铁酸镧的合成及应用研究进展
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摘要
铁酸镧(LaFeO_3),一种稀土复合金属氧化物。具有典型的钙钛矿结构,稳定的晶体结构,以及丰富的物理化学性能,因此它在传感器,催化,固体燃料电池等方面都有着广泛的应用前景。简述了LaFeO_3的结构,现今常用制备方法,制备方法包括溶胶凝胶法,水热法,模板法,还有改性制备。介绍了改性方式,包括掺杂和复合改性。简述将其作为传感器,催化剂,电极使用的原理还有现今的研究进展,最后基于研究现状和不足,展望了铁酸镧的研究方向。
LaFeO_3 is a rare earth composite metal oxide which has a typical perovskite structure. LaFeO_3 has a stable crystal structure and rich physical and chemical properties,so it has a wide applications as sensors,catalysis,solid fuel cells and at other aspects. The structure of LaFeO_3 and the preparation methods commonly used nowadays were briefly described. Include sol-gel method,hydrothermal method,template method,and modified preparation. Modification methods are introduced,including doping and compound modification. The principle of the use as sensors, catalysts and electrodes was briefly described,and the current research progress of LaFeO_3 was introduced. Finally,based on the research status and deficiencies,the research direction of barium ferrite is prospected.
LaFeO_3 is a rare earth composite metal oxide which has a typical perovskite structure. LaFeO_3 has a stable crystal structure and rich physical and chemical properties,so it has a wide applications as sensors,catalysis,solid fuel cells and at other aspects. The structure of LaFeO_3 and the preparation methods commonly used nowadays were briefly described. Include sol-gel method,hydrothermal method,template method,and modified preparation. Modification methods are introduced,including doping and compound modification. The principle of the use as sensors, catalysts and electrodes was briefly described,and the current research progress of LaFeO_3 was introduced. Finally,based on the research status and deficiencies,the research direction of barium ferrite is prospected.
引文
[1]辇理.Mg掺杂La Fe O3纳米粒子及稀土元素掺杂的La PO4纳米棒的合成与性质表征[D].长春:吉林大学,2013.
[2]Arman M M,Ahmed M A,El-Dek S I.Role of a cation vacancy in the exchange-biased La Fe O3multiferroic nanocrystals[J].Journal of Superconductivity&Novel Magnetism,2017,30:1-13.
[3]肖立新,邹德春,等.钙钛矿太阳能电池[M].北京:北京大学出版社,2016:2-5.
[4]杨幸星.柠檬酸溶胶凝胶法合成A位掺杂La Fe O3材料的磁性能研究[D].桂林:广西师范大学,2013.
[5]Sasikala C,Durairaj N,Baskaran I,et al.Transition metal titanium(Ti)doped La Fe O3,nanoparticles for enhanced optical structural and magnetic properties[J].Journal of Alloys&Compounds,2017,712:870-877.
[6]钟慧琼,杨骏,张渊明.制备方法对La Fe O3可见光光催化活性的影响[J].中国有色金属学报,2009,19(1):160-165.
[7]刘阳.Ti O2/La Fe O3微纳米纤维的可控制备及其光催化性能[D].长春:长春工业大学,2014.
[8]崔婷婷.溶胶凝胶法制备La Fe O3纳米颗粒的磁性研究[D].太原:太原理工大学,2017
[9]田旭.钙钛矿型La Mn O3的制备,掺杂及其CO催化氧化性能研究[D].广州:广东工业大学,2016.
[10]吴延龙.Co/Mn掺杂La Fe O3型钙钛矿氧化物的制备及其储氢性能研究[D].西安:西安建筑科技大学,2015.
[11]Zhang Y,Jiang B,Yuan M,et al.Formaldehyde-sensing properties of La Fe O3particles synthesized by citrate sol-gel method[J].Journal of Sol-Gel Science and Technology,2016,79(1):167-175.
[12]肖然.负载型钙钛矿催化剂上丙烯腈催化燃烧的研究[D].北京:北京化工大学,2015.
[13]Singh S,Singh D.Synthesis of La Fe O3nanopowders by glycine-nitrate process without using any solvent:effect of temperature[J].Monatshefte für Chemie-Chemical Monthly,2017,148(5):879-886.
