气体水合物的研究概述
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摘要
气体水合物是能源开采以及化学工业生产过程中常见的物质。本文综述了水合物的形成机理和分子结构,对水合物的分析、合成与分解的研究,以及水合物的应用与防治等。在形成机理方面主要介绍了水合物的成核过程和生长过程的模型,在水合物的分析方面,主要介绍了对水合物组成和水合物结构的分析方法。
Gas hydrate was a kind of material which was usually seen during energy extraction or the process of chemical industry.This paper reviewed the formation mechanism of gas hydrate,the molecular structure of gas hydrate and the research on analysis,synthetic and resolve of gas hydrate.The use and the prevention of gas hydrate was summarized.In the aspect of the formation mechanism,the process of nucleus formation and the growth of gas hydrate were introduced.In the aspect of analysis of gas hydrate,the analysis methods for the composition and structure of gas hydrate was introduced.
Gas hydrate was a kind of material which was usually seen during energy extraction or the process of chemical industry.This paper reviewed the formation mechanism of gas hydrate,the molecular structure of gas hydrate and the research on analysis,synthetic and resolve of gas hydrate.The use and the prevention of gas hydrate was summarized.In the aspect of the formation mechanism,the process of nucleus formation and the growth of gas hydrate were introduced.In the aspect of analysis of gas hydrate,the analysis methods for the composition and structure of gas hydrate was introduced.
引文
[1]孙长宇,陈光进,郭天民.水合物成核动力学研究现状[J].石油学报,2001(4):82-86.
[2]Sloan E D,Fleyfel F.A molecular mechanism for gas hydrate nucleation from ice[J].AIChE J.,1991,37(9):1281-1292.
[3]Christiansen R L,Sloan E D.Mechanisms and kinetics of hydrate formation[A].In:Sloan E D,Happel J,Hnatow M A.International conference on natural gas hydrates[C].Annals of Nwe York Academy of Sciences,1994,715:283-305.
[4]Long J P.Gas hydrate formation mechanism and kinetic inhibition[D].Ph.D.Thesis,T-4265,Colorado School of Mines,Golden,CO,1994.
[5]BufFett BA.Clathrate hydrates[J].Annu.Rev.Earth Planet.Sci.,2000,28:477-507.
[6]白冬生.气体水合物成核与生长的分子动力学模拟研究[D].北京:北京化工大学,2013.
[7]孙长宇,黄强,陈光进.气体水合物形成的热力学与动力学研究进展[J].化工学报,2006(5):1031-1039.
[8]刘昌岭,业渝光.海洋天然气水合物实验分析技术[J].海洋地质动态,2008,24(11):13-16.
[9]张凌,蒋国盛,宁伏龙,吴翔,窦斌,涂运中.国外天然气水合物岩心处理分析技术综述[J].地质科技情报,2009,28(1):123-126.
[10]Stern L A,Circone S,Kirby S H,Durham W B.Anomalous preservation of pure methane hydrate at 1atm[J].The Journal of Physical Chemistry B,2001,105(9):1756-1762.
[11]Gudmundsson J S,Parlaktuna M.Storage of Natural Gas Hydrate at Refrigerated Conditons[Z].AICHE Spring National Meeting,1992:27-32.
[12]Uchida T,Moriwaki M,Takeya S,Ikeda I Y,Ohmura R,Nagao J,Minagawa H,Ebinuma T,Narita H,Gohara K,Mae S.Two-step formation of methane propane mixed gas hydrates in a batch-type reactor[J].AICh E Journal,2004,50(2):518-523.
[13]Takeya S,Shimada W,Kamata Y,Ebinuma T,UchidaT,Nagao J,Narita H.In situ X-ray diffractionmeasurements of the self-preservation effect of CH4 hydrate[J].The Journal of Physical Chemistry A,2001,105(42):9756-9759.
[14]Subramanian S,Sloan E D.Fluid Phase Equilibria,1999,158-160(6):813.
[15]Simon R.Davies,E.Dendy Sloan,Amadeu K.Sum,Carolyn A.Koh.In situ studies of the mass transfer mechanism across a methane hydrate film using high-resolution confocal Raman spectroscopy[J].Journal of Physical Chemistry C,2010,14(2):1173-1180.
[16]Komai T,Kang S P,Yoon J H,Yamamoto Y,Kawamura T,Ohtake M.In Situ Raman Spectroscopy Investigation of the Dissociation of Methane Hydrate at Temperatures Just below the Ice Point[J].The Journal of Physical Chemistry B,2004,108(23):8062-8068.
[17]Subramanian S,Kini R A,Dec S F,et al.Evidence of structure II hydrate formation from methane+ethane mixtures[J].Chemical Engineering Science,2000,55(11):1981-1999.
