MOF衍生的球形银耳状Sb_2O_3结构的合成及其储锂性能（英文）
|
摘要
在液相反应条件下通过MOFs制备了一种新颖的球形银耳状的Sb_2O_3材料,并将其用作锂离子电池(LIBs)的负极材料。探究了反应温度和时间对Sb_2O_3形貌的影响,通过SEM和TEM的结果表明,银耳状Sb_2O_3结构是由许多具有高比表面积的纳米片组成。当银耳状Sb_2O_3用作LIBs负极时,首次放电和充电容量分别达到724和446mA?h/g。在20mA/g的电流密度下循环50圈后,电极仍保持275mA?h/g的高容量,因此该材料极有希望应用于LIBs。
A novel spherical tremella-like Sb_2O_3 was prepared by using metal-organic framworks(MOFs) method under a mild liquid-phase reaction condition, and was further employed as an anode material for lithium-ion batteries(LIBs). The effect of reaction temperature and time on morphologies of Sb_2O_3 was studied. The results from SEM and TEM demonstrate that the tremella-like Sb_2O_3 architecture are composed of numerous nanosheets with high specific surface area. When the tremella-like Sb_2O_3 was used as LIBs anode, the discharge and charge capacities can achieve 724 and 446 mA?h/g in the first cycle, respectively. Moreover, the electrode retains an impressive high capacity of 275 mA?h/g even after 50 cycles at 20 mA/g, indicating that the material is extremely promising for application in LIBs.
A novel spherical tremella-like Sb_2O_3 was prepared by using metal-organic framworks(MOFs) method under a mild liquid-phase reaction condition, and was further employed as an anode material for lithium-ion batteries(LIBs). The effect of reaction temperature and time on morphologies of Sb_2O_3 was studied. The results from SEM and TEM demonstrate that the tremella-like Sb_2O_3 architecture are composed of numerous nanosheets with high specific surface area. When the tremella-like Sb_2O_3 was used as LIBs anode, the discharge and charge capacities can achieve 724 and 446 mA?h/g in the first cycle, respectively. Moreover, the electrode retains an impressive high capacity of 275 mA?h/g even after 50 cycles at 20 mA/g, indicating that the material is extremely promising for application in LIBs.
引文
[1]JI Li-wen,LIN Zhan,ALCOUTLABI M,ZHANG Xiang-wu.Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries[J].Energy Environmental Science,2011,4(8):2682-2699.
[2]WU Hao-bin,CHEN Jun-song,HNG Huey-hoon,LOUXiong-wen.Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries[J].Nanoscale,2012,4(8):2526-2542.
[3]SHI Chong-fu,XIANG Kai-xiong,ZHU Yi-rong,CHENXian-hong,ZHOU Wei,CHEN Han.Preparation and electrochemical properties of nanocable-like Nb2O5/surface-modified carbon nanotubes composites for anode materials in lithium ion batteries[J].Electrochimecal Acta,2017,246:1088-1096.
[4]LONG Zhao-hui,DING Jing,DENG Bo-hua,GONG Jin,LIXiao-bo,YIN Fu-cheng.First-principle study of Li-insertion properties of Ni Si2 as anode materials for lithium-ion batteries[J].Journal of Central South University,2018,49(2):323-329.
[5]ZHOU Hong-ming,GENG Wen-jun,LI Jian.LiPF6 and lithium difluoro(oxalato)borate/ethylene carbonate+dimethyl carbonate+ethyl(methyl)carbonate electrolyte for LiNi0.5Mn1.5O4 cathode[J].Journal of Central South University,2017,24:1013-1018.
[6]LI N,LIAO S,SUN Y,SONG H W,WANG C X.Uniformly dispersed self-assembled growth of Sb2O3/Sb@graphene nanocomposites on a 3D carbon sheet network for high Na-storage capacity and excellent stability[J].Journal of Materials Chemistry A,2015,3(11):5820-5828.
[7]NAM D G,HONG K S,LIM S J,KIM M J,KWON H S.High-performance Sb/Sb2O3 anode materials using a polypyrrole nanowire network for Na-ion batteries[J].Small,2015,11(24):2885-2892.
[8]WU Feng-dan,WANG Yong,TANG Jun-jun.Microwaveassisted synthesis of antimony oxide nanostructures and their electrochemical properties[J].Materials Science Forum,2010,650:157-162.
