,房永广.回收电镀污泥中镍和铜的研究[J].华北水利水电学院学报,2007(1):91-93.
[43]郭学益,石文堂,李栋,等.从电镀污泥中回收镍、铜和铬的工艺研究[J].北京科技大学学报,2011(3):328-333.
[44]陈娴,程洁红,周全法,等.火法-湿法联合工艺回收电镀污泥中的铜[J].环境工程,2012(2):68-71.
[45]陈鹏,赖少弼.电镀污泥中铜镍回收技术的研究[J].广东化工,2013(3):123-124.
[46]刘建华,张焕然,王瑞祥.氨法浸出电镀废渣中镍铜的工艺[J].中国有色冶金,2011(5):73-76.
[47]胡海娇,刘定富.P2O4浮选法回收电镀污泥中的铜和镍[J].广州化工,2013(21):69-71.
[48]程洁红,陈娴,孔峰,等.氨浸-加压氢还原法回收电镀污泥中的铜和镍[J].环境科学与技术,2010(S1):135-137.
[49]张晶.生物淋滤去除电镀污泥中重金属的研究[D].太原:太原理工大学环境科学与工程,2014.
[50]Yan S,Taiping Z,M ugui L,et al.Bio-leaching of heavy metals from electroplating sludge by Thiobacillus[J].生态环境,2008,17(5).
[51]张再平,应群姣,马王钢.低品位电镀污泥对氧化亚铁硫杆菌活性的影响[J].环境工程学报,2013(9):3 555-3 560.
[52]谢鑫源,孙培德,楼菊青,等.模拟电镀污泥重金属浸出液对氧化亚铁硫杆菌活性的影响[J].环境科学,2013(1):209-216.
[53]李磊.电镀重金属污泥的资源化研究及应用[D].惠州:江南大学,2014.
[54]余训民,黄雯琦,庄田.电镀污泥中铬的无害化处理及动力学分析[J].武汉工程大学学报,2014(2):31-37.
[55]彭滨.从电镀污泥中回收铜和镍[J].广东化工,2005,32(12):59-60.
[56]祝万鹏,杨志华.溶剂萃取法回收电镀污泥中的有价金属[J].给水排水,1995(12):16-18.
[57]李强,赵峰,杨卜,等.电镀污泥多金属资源化利用研究[J].有色金属(冶炼部分),2016(4):63-65.
[58]郭学益,石文堂,李栋,等.采用旋流电积技术从电镀污泥中回收铜和镍[J].中国有色金属学报,2010(12):2425-2430.
[59]杨振宁,陈志传,高大明,等.电镀污泥中铜镍回收方法及工艺的研究[J].环境污染与防治,2008(7):58-61.
[2]M ag觔lhaes J M,Silva J E,Castro F P,et al.Physical and chemical characterisation of metal finishing industrial w astes[J].Journal of Environmental M anagement,2005,75(2):157-166.
[3]石太宏,陈可.电镀重金属污泥的无害化处置和资源化利用[J].污染防治技术,2007(2):48-52.
[4]易龙生,冯泽平,汪洲,等.电镀污泥资源化处理技术综述[J].电镀与精饰,2014(12):16-20.
[5]张焕然,王俊娥.电镀污泥资源化利用及处置技术进展[J].矿产保护与利用,2016(3):73-78.
[6]苗远,王尚芝,张超,等.剩余污泥中重金属处理技术研究进展[J].四川环境,2014(4):135-139.
[7]Ayd1n A A,Ayd1n A.Development of an immobilization process for heavy metal containing galvanic solid w astes by use of sodium silicate and sodium tetraborate[J].Journal of Hazardous M aterials,2014,270:35-44.
[8]Silva A C,M ello-Castanho S R H.Vitrified galvanic w aste chemical stability[J].Journal of the European Ceramic Society,2007,27(2-3):565-570.
[9]Cioffi R,Lavorgna M,Santoro L.Environmental and technological effectiveness of a process for the stabilization of a galvanic sludge[J].Journal of Hazardous M aterials,2002.
