重金属离子的光学检测方法综述
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摘要
研究了环境和食品中重金属离子的检测方法。介绍了电化学分析法等非光学检测方法,较深入地分析了原子吸收光谱法、原子荧光光度法、原子发射光谱法、紫外可见分光光度法、表面等离子体共振技术测量法、试纸—光电反射测量法、共振光散射技术测量法以及激光诱导击穿光谱法等光学检测方法,给出了重金属离子检测的研究重点与发展方向。
Detection methods for heavy metals ions in environment and food are studied. Non-optical detection methods such as electrochemical analysis method are introduced. And also,the optical detection methods such as atomic absorption spectrometry,atomic fluorescence spectrometry,atomic emission spectrometry,UV-visible spectrophotometry,surface plasmon resonance technology,test-paper photoelectric reflectance measurement,resonance light scattering technique,and laser induced breakdown spectroscopy are analyzed deeply. Research emphasis and development direction of the heavy metal ions detection are given.
Detection methods for heavy metals ions in environment and food are studied. Non-optical detection methods such as electrochemical analysis method are introduced. And also,the optical detection methods such as atomic absorption spectrometry,atomic fluorescence spectrometry,atomic emission spectrometry,UV-visible spectrophotometry,surface plasmon resonance technology,test-paper photoelectric reflectance measurement,resonance light scattering technique,and laser induced breakdown spectroscopy are analyzed deeply. Research emphasis and development direction of the heavy metal ions detection are given.
引文
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[8]王文华,熊正烨,师文庆,等.光纤表面等离子体共振传感技术[J].激光与光电子学进展,2017,54(9):09000810—09000811.
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[10] Yu Jorn C C,Lai Edward P C,Sadeghi S. Surface plasmon resonance sensor for Hg(II)detection by binding interactions with polypyrrole and 2-mercaptobenzothiazole[J]. Sensors and Actuators B:Chemical,2004,101(l/2):236-240.
[11] Lee M M,Russell D A. Novel determination of cadmium ions using an enzyme self-assembled monolayer with surface plasmon resonance[J]. Analytica Chimica Aeta,2003,500(l/2):119-125.
[12] Chah S,Yi J,Zare R N. Surface plasmon resonance analysis of aqueous mercuric ions[J]. Sensors and Actuators B:Chemical,2004,99(2/3):216-222.
[13] Fen Y W,Yunus W,Mahmood M,et al. Analysis of Pb(II)ion sensing by crosslinked chitosan thin film using surface plasmon resonance spectroscopy[J]. Optik,2013,124:126-133.
[14] Ericas F,Haiqian Z. Detection of heavy metal ions in drinking water using a high-resolution differential surface plasmon resonance sensor[J]. Environmental Science&Technology,2005,39:1257-1262.
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[17] Fan Y,Long Y F,Li Y F. A sensitive resonance light scattering spectrometry of trace Hg2+with sulfur ion modified gold nanoparticles[J]. Analytica Chimica Acta,2009,653(2):207-211.
[18] Liu Z D,Li Y F,Huang C Z,et al. A localized surface plasmon resonance light-scattering assay of mercury(II)on the basis of Hg2+-DNAcomplex induced aggregation of gold nanoparticles[J]. Environmental Science&Technology,2009,43(13):5022-5027.
[19] Wang H,Wang Y X,Jin J Y,et al. Gold nanoparticle-based colorimetric and“Turn-On”fluorescent probe for mercury(II)ions in aqueous solution[J]. Analytical Chemistry,2008,80:9021-9028.
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[22]吴文韬,马晓红,郑华凤,等.激光诱导击穿光谱定量检测土壤微量重金属元素方法研究[J].光谱学与光谱分析,2011,31(2):452-455.
[23] Knopp R,Scherbaum F,Kim J I. Laser induced breakdown spectroscopy(LIBS)as an analytical tool for the detection of metal ions in aqueous solutions[J]. Fresenius Journal of Analytical Chemistry,1996,355(2):16-20.
[24] Yu Y L,Zhou W D,Su X J. Detection of Cu in solution with double pulse laser-induced break-down spectroscopy[J]. Optics Communications,2014,333(6):62-66.
[25]常亮,林兆祥,李捷,等.溶液中金属元素的激光诱导击穿光谱[J].强激光与粒子束,2010,22(6):1369-1372.
[26] Samu T J,Sampo S,Jorma K,et al. Detection of Ni,Pb and Zn in water using electrodynamic single-particle levitation and laserinduced breakdown spectroscopy[J]. Spectrochimica Acta Part B:Atomic Spectroscopy,2014,99(1):9-14.
[27]彭秋梅.激光诱导击穿光谱技术检测新鲜桔子叶中重金属元素的试验研究[D].南昌:江西农业大学,2013.
[28]王伟辉.基于反射光检测重金属浓度系统设计与实现[D].南京:南京理工大学,2015.
[2]姚端华,赵越,王东,等.重点流域水污染防治“十二·五”规划的总体设计[J].中国人口资源与环境,2011,21(3):419-421.
[3]孙博思,赵丽娇,任婷.水环境中重金属检测方法研究进展[J].环境科学与技术,2012,35(7):157-162.
