聚脲弹性体在不同条件下的退化行为及改性研究进展
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摘要
首先介绍了聚脲弹性体的合成原料和合成机理,然后根据合成原料的不同,对聚脲弹性体进行了分类,简述了不同种类聚脲弹性体的特点。在此基础上,总结了聚脲弹性在温度、紫外光、腐蚀介质等单因素条件作用下的退变行为和在氯盐浸渍、干湿循环、荷载作用和冻融循环等多因素耦合作用条件下的退化行为。综述了提升聚脲弹性体防腐性能、力学性能和附着力的改性研究进展,最后指出了当前聚脲弹性体退化行为研究中存在的不足,并展望了未来的研究趋势。
This article first introduced the synthetic materials and principles of polyurea elastomers, classified them by their different synthetic materials, and described characteristics of different kinds of polyurea elastomers. On this basis, it further concluded two types of degradation behaviors. The former resulted from single-factor conditions of the temperature, ultraviolet ray,and aggressive medium; while the later was caused by multi-factor coupling effects of chlorine salt immersion, dry-wet cycle,load effect, and freeze-thaw cycles. Furthermore, this article summarized the progress of studies on improving antiseptic properties and mechanical properties, and modifying adhesive force of polyurea elastomers. In the end, deficiencies and outlook of research trends of studies on polyurea elastomer degradation behaviors were pointed out.
This article first introduced the synthetic materials and principles of polyurea elastomers, classified them by their different synthetic materials, and described characteristics of different kinds of polyurea elastomers. On this basis, it further concluded two types of degradation behaviors. The former resulted from single-factor conditions of the temperature, ultraviolet ray,and aggressive medium; while the later was caused by multi-factor coupling effects of chlorine salt immersion, dry-wet cycle,load effect, and freeze-thaw cycles. Furthermore, this article summarized the progress of studies on improving antiseptic properties and mechanical properties, and modifying adhesive force of polyurea elastomers. In the end, deficiencies and outlook of research trends of studies on polyurea elastomer degradation behaviors were pointed out.
引文
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[2]HONG K,PARK S.Polyurea Microcapsules with Different Structures:Preparation and Properties[J].Journal of Applied Polymer Science,2015,78(4):894-898.
[3]FENG L,IROH J O.Corrosion Resistance and Lifetime of Polyimide-b-Polyurea Novel Copolymer Coatings[J].Progress in Organic Coatings,2014,77(3):590-599.
[4]RIEHLE N,G?TZ T,KANDELBAUER A,et al.Synthesis and Mechanical Characterization of Polysiloxanebased Urea-elastomers Prepared from Amino-terminated Polydimethylsiloxanes and Polydimethyl-methyl-phenylsiloxane-copolymers[J].Data in Brief,2018,18:1784.
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[6]HASNAIN S,RASOOL R,NISHAT N.Antimicrobial Polyurea:Synthesis,Spectral,and Thermal Overview of Some New Metal Polychelates[J].Advances in Polymer Technology,2015,36(2):432-436.
[7]O′CONNOR K S,WATTS A,VAIDYA T,et al.Controlled Chain Walking for the Synthesis of Thermoplastic Polyolefin Elastomers:Synthesis,Structure,and Properties[J].Macromolecules,2016,49(18):6743-6751.
[8]JIANBO L I,BINGQI L I,JIE Y.Experimental Study of Spray Polyurea Elastomer on Dam Face Seepage Engineering[J].Journal of Hydroelectric Engineering,201433(5):187-191.
[9]黄微波.喷涂聚脲弹性体结构与性能的关系——聚天冬氨酸酯SPUA材料[J].上海涂料,2006,44(7):36-38.
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[11]黄微波.喷涂聚脲弹性体结构与性能的关系——芳香族SPUA材料[J].上海涂料,2006,44(5):63-66.
[12]李海扬.港珠澳大桥混凝土聚脲防护技术应用的研究[D].青岛:青岛理工大学,2014.
[13]谢远伟.钢结构防护用聚脲涂层耐海洋大气环境腐蚀研究[D].青岛:青岛理工大学,2013.
[14]向佳瑜.水利工程防护用聚脲涂层附着性能研究[D].青岛:青岛理工大学,2012.
[15]李鑫茂.聚脲防护涂层耐候老化及耐介质腐蚀性能研究[D].青岛:青岛理工大学,2011.
[16]李华灵.温湿度对聚脲力学性能的影响研究[D].青岛:青岛理工大学,2011.
[17]张翔宇.管道防腐大修用聚脲涂料的研究与制备[D].西安:西北工业大学,2007.
[18]曹文豪.TWIP钢可膨胀套管CO_2腐蚀及聚脲涂层的防护效果研究[D].成都:西南石油大学,2012.
[19]徐菲.金属防护用聚脲涂层附着性能研究[D].青岛:青岛理工大学,2014.
[20]黄微波,谢远伟,胡晓,等.海洋腐蚀环境下纯聚脲重防腐涂层耐久性研究[J].上海涂料,2013,51(4):1-5.