[18]刘昌岭,孟庆国,业渝光.固体核磁共振技术在气体水合物研究中的应用[J].波谱学杂志,2012(3):465-474.
[19]Ripmeester J A,Tse J S,Ratcliffe C I,et al.A new clathrate hydrate structure[J].Nature,1987,325:135.
[20]Ripmeester J A,Ratcliffe C I.129Xe NME studies of clathrate hydrate new guests for structure II and structure H[J].J.Phys.Chem.,1990,94(25):8773.
[21]贺行良.天然气水合物气体组成分析方法研究与应用[D].青岛:中国海洋大学,2012.
[22]Guilbot P,Valtz A,Legendre H,et al.Rapid on-line sampler-injector:a reliable tool for HT-HP sampling and on-line GC analysis[J].Analusis,2000,28(5):426-431.
[23]贺行良,刘昌岭,王江涛,张媛媛,孟庆国.气相色谱-同位素比值质谱法测定天然气水合物气体单体碳氢同位素[J].岩矿测试,2012,31(1):154-158.
[24]赵义,丁静,杨晓西,叶国兴.天然气水合物及其生成促进与抑制研究进展[J].天然气工业,2004(12):132-134.
[25]王安印,诸林,王治红,郑蓉.二氧化碳水合物促进剂的研究进展[J].应用化工,2013,42(11):2068-2071.
[26]王书淼,吴明,王国付,刘宏波.管内天然气水合物抑制剂的应用研究[J].油气储运,2006(2):43-46.
[27]白净,李凌乾,刘风莉,陈俊英,常春,方书起,韩秀丽,刘金盾,张小水.机械扰动强化气体水合物快速生成研究进展[J].化工进展,2018,37(1):60-67.
[28]喻平.油气储运技术及其创新研究[J].化工管理,2018(17):82-83.
[29]巩艳.水合物法储运天然气技术[J].内蒙古石油化工,2017,43(10):93-95.
[30]Bachu S,Adams JJ.Sequestration of CO2 in geological media in response to climate change:capacity of deep saline aquifers to sequester CO2 in solution[J].Energy Convers.Manage.,2003,44:3151-3175.
[31]孟凡飞,张雁玲.可用于炼厂气综合利用的水合物分离技术研究进展[J].石油化工,2017,46(7):944-952.
[32]樊栓狮,郭开华.从催化裂化干气中分离回收乙烯的方法及装置:CN,1301 684A[P].2001-07-04.
[33]郭望.天然气水合物冻堵分解技术探究[J].石化技术,2018,25(4):37.
[34]张敬升.浅冷油吸收工艺回收炼油厂饱和干气的模拟[J].石油化工,2014,43(9):1069-1075.
[35]张敬升,李东风,过良,刘智信.浅冷油吸收技术在炼厂饱和干气回收中的应用[J].石油石化绿色低碳,2018(4):16-20.
[36]高敦仁.中冷油吸收法回收炼厂烯烃技术经济比较[J].石油化工,1991(7):481-487.
[2]Sloan E D,Fleyfel F.A molecular mechanism for gas hydrate nucleation from ice[J].AIChE J.,1991,37(9):1281-1292.
[3]Christiansen R L,Sloan E D.Mechanisms and kinetics of hydrate formation[A].In:Sloan E D,Happel J,Hnatow M A.International conference on natural gas hydrates[C].Annals of Nwe York Academy of Sciences,1994,715:283-305.
[4]Long J P.Gas hydrate formation mechanism and kinetic inhibition[D].Ph.D.Thesis,T-4265,Colorado School of Mines,Golden,CO,1994.
[5]BufFett BA.Clathrate hydrates[J].Annu.Rev.Earth Planet.Sci.,2000,28:477-507.
[6]白冬生.气体水合物成核与生长的分子动力学模拟研究[D].北京:北京化工大学,2013.
[7]孙长宇,黄强,陈光进.气体水合物形成的热力学与动力学研究进展[J].化工学报,2006(5):1031-1039.
[8]刘昌岭,业渝光.海洋天然气水合物实验分析技术[J].海洋地质动态,2008,24(11):13-16.
[9]张凌,蒋国盛,宁伏龙,吴翔,窦斌,涂运中.国外天然气水合物岩心处理分析技术综述[J].地质科技情报,2009,28(1):123-126.
[10]Stern L A,Circone S,Kirby S H,Durham W B.Anomalous preservation of pure methane hydrate at 1atm[J].The Journal of Physical Chemistry B,2001,105(9):1756-1762.