[4]栾云霞,李伟国,陆安详,等.原子荧光光谱法同时测定土壤中的砷和汞[J].安徽农业科学,2009,37(12):5344-5346.
[5]唐莲仙,吴晓,郑绍成.氢化物发生—原子荧光光谱法测定白酒中的痕量铅[J].化学分析计量,2008,17(2):34-37.
[6]罗庆尧,邓延倬,蔡汝秀.分光光度分析[M].北京:科学出版社,1992.
[7]游效曾,孟庆金,韩万书.配位化学进展[M].北京:高等敎育出版社,2000.
[8]王文华,熊正烨,师文庆,等.光纤表面等离子体共振传感技术[J].激光与光电子学进展,2017,54(9):09000810—09000811.
[9] Kabashin A V,Patskovsky S,Grigorenko A N. Phase and amplitude sensitivities in surface plasmon resonance bio and chemical sensing[J]. Optics Express,2009,17(23):21191-21204.
[10] Yu Jorn C C,Lai Edward P C,Sadeghi S. Surface plasmon resonance sensor for Hg(II)detection by binding interactions with polypyrrole and 2-mercaptobenzothiazole[J]. Sensors and Actuators B:Chemical,2004,101(l/2):236-240.
[11] Lee M M,Russell D A. Novel determination of cadmium ions using an enzyme self-assembled monolayer with surface plasmon resonance[J]. Analytica Chimica Aeta,2003,500(l/2):119-125.
[12] Chah S,Yi J,Zare R N. Surface plasmon resonance analysis of aqueous mercuric ions[J]. Sensors and Actuators B:Chemical,2004,99(2/3):216-222.
[13] Fen Y W,Yunus W,Mahmood M,et al. Analysis of Pb(II)ion sensing by crosslinked chitosan thin film using surface plasmon resonance spectroscopy[J]. Optik,2013,124:126-133.
[14] Ericas F,Haiqian Z. Detection of heavy metal ions in drinking water using a high-resolution differential surface plasmon resonance sensor[J]. Environmental Science&Technology,2005,39:1257-1262.
[15] Mirkin C A,Letsinger R L,Mueie R C,et al. A DNA-based method for rationally assembling nanoparticles into macroscopic materials[J]. Nature,1996,382(6592):607-609.
[16] Yguerabide J,Yguerabide E E. Light-scattering submicroscopic particles as highly fluorescent analogs and their use as tracer labels in clinical and biological applications[J]. Analytical Biochemistry,1998,262:137-156.
[17] Fan Y,Long Y F,Li Y F. A sensitive resonance light scattering spectrometry of trace Hg2+with sulfur ion modified gold nanoparticles[J]. Analytica Chimica Acta,2009,653(2):207-211.
[18] Liu Z D,Li Y F,Huang C Z,et al. A localized surface plasmon resonance light-scattering assay of mercury(II)on the basis of Hg2+-DNAcomplex induced aggregation of gold nanoparticles[J]. Environmental Science&Technology,2009,43(13):5022-5027.
[19] Wang H,Wang Y X,Jin J Y,et al. Gold nanoparticle-based colorimetric and“Turn-On”fluorescent probe for mercury(II)ions in aqueous solution[J]. Analytical Chemistry,2008,80:9021-9028.
[20] Liu D B,Qu W S,Chen W W,et al. Highly sensitive,colorimetric detection of mercury(II)in aqueous media by quaternary ammonium group-capped gold nanoparticles at room temperature[J].Analytical Chemistry,2010,82:9606-9610.
[21] Srungaram P K,Ayyalasomayajula K K,Fang Y Y,et al. Comparison of laser induced breakdown spectroscopy and spark induced breakdown spectroscopy for determination of mercury in soils[J].Spectrochimica Acta Part B:Atomic Spectroscopy,2013,87(12):108-113.
[22]吴文韬,马晓红,郑华凤,等.激光诱导击穿光谱定量检测土壤微量重金属元素方法研究[J].光谱学与光谱分析,2011,31(2):452-455.
[23] Knopp R,Scherbaum F,Kim J I. Laser induced breakdown spectroscopy(LIBS)as an analytical tool for the detection of metal ions in aqueous solutions[J]. Fresenius Journal of Analytical Chemistry,1996,355(2):16-20.
[24] Yu Y L,Zhou W D,Su X J. Detection of Cu in solution with double pulse laser-induced break-down spectroscopy[J]. Optics Communications,2014,333(6):62-66.
[25]常亮,林兆祥,李捷,等.溶液中金属元素的激光诱导击穿光谱[J].强激光与粒子束,2010,22(6):1369-1372.
[26] Samu T J,Sampo S,Jorma K,et al. Detection of Ni,Pb and Zn in water using electrodynamic single-particle levitation and laserinduced breakdown spectroscopy[J]. Spectrochimica Acta Part B:Atomic Spectroscopy,2014,99(1):9-14.
[27]彭秋梅.激光诱导击穿光谱技术检测新鲜桔子叶中重金属元素的试验研究[D].南昌:江西农业大学,2013.
[28]王伟辉.基于反射光检测重金属浓度系统设计与实现[D].南京:南京理工大学,2015.