[21]黄微波,谢远伟,胡晓,等.海洋大气环境下纯聚脲重防腐涂层耐久性研究[J].材料导报,2013,27(6):23-26.
[22]黄微波,姜琳琳,李晶.纯聚脲技术在油气管道防腐中的应用研究[J].涂料工业,2013,43(11):59-63.
[23]李全德,孟惠民.人工加速老化对聚脲涂料防护性能的影响[J].北京科技大学学报,2011,33(1):71-75.
[24]刘郅媛.聚天门冬氨酸酯聚脲涂层失效行为的EIS研究[D].北京:北京化工大学,2013.
[25]吕平,李志高,张静.聚脲涂层的耐酸?碱?盐腐蚀试验及结果[J].腐蚀与防护,2011,32(2):103-106.
[26]吕平,李鑫茂,马学强.腐蚀介质对聚脲性能的影响[J].新型建筑材料,2010,37(10):59-61.
[27]骆文正,封云芳.紫外线照射导致真丝绸黄变的机理[J].浙江丝绸工学院学报,1990(2):52-57.
[28]吕平.海洋混凝土防护用新型聚天冬氨酸酯聚脲涂层的研究[D].青岛:中国海洋大学,2007.
[29]孙宏刚.海洋混凝土结构防护涂层性能研究[D].青岛:青岛理工大学,2018.
[30]张晓丽.海洋环境作用下混凝土涂层防护性能研究[D].青岛:青岛理工大学,2016.
[31]何金文,杨清萍,黄顺礼,等.环氧大豆油改性聚天冬氨酸酯的制备与研究[J].涂料工业,2015,45(8):29-33.
[32]KUNAL W,MUKESH K,ANAGHA S.High Performance Polyurea Coatings Based on Cardanol[J]Progress in Organic Coatings,2017,106:96-110.
[33]李义滨.新型含氟聚脲的合成?表征及性能研究[D].济南:济南大学,2016.
[34]刘子康,王新锋,段文锋.环氧改性聚脲超重防腐蚀涂料的研制[J].腐蚀与防护,2015,36(04):325-328+333.
[35]司姗姗.注气环境中改性聚脲涂层/P110钢体系的耐蚀性能研究[D].青岛:中国石油大学(华东),2015.
[36]邹涛,李珍,汪在芹,等.聚天冬氨酸酯聚脲纳米复合材料研究[J].长江科学院院报,2010,27(04):53-57.
[37]PRIMEAUX D J.Sprayed Polyureas offer Superior Performance[C]//UTECH’90 meeting.The Hague:Netherlands Congress Center,April 1990.
[38]杨娟,王贵友,胡春圃.改性二胺合成新型脂肪族聚脲弹性体[J].华东理工大学学报,2003(5):480-483+488.
[39]吕平,陈国华,黄微波.不同硬段含量聚天冬氨酸酯聚脲结构和性能研究[J].现代化工,2006(9):28-31+33.
[40]衡丽娜.脂肪族聚脲弹性体及其纳米复合材料的制备[D].大连:大连海事大学,2013.
[41]赵斌,王炳英,侯振波,等.20CrMo钢表面喷涂有机硅改性聚脲的腐蚀行为[J].热加工工艺,2012,41(18):154-156.
[42]王伟.聚脲配套底涂剂附着力影响因素研究[C]//中国聚氨酯工业协会第十八次年会论文集.北京:中国聚氨酯工业协会,2016.
[2]HONG K,PARK S.Polyurea Microcapsules with Different Structures:Preparation and Properties[J].Journal of Applied Polymer Science,2015,78(4):894-898.
[3]FENG L,IROH J O.Corrosion Resistance and Lifetime of Polyimide-b-Polyurea Novel Copolymer Coatings[J].Progress in Organic Coatings,2014,77(3):590-599.
[4]RIEHLE N,G?TZ T,KANDELBAUER A,et al.Synthesis and Mechanical Characterization of Polysiloxanebased Urea-elastomers Prepared from Amino-terminated Polydimethylsiloxanes and Polydimethyl-methyl-phenylsiloxane-copolymers[J].Data in Brief,2018,18:1784.
[5]SAMSON N,MECHIN F,PASCAULT J.Relationships between Synthesis and Mechanical Properties of New Polyurea Materials[J].Journal of Applied Polymer Science,2015,65(12):2265-2280.
[6]HASNAIN S,RASOOL R,NISHAT N.Antimicrobial Polyurea:Synthesis,Spectral,and Thermal Overview of Some New Metal Polychelates[J].Advances in Polymer Technology,2015,36(2):432-436.
[7]O′CONNOR K S,WATTS A,VAIDYA T,et al.Controlled Chain Walking for the Synthesis of Thermoplastic Polyolefin Elastomers:Synthesis,Structure,and Properties[J].Macromolecules,2016,49(18):6743-6751.
[8]JIANBO L I,BINGQI L I,JIE Y.Experimental Study of Spray Polyurea Elastomer on Dam Face Seepage Engineering[J].Journal of Hydroelectric Engineering,201433(5):187-191.