[14]沈宏芳,李清明,王燕民,等.超声波辅助溶胶-凝胶法合成纳米铁酸镧及其光催化性能[J].硅酸盐学报,2018,46(3):402-412.
[15]杨鑫.钙钛矿氧化物微纳结构的水热合成,表征及性能研究[D].杭州:浙江大学,2014.
[16]郭美荣.新型钙钛矿型类纳米纤维的设计,合成及性能研究[D].临汾:山西师范大学,2013.
[17]Phan T T N,Nikoloski A N,Bahri P A,et al.Heterogeneous photo-Fenton degradation of organics using highly efficient Cu-doped La Fe O3,under visible light[J].Journal of Industrial&Engineering Chemistry,2017,61(25):53-64.
[18]杨威.高活性纳米La Fe系钙钛矿的控制合成及其催化脱除小分子污染气体的机制研究[D].北京:北京化工大学,2013.
[19]高宝族.多孔La Fe O3的硬模板制备及其对一氧化碳和甲苯氧化的催化性能研究[D].北京:北京工业大学,2013.
[20]Zhao S,Wang L,Wang Y,et al.Hierarchically porous La Fe O3perovskite prepared from the pomelo peel bio-template for catalytic oxidation of NO[J].Journal of Physics&Chemistry of Solids,2018,116:43-49.
[21]韦娇龙.甲烷解离反应中铁酸镧催化剂表面吸附行为的第一性原理计算研究[D].上海:华东理工大学,2014.
[22]曹枫,刘日胜,屠春燕,等.Sc掺杂La Fe O3的制备及其光催化性能研究[J].稀有金属材料与工程,2016(s1):493-496.
[23]Palima S,Kaushik S D,Siruguri V,et al.Investigation of Ca substitution on the gas sensing potential of La Fe O3nanoparticles towards low concentration SO2gas[J].Dalton Transactions,2016,45(34):13547-13555.
[24]Jeong J H,Song C G,Kim K H,et al.Effect of Mn doping on particulate size and magnetic properties of La Fe O3nanofiber synthesized by electrospinning[J].Journal of Alloys&Compounds,2018,749:599-604.
[25]Mitra A,Mahapatra A S,Mallick A,et al.Improved magneto-electric properties of La Fe O3in La0.8Gd0.2Fe0.97Nb0.03O3[J].Ceramics International,2018,44(4):4442-4449.
[26]Mahapatra A S,Mitra A,Mallick A,et al.Modulation of magnetic and dielectric property of La Fe O3by simultaneous doping with Ca2+and Co2+-ions[J].Journal of Alloys&Compounds,2018,743(30):274-282.
[27]Soltanabadi Y,Jourshabani M,Shariatinia Z.Synthesis of novel Cu O/La Fe O3nanocomposite photocatalysts with superior Fenton-like and visible light photocatalytic activities for degradation of aqueous organic contaminants[J].Separation&Purification Technology,2018,202:227-241.
[28]Kumar R D,Thangappan R,Jayavel R.Synthesis and characterization of La Fe O3/Ti O2nanocomposites for visible light photocatalytic activity[J].Journal of Physics&Chemistry of Solids,2017,101:25-33.
[29]Acharya S,Parida K.A visible light-driven Zn/Cr-La Fe O3nanocomposite with enhanced photocatalytic activity towards H2production and Rh B degradation[J].Chemistryselect,2017,2(31):10239-10248.
[30]Acharya S,Padhi D K,Parida K M.Visible light driven La Fe O3nano sphere/RGO composite photocatalysts for efficient water decomposition reaction[J].Catalysis Today,2017.
[31]王小风.氧化物纳米材料对CO2及还原性气体的气敏性研究[D].济南:山东大学,2014.
[32]Cao E,Wang H,Wang X,et al.Enhanced ethanol sensing performance for chlorine doped nanocrystalline La Fe O3-δ,powders by citric sol-gel method[J].Sensors&Actuators B Chemical,2017,251:885-893.