[9]ZHOU Jing,ZHENG Cai-hong,WANG Hua,YANG Jie,HUPeng-fei,GUO Lin.3D nest-shaped Sb2O3/RGO composite based high-performance lithium-ion batteries[J].Nanoscale,2016,8(39):17131-17135.
[10]ZHOU Xiao-si,LIU Xia,XU Yan,LIU Yun-xia,DAIZhi-hui,BAO Jian-chun.An Sb Ox/reduced graphene oxide composite as a high-rate anode material for sodium-ion batteries[J].Journal of Physical Chemistry C,2014,118(41):23527-23534.
[11]XUE Ming-zhe,FU Zheng-wen.Electrochemical reaction of lithium with nanostructured thin film of antimony trioxide[J].Electrochemical Communications,2006,8(8):1250-1256.
[12]SIMONIN L,LAFONT U,TABRIZI N,SCHMIDT-OTT A,KELDER E-M.Sb/O nano-composites produced via spark discharge generation for Li-ion battery anodes[J].Journal Power Sources,2007,174(2):805-809.
[13]ZHOU Xiao-zhong,ZHANG Zheng-feng,XU Xiao-hu,YAN Jian,MA Guo-fu,LEI Zi-qiang.Anchoring Sb6O13nanocrystals on graphene sheets for enhanced lithium storage[J].ACS Applied Materials Interfaces,2016,8(51):35398-35406.
[14]HE Meng,KRAVCHYK K,WALTER M,KOVALENKO MV.Antimony nanocrystals for high-rate Li-ion and Na-ion battery anodes:Nano versus bulk[J].Nano Letters,2014,14(3):1255-1262.
[15]HU Xing-yun,KONG Ling-hao,HE Meng-chang.Kinetics and mechanism of photopromoted oxidative dissolution of antimony trioxide[J].Environment Science Technology,2014,48(24):14266-14272.
[16]BRYNGELSSON H,ESKHULT J,NYHOLM L,HERRANEN M,ALM O,EDSTR?M K.Electrodeposited Sb and Sb/Sb2O3 nanoparticle coatings as anode materials for Li-ion batteries[J].Chemistry of Materials,2007,19(5):1170-1180.
[17]DENG Zheng-tao,CHEN Dong,TANG Fang-qiong,MENGXian-wei,REN Jun,ZHANG Lin.Orientated attachment assisted self-assembly of Sb2O3 nanorods and nanowires:End-to-end versus side-by-side[J].Journal of Physical Chemistry C,2007,111(14):5325-5330.
[18]WANG Gui-zhi,FENG Jian-min,DONG Lei,LI Xi-fei,LIDe-jun.Antimony(IV)oxide nanorods/reduced graphene oxide as the anode material of sodium-ion batteries with excellent electrochemical performance[J].Electrochimistry Acta,2017,240:203-214.
[19]LI Bin-jie,XU Xiang-min,ZHAO Yan-bao,ZHANG Zhi-jun.Fabrication of Sb2O3 nanobelt bundles via a facile ultrasound-assisted room temperature liquid phase chemical route and evaluation of their optical properties[J].Materials Research Bulletin,2013,48(3):1281-1287.
[20]LI Wei,WANG Kang-li,CHENG Shi-jie,JIANG Kai.Atwo-dimensional hybrid of SbOx nanoplates encapsulated by carbon flakes as a high performance sodium storage anode[J].Journal of Materials Chemistry A,2017,5(3):1160-1167.
[21]DENG Ming-xiang,LI Si-jie,HONG Wan-wan,JIANGYun-ling,XU Wei,SHUAI Hong-lei,ZOU Guo-qiang,HUYun-chu,HOU Hong-shuai,WANG Wen-lei,JI Xiao-bo.Octahedral Sb2O3 as high-performance anode for lithium and sodium storage[J].Materials Chemistry and Physics,2019,223:46-52
[22]KIBSGAARD J,CHEN Zhe-bo,REINECKE B N,JARAMILLO T F.Engineering the surface structure of MoS2to preferentially expose active edge sites for electrocatalysis[J].Nature Materials,2012,11(11):963-969.
[23]WU Ren-bing,QIAN Xu-kun,YU Feng,LIU Hai,ZHOUKun,WEI Jun,HUANG Yi-zhong.MOF-templated formation of porous CuO hollow octahedra for lithium-ion battery anode materials[J].Journal of Materials Chemistry A,2013,1:11126-11129.
