白铅矿浮选的表面硫化研究进展
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摘要
近年来随着硫化铅矿资源的枯竭,氧化铅矿资源的开发利用越来越受到关注。硫化浮选是回收氧化铅矿资源最为经济有效的方法,而白铅矿是最具有工业价值的氧化铅矿物,因此白铅矿的硫化问题成为氧化铅矿资源开发的关键问题。本文简要介绍了各种硫化方法,分析了各自的优缺点,重点总结和分析了表面硫化及其影响因素,认为正确认识白铅矿硫化的本质并在此基础上研究硫化的影响因素是今后研究的重点。
In recent years,with the depletion of lead sulfide resources,the exploitation and utilization of lead oxidized resources has attracted more and more attention.Sulfidization flotation is the most economic and effective method to recovery of lead oxidized minerals,and cerussite have the most commercial value in lead oxidized minerals,so the sulfidization of cerussite becomes the key issue in lead oxidized resources development.This paper briefly introduces kinds of sulfidization methods,analyzes their advantages and disadvantages,summarizes and analyzes the surface sulfidization and its influencing factors.It is important to correctly understand the nature of cerussitesulf idization and study the influencing factors of sulfidization on this basis.
In recent years,with the depletion of lead sulfide resources,the exploitation and utilization of lead oxidized resources has attracted more and more attention.Sulfidization flotation is the most economic and effective method to recovery of lead oxidized minerals,and cerussite have the most commercial value in lead oxidized minerals,so the sulfidization of cerussite becomes the key issue in lead oxidized resources development.This paper briefly introduces kinds of sulfidization methods,analyzes their advantages and disadvantages,summarizes and analyzes the surface sulfidization and its influencing factors.It is important to correctly understand the nature of cerussitesulf idization and study the influencing factors of sulfidization on this basis.
引文
[1]SCHERODERr-WOLTHOON,ANKE,KUITER,et al.Application of sulfate reduction for the biological conversion of anglesite(PbSO4)to galena(PbS)[J].Hydrometallurgy,2008,94(1):105-109.
[2]苏永津.全球铅资源供需形势分析[J].中国经贸导刊,2016(20):6-9.
[3]ANTAO S M,HASSAN I.The orthorhombic structure of CaCO3,SrCO3,PbCO3and BaCO3;linear structural trends[J].Canadian Mineralogist,2009,47(5):1245-1255.
[4]白旭,文书明,刘建,等.缅甸高品位白铅矿试验研究[J].矿产综合利用,2015(5):58-61.
[5]刘凤霞.氧化铅浮选黄药分子结构与性能研究[D].南宁:广西大学,2007.
[6]曹俊雅,鲁倍倍,马斌,等.氧化铅锌矿硫化技术研究进展[J].矿产综合利用,2016(2):17-21.
[7]刘凤霞,陈建华,魏宗武.氧化铅矿浮选研究进展[J].矿产保护与利用,2008(1):48-55.
[8]YUAN W,LI J,ZHANG Q,et al.Mechanochemical sulfidization of lead oxides by grinding with sulfur[J].Powder Technology,2012,230:63-66.
[9]LI CUNXIONG,WEI CHANG,SONG YAN,et al.Hydrothermal sulfidation of white lead with elemental sulfur[J].Advanced Materials Research,2012,(396-398):624-630.
[10]魏昶,李存兄,徐红胜,等.高温下S-H2O系ε-pH图及水热硫化的应用[C]//全国冶金物理化学学术会议专辑,2010.
[11]李存兄,魏昶,邓志敢,等.氧化铅锌矿元素硫水热硫化-浮选实验研究[J].昆明理工大学学报(自然科学版),2013,38(2):1-6.
[12]任占誉,王吉坤,魏昶,等.低品位氧化铅锌矿的硫化及浮选[J].云南冶金,2009,38(1):27-29.
[13]李磊,廖彬,王华,等.锡铁矿硫化焙烧脱锡[J].过程工程学报,2013,13(3):409-414.
[14]董传山.氧化铅矿物的合成、表面硫化及对黄药的吸附行为研究[D].济南:济南大学,2012.
[15]李建兵,徐会华.某高泥氧化铅锌矿硫化焙烧---浮选试验[J].现代矿业,2017,33(10):103-106.
[16]李勇.低品位氧化铅锌矿硫化-浮选工艺及理论研究[D].昆明:昆明理工大学,2009.
[17]韩聪.铅锌含氧盐矿物的浮选行为研究[D].沈阳:东北大学,2013.
[18]丰奇成.白铅矿氯离子强化硫化浮选试验及机理研究[D].昆明:昆明理工大学,2016.
[19]郭才虞.硫化钠在浮选中的作用机理[J].云南冶金,1981(3):22-28.
[20]谭欣,李长根.国内外氧化铅锌矿浮选研究进展(Ⅰ)[J].国外金属矿选矿,2000(3):7-14.
