制备正极材料磷酸钴锂的研究进展
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摘要
综述了磷酸钴锂(LiCoPO4)材料的制备方法,包括固相反应法、溶胶-凝胶法、水热/溶剂热法、微波法和喷雾热分解法等方法,并对各种制备方法进行了分析和总结。
Methods to prepare lithium cobalt phosphate( LiCoPO4),including solid phase reaction,sol-gel,hydrothermal/solvothermal,microwave and spray-pyrolysis methods,were summarized and discussed.
Methods to prepare lithium cobalt phosphate( LiCoPO4),including solid phase reaction,sol-gel,hydrothermal/solvothermal,microwave and spray-pyrolysis methods,were summarized and discussed.
引文
[1]Wolfenstine J,Allen J.Ni3+/Ni2+redox potential in LiNiPO4[J].J Power Sources,2005,142(1-2):389-390.
[2]Padhi A K,Nanjundaswamy K,Goodenough J B.Phospho-olivines as positive electrode materials for rechargeable lithium batteries[J].J Electrochem Soc,1997,144(4):1 188-1 194.
[3]Amine K,Yasuda H,Yamachi M.Olivine LiCoPO4as 4.8 V electrode material for lithium batteries[J].Electrochem Solid-State Lett,2000,3(4):178-179.
[4]Bramnik N N,Bramnik K G,Baehtz C,et al.Study of the effect of different synthesis routes on Li extraction insertion from LiCoPO4[J].J Power Sources,2005,145(1):74-81.
[5]Bramnik N N,Bramnik K G,Buhrmester T,et al.Electrochemical and structural study of LiCoPO4-based electrodes[J].J Solid State Eletrochem,2004,8(8):558-564.
[6]Bramnik N N,Nikolowski K,Baehtz C,et al.Phase transitions occurring upon lithium insertion extraction of LiCoPO4[J].Chem Mater,2007,19(4):908-915.
[7]WANG Shao-liang(王绍亮),TANG Zhi-yuan(唐致远),SHA Ou(沙鸥),et al.溶胶-凝胶法制备LiCoPO4及其电化学性能[J].Acta Physico-Chimica Sinica(物理化学学报),2012,28(2):343-348.
[8]Eftekhari A.Surface modification of thin-film based LiCoPO45 V cathode with metal oxide[J].J Electrochem Soc,2004,151(9):A1 456-A1 460.
[9]Satya K M V V M,Varadaraju U V.Influence of isovalent ion substitution on the electrochemical performance of LiCoPO4[J].Mater Res Bull,2005,40(10):1 705-1 712.
[10]LI Lin(李玲),HAN En-shan(韩恩山),ZHU Ling-zhi(朱令之),et al.高温固相法合成Li0.98M0.02Fe0.95V0.05PO4/C的电化学性能[J].Battery Bimonthly(电池),2012,42(2):96-99.
[11]Jin B,Gu H B,Kim K W.Effect of different conductive additives on charge/discharge properties of LiCoPO4/Li batteries[J].J Solid State Electrochem,2008,12(2):105-111.
[12]Wang F,Yang J,Nuli Y N,et al.Highly promoted electrochemical performance of 5 V LiCoPO4cathode material by addition of vanadium[J].J Power Sources,2010,195(19):6 884-6 887.
[13]ZHANG Zhen(张真),LIU Xing-quan(刘兴泉),ZHANG Zheng(张峥),et al.5 V锂离子电池正极材料LiNi0.5Mn1.5O4的进展[J].Battery Bimonthly(电池),2011,41(1):47-50.
[14]LIU Xiao-hong(刘晓红),ZHOU Mei-jie(邹美捷),XU Chun-xiao(许春晓),et al.溶胶-凝胶法所制LiCoPO4及其掺碳材料的电化学性能[J].Journal of Nanchang University(Engineering&Technology)[南昌大学学报(工科版)],2011,33(1):12-16.
[15]Ni J F,Wang H B,Gao L J,et al.A high performance LiCoPO4/C core/shell composite for Li-ion batteries[J].Electrochim Acta,2012,70(1):349-354.
[16]PAN Lin(潘琳),OU Xiu-qin(欧秀芹),SONG Qin-zu(宋清竹),et al.无模板水热合成LiFePO4/C的低温性能[J].Battery Bimonthly(电池),2011,41(4):184-186.
[17]Zhao Y,Wang S,Zhao C,et al.Synthesis and electrochemical performance of LiCoPO4micron-rods by dispersant-aided hydrothermal method for lithium ion batteries[J].Rare Metals,2009,28(2):117-121.