[24]SO MONICA C,WIEDERRECHT G P,MONDLOCH J E,HUPP J T,FARHA O K.Metal-organic framework materials for light-harvesting and energy transfer[J].Chemical Communications,2015,51(17):3501-3510.
[25]TAN Yu-ming,CHEN Li-juan,CHEN Han,HOU Qing-lin,CHEN Xian-hong.Synthesis of a symmetric bundle-shaped Sb2O3 and its application for anode materials in lithium ion batteries[J].Materials Letters,2018,212:103-106.
[26]WANG Lu,HAN Yu-zhen,FENG Xiao,ZHOU Jun-wen,QIPeng-fei,WANG Bo.Metal-organic frameworks for energy storage:Batteries and supercapacitors[J].Coordination Chemistry Reviews,2016,307:361-381.
[27]HE Han-na,HUANG Dan,TANG You-gen,WANG Qi,JIXiao-bo,WANG Hai-yan,GUO Zai-ping.Tuning nitrogen species in three-dimensional porous carbon via phosphorus doping for ultra-fast potassium storage[J].Nano Energy,2019,57:728-736.
[28]DONG Shi-hua,LI Cai-xia,GE Xiao-li,LI Zhao-qiang,MIAO Xian-guang,YIN Long-wei.ZnS-Sb2S3@C coredouble shell polyhedron structure derived from metalorganic framework as anodes for high performance sodium ion batteries[J].ACS Nano,2017,11(6):6474-6482.
[29]ZHU Zhi-qiang,WANG Shi-wen,DU Jing,JIN Qi,ZHANGTian-ran,CHENG Fang-yi,CHEN Jun.Ultrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries[J].Nano Letters,2013,14(1):153-157.
[30]ZHANG Lei,WU Hao-bin,MADHAVI S,HNG H H,LOUXiong-wen(David).Formation of Fe2O3 microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties[J].Journal of the American Chemical Society,2012,134:17388-17391.
[31]KANG Wen-pei,TANG Yong-bing,LI Wen-yue,YANG Xia,XUE Hong-tao,YANG Qing-dan,LEE Chun-sing.High interfacial storage capability of porous NiMn2O4/Chierarchical tremella-like nanostructures as the lithium ion battery anode[J].Nanoscale,2015,7(1):225-231.
[32]LIU Hai-yan,ZHANG Wei,SONG Huai-he,CHENXiao-hong,ZHOU Ji-sheng,MA Zhao-kun.Tremella-like graphene/polyaniline spherical electrode material for supercapacitors[J].Electrochimistry Acta,2014,146:511-517.
[33]WANG Qian,YAN Jun,WANG Yan-bo,WEI Tong,ZHANGMi-lin,JING Xiao-yan,FAN Zhuang-jun.Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors[J].Carbon,2014,67(2):119-127.
[34]LIU Hui,ZHANG Fan,LI Wen-yue,ZHANG Xiao-long,LEE Chun-sing,WANG Wen-lou,TANG Yong-bing.Porous tremella-like Mo S2/polyaniline hybrid composite with enhanced performance for lithium-ion battery anodes[J].Electrochimistry Acta,2015,167:132-138.
[35]ZHANG Rui,LI Hui-yong,SUN Dan,LUAN Jing-yi,HUANG Xiao-bing,TANG You-gen,WANG Hai-yan.Facile preparation of robust porous MoS2/C nanosheet networks as anode material for sodium ion batteries[J].Journal of Materials Science,2019,54(3):2472-2482.
[36]ZENG H C.Vapour phase growth of orthorhombic molybdenum trioxide crystals at normal pressure of purified air[J].Journal of Crystal Growth,1998,186:393-402.
[37]ZHANG Zao-li,GUO Lin,WANG Wen-dong.Synthesis and characterization of antimony oxide nanoparticles[J].Journal of Materials Research,2001,16(3):803-805.
[38]WU Ren-bing,QIAN Xu-kun,RUI Xian-hong,LIU Hai,YADIAN Bo-luo,ZHOU Kun,WEI Jun,YAN Qing-yu,FENG Xi-qiao,LONG Yi,WANG Liu-ying,HUANGYi-zhong.Zeolitic imidazolate framework 67-derived high symmetric porous Co3O4 hollow dodecahedra with highly enhanced lithium storage capability[J].Small,2014,10(10):1932-1938.
