UV固化聚氨酯丙烯酸酯涂料的研究进展
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摘要
综述了紫外光固化聚氨酯丙烯酸酯(PUA)的反应机理、合成路线及方法,主要介绍了水性PUA、有机氟改性PUA、粉末型PUA、超支化PUA、纳米改性PUA、有机硅改性PUA的制备及其应用,并展望了PUA涂料的发展趋势。
The reaction mechanism, synthetic routes and methods of UV curing polyurethane acrylate(PUA) were reviewed. The preparation and applications of waterborne PUA, organofluorine modified PUA, powder PUA, hyperbranched PUA, nano modified PUA, and organosilicon modified PUA were mainly introduced, and the development trend of PUA coatings was proposed.
The reaction mechanism, synthetic routes and methods of UV curing polyurethane acrylate(PUA) were reviewed. The preparation and applications of waterborne PUA, organofluorine modified PUA, powder PUA, hyperbranched PUA, nano modified PUA, and organosilicon modified PUA were mainly introduced, and the development trend of PUA coatings was proposed.
引文
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[24]YU Bin,WANG Xin,XING Weiyi,et al.UV-Curable functionalized graphene oxide/polyurethane acrylate nanocomposite coatings with enhanced thermal stability and mechanical properties[J].Industrial&Engineering Chemistry Research,2012,51(45):14629-14636.
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[26]LEE J,TURNG L S,DOUGHERTY E,et al.Novel foam injection molding technology using carbon dioxide-laden pellets[J].Polymer Engineering&Science,2011,51(11):2295-2303.
[27]史金,孙芳,杜洪光.有机硅聚氨酯丙烯酸酯预聚物的合成[J].精细与专用化学品,2009,17(23):26-29.
[28]韦军,安庆莲,路璐.光固化聚氨酯丙烯酸酯/Si O2杂化涂层的制备及性能[J].高分子材料科学与工程,2016,32(3):92-95.
[29]曾建伟,唐世英,殷永彪,等.有机硅改性水性聚氨酯丙烯酸酯的合成方法:中国,102060974A[P].2011-05-18.
[30]YU Yong,LIAO Bo,LI Guonai,et al.Synthesis and properties of photosensitive silicone-containing polyurethane acrylate for leather finishing agent[J].Industrial&Engineering Chemistry Research,2014,53(2):564-571.
[31]操越,程继业,孙芳.光聚合型聚硅氧烷改性聚醚聚氨酯丙烯酸酯低聚物的合成、表征与性能[J].精细化工,2015,32(12):1321-1326.
[32]胡飞燕,任碧野,童真,等.有机硅聚氨酯丙烯酸酯UV固化预聚物的研制[J].热固性树脂,2014,29(1):42-45.
[2]王邦清.聚酯型聚氨酯丙烯酸的合成及应用[D].广州:华南理工大学,2012.
[3]姜其斌,李鸿岩,陈红生.绝缘树脂材料工艺与应用[M].北京:化工工业出版社,2013.
[4]陈一虹,黄剑莹,褚佳岩,等.聚氨酯丙烯酸酯的合成和性能研究[J].厦门大学学报(自然版),2006,45(3):370-374.
[5]余宗萍,孙余凭.UV固化三官能脂肪族聚氨酯丙烯酸酯的合成[J].热固性树脂,2006,21(4):23-25.
[6]彭威.紫外光固化聚氨酯丙烯酸酯的制备及性能研究[D].湖南:湖南工业大学,2011.
[7]杨泽惠,倪爱清,殷燕子,等.溶胶-凝胶法制备紫外光固化聚氨酯丙烯酸酯/环氧丙烯酸酯/纳米二氧化硅杂化材料[J].高分子材料科学与工程,2013,29(4):121-124.
[8]WANG Zhiming,GAO Dongbo,YANG Jianwen,et al.Synthesis and characterization of UV-curable waterborne polyurethane-acrylate ionomers for coatings[J].Journal of Applied Polymer Science,1999,73(14):2869-2876.
[9]XU Heping,QIU Fengxian,WANG Yingying,et al.UV-curable waterborne polyurethane-acrylate:preparation,characterization and properties[J].Progress in Organic Coatings,2012,73(1):47-53.
[10]张文君,张海召,杨永登,等.新型水性紫外光固化聚氨酯丙烯酸酯的制备及性能[J].涂料工业,2016,46(8):58-63.