[33]Wang B,Yu Q,Zhang S,et al.Gas sensing with yolk-shell La Fe O3microspheres prepared by facile hydrothermal synthesis[J].Sensors&Actuators B Chemical,2018,258(1):1215-1222.
[34]陈家浩.镧基钙钛矿型催化剂的NO氧化催化性能研究[D].天津:天津大学,2013.
[35]Roseno K T C,Brackmann R,Silva M A D,et al.Investigation of La Co O3,La Fe O3,and La Co0.5Fe0.5O3,perovskites as catalyst precursors for syngas production by partial oxidation of methane[J].International Journal of Hydrogen Energy,2016,41(40):18178-18192.
[36]Onn T M,Monai M,Dai S,et al.Smart Pd catalyst with improved thermal stability supported on high-surface-area La Fe O3prepared by atomic layer deposition[J].Journal of the American Chemical Society,2018,140(14):4841-4848.
[37]薛荣荣.钙钛矿上含氧有机物选择性催化脱除NO的研究[D].北京:北京化工大学,2013.
[38]孙凤霞,谢燊坤,崔艳丽,等.Sr2+掺杂及非化学计量La Fe O3的溶剂热制备及光催化性能[J].复合材料学报,2016,33(8):1755-1761.
[39]Liang Q,Jin J,Liu C,et al.Constructing a novel p-n heterojunction photocatalyst La Fe O3/g-C3N4,with enhanced visible-light-driven photocatalytic activity[J].Journal of Alloys&Compounds,2017,709:542-548.
[40]Afifah N,Saleh R.Enhancement of photocatalytic activities of perovskite La Fe O3composite by incorporating nanographene platelets[J].Materials Science and Engineering,2017,188(1):012054.
[41]Iervolino G,Vaiano V,Sannino D,et al.Enhanced photocatalytic hydrogen production from glucose aqueous matrices on Ru-doped La Fe O3[J].Applied Catalysis B Environmental,2017,207:182-194.
[42]Dükkanci M.Degradation of bisphenol-a using a sonophoto Fenton-like hybrid process over a La Fe O3perovskite catalyst and a comparison of its activity with that of a Ti O2photocatalyst[J].Turkish Journal of Chemistry,2016,40(5):784-801.
[43]Rusevova K,K9ferstein R,Rosell M,et al.La Fe O3,and Bi Fe O3,perovskites as nanocatalysts for contaminant degradation in heterogeneous Fentonlike reactions[J].Chemical Engineering Journal,2014,239(3):322-331.
[44]Nie Y,Zhang L,Li Y Y,et al.Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of La Fe O3and H2O2[J].Journal of Hazardous Materials,2015,294:195-200.
[45]Jauhar S,Dhiman M,Bansal S,et al.Mn3+ion in perovskite lattice:a potential Fenton’s reagent exhibiting remarkably enhanced degradation ofcationic and anionic dyes[J].Journal of Sol-Gel Science and Technology,2015,75(1):124-133.
[46]罗永春,李慷,张国庆,等.溶胶凝胶法制备钙钛矿型La Fe O3薄膜及其在碱性水溶液中的电化学行为[J].兰州理工大学学报,2014,40(2):1-7.
[47]王玉玲.La M1-xFexO3(M=Ni和Co;0≤x≤1)表征及NOx净化性能的研究[D].福州:福州大学,2014.
[48]Xu Z,Yin Y M,Lu J,et al.A high performance Ni-free redox reversible ceramic anode R-La0.5Sr0.5Fe0.8Cu0.1Ti0.1O3-δfor intermediate temperature solid oxide fuel cells[J].Journal of the Electrochemical Society,2016,163(7):737-743.
[49]Bian L Z,Duan C,Wang L J,et al.Ce-doped La0.7Sr0.3Fe0.9Ni0.1O3-δas symmetric electrode for high performance direct hydrocarbon solid oxide fuel cell[J].Journal of Materials Chemistry A,2017(29):15253-15259.
[50]Chrzan A,Karczewski J,Gazda M,et al.La0.6Sr0.4Co0.2Fe0.8O3-δ,oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone[J].Journal of the European Ceramic Society,2017,37(11):3559-3564.
