超疏水性铜表面处理技术的研究
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摘要
在电解法制备的低轮廓铜箔表面,采用一种特殊的表面处理工艺和粗化添加剂制备出具有类似荷叶表面微观结构的铜表面。铜表面的超疏水效果良好,静态接触角达到153.6°。该制备方法以目前的电解铜箔生产线为基础,具有操作简单、控制容易、成本较低、条件温和等优点,非常适合连续化生产。该方法可推动超疏水性铜在实际生产中的广泛应用。
A lotus-leaf-like super-hydrophobic surface on the low profile copper foil was fabricated by means of a unique surface treatment technology and with coarsening additive.The copper surface showed good super-hydrophobic effect,and the static contact angle reached 153.6°.This method was based on the current electrolysis copper foil product line,and it has the advantages of simple to operate,easy control,lower cost,mild conditions and very suitable for continuous production.This method can promote the super-hydrophobic surface on copper foil to be widely used in practical production.
A lotus-leaf-like super-hydrophobic surface on the low profile copper foil was fabricated by means of a unique surface treatment technology and with coarsening additive.The copper surface showed good super-hydrophobic effect,and the static contact angle reached 153.6°.This method was based on the current electrolysis copper foil product line,and it has the advantages of simple to operate,easy control,lower cost,mild conditions and very suitable for continuous production.This method can promote the super-hydrophobic surface on copper foil to be widely used in practical production.
引文
[1]BARTHLOTT W,NEINHUIS C.Purity of the sacred lotus,or escape from contamination in biological surface[J].Planta,1997,202(1):1-8.
[2]NEINHUIS C,BARTHLOTT W.Characterization and distribution of water-repellent,self-cleaning plant surfaces[J].Annals of botany,1997,79(6):667-677.
[3]FENG L,LI S H,LI Y S.Super-hydrophobic surface:from natural to artificial[J].Chemlnform,2003,34(24):1857-1860.
[4]LIU K,YAO X,JIANG L.Recent developments in bioinspired special wettability[J].Chemical society reviews,2010,39(8):3240-3255.
[5]FERRER M,CRUCES M A,PLOU F J,et al.A simple procedure for the regioselective synthesis of fatty acid esters of maltose,leucrose,maltotriose and n-dodecyl maltosides[J].Tetrahedron,2000,56:4053-4061.
[6]WISDOM K M,WATSON J A,QU X,et al.Self-cleaning of superhydrophobic surfaces by self-propelled jumping condensate[J].Proceedings of the national academy of sciences,2013,110(20):7992-7997.
[7]SHE Z,LI Q,WANG Z,et al.Researching the fabrication of anticorrosion superhydrophobic surface on magnesium alloy and its mechanical stability and durability[J].Chemical engineering journal,2013,228(28):415-424.
[8]BLOSSEY R.Self-cleaning surfaces-virtual realities[J].Nature materials,2003,2(5):301-306.
[9]霍素斌,于志家,李艳峰,等.超疏水表面微通道内水的流动特性[J].化工学报,2007,58(11):2721-2726.
[10]LAFUMA A,QUERE D.Superhydrophobic states[J].Nature materials,2003,2(7):457-460.
[11]霍正元,陈枫,杨晋涛,等.利用室温等离子体预处理和紫外光引发接枝聚合构造聚丙烯超疏水表面研究[J].科技通报,2009,25(6):711-714.
[12]PAN Q,LIU J,ZHU Q.A water strider-like model with large and stable loading capacity fabricated from superhydrophobic copper foils[J].ACS applied materials&interfaces,2010,2(7):2026-2030.
[13]XU X,ZHANG Z,GUO F,et al.Fabrication of bionic superhydrophobic manganese oxide/polystyrene nanocomposite coating[J].Journal of bionic engineering,2012,9(1):11-17.
[14]LIU K,JIANG L.Metallic surfaces with special wettability[J].Nanoscale,2011,3(3):825-838.
[15]邱宇辰,刘克松,江雷.花生叶表面的高黏附超疏水特性研究及其仿生制备[J].中国科学:化学,2011(2):403-408.
[16]叶霞,周明,李健,等.从自然到仿生的超疏水表面的微观结构[J].纳米技术与精密工程,2009,7(5):381-386.
[17]TESCH S,GERHARDS C,SCHUBERT H.Stabilization of emulsions by OSA starches[J].Journal of food engineering,2002,54(2):167-174.
