有机泡沫浸渍法氧化铝多孔陶瓷制备研究
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摘要
有机泡沫浸渍法是当前制备多孔陶瓷最为常见的一种工艺,因其可以制备出气孔分布均匀、气孔率超高、贯通且结构为三维立体网络状的多孔陶瓷。本文研究了添加不同种类以及不同含量的分散剂对α-Al2O3在悬浮液中稳定性的影响,结果表明当固含量为5 wt%时,选用阿拉伯树胶分散剂、且添加量为0.8 wt%时,α-Al2O3悬浮液的稳定性最佳。为了有效降低氧化铝陶瓷的烧结温度,通过实验研究选择的助烧剂质量比为2:1的Si O2/Cu O,添加量为3 wt%。使用气孔率分别为75%、80%、95%的有机泡沫模板,在固含量选取为30 wt%的悬浮液中浸渍后干燥,最后在1200℃烧结2 h,分别制备得到了气孔率为65%、72%、93%的多孔氧化铝陶瓷。
The polymeric sponge impregnation process is the most common process of the preparation of porous ceramics,since this method can prepare porous ceramics with uniform pore distribution, through holes,three-dimensional network structure and high porosity porous ceramic.This paper studies the effect of different types and different dosage of dispersants on the stability of α-Al2O3 powders in the suspension. The results show when the solid content was 5 wt%, gum arabic was chosen as the dispersant and its dosage was 0.8wt%, α-Al2O3 powders in the suspension had the best stability after laying aside for 12 hours. In order to lower the sintering temperature of the alumina ceramic, sintering aids of Si O2/Cu O with a weight ratio of 2:1 and dosage of 3 wt%, were added in the starting materials. When the PU foams with porosity of75%, 80%, 95% respectively were used as the templates, and the solid content of the suspension was 30wt%, porous alumina ceramic with porosity of 65%, 72%, 93% respectively were prepared. In a word, the organic foam impregnation method is a ceramic preparation process which can achieve the control of porosity in a large range.
The polymeric sponge impregnation process is the most common process of the preparation of porous ceramics,since this method can prepare porous ceramics with uniform pore distribution, through holes,three-dimensional network structure and high porosity porous ceramic.This paper studies the effect of different types and different dosage of dispersants on the stability of α-Al2O3 powders in the suspension. The results show when the solid content was 5 wt%, gum arabic was chosen as the dispersant and its dosage was 0.8wt%, α-Al2O3 powders in the suspension had the best stability after laying aside for 12 hours. In order to lower the sintering temperature of the alumina ceramic, sintering aids of Si O2/Cu O with a weight ratio of 2:1 and dosage of 3 wt%, were added in the starting materials. When the PU foams with porosity of75%, 80%, 95% respectively were used as the templates, and the solid content of the suspension was 30wt%, porous alumina ceramic with porosity of 65%, 72%, 93% respectively were prepared. In a word, the organic foam impregnation method is a ceramic preparation process which can achieve the control of porosity in a large range.
引文
[1]李飞舟.有机泡沫浸渍法制备氧化铝多孔陶瓷的研究[D].西安:长安大学,2011.
[2]王苏新.多孔陶瓷的制备方法及用途[J].江苏陶瓷,2002,35(4):26~28.
[3]秦旭芝.矿物多孔材料的制备及其性能研究[D].桂林:广西大学,2008.
[2]王苏新.多孔陶瓷的制备方法及用途[J].江苏陶瓷,2002,35(4):26~28.
[3]秦旭芝.矿物多孔材料的制备及其性能研究[D].桂林:广西大学,2008.