[39]PHAN A,DOONAN C J,URIBE-ROMO F J,KNOBLER CB,O’KEEFFE M,YAGHI O M.Synthesis,structure,and carbon dioxide capture properties of zeolitic imidazolate frameworks[J].Accounts of Chemical Research,2010,43(1):58-67.
[40]HU Ling-ling,QU Bai-hua,CHEN Li-bao,LI Qiu-hong.Low-temperature preparation of ultrathin nanoflakes assembled tremella-like NiO hierarchical nanostructures for high-performance lithium-ion batteries[J].Materials Letters,2013,108:92-95.
[41]YI Zheng,HAN Qi-gang,LI Xiang,WU Yao-ming,CHENGYong,WANG Li-min.Two-step oxidation of bulk Sb to one-dimensional Sb2O4 submicron-tubes as advanced anode materials for lithium-ion and sodium-ion batteries[J].Chemical Engineering Journal,2017,315:101-107.
[42]ZHOU Xiao-zhong,ZHANG Zheng-feng,LU Xiao-fang,LVXue-yan,MA Guo-fu,WANG Qing-tao,LEI Zi-qiang.Sb2O3nanoparticles anchored on graphene sheets via alcohol dissolution-reprecipitation method for excellent lithium storage properties[J].ACS Applied Materials Interfaces,2017,9:34927-34936.
[43]SUN Qian,REN Qin-qi,LI Hong,FU Zheng-wen.High capacity Sb2O4 thin film electrodes for rechargeable sodium battery[J].Electrochemistry Communications,2011,13(12):1462-1464.
[44]LV Hai-long,QIU Song,LU Gui-xia,FU Ya,LI Xiao-yu,HU Chen-xi,LIU Jiu-rong.Nanostructured antimony/carbon composite fibers as anode material for lithium-ion battery[J].Electrochimistry Acta,2015,151:214-221.
[45]ZHOU Xiao-zhong,ZHANG Zheng-feng,WANG Jian-wen,WANG Qing-tao,MA Guo-fu,LEI Zi-qiang.Sb2O4/reduced graphene oxide composite as high-performance anode material for lithium ion batteries[J].Journal of Alloys and Compounds,2017,699:611-618.
[46]HU Ling-yun,ZHU Xiao-shu,DU Yi-chen,LI Ya-fei,ZHOUXiao-si,BAO Jian-chun.A chemically coupled antimony/multilayer graphene hybrid as a high-performance anode for sodium-ion batteries[J].Chemistry of Materials,2015,27(23):8138-8145.
[47]HOU Hong-shuai,JING Ming-jun,YANG Ying-chang,ZHUYi-rong,FANG Lai-bing,SONG Wei-xin,PAN Cheng-chi,YANG Xu-ming,JI Xiao-bo.Sodium/lithium storage behavior of antimony hollow nanospheres for rechargeable batteries[J].ACS Applied Materials Interfaces,2014,6(18):16189-16196.
[48]ZHANG Yan-dong,XIE Jian,ZHU Tie-jun,CAO Gao-shao,ZHAO Xin-bing,ZHANG Shi-chao.Activation of electrochemical lithium and sodium storage of nanocrystalline antimony by anchoring on graphene via a facile in situ solvothermal route[J].Journal of Power Sources,2014,247(3):204-212.
[2]WU Hao-bin,CHEN Jun-song,HNG Huey-hoon,LOUXiong-wen.Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries[J].Nanoscale,2012,4(8):2526-2542.
[3]SHI Chong-fu,XIANG Kai-xiong,ZHU Yi-rong,CHENXian-hong,ZHOU Wei,CHEN Han.Preparation and electrochemical properties of nanocable-like Nb2O5/surface-modified carbon nanotubes composites for anode materials in lithium ion batteries[J].Electrochimecal Acta,2017,246:1088-1096.
[4]LONG Zhao-hui,DING Jing,DENG Bo-hua,GONG Jin,LIXiao-bo,YIN Fu-cheng.First-principle study of Li-insertion properties of Ni Si2 as anode materials for lithium-ion batteries[J].Journal of Central South University,2018,49(2):323-329.