[51]Nikonov A V,Pavzderin N B,Shkerin S N,et al.Fabrication of multilayer ceramic structure for fuel cell based on La(Sr)Ga(Mg)O3-La(Sr)Fe(Ga)O3,cathode[J].Russian Journal of Applied Chemistry,2017,90(3):369-373.
[52]Wheeler G P,Choi K S.Photoelectrochemical properties and stability of nanoporous p-type La Fe O3photoelectrodes prepared by electrodeposition[J].Acs Energy Letters,2017,2(10):2378-2382.
[53]裴亚茹.钙钛矿型氧化物La Fe O3改性处理及其高温电化学性能研究[D].秦皇岛:燕山大学,2015.
[54]Zhu Z,Peelaers H,Walle C G V D.Electronic and protonic conduction in La Fe O3[J].Journal of Materials Chemistry A,2017,5(29):15367-15379.
[55]Díez-García M I,Gómez R.Metal doping for enhancing the photoelectrochemical behavior of La Fe O3photocathodes[J].Chemsuschem,2017,10(11):2457-2462.
[2]Arman M M,Ahmed M A,El-Dek S I.Role of a cation vacancy in the exchange-biased La Fe O3multiferroic nanocrystals[J].Journal of Superconductivity&Novel Magnetism,2017,30:1-13.
[3]肖立新,邹德春,等.钙钛矿太阳能电池[M].北京:北京大学出版社,2016:2-5.
[4]杨幸星.柠檬酸溶胶凝胶法合成A位掺杂La Fe O3材料的磁性能研究[D].桂林:广西师范大学,2013.
[5]Sasikala C,Durairaj N,Baskaran I,et al.Transition metal titanium(Ti)doped La Fe O3,nanoparticles for enhanced optical structural and magnetic properties[J].Journal of Alloys&Compounds,2017,712:870-877.
[6]钟慧琼,杨骏,张渊明.制备方法对La Fe O3可见光光催化活性的影响[J].中国有色金属学报,2009,19(1):160-165.
[7]刘阳.Ti O2/La Fe O3微纳米纤维的可控制备及其光催化性能[D].长春:长春工业大学,2014.
[8]崔婷婷.溶胶凝胶法制备La Fe O3纳米颗粒的磁性研究[D].太原:太原理工大学,2017
[9]田旭.钙钛矿型La Mn O3的制备,掺杂及其CO催化氧化性能研究[D].广州:广东工业大学,2016.
[10]吴延龙.Co/Mn掺杂La Fe O3型钙钛矿氧化物的制备及其储氢性能研究[D].西安:西安建筑科技大学,2015.
[11]Zhang Y,Jiang B,Yuan M,et al.Formaldehyde-sensing properties of La Fe O3particles synthesized by citrate sol-gel method[J].Journal of Sol-Gel Science and Technology,2016,79(1):167-175.
[12]肖然.负载型钙钛矿催化剂上丙烯腈催化燃烧的研究[D].北京:北京化工大学,2015.
[13]Singh S,Singh D.Synthesis of La Fe O3nanopowders by glycine-nitrate process without using any solvent:effect of temperature[J].Monatshefte für Chemie-Chemical Monthly,2017,148(5):879-886.
[14]沈宏芳,李清明,王燕民,等.超声波辅助溶胶-凝胶法合成纳米铁酸镧及其光催化性能[J].硅酸盐学报,2018,46(3):402-412.
[15]杨鑫.钙钛矿氧化物微纳结构的水热合成,表征及性能研究[D].杭州:浙江大学,2014.
[16]郭美荣.新型钙钛矿型类纳米纤维的设计,合成及性能研究[D].临汾:山西师范大学,2013.
[17]Phan T T N,Nikoloski A N,Bahri P A,et al.Heterogeneous photo-Fenton degradation of organics using highly efficient Cu-doped La Fe O3,under visible light[J].Journal of Industrial&Engineering Chemistry,2017,61(25):53-64.
[18]杨威.高活性纳米La Fe系钙钛矿的控制合成及其催化脱除小分子污染气体的机制研究[D].北京:北京化工大学,2013.
[19]高宝族.多孔La Fe O3的硬模板制备及其对一氧化碳和甲苯氧化的催化性能研究[D].北京:北京工业大学,2013.