[21]沈同喜.氧化铅矿硫化浮选强化技术研究[D].江西赣州:江西理工大学,2013.
[22]梁冬云,张志雄.白铅矿,菱锌矿晶体化学性质与硫化行为[J].材料研究与应用,1992(2):83-88.
[23]白旭.白铅矿硫化浮选及机理研究[D].昆明:昆明理工大学,2016.
[24]陈经华,张方齐.白铅矿硫化浮选体系的电化学性质研究[J].矿冶工程,2017,37(4):38-40.
[25]HERRERA-URBINA R,SOTILLO F J,FUERSTENAU DW.Amyl xanthate uptake by natural and sulfide-treated cerussite and galena[J].International Journal of Mineral Processing,1998,55(2):113-128.
[26]张方齐,陈经华,吴熙群.白铅矿的硫化电位控制浮选机理研究[J].有色金属(选矿部分),2015(3):19-23.
[27]SONG S,LOPEZ-VALDIVIESO A,REYES-BAHENAJ L,et al.Floc flotation of galena and sphaleritefines[J].Minerals Engineering,2001,14(1):87-98.
[28]魏宗武,陈晔.黄药体系中白铅矿的浮选行为研究[J].有色金属科学与工程,2008,22(1):19-21.
[29]MARABINI A M,CIRIACHI M,PLESCIA P,et al.Chelating reagents for flotation[J].Minerals Engineering,2007,20(10):1014-1025.
[30]陆智,蔡振波,刘子帅.氧化铅锌矿浮选工艺研究进展[J].有色金属工程,2014(4):77-80.
[31]FUERSTENAU M C,OLIVAS S A,HERRERA-URBINA R,et al.The surface characteristics and flotation behavior of anglesite and cerussite[J].International Journal of Mineral Processing,1987,20(1):73-85.
[32]FENG Q,WEN S,ZHAO W,et al.Adsorption of sulfide ions on cerussite surfaces and implications for flotation[J].Applied Surface Science,2016,360:365-372.
[33]刘凤霞,陈建华,吴伯增,等.白铅矿、褐铁矿的硫化浮选试验研究[J].矿产保护与利用,2007(1):27-30.
[34]黄礼煌.金属硫化矿物低碱介质浮选[M].北京:冶金工业出版社,2015:21-26.
[35]石道民,杨敖.氧化铅锌矿的浮选[M].昆明:云南科技出版社,1996:43-44.
[36]NAL G,BULUT G,Gl A,et al.Flotation of Aladag oxide lead-zinc ores[J].Minerals Engineering,2005.
[37]戈保梁,张文彬.氧化铜矿选矿研究进展[J].云南冶金:科学技术版,1994(4):13-18.
[38]高军,赵蕾.氧化铅矿石硫化浮选工艺研究[J].科学技术创新,2010(13):8-10.
[39]梁冬云,张志雄.白铅矿,菱锌矿晶体化学性质与硫化行为[J].材料研究与应用,1992(2):83-88.
[40]高跃升,高志勇,孙伟.萤石表面性质各向异性研究及进展[J].中国有色金属学报,2016,26(2):415-422.
[41]FENG Q,ZHAO W,WEN S,et al.Copper sulfide species formed on malachite surfaces in relation to flotation[J].Journal of Industrial&Engineering Chemistry,2017,48:125-132.
[42]宋凯伟,李佳磊,蔡锦鹏,等.典型氧化铜铅锌矿物浮选的表面硫化研究进展[J].化工进展,2018(9).
[2]苏永津.全球铅资源供需形势分析[J].中国经贸导刊,2016(20):6-9.
[3]ANTAO S M,HASSAN I.The orthorhombic structure of CaCO3,SrCO3,PbCO3and BaCO3;linear structural trends[J].Canadian Mineralogist,2009,47(5):1245-1255.
[4]白旭,文书明,刘建,等.缅甸高品位白铅矿试验研究[J].矿产综合利用,2015(5):58-61.
[5]刘凤霞.氧化铅浮选黄药分子结构与性能研究[D].南宁:广西大学,2007.
[6]曹俊雅,鲁倍倍,马斌,等.氧化铅锌矿硫化技术研究进展[J].矿产综合利用,2016(2):17-21.
[7]刘凤霞,陈建华,魏宗武.氧化铅矿浮选研究进展[J].矿产保护与利用,2008(1):48-55.
[8]YUAN W,LI J,ZHANG Q,et al.Mechanochemical sulfidization of lead oxides by grinding with sulfur[J].Powder Technology,2012,230:63-66.
[9]LI CUNXIONG,WEI CHANG,SONG YAN,et al.Hydrothermal sulfidation of white lead with elemental sulfur[J].Advanced Materials Research,2012,(396-398):624-630.
[10]魏昶,李存兄,徐红胜,等.高温下S-H2O系ε-pH图及水热硫化的应用[C]//全国冶金物理化学学术会议专辑,2010.
