厦门湾南PM_(10)和PM_(2.5)中重金属特征与健康风险评价
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摘要
于2014年9月-2017年8月在厦门湾南岸收集大气中PM_(10)和PM_(2.5)样品,分别利用冷原子荧光法(CVAFS)与电感耦合等离子体质谱(ICP/MS)分析其中Hg与其他8种典型重金属(Cr、Mn、Ni、Cu、Zn、As、Cd和Pb)的质量浓度,并对重金属的污染水平、来源与健康效应进行评估。结果表明,PM_(10)与PM_(2.5)的质量浓度处于较低的水平,均呈现出冬季>春季、秋季>夏季的特点,且各重金属质量浓度的季节峰值均出现在秋冬季。地累积指数(Igeo)结果显示各重金属的污染程度排序为Mn The concentrations of PM_(2.5) and PM_(10) particles as well as heavy metal concentration in them were studied from September 2014 to August 2017 in the south coast of Xiamen Bay.The analytical techniques used to identify the seasonal variation and their influencing factors were gravimetric and instrumental analysis methods(AFS for Hg and ICP/MS for Cr,Mn,Ni,Cu,Zn,As,Cd and Pb,respectively).The pollution levels and their sources as well as human health risk were assessed.The results indicated that the concentrations of PM_(2.5) and PM_(10) in spring and autumn were lower than that in winter and higher than that in summer.These concentrations were affected by the winds significantly.The highest concentrations of heavy metals were observed in autumn or winter.The values of geo-accumulation index revealed the pollution level order as Mn
引文
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