[18]Wang F,Yang J,Nuli Y N,et al.Novel hedgehog-like 5 V LiCoPO4positive electrode material for rechargeable lithium battery[J].J Power Sources,2011,196(1):4 806-4 810.
[19]FU Peng-li(傅鹏立),GU Shu-hua(谷书华),WANG Li-zhen(王力臻),et al.辐射时间对微波法合成Li3V2(PO4)3/C的影响[J].Battery Bimonthly(电池),2011,41(3):129-131.
[20]Li H H,Jin J,Wei J P,et al.Fast synthesis of core-shell LiCoPO4/C nanocomposite via microwave heating and its electrochemical Li intercalation performances[J].Electrochem Commun,2009,11(1):95-98.
[21]Han D W,Kang Y M,Yin R Z,et al.Effects of Fe doping on the electrochemical performance of LiCoPO4/C composites for high power-density cathode materials[J].Electrochem Commun,2009,11(1):137-140.
[22]CHEN Zu-yao(陈祖耀),ZHANG Da-jie(张大杰),QIAN Yi-tai(钱逸泰).喷雾热解法制备超细粉末及其应用[J].Bulletin of the Chinese Ceramic Society(硅酸盐通报),1988,7(6):54-61.
[23]Liu J,Conry T E,Song X Y,et al.Spherical nanoporous LiCoPO4/C composites as high performance cathode materials for rechargeable lithium-ion batteries[J].J Mater Chem,2011,21(27):9 984-9 987.
[24]Doan T N L,Taniguchi I.Preparation of LiCoPO4/C nano composite cathode of lithium batteries with high rate performance[J].J Power Sources,2011,196(13):5 679-5 684.
[25]Tan L,Luo Z M,Liu H W,et al.Synthesis of novel high-voltage cathode material LiCoPO4via rheological phase method[J].J Alloys Compd,2010,502(2):407-410.
[26]Shanmukaraj D,Murugan R.Synthesis and characterization of Li-Ni y Co1-y PO4(y=0~1)cathode materials for lithium secondary batteries[J].Ionics,2004,10(1):88-92.
[27]Devaraju M K,Rangappa D,Honma I.Controlled synthesis of plate-like LiCoPO4nanoparticles via supercritical method and their electrode property[J].Electrochim Acta,85(15):548-553.
[28]SONG Bao-ling(宋宝玲),ZHONG Li-na(种丽娜),LIAO Shen(廖森),et al.低热固相合成锂离子电池正极材料磷酸钴锂[J].Technology&Development of Chemical Industry(化工技术与开发),2009,38(12):1-15.
[2]Padhi A K,Nanjundaswamy K,Goodenough J B.Phospho-olivines as positive electrode materials for rechargeable lithium batteries[J].J Electrochem Soc,1997,144(4):1 188-1 194.
[3]Amine K,Yasuda H,Yamachi M.Olivine LiCoPO4as 4.8 V electrode material for lithium batteries[J].Electrochem Solid-State Lett,2000,3(4):178-179.
[4]Bramnik N N,Bramnik K G,Baehtz C,et al.Study of the effect of different synthesis routes on Li extraction insertion from LiCoPO4[J].J Power Sources,2005,145(1):74-81.
[5]Bramnik N N,Bramnik K G,Buhrmester T,et al.Electrochemical and structural study of LiCoPO4-based electrodes[J].J Solid State Eletrochem,2004,8(8):558-564.
[6]Bramnik N N,Nikolowski K,Baehtz C,et al.Phase transitions occurring upon lithium insertion extraction of LiCoPO4[J].Chem Mater,2007,19(4):908-915.
[7]WANG Shao-liang(王绍亮),TANG Zhi-yuan(唐致远),SHA Ou(沙鸥),et al.溶胶-凝胶法制备LiCoPO4及其电化学性能[J].Acta Physico-Chimica Sinica(物理化学学报),2012,28(2):343-348.
[8]Eftekhari A.Surface modification of thin-film based LiCoPO45 V cathode with metal oxide[J].J Electrochem Soc,2004,151(9):A1 456-A1 460.
[9]Satya K M V V M,Varadaraju U V.Influence of isovalent ion substitution on the electrochemical performance of LiCoPO4[J].Mater Res Bull,2005,40(10):1 705-1 712.
