压敏胶黏剂研究进展
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摘要
综述了几类压敏胶黏剂(包括橡胶型压敏胶、热塑弹性体型压敏胶、丙烯酸酯型压敏胶、有机硅型压敏胶及聚氨酯型压敏胶等)的结构、性能特点及其研究现状,并指出采用本体法的UV-LED引发、交联的压敏胶黏剂是一种节能、环保型压敏胶,也是今后的发展方向。
Several kinds of structure and performance characteristics of the pressure sensitive adhesives, including rubber type, thermoplastic elastomer type, acrylic type, silicone type and polyurethane type were reviewed. It is pointed out that the pressure sensitive adhesive initiated and crosslinked by bulk method, UV-LED is a kind of energy-saving and environment-friendly pressure sensitive adhesive, which is also the development direction in the future.
Several kinds of structure and performance characteristics of the pressure sensitive adhesives, including rubber type, thermoplastic elastomer type, acrylic type, silicone type and polyurethane type were reviewed. It is pointed out that the pressure sensitive adhesive initiated and crosslinked by bulk method, UV-LED is a kind of energy-saving and environment-friendly pressure sensitive adhesive, which is also the development direction in the future.
引文
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[2]杨玉崑.压敏胶粘剂[M].北京:科学出版社,1991:8-9.
[3]Sadequl A M,Ishiaku U S,Poh B T.Cure index and activation energy of ENR-25 compared with SMR-L in various vulcanization systems[J].European Polymer Journal,1999,35:711-719.
[4]Kumooka Y.Discrimination of rubber-based pressure sensitive adhesives by size exclusion chromatography[J].Forensic Science International,2007,171(1):5-8.
[5]Poh B T,The Y Y.Adhesion properties of(epoxidized natural rubber)/(ethylene-propylene-diene rubber)blend adhesive:Effect of blend ratio and testing rate[J].Journal of Vinyl and Additive Technology,2016,22(2):134-139.
[6]Suid N H,Poh B T.Effect of zinc oxide on the viscosity and adhesion property of epoxidized natural rubber/acrylonitrilebutadiene rubber-based pressure-sensitive adhesives[J].Journal of Vinyl and Additive Technology,2016,22(4):410-414.
[7]Poh B T,Lim C H.Effect of cross-linking on adhesion property of benzoyl-peroxide-cured epoxidized natural rubber(ENR 50)adhesives[J].Journal of Elastomers&Plastics,2014,46(2):187-198.
[8]王承潇,汤秀珍,沈平孃,等.热熔压敏胶应用于中药贴剂的研究进展[J].中草药,2010,41(3):496-499.
[9]吴国梁.热塑性弹性体SBS的改性及其应用研究[D].长沙:湖南大学,2010.
[10]Phillips J P,Xiao D,Stephen R R,et al.Nano and bulk-tack adhesives properties of stimuli-responsive,fullerene-polymer blends containing polystyrene-block-polybutadiene-blockpolystyrene and polystyrene-block-polyisoprene-blockpolystyrene rubber-based adhesives[J].Polymer,2007,48(23):6 773-6 781.
[11]Wu G H,Jiang Y,Ye L,et al.A novel UV-crosslinked pressure-sensitive adhesive based on photoinitiator-grafted SBS[J].International Journal of Adhesion and Adhesives,2010,30(1):43-46.
[12]Zhao Z F,Liu P Y,Zhang C Q,et al.Synthesis and structureproperty relationships of SIS-g-PB copolymers and their application in hot-melt pressure-sensitive adhesives[J].RSCAdvances,2017,7(70):44 068-44 075.
[13]Shen H Z,Zhang J Y,Liu S J,et al.Effect of the chaintransfer-agent content on the emulsion polymerization process and adhesive properties of poly(n-butyl acrylate-coacrylicacid)latexes[J].Journal of Applied Polymer Science,2008,107(35):1 793-1 802.
[14]Xu H P,Wang N Y,Qu T G,et al.Eect of the MMA content on the emulsion polymerization process and adhesive properties of poly(BA-co-MMA-co-AA)latexes[J].Journal of Applied Polymer Science,2012,123(2):1 068-1 078.
[15]翟珍,张广林,姚艳梅,等.不同粒径聚丙烯酸酯乳液的制备及共混物压敏特性[J].高分子材料科学与工程,2011,27(1):35-38.
[16]韩君.反光膜用溶剂型聚丙烯酸酯压敏胶的研究[J].中国胶粘剂,2017,26(11):35-38.
[17]翟亚峰,闫沙沙,高建宾.电子保护膜用溶剂型压敏胶的制备[J].广东化工,2017,44(16):79-80.
[18]Marta W.The crosslinking reaction of acrylic PSA using chelate metal acetylacetonates[J].European Polymer Journal,2006,42(9):2 153-2 160.
[19]Zhang X,Ding Y,Zhang G.Preparation and rheological studies on the solvent based acrylic pressure sensitive adhesives with different crosslinking density[J].International Journal of Adhesion and Adhesives,2011,31(7):760-766.
[20]杨秀珍,王成潇,张皓,等.星点设计-效应面法优化关节止痛膏贴剂处方[J].中草药,2012,43(1):86-90.
[21]贺贝贝,解一军.紫外光本体聚合制备丙烯酸酯压敏胶[J].化工进展,2017,36(12):4 508-4 512.
[22]Czech Z,Butwin A,Kabatc J.Photoreactive UV crosslinkable acrylic pressuer-sensitive adhesives containing type-IIphotoinitiators[J].European Polymer Journal,2011,47(2):225-229.
[23]Kabatc J,Czech Z,Kowalczyk A.The applicationof halomethyl 1,3,5-triazine as a photoinitiator or coinitiator for acrylate monomer polymerization[J].Journal of Photochemistry and Photobiology A:Chemistry,2011,219(1):16-25.
[24]Yamaguchi S,Hasuo R,Kawahara S,et al.“Cool off”function of a silicone pressure-sensitive adhesive containing a side-chain crystalline polysiloxane[J].Chemistry Letters,2016,45(4):466-468.
[25]黄振宏,陈志亮,陆文灿.MQ硅树脂及其在医用压敏胶领域的应用[J].有机硅材料,2017,31(S1):45-47.
[26]李坚辉,刘彩召,张斌,等.硅氢加成和自由基双交联有机硅压敏胶的研究[J].中国胶粘剂,2017,26(6):31-34.
[27]周传玉,陶林华,黄俊鹏,等.聚氨酯压敏胶的合成与性能研究[J].涂料工业,2015,45(1):76-80.