淀粉纳米粒的制备与应用研究进展
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摘要
淀粉纳米粒因其可再生、环保可降解等诸多优点,成为当下纳米材料研究领域的热点,具有广阔的应用前景。对淀粉颗粒结构迚行了剖析,对淀粉纳米粒制备方法迚行了综述,介绍了酸处理法、酶处理法、物理法、纳米沉淀、乳液交联及一些复合方法制备淀粉纳米粒的优势及所存在的局限。阐述了淀粉纳米粒作为复合材料充填剂、乳液稳定剂、包装材料、药物载体、污水处理剂和造纸粘合剂的应用性能,对其研究方向和工业应用前景迚行了展望。
Due to its renewable, environmentally friendly and degradable advantages, starch nanoparticals(SNPs) have become the hotspot in the field of nanomaterials, and have broad application prospects. In this paper, the structure of starch was studied, different preparations methods of SNPs, including acid hydrolysis, enzymatic treatment, physical treatments, nano-precipitation, emulsion cross-linking, and some other combined methods were summarized. The application of SNPs as part of composites, emulsion stabilizer, packing component, drug carrier, adsorbents of wastewater treatment and binder in paper coating were also introduced. At last, the research direction and industrial application prospects of SNPs were forecasted.
Due to its renewable, environmentally friendly and degradable advantages, starch nanoparticals(SNPs) have become the hotspot in the field of nanomaterials, and have broad application prospects. In this paper, the structure of starch was studied, different preparations methods of SNPs, including acid hydrolysis, enzymatic treatment, physical treatments, nano-precipitation, emulsion cross-linking, and some other combined methods were summarized. The application of SNPs as part of composites, emulsion stabilizer, packing component, drug carrier, adsorbents of wastewater treatment and binder in paper coating were also introduced. At last, the research direction and industrial application prospects of SNPs were forecasted.
引文
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[30]Sun Q,Gong M,Li Y,et al.Effect of retrogradation time on preparation and characterization of proso millet starch nanoparticles[J].Carbohydrate polymers,2014,111:133-138.
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[33]Li C,Sun P,Yang C.Emulsion stabilized by starch nanocrystals[J].Starch-St?rke,2012,64(6):497-502.
[34]García N L,Ribba L,Dufresne A,et al.Physico‐mechanical properties of biodegradable starch nanocomposites[J].Macromolecular Materials and Engineering,2009,294(3):169-177.
[35]Brodke D S,Gollogly S,Mohr R A,et al.Dynamic cervical plates:biomechanical evaluation of load sharing and stiffness[J].Spine,2001,26(12):1324-1329.
[36]Sharma Y C,Singh B,Agrawal A,et al.Removal of chromium by riverbed sand from water and wastewater:Effect of important parameters[J].Journal of hazardous materials,2008,151(2-3):789-793.
[37]Alila S,Aloulou F,Thielemans W,et al.Sorption potential of modified nanocrystals for the removal of aromatic organic pollutant from aqueous solution[J].Industrial crops and products,2011,33(2):350-357.
[38]Bloembergen S,VanEgdom E,Wildi R,et al.Biolatex binders for paper and paperboard applications[J].Journal of Pulp and Paper Science,2010,36(3-4):151-161.
[2]Namazi H,Dadkhah A.Convenient method for preparation of hydrophobically modified starch nanocrystals with using fatty acids[J].Carbohydrate Polymers,2010,79(3):731-737.
[3]Kim H Y,Lee J H,Kim J Y,et al.Characterization of nanoparticles prepared by acid hydrolysis of various starches[J].Starch-St?rke,2012,64(5):367-373.
[4]卢麒麟,黄彪,唐丽荣,等.机械力化学作用下纳米淀粉的制备与性能[J].中国粮油学报,2014,29(11):24-29.
[5]Kristo E,Biliaderis C G.Physical properties of starch nanocrystalreinforced pullulan films[J].Carbohydrate Polymers,2007,68(1):146-158.
[6]Lin N,Huang J,Chang P R,et al.Effect of polysaccharide nanocrystals on structure,properties,and drug release kinetics of alginate-based microspheres[J].Colloids and Surfaces B:Biointerfaces,2011,85(2):270-279.
[7]Tester R F,Karkalas J,Qi X.Starch-composition,fine structure and architecture[J].Journal of cereal Science,2004,39(2):151-165.
[8]段彬,杨成.淀粉纳米晶粒的制备及其性质研究[J].材料导报,2008,22:41-42+51.
[9]Angellier H,Choisnard L,Molina-Boisseau S,et al.Optimization of the preparation of aqueous suspensions of waxy maize starch nanocrystals using a response surface methodology[J].Biomacromolecules,2004,5(4):1545-1551.
[10]Chang P R,Ai F,Chen Y,et al.Effects of starch nanocrystalgraft-polycaprolactone on mechanical properties of waterborne polyurethane-based nanocomposites[J].Journal of Applied Polymer Science,2009,111(2):619-627.
[11]Kim J Y,Park D J,Lim S T.Fragmentation of waxy rice starch granules by enzymatic hydrolysis[J].Cereal Chemistry,2008,85(2):182-187.