[5]ZHOU Hong-ming,GENG Wen-jun,LI Jian.LiPF6 and lithium difluoro(oxalato)borate/ethylene carbonate+dimethyl carbonate+ethyl(methyl)carbonate electrolyte for LiNi0.5Mn1.5O4 cathode[J].Journal of Central South University,2017,24:1013-1018.
[6]LI N,LIAO S,SUN Y,SONG H W,WANG C X.Uniformly dispersed self-assembled growth of Sb2O3/Sb@graphene nanocomposites on a 3D carbon sheet network for high Na-storage capacity and excellent stability[J].Journal of Materials Chemistry A,2015,3(11):5820-5828.
[7]NAM D G,HONG K S,LIM S J,KIM M J,KWON H S.High-performance Sb/Sb2O3 anode materials using a polypyrrole nanowire network for Na-ion batteries[J].Small,2015,11(24):2885-2892.
[8]WU Feng-dan,WANG Yong,TANG Jun-jun.Microwaveassisted synthesis of antimony oxide nanostructures and their electrochemical properties[J].Materials Science Forum,2010,650:157-162.
[9]ZHOU Jing,ZHENG Cai-hong,WANG Hua,YANG Jie,HUPeng-fei,GUO Lin.3D nest-shaped Sb2O3/RGO composite based high-performance lithium-ion batteries[J].Nanoscale,2016,8(39):17131-17135.
[10]ZHOU Xiao-si,LIU Xia,XU Yan,LIU Yun-xia,DAIZhi-hui,BAO Jian-chun.An Sb Ox/reduced graphene oxide composite as a high-rate anode material for sodium-ion batteries[J].Journal of Physical Chemistry C,2014,118(41):23527-23534.
[11]XUE Ming-zhe,FU Zheng-wen.Electrochemical reaction of lithium with nanostructured thin film of antimony trioxide[J].Electrochemical Communications,2006,8(8):1250-1256.
[12]SIMONIN L,LAFONT U,TABRIZI N,SCHMIDT-OTT A,KELDER E-M.Sb/O nano-composites produced via spark discharge generation for Li-ion battery anodes[J].Journal Power Sources,2007,174(2):805-809.
[13]ZHOU Xiao-zhong,ZHANG Zheng-feng,XU Xiao-hu,YAN Jian,MA Guo-fu,LEI Zi-qiang.Anchoring Sb6O13nanocrystals on graphene sheets for enhanced lithium storage[J].ACS Applied Materials Interfaces,2016,8(51):35398-35406.
[14]HE Meng,KRAVCHYK K,WALTER M,KOVALENKO MV.Antimony nanocrystals for high-rate Li-ion and Na-ion battery anodes:Nano versus bulk[J].Nano Letters,2014,14(3):1255-1262.
[15]HU Xing-yun,KONG Ling-hao,HE Meng-chang.Kinetics and mechanism of photopromoted oxidative dissolution of antimony trioxide[J].Environment Science Technology,2014,48(24):14266-14272.
[16]BRYNGELSSON H,ESKHULT J,NYHOLM L,HERRANEN M,ALM O,EDSTR?M K.Electrodeposited Sb and Sb/Sb2O3 nanoparticle coatings as anode materials for Li-ion batteries[J].Chemistry of Materials,2007,19(5):1170-1180.
[17]DENG Zheng-tao,CHEN Dong,TANG Fang-qiong,MENGXian-wei,REN Jun,ZHANG Lin.Orientated attachment assisted self-assembly of Sb2O3 nanorods and nanowires:End-to-end versus side-by-side[J].Journal of Physical Chemistry C,2007,111(14):5325-5330.
[18]WANG Gui-zhi,FENG Jian-min,DONG Lei,LI Xi-fei,LIDe-jun.Antimony(IV)oxide nanorods/reduced graphene oxide as the anode material of sodium-ion batteries with excellent electrochemical performance[J].Electrochimistry Acta,2017,240:203-214.
[19]LI Bin-jie,XU Xiang-min,ZHAO Yan-bao,ZHANG Zhi-jun.Fabrication of Sb2O3 nanobelt bundles via a facile ultrasound-assisted room temperature liquid phase chemical route and evaluation of their optical properties[J].Materials Research Bulletin,2013,48(3):1281-1287.
[20]LI Wei,WANG Kang-li,CHENG Shi-jie,JIANG Kai.Atwo-dimensional hybrid of SbOx nanoplates encapsulated by carbon flakes as a high performance sodium storage anode[J].Journal of Materials Chemistry A,2017,5(3):1160-1167.