[10]LI Lin(李玲),HAN En-shan(韩恩山),ZHU Ling-zhi(朱令之),et al.高温固相法合成Li0.98M0.02Fe0.95V0.05PO4/C的电化学性能[J].Battery Bimonthly(电池),2012,42(2):96-99.
[11]Jin B,Gu H B,Kim K W.Effect of different conductive additives on charge/discharge properties of LiCoPO4/Li batteries[J].J Solid State Electrochem,2008,12(2):105-111.
[12]Wang F,Yang J,Nuli Y N,et al.Highly promoted electrochemical performance of 5 V LiCoPO4cathode material by addition of vanadium[J].J Power Sources,2010,195(19):6 884-6 887.
[13]ZHANG Zhen(张真),LIU Xing-quan(刘兴泉),ZHANG Zheng(张峥),et al.5 V锂离子电池正极材料LiNi0.5Mn1.5O4的进展[J].Battery Bimonthly(电池),2011,41(1):47-50.
[14]LIU Xiao-hong(刘晓红),ZHOU Mei-jie(邹美捷),XU Chun-xiao(许春晓),et al.溶胶-凝胶法所制LiCoPO4及其掺碳材料的电化学性能[J].Journal of Nanchang University(Engineering&Technology)[南昌大学学报(工科版)],2011,33(1):12-16.
[15]Ni J F,Wang H B,Gao L J,et al.A high performance LiCoPO4/C core/shell composite for Li-ion batteries[J].Electrochim Acta,2012,70(1):349-354.
[16]PAN Lin(潘琳),OU Xiu-qin(欧秀芹),SONG Qin-zu(宋清竹),et al.无模板水热合成LiFePO4/C的低温性能[J].Battery Bimonthly(电池),2011,41(4):184-186.
[17]Zhao Y,Wang S,Zhao C,et al.Synthesis and electrochemical performance of LiCoPO4micron-rods by dispersant-aided hydrothermal method for lithium ion batteries[J].Rare Metals,2009,28(2):117-121.
[18]Wang F,Yang J,Nuli Y N,et al.Novel hedgehog-like 5 V LiCoPO4positive electrode material for rechargeable lithium battery[J].J Power Sources,2011,196(1):4 806-4 810.
[19]FU Peng-li(傅鹏立),GU Shu-hua(谷书华),WANG Li-zhen(王力臻),et al.辐射时间对微波法合成Li3V2(PO4)3/C的影响[J].Battery Bimonthly(电池),2011,41(3):129-131.
[20]Li H H,Jin J,Wei J P,et al.Fast synthesis of core-shell LiCoPO4/C nanocomposite via microwave heating and its electrochemical Li intercalation performances[J].Electrochem Commun,2009,11(1):95-98.
[21]Han D W,Kang Y M,Yin R Z,et al.Effects of Fe doping on the electrochemical performance of LiCoPO4/C composites for high power-density cathode materials[J].Electrochem Commun,2009,11(1):137-140.
[22]CHEN Zu-yao(陈祖耀),ZHANG Da-jie(张大杰),QIAN Yi-tai(钱逸泰).喷雾热解法制备超细粉末及其应用[J].Bulletin of the Chinese Ceramic Society(硅酸盐通报),1988,7(6):54-61.
[23]Liu J,Conry T E,Song X Y,et al.Spherical nanoporous LiCoPO4/C composites as high performance cathode materials for rechargeable lithium-ion batteries[J].J Mater Chem,2011,21(27):9 984-9 987.
[24]Doan T N L,Taniguchi I.Preparation of LiCoPO4/C nano composite cathode of lithium batteries with high rate performance[J].J Power Sources,2011,196(13):5 679-5 684.
[25]Tan L,Luo Z M,Liu H W,et al.Synthesis of novel high-voltage cathode material LiCoPO4via rheological phase method[J].J Alloys Compd,2010,502(2):407-410.
[26]Shanmukaraj D,Murugan R.Synthesis and characterization of Li-Ni y Co1-y PO4(y=0~1)cathode materials for lithium secondary batteries[J].Ionics,2004,10(1):88-92.
[27]Devaraju M K,Rangappa D,Honma I.Controlled synthesis of plate-like LiCoPO4nanoparticles via supercritical method and their electrode property[J].Electrochim Acta,85(15):548-553.
[28]SONG Bao-ling(宋宝玲),ZHONG Li-na(种丽娜),LIAO Shen(廖森),et al.低热固相合成锂离子电池正极材料磷酸钴锂[J].Technology&Development of Chemical Industry(化工技术与开发),2009,38(12):1-15.