[11]Gudmundsson J S,Parlaktuna M.Storage of Natural Gas Hydrate at Refrigerated Conditons[Z].AICHE Spring National Meeting,1992:27-32.
[12]Uchida T,Moriwaki M,Takeya S,Ikeda I Y,Ohmura R,Nagao J,Minagawa H,Ebinuma T,Narita H,Gohara K,Mae S.Two-step formation of methane propane mixed gas hydrates in a batch-type reactor[J].AICh E Journal,2004,50(2):518-523.
[13]Takeya S,Shimada W,Kamata Y,Ebinuma T,UchidaT,Nagao J,Narita H.In situ X-ray diffractionmeasurements of the self-preservation effect of CH4 hydrate[J].The Journal of Physical Chemistry A,2001,105(42):9756-9759.
[14]Subramanian S,Sloan E D.Fluid Phase Equilibria,1999,158-160(6):813.
[15]Simon R.Davies,E.Dendy Sloan,Amadeu K.Sum,Carolyn A.Koh.In situ studies of the mass transfer mechanism across a methane hydrate film using high-resolution confocal Raman spectroscopy[J].Journal of Physical Chemistry C,2010,14(2):1173-1180.
[16]Komai T,Kang S P,Yoon J H,Yamamoto Y,Kawamura T,Ohtake M.In Situ Raman Spectroscopy Investigation of the Dissociation of Methane Hydrate at Temperatures Just below the Ice Point[J].The Journal of Physical Chemistry B,2004,108(23):8062-8068.
[17]Subramanian S,Kini R A,Dec S F,et al.Evidence of structure II hydrate formation from methane+ethane mixtures[J].Chemical Engineering Science,2000,55(11):1981-1999.
[18]刘昌岭,孟庆国,业渝光.固体核磁共振技术在气体水合物研究中的应用[J].波谱学杂志,2012(3):465-474.
[19]Ripmeester J A,Tse J S,Ratcliffe C I,et al.A new clathrate hydrate structure[J].Nature,1987,325:135.
[20]Ripmeester J A,Ratcliffe C I.129Xe NME studies of clathrate hydrate new guests for structure II and structure H[J].J.Phys.Chem.,1990,94(25):8773.
[21]贺行良.天然气水合物气体组成分析方法研究与应用[D].青岛:中国海洋大学,2012.
[22]Guilbot P,Valtz A,Legendre H,et al.Rapid on-line sampler-injector:a reliable tool for HT-HP sampling and on-line GC analysis[J].Analusis,2000,28(5):426-431.
[23]贺行良,刘昌岭,王江涛,张媛媛,孟庆国.气相色谱-同位素比值质谱法测定天然气水合物气体单体碳氢同位素[J].岩矿测试,2012,31(1):154-158.
[24]赵义,丁静,杨晓西,叶国兴.天然气水合物及其生成促进与抑制研究进展[J].天然气工业,2004(12):132-134.
[25]王安印,诸林,王治红,郑蓉.二氧化碳水合物促进剂的研究进展[J].应用化工,2013,42(11):2068-2071.
[26]王书淼,吴明,王国付,刘宏波.管内天然气水合物抑制剂的应用研究[J].油气储运,2006(2):43-46.
[27]白净,李凌乾,刘风莉,陈俊英,常春,方书起,韩秀丽,刘金盾,张小水.机械扰动强化气体水合物快速生成研究进展[J].化工进展,2018,37(1):60-67.
[28]喻平.油气储运技术及其创新研究[J].化工管理,2018(17):82-83.
[29]巩艳.水合物法储运天然气技术[J].内蒙古石油化工,2017,43(10):93-95.
[30]Bachu S,Adams JJ.Sequestration of CO2 in geological media in response to climate change:capacity of deep saline aquifers to sequester CO2 in solution[J].Energy Convers.Manage.,2003,44:3151-3175.
[31]孟凡飞,张雁玲.可用于炼厂气综合利用的水合物分离技术研究进展[J].石油化工,2017,46(7):944-952.
[32]樊栓狮,郭开华.从催化裂化干气中分离回收乙烯的方法及装置:CN,1301 684A[P].2001-07-04.
[33]郭望.天然气水合物冻堵分解技术探究[J].石化技术,2018,25(4):37.
[34]张敬升.浅冷油吸收工艺回收炼油厂饱和干气的模拟[J].石油化工,2014,43(9):1069-1075.
[35]张敬升,李东风,过良,刘智信.浅冷油吸收技术在炼厂饱和干气回收中的应用[J].石油石化绿色低碳,2018(4):16-20.
[36]高敦仁.中冷油吸收法回收炼厂烯烃技术经济比较[J].石油化工,1991(7):481-487.