[21]DENG Ming-xiang,LI Si-jie,HONG Wan-wan,JIANGYun-ling,XU Wei,SHUAI Hong-lei,ZOU Guo-qiang,HUYun-chu,HOU Hong-shuai,WANG Wen-lei,JI Xiao-bo.Octahedral Sb2O3 as high-performance anode for lithium and sodium storage[J].Materials Chemistry and Physics,2019,223:46-52
[22]KIBSGAARD J,CHEN Zhe-bo,REINECKE B N,JARAMILLO T F.Engineering the surface structure of MoS2to preferentially expose active edge sites for electrocatalysis[J].Nature Materials,2012,11(11):963-969.
[23]WU Ren-bing,QIAN Xu-kun,YU Feng,LIU Hai,ZHOUKun,WEI Jun,HUANG Yi-zhong.MOF-templated formation of porous CuO hollow octahedra for lithium-ion battery anode materials[J].Journal of Materials Chemistry A,2013,1:11126-11129.
[24]SO MONICA C,WIEDERRECHT G P,MONDLOCH J E,HUPP J T,FARHA O K.Metal-organic framework materials for light-harvesting and energy transfer[J].Chemical Communications,2015,51(17):3501-3510.
[25]TAN Yu-ming,CHEN Li-juan,CHEN Han,HOU Qing-lin,CHEN Xian-hong.Synthesis of a symmetric bundle-shaped Sb2O3 and its application for anode materials in lithium ion batteries[J].Materials Letters,2018,212:103-106.
[26]WANG Lu,HAN Yu-zhen,FENG Xiao,ZHOU Jun-wen,QIPeng-fei,WANG Bo.Metal-organic frameworks for energy storage:Batteries and supercapacitors[J].Coordination Chemistry Reviews,2016,307:361-381.
[27]HE Han-na,HUANG Dan,TANG You-gen,WANG Qi,JIXiao-bo,WANG Hai-yan,GUO Zai-ping.Tuning nitrogen species in three-dimensional porous carbon via phosphorus doping for ultra-fast potassium storage[J].Nano Energy,2019,57:728-736.
[28]DONG Shi-hua,LI Cai-xia,GE Xiao-li,LI Zhao-qiang,MIAO Xian-guang,YIN Long-wei.ZnS-Sb2S3@C coredouble shell polyhedron structure derived from metalorganic framework as anodes for high performance sodium ion batteries[J].ACS Nano,2017,11(6):6474-6482.
[29]ZHU Zhi-qiang,WANG Shi-wen,DU Jing,JIN Qi,ZHANGTian-ran,CHENG Fang-yi,CHEN Jun.Ultrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries[J].Nano Letters,2013,14(1):153-157.
[30]ZHANG Lei,WU Hao-bin,MADHAVI S,HNG H H,LOUXiong-wen(David).Formation of Fe2O3 microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties[J].Journal of the American Chemical Society,2012,134:17388-17391.
[31]KANG Wen-pei,TANG Yong-bing,LI Wen-yue,YANG Xia,XUE Hong-tao,YANG Qing-dan,LEE Chun-sing.High interfacial storage capability of porous NiMn2O4/Chierarchical tremella-like nanostructures as the lithium ion battery anode[J].Nanoscale,2015,7(1):225-231.
[32]LIU Hai-yan,ZHANG Wei,SONG Huai-he,CHENXiao-hong,ZHOU Ji-sheng,MA Zhao-kun.Tremella-like graphene/polyaniline spherical electrode material for supercapacitors[J].Electrochimistry Acta,2014,146:511-517.
[33]WANG Qian,YAN Jun,WANG Yan-bo,WEI Tong,ZHANGMi-lin,JING Xiao-yan,FAN Zhuang-jun.Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors[J].Carbon,2014,67(2):119-127.
[34]LIU Hui,ZHANG Fan,LI Wen-yue,ZHANG Xiao-long,LEE Chun-sing,WANG Wen-lou,TANG Yong-bing.Porous tremella-like Mo S2/polyaniline hybrid composite with enhanced performance for lithium-ion battery anodes[J].Electrochimistry Acta,2015,167:132-138.
