复合分子筛在石油化工领域的研究进展
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摘要
复合分子筛是一类能将两种或多种分子筛的孔道结构和酸性质结合在一起的新型催化材料,该类材料往往具有单一分子筛所不具有的优势。复合分子筛的高比表面积和孔体积比使其在反应过程中具有高的扩散系数和较少的传输限制,能比单一分子筛表现出更高的催化活性,因此被广泛应用于石油化工领域。重点综述了复合分子筛在催化裂化、异构化、芳构化、烷基化、甲醇制烃等领域的应用进展情况,并对复合分子筛的应用进行了展望。
Composite molecular sieves is a new type of catalytic material that can combine a variety of pore structure and acidity. This material often has the advantages that a single molecular sieve does not have. The high specific surface area and pore volume ratio in the composite molecular sieves also make it easy to transmit in the reaction process. The progress of the application of composite molecular sieves in petrochemical industry fields such as catalytic cracking, isomerization, aromatization, alkylation, and methanol to hydrocarbon production was reviewed. Moreover, the further developments of the composite molecular sieves were forecasted.
Composite molecular sieves is a new type of catalytic material that can combine a variety of pore structure and acidity. This material often has the advantages that a single molecular sieve does not have. The high specific surface area and pore volume ratio in the composite molecular sieves also make it easy to transmit in the reaction process. The progress of the application of composite molecular sieves in petrochemical industry fields such as catalytic cracking, isomerization, aromatization, alkylation, and methanol to hydrocarbon production was reviewed. Moreover, the further developments of the composite molecular sieves were forecasted.
引文
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[26]Liping Li,Xiaojing Cui,Junfen Li,et al.Synthesis of SAPO-34/ZSM-5 composite and its catalytic performance in the conversion of methanol to hydrocarbons[J].Journal of Brazilian Chemical Society,2015,17(1):1-5.
[27]Zuoxing Di,Cheng Yang,Xuejing Jiao,et al.A ZSM-5/MCM-48 based catalyst for methanol to gasoline conversion[J].Fuel,2013,104(104):878-881.
[28]Ho-Jeong Chae,Young-Ha Song,Kwang-Eun Jeong,et al.Physicochemical characteristics of ZSM-5/SAPO-34 composite catalyst for MTOreaction[J].Journal of Physics and Chemistry of Solids,2010,71:600-603.
[29]王政,王林,张国香,等.ZSM-5/磷酸铝复合分子筛在甲醇制烯烃反应中的应用[J].石油学报(石油加工),2011,27(4):543-548.
[30]邢爱华,张新锋.SAPO-5/SAPO-18的合成及其在甲醇制烯烃中的应用[J].天然气化工(C1化学与化工),2017,42(4):22-28.
[2]Esmat Koohsaryan,Mansoor Anbia.纳米多级孔分子筛:简短的综述(英文)[J].催化学报,2016,37(4):447-467.
[3]许俊强,张川,郭芳,等.MCM-41介孔壳层包覆的核壳结构复合分子筛研究进展[J].硅酸盐学报,2017,45(4):592-600.
[4]Junsu Jin,Chaoyun Peng,Jiujiang Wang,et al.Facile Synthesis of Mesoporous Zeolite Y with Improved Catalytic Performance for Heavy Oil Fluid Catalytic Cracking[J].Industrial and Engineering Chemistry Research,2014,3(8):3406-3411.
[5]Peter Lovás,Pavol Hudec,Marcela Hadvinová,et al.Conversion of rapeseed oil via catalytic cracking:Effect of the ZSM-5 catalyst on the deoxygenation process[J].Fuel Processing Technology,2015,134(5):223-230.
[6]A AfsharEbrahimi,S Tarighi.The Influence of Temperature and Catalyst Additives on Catalytic Cracking of a Heavy Fuel Oil[J].Petroleum Science and Technology,2015,33(4):415-421.
[7]李文林,郑金玉,罗一斌,等.多级孔分子筛制备方法、机理和应用研究进展[J].石油学报(石油加工),2016,32(6):1273-1286.
[8]Xinmei Liu,Tingting Yang,Peng Bai,et al.Y/MCM-41 composites assembled from nanocrystals[J].Microporous and Mesoporous Materials,2013,181:116-122.
[9]陈洪林,申宝剑,潘惠芳.ZSM-5/Y复合分子筛的酸性及其重油催化裂化性能[J].催化学报,2004,25(9):715-720.