[9]黄微波.喷涂聚脲弹性体结构与性能的关系——聚天冬氨酸酯SPUA材料[J].上海涂料,2006,44(7):36-38.
[10]黄微波.喷涂聚脲弹性体结构与性能的关系——脂肪族SPUA材料[J].上海涂料,2006,44(6):36-38.
[11]黄微波.喷涂聚脲弹性体结构与性能的关系——芳香族SPUA材料[J].上海涂料,2006,44(5):63-66.
[12]李海扬.港珠澳大桥混凝土聚脲防护技术应用的研究[D].青岛:青岛理工大学,2014.
[13]谢远伟.钢结构防护用聚脲涂层耐海洋大气环境腐蚀研究[D].青岛:青岛理工大学,2013.
[14]向佳瑜.水利工程防护用聚脲涂层附着性能研究[D].青岛:青岛理工大学,2012.
[15]李鑫茂.聚脲防护涂层耐候老化及耐介质腐蚀性能研究[D].青岛:青岛理工大学,2011.
[16]李华灵.温湿度对聚脲力学性能的影响研究[D].青岛:青岛理工大学,2011.
[17]张翔宇.管道防腐大修用聚脲涂料的研究与制备[D].西安:西北工业大学,2007.
[18]曹文豪.TWIP钢可膨胀套管CO_2腐蚀及聚脲涂层的防护效果研究[D].成都:西南石油大学,2012.
[19]徐菲.金属防护用聚脲涂层附着性能研究[D].青岛:青岛理工大学,2014.
[20]黄微波,谢远伟,胡晓,等.海洋腐蚀环境下纯聚脲重防腐涂层耐久性研究[J].上海涂料,2013,51(4):1-5.
[21]黄微波,谢远伟,胡晓,等.海洋大气环境下纯聚脲重防腐涂层耐久性研究[J].材料导报,2013,27(6):23-26.
[22]黄微波,姜琳琳,李晶.纯聚脲技术在油气管道防腐中的应用研究[J].涂料工业,2013,43(11):59-63.
[23]李全德,孟惠民.人工加速老化对聚脲涂料防护性能的影响[J].北京科技大学学报,2011,33(1):71-75.
[24]刘郅媛.聚天门冬氨酸酯聚脲涂层失效行为的EIS研究[D].北京:北京化工大学,2013.
[25]吕平,李志高,张静.聚脲涂层的耐酸?碱?盐腐蚀试验及结果[J].腐蚀与防护,2011,32(2):103-106.
[26]吕平,李鑫茂,马学强.腐蚀介质对聚脲性能的影响[J].新型建筑材料,2010,37(10):59-61.
[27]骆文正,封云芳.紫外线照射导致真丝绸黄变的机理[J].浙江丝绸工学院学报,1990(2):52-57.
[28]吕平.海洋混凝土防护用新型聚天冬氨酸酯聚脲涂层的研究[D].青岛:中国海洋大学,2007.
[29]孙宏刚.海洋混凝土结构防护涂层性能研究[D].青岛:青岛理工大学,2018.
[30]张晓丽.海洋环境作用下混凝土涂层防护性能研究[D].青岛:青岛理工大学,2016.
[31]何金文,杨清萍,黄顺礼,等.环氧大豆油改性聚天冬氨酸酯的制备与研究[J].涂料工业,2015,45(8):29-33.
[32]KUNAL W,MUKESH K,ANAGHA S.High Performance Polyurea Coatings Based on Cardanol[J]Progress in Organic Coatings,2017,106:96-110.
[33]李义滨.新型含氟聚脲的合成?表征及性能研究[D].济南:济南大学,2016.
[34]刘子康,王新锋,段文锋.环氧改性聚脲超重防腐蚀涂料的研制[J].腐蚀与防护,2015,36(04):325-328+333.
[35]司姗姗.注气环境中改性聚脲涂层/P110钢体系的耐蚀性能研究[D].青岛:中国石油大学(华东),2015.
[36]邹涛,李珍,汪在芹,等.聚天冬氨酸酯聚脲纳米复合材料研究[J].长江科学院院报,2010,27(04):53-57.
[37]PRIMEAUX D J.Sprayed Polyureas offer Superior Performance[C]//UTECH’90 meeting.The Hague:Netherlands Congress Center,April 1990.
[38]杨娟,王贵友,胡春圃.改性二胺合成新型脂肪族聚脲弹性体[J].华东理工大学学报,2003(5):480-483+488.
[39]吕平,陈国华,黄微波.不同硬段含量聚天冬氨酸酯聚脲结构和性能研究[J].现代化工,2006(9):28-31+33.
[40]衡丽娜.脂肪族聚脲弹性体及其纳米复合材料的制备[D].大连:大连海事大学,2013.
[41]赵斌,王炳英,侯振波,等.20CrMo钢表面喷涂有机硅改性聚脲的腐蚀行为[J].热加工工艺,2012,41(18):154-156.
[42]王伟.聚脲配套底涂剂附着力影响因素研究[C]//中国聚氨酯工业协会第十八次年会论文集.北京:中国聚氨酯工业协会,2016.