[35]ZHANG Rui,LI Hui-yong,SUN Dan,LUAN Jing-yi,HUANG Xiao-bing,TANG You-gen,WANG Hai-yan.Facile preparation of robust porous MoS2/C nanosheet networks as anode material for sodium ion batteries[J].Journal of Materials Science,2019,54(3):2472-2482.
[36]ZENG H C.Vapour phase growth of orthorhombic molybdenum trioxide crystals at normal pressure of purified air[J].Journal of Crystal Growth,1998,186:393-402.
[37]ZHANG Zao-li,GUO Lin,WANG Wen-dong.Synthesis and characterization of antimony oxide nanoparticles[J].Journal of Materials Research,2001,16(3):803-805.
[38]WU Ren-bing,QIAN Xu-kun,RUI Xian-hong,LIU Hai,YADIAN Bo-luo,ZHOU Kun,WEI Jun,YAN Qing-yu,FENG Xi-qiao,LONG Yi,WANG Liu-ying,HUANGYi-zhong.Zeolitic imidazolate framework 67-derived high symmetric porous Co3O4 hollow dodecahedra with highly enhanced lithium storage capability[J].Small,2014,10(10):1932-1938.
[39]PHAN A,DOONAN C J,URIBE-ROMO F J,KNOBLER CB,O’KEEFFE M,YAGHI O M.Synthesis,structure,and carbon dioxide capture properties of zeolitic imidazolate frameworks[J].Accounts of Chemical Research,2010,43(1):58-67.
[40]HU Ling-ling,QU Bai-hua,CHEN Li-bao,LI Qiu-hong.Low-temperature preparation of ultrathin nanoflakes assembled tremella-like NiO hierarchical nanostructures for high-performance lithium-ion batteries[J].Materials Letters,2013,108:92-95.
[41]YI Zheng,HAN Qi-gang,LI Xiang,WU Yao-ming,CHENGYong,WANG Li-min.Two-step oxidation of bulk Sb to one-dimensional Sb2O4 submicron-tubes as advanced anode materials for lithium-ion and sodium-ion batteries[J].Chemical Engineering Journal,2017,315:101-107.
[42]ZHOU Xiao-zhong,ZHANG Zheng-feng,LU Xiao-fang,LVXue-yan,MA Guo-fu,WANG Qing-tao,LEI Zi-qiang.Sb2O3nanoparticles anchored on graphene sheets via alcohol dissolution-reprecipitation method for excellent lithium storage properties[J].ACS Applied Materials Interfaces,2017,9:34927-34936.
[43]SUN Qian,REN Qin-qi,LI Hong,FU Zheng-wen.High capacity Sb2O4 thin film electrodes for rechargeable sodium battery[J].Electrochemistry Communications,2011,13(12):1462-1464.
[44]LV Hai-long,QIU Song,LU Gui-xia,FU Ya,LI Xiao-yu,HU Chen-xi,LIU Jiu-rong.Nanostructured antimony/carbon composite fibers as anode material for lithium-ion battery[J].Electrochimistry Acta,2015,151:214-221.
[45]ZHOU Xiao-zhong,ZHANG Zheng-feng,WANG Jian-wen,WANG Qing-tao,MA Guo-fu,LEI Zi-qiang.Sb2O4/reduced graphene oxide composite as high-performance anode material for lithium ion batteries[J].Journal of Alloys and Compounds,2017,699:611-618.
[46]HU Ling-yun,ZHU Xiao-shu,DU Yi-chen,LI Ya-fei,ZHOUXiao-si,BAO Jian-chun.A chemically coupled antimony/multilayer graphene hybrid as a high-performance anode for sodium-ion batteries[J].Chemistry of Materials,2015,27(23):8138-8145.
[47]HOU Hong-shuai,JING Ming-jun,YANG Ying-chang,ZHUYi-rong,FANG Lai-bing,SONG Wei-xin,PAN Cheng-chi,YANG Xu-ming,JI Xiao-bo.Sodium/lithium storage behavior of antimony hollow nanospheres for rechargeable batteries[J].ACS Applied Materials Interfaces,2014,6(18):16189-16196.
[48]ZHANG Yan-dong,XIE Jian,ZHU Tie-jun,CAO Gao-shao,ZHAO Xin-bing,ZHANG Shi-chao.Activation of electrochemical lithium and sodium storage of nanocrystalline antimony by anchoring on graphene via a facile in situ solvothermal route[J].Journal of Power Sources,2014,247(3):204-212.