[10]申宝剑,陈洪林,潘惠芳.ZSM-5/Y复合分子筛在烃类催化裂化催化剂中的应用研究[J].燃料化学学报,2004,32(6):745-749.
[11]程俊杰,李振荣,赵亮富.Hβ/Al-SBA-15介微孔复合分子筛负载Ni-W催化剂对萘加氢裂化制BTX的催化性能[J].燃料化学学报,2017,45(1):93-99.
[12]Qiang Zhang,Chunyi Li,Shaojun Xu,et al.Synthesis of a ZSM-5(core)/SAPO-5(shell)composite and its application in FCC[J].Journal of Porous Materials,2013,20(1):171-176.
[13]Shujin Zhu,Suyao Liu,Huaike Zhang,et al.Investigation of synthesis and hydroisomerization performance of SAPO-11/Beta composite molecular sieve[J].Chinese Journal of Catalys is,2014,35(10):1676-1686.
[14]张君涛,宋菁,甄星,等.MCM-41/MOR复合分子筛的制备及其烷烃异构化性能研究[J].燃料化学学报,2017,45(6):675-681.
[15]张君涛,崔生航,申志兵,等.核壳型多级孔道ZSM-5/MCM-41分子筛的制备及其在汽油改质中的应用[J].石油学报(石油加工),2016,32(4):703-709.
[16]Ping Liu,Yue Yao,Jun Wang.Usingβ-MCM-41 composite molecular sieves as supports of bifunctional catalysts for the hydroisomerization of n-heptane[J].Reaction Kinetics Mechanisms&Catalysis,2010,101(2):465-475.
[17]万海,张小雨,张若杰,等.高效ZSM-5-L二元复合分子筛的合成及正戊烷芳构化性能[J].高等学校化学学报,2014,35(10):2220-2226.
[18]史春薇,周文丰,孙晓辉,等.Y/SBA-15复合分子筛的形貌控制及催化正戊烷芳构化性能的研究[J].应用化工,2016,45(6):1085-1088.
[19]张瑞珍,温少波,邢普,等.HZSM-5/SAPO-11复合分子筛的制备、表征及在异丁烷芳构化反应中的催化性能[J].高等学校化学学报,2017,38(1):126-132.
[20]纪永军,张斌,张坤,等.ZSM-5@Mesoporous Silica核壳复合结构分子筛的制备及其甲苯甲醇烷基化择形催化性能的研究[J].化学学报,2013,71(3):371-380.
[21]VAN Vu Dung,MIYAMOTO M,NISHIYAMA N,et al.Catalytic activities and structures of silicalite-1/H-ZSM-5 zeolite composites[J].Micropor Mesopor Mater,2008,115:106-112.
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[23]刘鹏,沈健.ZSM-5-SBA-15复合分子筛制备及甲苯甲醇烷基化性能研究[J].燃料化学学报,2015,43(9):1147-1152.
[24]Ling Zhang,Zhongxiang Jiang,Yue Yu,et al.Synthesis of core-shell ZSM-5@meso-SAPO-34composite and its application in methanol to aromatics[J].Rsc Advances,2015,5(69):55825-55831.
[25]杨冬花,王新波,石宝宝,等.甲醇定向转化制二甲苯的复合分子筛ZSM-5/EU-1的合成及其应用[J].无机材料学报,2014,29(4):357-363.
[26]Liping Li,Xiaojing Cui,Junfen Li,et al.Synthesis of SAPO-34/ZSM-5 composite and its catalytic performance in the conversion of methanol to hydrocarbons[J].Journal of Brazilian Chemical Society,2015,17(1):1-5.
[27]Zuoxing Di,Cheng Yang,Xuejing Jiao,et al.A ZSM-5/MCM-48 based catalyst for methanol to gasoline conversion[J].Fuel,2013,104(104):878-881.
[28]Ho-Jeong Chae,Young-Ha Song,Kwang-Eun Jeong,et al.Physicochemical characteristics of ZSM-5/SAPO-34 composite catalyst for MTOreaction[J].Journal of Physics and Chemistry of Solids,2010,71:600-603.
[29]王政,王林,张国香,等.ZSM-5/磷酸铝复合分子筛在甲醇制烯烃反应中的应用[J].石油学报(石油加工),2011,27(4):543-548.
[30]邢爱华,张新锋.SAPO-5/SAPO-18的合成及其在甲醇制烯烃中的应用[J].天然气化工(C1化学与化工),2017,42(4):22-28.