膨胀蛭石包覆聚苯乙烯发泡颗粒/水泥复合泡沫材料的制备及性能
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摘要
利用环氧树脂将膨胀蛭石黏附在聚苯乙烯发泡(EPS)颗粒表面上,制备表面无机化包覆的EPS颗粒(CEPS),将其与水泥胶凝材料混合,制备CEPS/水泥复合泡沫材料.探讨膨胀蛭石的包覆量及CEPS颗粒用量等对复合泡沫材料的力学性能和保温性能的影响,并采用锥形量热法和喷枪火焰燃烧法研究了复合泡沫材料的防火性能.研究结果表明,复合泡沫的抗折强度、抗压强度、干密度和导热系数均随包覆量的增大而增加;当CEPS颗粒用量为1000 m L时,复合泡沫材料的干密度和导热系数较低,分别为269.3 kg/m~3和0.0544 W/(m·K),抗折强度和抗压强度相对较高.锥形量热实验结果表明,随着包覆量的增加,复合泡沫的最大热释放速率、总放热量和烟释放量都逐渐降低,着火时间逐渐延长.喷枪火焰燃烧法实验结果表明,除了复合泡沫断面上与火焰接触的表面裸露的EPS颗粒燃尽外,燃烧后断面结构都能够保持比较完整.
Expanded polystyrene( EPS) particles were encapsulated with epoxy resin and then with expanded vermiculite( EV) to obtain surface inorganically modified EPS( CEPS) particles. The CEPS particles were mixed with cement,water and other additives,and cured at room temperature to prepare CEPS/cement composite foams. The effects of the coating amount and CEPS content on mechanical properties and insulation performance of the composite foams were investigated,and the fire resistance of composite foam materials was also studied by cone calorimetry and butane flame spray combustion. The results show that the flexural strength,compressive strength,dry density and thermal conductivity of the composite foams increase with the increase of the coating amount. The composite foam with 1000 m L of CEPS has lower dry density and thermal conductivity,which are 269. 3 kg/m~3 and 0. 0544 W/( m · K),respectively,and the flexural strength and compressive strength of the composite foam are relatively high. The cone calorimeter test results show that the peak heat release rate,total heat release and total smoke release of the composite foams are decreased gradually with the increase of the coating amount,and the ignition time of the foams is prolonged. The results of butane flame spray combustion indicate that the fractured surface of the composite foams can be maintained intact after burning,and only the EPS beads exposed on the fractured surface of the composite foams are burned out.
Expanded polystyrene( EPS) particles were encapsulated with epoxy resin and then with expanded vermiculite( EV) to obtain surface inorganically modified EPS( CEPS) particles. The CEPS particles were mixed with cement,water and other additives,and cured at room temperature to prepare CEPS/cement composite foams. The effects of the coating amount and CEPS content on mechanical properties and insulation performance of the composite foams were investigated,and the fire resistance of composite foam materials was also studied by cone calorimetry and butane flame spray combustion. The results show that the flexural strength,compressive strength,dry density and thermal conductivity of the composite foams increase with the increase of the coating amount. The composite foam with 1000 m L of CEPS has lower dry density and thermal conductivity,which are 269. 3 kg/m~3 and 0. 0544 W/( m · K),respectively,and the flexural strength and compressive strength of the composite foam are relatively high. The cone calorimeter test results show that the peak heat release rate,total heat release and total smoke release of the composite foams are decreased gradually with the increase of the coating amount,and the ignition time of the foams is prolonged. The results of butane flame spray combustion indicate that the fractured surface of the composite foams can be maintained intact after burning,and only the EPS beads exposed on the fractured surface of the composite foams are burned out.