[11]李存兄,魏昶,邓志敢,等.氧化铅锌矿元素硫水热硫化-浮选实验研究[J].昆明理工大学学报(自然科学版),2013,38(2):1-6.
[12]任占誉,王吉坤,魏昶,等.低品位氧化铅锌矿的硫化及浮选[J].云南冶金,2009,38(1):27-29.
[13]李磊,廖彬,王华,等.锡铁矿硫化焙烧脱锡[J].过程工程学报,2013,13(3):409-414.
[14]董传山.氧化铅矿物的合成、表面硫化及对黄药的吸附行为研究[D].济南:济南大学,2012.
[15]李建兵,徐会华.某高泥氧化铅锌矿硫化焙烧---浮选试验[J].现代矿业,2017,33(10):103-106.
[16]李勇.低品位氧化铅锌矿硫化-浮选工艺及理论研究[D].昆明:昆明理工大学,2009.
[17]韩聪.铅锌含氧盐矿物的浮选行为研究[D].沈阳:东北大学,2013.
[18]丰奇成.白铅矿氯离子强化硫化浮选试验及机理研究[D].昆明:昆明理工大学,2016.
[19]郭才虞.硫化钠在浮选中的作用机理[J].云南冶金,1981(3):22-28.
[20]谭欣,李长根.国内外氧化铅锌矿浮选研究进展(Ⅰ)[J].国外金属矿选矿,2000(3):7-14.
[21]沈同喜.氧化铅矿硫化浮选强化技术研究[D].江西赣州:江西理工大学,2013.
[22]梁冬云,张志雄.白铅矿,菱锌矿晶体化学性质与硫化行为[J].材料研究与应用,1992(2):83-88.
[23]白旭.白铅矿硫化浮选及机理研究[D].昆明:昆明理工大学,2016.
[24]陈经华,张方齐.白铅矿硫化浮选体系的电化学性质研究[J].矿冶工程,2017,37(4):38-40.
[25]HERRERA-URBINA R,SOTILLO F J,FUERSTENAU DW.Amyl xanthate uptake by natural and sulfide-treated cerussite and galena[J].International Journal of Mineral Processing,1998,55(2):113-128.
[26]张方齐,陈经华,吴熙群.白铅矿的硫化电位控制浮选机理研究[J].有色金属(选矿部分),2015(3):19-23.
[27]SONG S,LOPEZ-VALDIVIESO A,REYES-BAHENAJ L,et al.Floc flotation of galena and sphaleritefines[J].Minerals Engineering,2001,14(1):87-98.
[28]魏宗武,陈晔.黄药体系中白铅矿的浮选行为研究[J].有色金属科学与工程,2008,22(1):19-21.
[29]MARABINI A M,CIRIACHI M,PLESCIA P,et al.Chelating reagents for flotation[J].Minerals Engineering,2007,20(10):1014-1025.
[30]陆智,蔡振波,刘子帅.氧化铅锌矿浮选工艺研究进展[J].有色金属工程,2014(4):77-80.
[31]FUERSTENAU M C,OLIVAS S A,HERRERA-URBINA R,et al.The surface characteristics and flotation behavior of anglesite and cerussite[J].International Journal of Mineral Processing,1987,20(1):73-85.
[32]FENG Q,WEN S,ZHAO W,et al.Adsorption of sulfide ions on cerussite surfaces and implications for flotation[J].Applied Surface Science,2016,360:365-372.
[33]刘凤霞,陈建华,吴伯增,等.白铅矿、褐铁矿的硫化浮选试验研究[J].矿产保护与利用,2007(1):27-30.
[34]黄礼煌.金属硫化矿物低碱介质浮选[M].北京:冶金工业出版社,2015:21-26.
[35]石道民,杨敖.氧化铅锌矿的浮选[M].昆明:云南科技出版社,1996:43-44.
[36]NAL G,BULUT G,Gl A,et al.Flotation of Aladag oxide lead-zinc ores[J].Minerals Engineering,2005.
[37]戈保梁,张文彬.氧化铜矿选矿研究进展[J].云南冶金:科学技术版,1994(4):13-18.
[38]高军,赵蕾.氧化铅矿石硫化浮选工艺研究[J].科学技术创新,2010(13):8-10.
[39]梁冬云,张志雄.白铅矿,菱锌矿晶体化学性质与硫化行为[J].材料研究与应用,1992(2):83-88.
[40]高跃升,高志勇,孙伟.萤石表面性质各向异性研究及进展[J].中国有色金属学报,2016,26(2):415-422.
[41]FENG Q,ZHAO W,WEN S,et al.Copper sulfide species formed on malachite surfaces in relation to flotation[J].Journal of Industrial&Engineering Chemistry,2017,48:125-132.
[42]宋凯伟,李佳磊,蔡锦鹏,等.典型氧化铜铅锌矿物浮选的表面硫化研究进展[J].化工进展,2018(9).