[11]杨帆,张涛,王潮霞,等.不同官能度水性聚氨酯丙烯酸酯的合成及性能[J].精细化工,2015,32(4):466-469,474.
[12]付建萍,赖小娟,李小瑞,等.无溶剂型有机氟改性聚氨酯-聚丙烯酸酯乳液及胶膜的制备与性能[J].功能材料,2016,47(1):1234-1238.
[13]营飞,王木立,顾斌,等.光固化氟化聚氨酯丙烯酸酯的合成与性能研究[J].涂料工业,2016,46(12):36-41.
[14]李培枝,沈一丁,李刚辉.全氟聚氨酯-丙烯酸酯聚合物的制备与应用[J].高分子材料科学与工程,2010,26(3):119-122.
[15]WENNING A,FRANZMANN G,SPYROU E.Powder coating compositions comprising crystalline urethane acrylates and use thereof:USA,US6960620B2[P].2005-11-01.
[16]HUANG Wei,LIANG Hongbo,ZOU Jianhua,et al.UV-curable powder coatings based on dendritic poly(ether-amide)[J].Journal of Applied Polymer Science,2003,90(1):287-291.
[17]ZHANG Yong,ASIF A,SHI Wenfang.Highly branched polyurethane acrylates and their waterborne UV curing coating[J].Progress in Organic Coatings,2011,71(3):295-301.
[18]BAO Fenfen,SHI Wenfang.Synthesis and properties of hyperbranched polyurethane acrylate used for UV curing coatings[J].Progress in Organic Coatings,2010,68(4):334-339.
[19]徐朝华,陈婵,孙宁,等.双键可控紫外光固化超支化聚氨酯丙烯酸酯的制备与表征[J].高等学校化学学报,2016,37(6):1224-1228.
[20]韦军,路璐.纳米Si O2的光敏改性及在光固化复合涂层中的应用[J].高分子材料科学与工程,2017,33(2):34-38.
[21]许雨晴,胡孝勇,柯勇,等.UV固化多官能度聚氨酯丙烯酸酯涂料的制备与性能研究[J].聚氨酯工业,2015(5):26-29.
[22]WANG Xin,XING Weiyi,SONG Lei,et al.Preparation of UV-curable functionalized graphene/polyurethane acrylate nanocomposite with enhanced thermal and mechanical behaviors[J].Reactive and Functional Polymers,2013,73(6):854-858.
[23]戴玉婷.UV固化氧化石墨烯/聚氨酯-丙烯酸酯复合功能涂料的制备及性能研究[D].镇江:江苏大学,2015.
[24]YU Bin,WANG Xin,XING Weiyi,et al.UV-Curable functionalized graphene oxide/polyurethane acrylate nanocomposite coatings with enhanced thermal stability and mechanical properties[J].Industrial&Engineering Chemistry Research,2012,51(45):14629-14636.
[25]KIM D,JEON K,LEE Y,et al.Preparation and characterization of UV-cured polyurethane acrylate/Zn O nanocomposite films based on surface modified Zn O[J].Progress in Organic Coatings,2012,74(3):435-442.
[26]LEE J,TURNG L S,DOUGHERTY E,et al.Novel foam injection molding technology using carbon dioxide-laden pellets[J].Polymer Engineering&Science,2011,51(11):2295-2303.
[27]史金,孙芳,杜洪光.有机硅聚氨酯丙烯酸酯预聚物的合成[J].精细与专用化学品,2009,17(23):26-29.
[28]韦军,安庆莲,路璐.光固化聚氨酯丙烯酸酯/Si O2杂化涂层的制备及性能[J].高分子材料科学与工程,2016,32(3):92-95.
[29]曾建伟,唐世英,殷永彪,等.有机硅改性水性聚氨酯丙烯酸酯的合成方法:中国,102060974A[P].2011-05-18.
[30]YU Yong,LIAO Bo,LI Guonai,et al.Synthesis and properties of photosensitive silicone-containing polyurethane acrylate for leather finishing agent[J].Industrial&Engineering Chemistry Research,2014,53(2):564-571.
[31]操越,程继业,孙芳.光聚合型聚硅氧烷改性聚醚聚氨酯丙烯酸酯低聚物的合成、表征与性能[J].精细化工,2015,32(12):1321-1326.
[32]胡飞燕,任碧野,童真,等.有机硅聚氨酯丙烯酸酯UV固化预聚物的研制[J].热固性树脂,2014,29(1):42-45.