[10]王继元.电镀重金属污泥的水泥固化处理试验研究[J].化工时刊,2006(1):44-47.
[11]涂洁,侯浩波.HAS土壤固化剂对电镀污泥处理效果的研究[J].环境工程,2003(4):44-47.
[12]LUZ C,ROCHA J,CHERIAF M,et al.Use of sulfoaluminate cement and bottom ash in the solidification/stabilization of galvanic sludge[J].Journal of Hazardous M aterials,2006,136(3):837-845.
[13]M ymrine V,Ponte M J J S,Ponte H A,et al.Oily diatomite and galvanic w astes as raw materials for red ceramics fabrication[J].Construction and Building M aterials,2013,41:360-364.
[14]张静文,徐淑红,姜佩华.电镀污泥制备陶粒的正交试验分析[J].砖瓦,2008(8):12-15.
[15]Andreola F,Barbieri L,Bondioli F,et al.Synthesis of chromium containing pigments from chromium galvanic sludges[J].Journal of Hazardous M aterials,2008,156(1-3):466-471.
[16]沈瑾.铁氧体法稳定污泥中重金属的实验研究[D].兰州:兰州交通大学,2013.
[17]季文佳,黄启飞,王琪,等.电镀污泥资源化与处置方法的研究[J].电镀与环保,2010(1):42-45.
[18]李磊,唐伟,朱渊博,等.电镀污泥的铁氧体化研究[J].现代化工,2013(10):62-65.
[19]陈丹,朱化军,钱光人,等.电镀污泥水热合成复合铁氧体与回收铜试验研究[J].环境科学学报,2007(05):873-879.
[20]黄卫东,张焕然.电镀污泥资源化利用技术及处置工艺现状[J].世界有色金属,2016(2):32-36.
[21]谭中欣,严建华,蒋旭光,等.电镀污泥焚烧过程中的热分析以及重金属的迁移规律[J].环境科学,2006(05):998-1 002.
[22]陈天明,王鑫,陆俊程,等.电镀污泥热处理过程中重金属Cu,Ni的迁移与形态变化[J].环境科学与管理,2016(5):48-50.
[23]廖昌华,孙水裕,张志.焚烧温度对电镀污泥后续处理影响研究[J].再生资源研究,2002(5):34-36.
[24]赵永超.电镀污泥焚烧预处理研究[J].河南化工,2006(9):20-21.
[25]智建辉.电镀重金属污泥综合利用研究[J].天津化工,2009(4):10-13.
[26]Espinosa D C R.Thermal behavior of chromium electroplating sludge[J].Waste M anagement,2000.
[27]党晓娥,周雪,吕军,等.螯合电镀污泥的基本理化特性及燃烧特性[J].环境科学学报,2015(11):3 762-3 768.
[28]裔兆军,严金龙,丁成.电镀污泥焚烧残渣中的Cu,Ni形态分析[J].环境工程,2012(4):80-82.
[29]李红艺,刘伟京,陈勇.电镀污泥中铜和镍的回收和资源化技术[J].中国资源综合利用,2005(12):7-10.
[30]ROSSINI G,BERNARDES A.Galvanic sludge metals recovery by pyrometallurgical and hydrometallurgical treatment[J].Journal of Hazardous M aterials,2006,131(1-3):210-216.
[31]陈娴,程洁红,顾冬梅.还原焙烧-酸浸回收电镀污泥中的铜[J].环境污染与防治,2011(06):48-51.
[32]Amaral F A D,Dos Santos V S,Bernardes A M.M etals recovery from galvanic sludge by sulfate roasting and thiosulfate leaching[J].M inerals Engineering,2014,60:1-7.
[33]郭茂新,沈晓明,楼菊青.中温焙烧/钠化氧化法回收电镀污泥中的铬[J].环境污染与防治,2009(4):21-23.
[34]齐美富,郑园芳.从电镀污泥中回收铜、镍、铬的工艺研究[J].电镀与涂饰,2010(09):43-45.