[20]Zhao S,Wang L,Wang Y,et al.Hierarchically porous La Fe O3perovskite prepared from the pomelo peel bio-template for catalytic oxidation of NO[J].Journal of Physics&Chemistry of Solids,2018,116:43-49.
[21]韦娇龙.甲烷解离反应中铁酸镧催化剂表面吸附行为的第一性原理计算研究[D].上海:华东理工大学,2014.
[22]曹枫,刘日胜,屠春燕,等.Sc掺杂La Fe O3的制备及其光催化性能研究[J].稀有金属材料与工程,2016(s1):493-496.
[23]Palima S,Kaushik S D,Siruguri V,et al.Investigation of Ca substitution on the gas sensing potential of La Fe O3nanoparticles towards low concentration SO2gas[J].Dalton Transactions,2016,45(34):13547-13555.
[24]Jeong J H,Song C G,Kim K H,et al.Effect of Mn doping on particulate size and magnetic properties of La Fe O3nanofiber synthesized by electrospinning[J].Journal of Alloys&Compounds,2018,749:599-604.
[25]Mitra A,Mahapatra A S,Mallick A,et al.Improved magneto-electric properties of La Fe O3in La0.8Gd0.2Fe0.97Nb0.03O3[J].Ceramics International,2018,44(4):4442-4449.
[26]Mahapatra A S,Mitra A,Mallick A,et al.Modulation of magnetic and dielectric property of La Fe O3by simultaneous doping with Ca2+and Co2+-ions[J].Journal of Alloys&Compounds,2018,743(30):274-282.
[27]Soltanabadi Y,Jourshabani M,Shariatinia Z.Synthesis of novel Cu O/La Fe O3nanocomposite photocatalysts with superior Fenton-like and visible light photocatalytic activities for degradation of aqueous organic contaminants[J].Separation&Purification Technology,2018,202:227-241.
[28]Kumar R D,Thangappan R,Jayavel R.Synthesis and characterization of La Fe O3/Ti O2nanocomposites for visible light photocatalytic activity[J].Journal of Physics&Chemistry of Solids,2017,101:25-33.
[29]Acharya S,Parida K.A visible light-driven Zn/Cr-La Fe O3nanocomposite with enhanced photocatalytic activity towards H2production and Rh B degradation[J].Chemistryselect,2017,2(31):10239-10248.
[30]Acharya S,Padhi D K,Parida K M.Visible light driven La Fe O3nano sphere/RGO composite photocatalysts for efficient water decomposition reaction[J].Catalysis Today,2017.
[31]王小风.氧化物纳米材料对CO2及还原性气体的气敏性研究[D].济南:山东大学,2014.
[32]Cao E,Wang H,Wang X,et al.Enhanced ethanol sensing performance for chlorine doped nanocrystalline La Fe O3-δ,powders by citric sol-gel method[J].Sensors&Actuators B Chemical,2017,251:885-893.
[33]Wang B,Yu Q,Zhang S,et al.Gas sensing with yolk-shell La Fe O3microspheres prepared by facile hydrothermal synthesis[J].Sensors&Actuators B Chemical,2018,258(1):1215-1222.
[34]陈家浩.镧基钙钛矿型催化剂的NO氧化催化性能研究[D].天津:天津大学,2013.
[35]Roseno K T C,Brackmann R,Silva M A D,et al.Investigation of La Co O3,La Fe O3,and La Co0.5Fe0.5O3,perovskites as catalyst precursors for syngas production by partial oxidation of methane[J].International Journal of Hydrogen Energy,2016,41(40):18178-18192.
[36]Onn T M,Monai M,Dai S,et al.Smart Pd catalyst with improved thermal stability supported on high-surface-area La Fe O3prepared by atomic layer deposition[J].Journal of the American Chemical Society,2018,140(14):4841-4848.
[37]薛荣荣.钙钛矿上含氧有机物选择性催化脱除NO的研究[D].北京:北京化工大学,2013.
[38]孙凤霞,谢燊坤,崔艳丽,等.Sr2+掺杂及非化学计量La Fe O3的溶剂热制备及光催化性能[J].复合材料学报,2016,33(8):1755-1761.