引文
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[16]Xiao J.Z.,Song Z.W.,Zhang F.,Journal of Building Materials,2010,13(1),17—21(肖建庄,宋志文,张枫.建筑材料学报,2010,13(1),17—21)
[17]Ramamurthy K.,Kunhanandan Nambiar E.K.,Indu Siva Ranjani G.,Cement&Concrete Composites,2009,(31),388—396
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[19]Posi P.,Ridtirud C.,Ekvong C.,Chammanee D.,Janthowong K.,Chindaprasirt P.,Construction and Building Materials,2015,(94),408—413
[20]Scudamore M.J.,Briggs P.J.,Prager F.H.,Fire and Materials,1991,15,65—84
[21]Cui J.,Li M.,Wang J.,Chu D.Z.,Zhang J.,Science and Technology of Safety Product,2017,13(6),47—52(崔箭,李明,王劫,初道忠,张军.中国安全生产科学技术,2017,13(6),47—52)
[22]Zhou Y.,Zhi M.,Fire Technology and Product Information,2013,(8),34—36(周游,支明.消防技术与产品信息,2013,(8),34—36)
[2]Zhang J.S.,Jin L.,Zhu L.,Liaoning Building Materials,2011,(2),17—22(张巨松,金亮,朱林.辽宁建材,2011,(2),17—22)
[3]Ferrandiz-Mas V.,Garcia-Alcocel E.,Materials and Construction,2012,62(308),547—566
[4]Yang F.Y.,Lu Z.Y.,He S.A.,Niu Y.H.,Concrete and Cement Products,2012,193(5),9—12(杨奉源,卢忠远,何顺爱,牛云辉.混凝土与水泥制品,2012,193(5),9—12)
[5]Ayse K.,Filiz K.,Construction and Building Materials,2016,(105),72—578
[6]Sri Ravindrarajah R.,Tuck A.J.,Cement&Concrete Composites,1994,(16),272—277
[7]Yi S.L.,Guo Y.S.,Wang X.L.,New Building Materials,2006,35—38(易松林,郭玉顺,王贤磊.新型建筑材料,2006,35—38)
[8]Zhou Z.F.,Wang S.M.,New Building Materials,2008,(7),21—24(周竹发,王淑梅.新型建筑材料,2008,(7),21—24)
[9]Perry S.H.,Bischsff P.H.,Yamura K.,Mag.Concr.Res.,1991,43,71—76
[10]Johari I.,Hamid A.,Lasim S.R.,Ahmad Z.A.,Materials Science Forum,2017,(888),234—238
[11]Hu X.,Huang S.W.,Zhang S.H.,Zeng L.,New Building Materials,2008,11,42—44(胡欣,黄少文,章少华,曾亮.新型建筑材料,2008,11,42—44)
[12]Zhang C.L.,Wang T.,Yang G.,Yu J.Y.,Block-Brick-Tile,2015,(3),5—8(章灿林,汪婷,杨光,余剑英.砖瓦,2015,(3),5—8)
[13]Wang Z.Z.,Yang T.,Shi Y.L.,Inorganic/organic Double Layer Coated Expanded Polystyrene Granule and Its Preparation,CN201611143113.2,2017-05-31(王正洲,杨婷,史逸伦.一种无机/有机双层包覆聚苯乙烯发泡颗粒及其制备方法,CN201611143113.2,2017-05-31)
[14]Chen L.F.,Chen Y.,Li L.,Lu Y.,Bulletin of the Chinese Ceramic Society,2015,34(10),2822—2828(陈连发,陈悦,李龙,陆洋.硅酸盐通报,2015,34(10),2822—2828)
[15]Gong J.Q.,Sun K.Q.,Journal of Hunan University(Natural Science Edition),2017,44(1),143—149(龚建清,孙凯强.湖南大学学报(自然科学版),2017,44(1),143—149)
[16]Xiao J.Z.,Song Z.W.,Zhang F.,Journal of Building Materials,2010,13(1),17—21(肖建庄,宋志文,张枫.建筑材料学报,2010,13(1),17—21)
[17]Ramamurthy K.,Kunhanandan Nambiar E.K.,Indu Siva Ranjani G.,Cement&Concrete Composites,2009,(31),388—396
[18]Kan A.,Demirboga R.,Indian Journal of Engineering&Materials Science,2007,(14),158—162
[19]Posi P.,Ridtirud C.,Ekvong C.,Chammanee D.,Janthowong K.,Chindaprasirt P.,Construction and Building Materials,2015,(94),408—413
[20]Scudamore M.J.,Briggs P.J.,Prager F.H.,Fire and Materials,1991,15,65—84
[21]Cui J.,Li M.,Wang J.,Chu D.Z.,Zhang J.,Science and Technology of Safety Product,2017,13(6),47—52(崔箭,李明,王劫,初道忠,张军.中国安全生产科学技术,2017,13(6),47—52)
[22]Zhou Y.,Zhi M.,Fire Technology and Product Information,2013,(8),34—36(周游,支明.消防技术与产品信息,2013,(8),34—36)