化学增强型超薄碱铝硅酸盐玻璃发展概况与展望
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摘要
本文结合触控屏所需的高强型盖板保护玻璃产业发展历程,重点综述了可化学增强碱铝硅酸盐玻璃品种,以溢流和浮法超薄成形工艺为基础,论述了玻璃化学组成特点及变化趋势、离子交换工艺变化,提出了以Al_2O_3含量进行产品分类的标准,定义了低铝玻璃、中铝玻璃、高铝玻璃、超高铝玻璃4个品种。分别讨论了国内外不同生产企业和科研机构在碱铝硅酸盐玻璃所做相关研发工作,对产品的开发和应用方向进行了展望,为广大科研工作者和产业发展提供借鉴。
This paper focused on the varieties of alkali alumina silicate glass with an emphasis of the development of high strength cover glass which is used in touch screen industry. On the basis of overflow and float forming processes,the development of chemical composition and ion exchange process were discussed. Meanwhile,the classification standard of alkali alumina silicate glass was put forward,which is determined by the content of Al_2O_3,defining four types of glass,low,middle,high and ultra-high alumina glass.The relevant researches on the alkali alumina silicate glass products at home and abroad were summarized. The application prospect and the orientation for the products were provided,which can offer a reference for researchers and industry.
This paper focused on the varieties of alkali alumina silicate glass with an emphasis of the development of high strength cover glass which is used in touch screen industry. On the basis of overflow and float forming processes,the development of chemical composition and ion exchange process were discussed. Meanwhile,the classification standard of alkali alumina silicate glass was put forward,which is determined by the content of Al_2O_3,defining four types of glass,low,middle,high and ultra-high alumina glass.The relevant researches on the alkali alumina silicate glass products at home and abroad were summarized. The application prospect and the orientation for the products were provided,which can offer a reference for researchers and industry.
引文
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[28]倪亚茹,张其土,陆春华,等.稀土硼铝硅酸盐玻璃结构及其耐碱性研究[J].材料科学与工程学报,2006,24(3):393-395.
[29]OSAKA A,ONO M,TAKAHASHI K.Aluminum oxide anomaly and structure model of alkali alumino silicate glasses[J].Journal of the American Ceramic Society,2010,70(4):242-245.
[30]TOPLIS M J,DINGWELL D B.The variable influence of P2O5on the viscosity of melts of differing alkali/ahnninium ratio:Implications for the structural role of phosphorus in silicate melts[J].Geochimica et Cosmochimica Acta,1996,21(60):4107-4121.
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[32]王承遇,卢琪,陶瑛.手机玻璃面板化学钢化若干问题的探讨[J].玻璃与搪瓷,2015,43(4):15-19.
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[34]安藤良太.碱铝硅酸盐玻璃的制造方法:CN104884401 A[P].2015-09-02.
[35]田英良,程金树,张磊,等.超薄铝硅酸盐玻璃生产关键技术探讨[J].玻璃与搪瓷,2011,39(1):22-26.
[36]邹世锋,姜宏,赵会峰,等.玻璃中Al2O3含量对离子交换增强性能的影响[J].材料科学与工程学报,2014,32(1):107-111.
[37]程金树,赵薇,肖子凡.化学增强铝硅酸盐玻璃扩散性能研究[J].武汉理工大学学报,2012,34(5):10-14.
[38]田英良,程金树,朱满康,等.K2O/Na2O比对高碱铝硅酸盐玻璃高温电阻特性影响研究[C]//2011国际先进玻璃熔制技术研讨会,上海:2011:73-79.
[39]王耀君.原料对铝硅酸盐触控屏玻璃性能的影响[J].玻璃,2015,40(7):10-12.
[40]王承遇,卢琪,陶瑛.触摸屏手机玻璃面板的性能与制备(二)[J].玻璃与搪瓷,2012,40(6):28-31.
[41]乔斯·西默,张广军,格哈德·劳滕施勒格尔,等.用于化学钢化的铝硅酸盐玻璃和玻璃陶瓷:CN 102690059 A[P].2012-09-26.
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[43]GROSS T M.Ion exchanged glass with high resistance to sharp contact failure and articles made therefrom:US 20130045375 A1[P]:2013-2-28.
[44]GLAESEMANN G S,PRICE J J,SABIA R,et al.Damage resistant chemically-toughened protective cover glass:US8367208[P].2013-2-5.
[45]闫娜,徐东勇,刘史敏,等.康宁公司溢流下拉法制备超薄电子玻璃专利分析[C]//中硅会电子玻璃分会2014年光电子玻璃技术研讨会,深圳,2014:50-57.
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