[39]Liang Q,Jin J,Liu C,et al.Constructing a novel p-n heterojunction photocatalyst La Fe O3/g-C3N4,with enhanced visible-light-driven photocatalytic activity[J].Journal of Alloys&Compounds,2017,709:542-548.
[40]Afifah N,Saleh R.Enhancement of photocatalytic activities of perovskite La Fe O3composite by incorporating nanographene platelets[J].Materials Science and Engineering,2017,188(1):012054.
[41]Iervolino G,Vaiano V,Sannino D,et al.Enhanced photocatalytic hydrogen production from glucose aqueous matrices on Ru-doped La Fe O3[J].Applied Catalysis B Environmental,2017,207:182-194.
[42]Dükkanci M.Degradation of bisphenol-a using a sonophoto Fenton-like hybrid process over a La Fe O3perovskite catalyst and a comparison of its activity with that of a Ti O2photocatalyst[J].Turkish Journal of Chemistry,2016,40(5):784-801.
[43]Rusevova K,K9ferstein R,Rosell M,et al.La Fe O3,and Bi Fe O3,perovskites as nanocatalysts for contaminant degradation in heterogeneous Fentonlike reactions[J].Chemical Engineering Journal,2014,239(3):322-331.
[44]Nie Y,Zhang L,Li Y Y,et al.Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of La Fe O3and H2O2[J].Journal of Hazardous Materials,2015,294:195-200.
[45]Jauhar S,Dhiman M,Bansal S,et al.Mn3+ion in perovskite lattice:a potential Fenton’s reagent exhibiting remarkably enhanced degradation ofcationic and anionic dyes[J].Journal of Sol-Gel Science and Technology,2015,75(1):124-133.
[46]罗永春,李慷,张国庆,等.溶胶凝胶法制备钙钛矿型La Fe O3薄膜及其在碱性水溶液中的电化学行为[J].兰州理工大学学报,2014,40(2):1-7.
[47]王玉玲.La M1-xFexO3(M=Ni和Co;0≤x≤1)表征及NOx净化性能的研究[D].福州:福州大学,2014.
[48]Xu Z,Yin Y M,Lu J,et al.A high performance Ni-free redox reversible ceramic anode R-La0.5Sr0.5Fe0.8Cu0.1Ti0.1O3-δfor intermediate temperature solid oxide fuel cells[J].Journal of the Electrochemical Society,2016,163(7):737-743.
[49]Bian L Z,Duan C,Wang L J,et al.Ce-doped La0.7Sr0.3Fe0.9Ni0.1O3-δas symmetric electrode for high performance direct hydrocarbon solid oxide fuel cell[J].Journal of Materials Chemistry A,2017(29):15253-15259.
[50]Chrzan A,Karczewski J,Gazda M,et al.La0.6Sr0.4Co0.2Fe0.8O3-δ,oxygen electrodes for solid oxide cells prepared by polymer precursor and nitrates solution infiltration into gadolinium doped ceria backbone[J].Journal of the European Ceramic Society,2017,37(11):3559-3564.
[51]Nikonov A V,Pavzderin N B,Shkerin S N,et al.Fabrication of multilayer ceramic structure for fuel cell based on La(Sr)Ga(Mg)O3-La(Sr)Fe(Ga)O3,cathode[J].Russian Journal of Applied Chemistry,2017,90(3):369-373.
[52]Wheeler G P,Choi K S.Photoelectrochemical properties and stability of nanoporous p-type La Fe O3photoelectrodes prepared by electrodeposition[J].Acs Energy Letters,2017,2(10):2378-2382.
[53]裴亚茹.钙钛矿型氧化物La Fe O3改性处理及其高温电化学性能研究[D].秦皇岛:燕山大学,2015.
[54]Zhu Z,Peelaers H,Walle C G V D.Electronic and protonic conduction in La Fe O3[J].Journal of Materials Chemistry A,2017,5(29):15367-15379.
[55]Díez-García M I,Gómez R.Metal doping for enhancing the photoelectrochemical behavior of La Fe O3photocathodes[J].Chemsuschem,2017,10(11):2457-2462.