[35]郑顺.氯盐体系电镀污泥中有价金属选择性提取工艺研究[D].南昌:江西理工大学,2015.
[36]Huang R,Huang K,Lin Z,et al.Recovery of valuable metals from electroplating sludge w ith reducing additives via vitrification[J].Journal of Environmental M anagement,2013,129:586-592.
[37]Chou I,Kuo Y,Lin C,et al.Electroplating sludge metal recovering w ith vitrification using mineral pow der additive[J].Resources,Conservation and Recycling,2012,58:45-49.
[38]王静,叶海明.含铜电镀污泥中铜的资源化回收技术[J].化学工程与装备,2010(8):197-199,205.
[39]全桂香,严金龙.电镀污泥中重金属酸浸条件试验[J].环境工程,2013(2):92-95.
[40]SILVA J,SOARES D,PAIVA A,et al.Leaching behaviour of a galvanic sludge in sulphuric acid and ammoniacal media[J].Journal of Hazardous M aterials,2005,121(1-3):195-202.
[41]JandováJ,TefanováT,NiemczykováR.Recovery of Cu-concentrates from w aste galvanic copper sludges[J].Hydrometallurgy,2000.
[42]安显威,韩伟,房永广.回收电镀污泥中镍和铜的研究[J].华北水利水电学院学报,2007(1):91-93.
[43]郭学益,石文堂,李栋,等.从电镀污泥中回收镍、铜和铬的工艺研究[J].北京科技大学学报,2011(3):328-333.
[44]陈娴,程洁红,周全法,等.火法-湿法联合工艺回收电镀污泥中的铜[J].环境工程,2012(2):68-71.
[45]陈鹏,赖少弼.电镀污泥中铜镍回收技术的研究[J].广东化工,2013(3):123-124.
[46]刘建华,张焕然,王瑞祥.氨法浸出电镀废渣中镍铜的工艺[J].中国有色冶金,2011(5):73-76.
[47]胡海娇,刘定富.P2O4浮选法回收电镀污泥中的铜和镍[J].广州化工,2013(21):69-71.
[48]程洁红,陈娴,孔峰,等.氨浸-加压氢还原法回收电镀污泥中的铜和镍[J].环境科学与技术,2010(S1):135-137.
[49]张晶.生物淋滤去除电镀污泥中重金属的研究[D].太原:太原理工大学环境科学与工程,2014.
[50]Yan S,Taiping Z,M ugui L,et al.Bio-leaching of heavy metals from electroplating sludge by Thiobacillus[J].生态环境,2008,17(5).
[51]张再平,应群姣,马王钢.低品位电镀污泥对氧化亚铁硫杆菌活性的影响[J].环境工程学报,2013(9):3 555-3 560.
[52]谢鑫源,孙培德,楼菊青,等.模拟电镀污泥重金属浸出液对氧化亚铁硫杆菌活性的影响[J].环境科学,2013(1):209-216.
[53]李磊.电镀重金属污泥的资源化研究及应用[D].惠州:江南大学,2014.
[54]余训民,黄雯琦,庄田.电镀污泥中铬的无害化处理及动力学分析[J].武汉工程大学学报,2014(2):31-37.
[55]彭滨.从电镀污泥中回收铜和镍[J].广东化工,2005,32(12):59-60.
[56]祝万鹏,杨志华.溶剂萃取法回收电镀污泥中的有价金属[J].给水排水,1995(12):16-18.
[57]李强,赵峰,杨卜,等.电镀污泥多金属资源化利用研究[J].有色金属(冶炼部分),2016(4):63-65.
[58]郭学益,石文堂,李栋,等.采用旋流电积技术从电镀污泥中回收铜和镍[J].中国有色金属学报,2010(12):2425-2430.
[59]杨振宁,陈志传,高大明,等.电镀污泥中铜镍回收方法及工艺的研究[J].环境污染与防治,2008(7):58-61.