[12]LeCorre D,Vahanian E,Dufresne A,et al.Enzymatic pretreatment for preparing starch nanocrystals[J].Biomacromolecules,2011,13(1):132-137.
[13]涂宗财,仸维,刘成梅,等.纳米级大米淀粉的制备及性质[J].农业工程学报,2008,24(1):250-253.
[14]Liu D,Wu Q,Chen H,et al.Transitional properties of starch colloid with particle size reduction from micro-to nanometer[J].Journal of Colloid and Interface Science,2009,339(1):117-124.
[15]Song D,Thio Y S,Deng Y.Starch nanoparticle formation via reactive extrusion and related mechanism study[J].Carbohydrate polymers,2011,85(1):208-214.
[16]陈洪杰,李志伟,陶小军,等.超声波在纳米材料制备中的应用[J].化学研究,2005,16(1):104-107.
[17]Haaj S B,Magnin A,Pétrier C,et al.Starch nanoparticles formation via high power ultrasonication[J].Carbohydrate polymers,2013,92(2):1625-1632.
[18]LeCorre D,Bras J,Dufresne A.Starch nanoparticles:a review[J].Biomacromolecules,2010,11(5):1139-1153.
[19]Kim H Y,Park S S,Lim S T.Preparation,characterization and utilization of starch nanoparticles[J].Colloids and Surfaces B:Biointerfaces,2015,126:607-620.
[20]Tan Y,Xu K,Li L,et al.Fabrication of size-controlled starch-based nanospheres by nanoprecipitation[J].ACS applied materials&interfaces,2009,1(4):956-959.
[21]Ma X,Jian R,Chang P R,et al.Fabrication and characterization of citric acid-modified starch nanoparticles/plasticized-starch composites[J].Biomacromolecules,2008,9(11):3314-3320.
[22]Fang Y,Wang L,Li D,et al.Preparation of crosslinked starch microspheres and their drug loading and releasing properties[J].Carbohydrate Polymers,2008,74(3):379-384.
[23]Franssen O,Hennink W E.A novel preparation method for polymeric microparticles without the use of organic solvents[J].International Journal of Pharmaceutics,1998,168(1):1-7.
[24]Shi A,Li D,Wang L,et al.Preparation of starch-based nanoparticles through high-pressure homogenization and miniemulsion cross-linking:Influence of various process parameters on particle size and stability[J].Carbohydrate Polymers,2011,83(4):1604-1610.
[25]Jain A K,Khar R K,Ahmed F J,et al.Effective insulin delivery using starch nanoparticles as a potential trans-nasal mucoadhesive carrier[J].European journal of pharmaceutics and biopharmaceutics,2008,69(2):426-435.
[26]Zhou G,Luo Z,Fu X.Preparation and characterization of starch nanoparticles in ionic liquid-in-oil microemulsions system[J].Industrial Crops and Products,2014,52:105-110.
[27]Jafari S M,Assadpoor E,He Y,et al.Re-coalescence of emulsion droplets during high-energy emulsification[J].Food hydrocolloids,2008,22(7):1191-1202.
[28]Kim H Y,Han J A,Kweon D K,et al.Effect of ultrasonic treatments on nanoparticle preparation of acid-hydrolyzed waxy maize starch[J].Carbohydrate polymers,2013,93(2):582-588.
[29]Kim H Y,Park D J,Kim J Y,et al.Preparation of crystalline starch nanoparticles using cold acid hydrolysis and ultrasonication[J].Carbohydrate polymers,2013,98(1):295-301.
[30]Sun Q,Gong M,Li Y,et al.Effect of retrogradation time on preparation and characterization of proso millet starch nanoparticles[J].Carbohydrate polymers,2014,111:133-138.
[31]Angellier H,Molina-Boisseau S,Dufresne A.Mechanical properties of waxy maize starch nanocrystal reinforced natural rubber[J].Macromolecules,2005,38(22):9161-9170.
[32]Arroyo M,Lopez-Manchado M A,Herrero B.Organo-montmorillonite as substitute of carbon black in natural rubber compounds[J].Polymer,2003,44(8):2447-2453.
[33]Li C,Sun P,Yang C.Emulsion stabilized by starch nanocrystals[J].Starch-St?rke,2012,64(6):497-502.
[34]García N L,Ribba L,Dufresne A,et al.Physico‐mechanical properties of biodegradable starch nanocomposites[J].Macromolecular Materials and Engineering,2009,294(3):169-177.
[35]Brodke D S,Gollogly S,Mohr R A,et al.Dynamic cervical plates:biomechanical evaluation of load sharing and stiffness[J].Spine,2001,26(12):1324-1329.
[36]Sharma Y C,Singh B,Agrawal A,et al.Removal of chromium by riverbed sand from water and wastewater:Effect of important parameters[J].Journal of hazardous materials,2008,151(2-3):789-793.
[37]Alila S,Aloulou F,Thielemans W,et al.Sorption potential of modified nanocrystals for the removal of aromatic organic pollutant from aqueous solution[J].Industrial crops and products,2011,33(2):350-357.
[38]Bloembergen S,VanEgdom E,Wildi R,et al.Biolatex binders for paper and paperboard applications[J].Journal of Pulp and Paper Science,2010,36(3-4):151-161.