[18]SPARROW R L,HEALEY G,PATTON K A,et al.Distribution of octenyl succinate groups in octenyl succinic anhydride modified waxy maize starch[J].Starch-Starke,2000,52(6):196-204.
[19]WENZEL R N.Resistance of solid surfaces to wetting by water[J].Industrial&engineering chemistry,1936,28(8):988-994.
[20]CASSIE A B D.Wettability of porous surfaces[J].Transactions of the faraday society,1994,40:546-551.
[21]QIAN B,SHEN Z.Fabrication of superhydrophobic surfaces by dislocation-selective chemical etching on aluminum,copper,and zinc substrates[J].Langmuir,2005,21(20):9007-9009.
[22]XI W,QIAO Z,ZHU C,et al.The preparation of lotus-like super-hydrophobic copper surfaces by electroplating[J].Applied surface science,2009,255(9):4836-4839.
[23]SARKAR D K,SALEEMA N.One-step fabrication process of super-hydrophobic green coatings[J].Surface and coatings technology,2010,204(15):2483-2486.
[24]THIEME M,FRENZEL R,SCHMIDT S,et al.Generation of ultra-hydrophobic properties of aluminum-a first step to selfcleaning transparently coated metal surfaces[J].Advanced engineering materials,2001,3(9):691-695.
[25]RAO A V,LATTHE S S,MAHADIK S A,et al.Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate[J].Applied surface science,2011,257(13):5772-5776.
[26]王景刚,王芳,罗和义,等.铜表面复合超疏水薄膜的制备与表征[J].精细化工,2011,28(2):108-110.
[27]曹凯,张谦,陈福明.酸性镀铜法制备黄铜基超疏水表面[J].电镀与涂饰,2014,33(4):137-141.
[28]张万强,陈新华,李大鹏,等.铜基底超疏水薄膜的制备[J].广东化工,2015,42(11):67-68.
[29]马福民,郝全勇,张燕,等.氧化还原法刻蚀制备铜基超疏水表面[J].科学技术与工程,2013,13(14):3960-3962.
[2]NEINHUIS C,BARTHLOTT W.Characterization and distribution of water-repellent,self-cleaning plant surfaces[J].Annals of botany,1997,79(6):667-677.
[3]FENG L,LI S H,LI Y S.Super-hydrophobic surface:from natural to artificial[J].Chemlnform,2003,34(24):1857-1860.
[4]LIU K,YAO X,JIANG L.Recent developments in bioinspired special wettability[J].Chemical society reviews,2010,39(8):3240-3255.
[5]FERRER M,CRUCES M A,PLOU F J,et al.A simple procedure for the regioselective synthesis of fatty acid esters of maltose,leucrose,maltotriose and n-dodecyl maltosides[J].Tetrahedron,2000,56:4053-4061.
[6]WISDOM K M,WATSON J A,QU X,et al.Self-cleaning of superhydrophobic surfaces by self-propelled jumping condensate[J].Proceedings of the national academy of sciences,2013,110(20):7992-7997.
[7]SHE Z,LI Q,WANG Z,et al.Researching the fabrication of anticorrosion superhydrophobic surface on magnesium alloy and its mechanical stability and durability[J].Chemical engineering journal,2013,228(28):415-424.
[8]BLOSSEY R.Self-cleaning surfaces-virtual realities[J].Nature materials,2003,2(5):301-306.
[9]霍素斌,于志家,李艳峰,等.超疏水表面微通道内水的流动特性[J].化工学报,2007,58(11):2721-2726.
[10]LAFUMA A,QUERE D.Superhydrophobic states[J].Nature materials,2003,2(7):457-460.
[11]霍正元,陈枫,杨晋涛,等.利用室温等离子体预处理和紫外光引发接枝聚合构造聚丙烯超疏水表面研究[J].科技通报,2009,25(6):711-714.
[12]PAN Q,LIU J,ZHU Q.A water strider-like model with large and stable loading capacity fabricated from superhydrophobic copper foils[J].ACS applied materials&interfaces,2010,2(7):2026-2030.
[13]XU X,ZHANG Z,GUO F,et al.Fabrication of bionic superhydrophobic manganese oxide/polystyrene nanocomposite coating[J].Journal of bionic engineering,2012,9(1):11-17.
[14]LIU K,JIANG L.Metallic surfaces with special wettability[J].Nanoscale,2011,3(3):825-838.
[15]邱宇辰,刘克松,江雷.花生叶表面的高黏附超疏水特性研究及其仿生制备[J].中国科学:化学,2011(2):403-408.
[16]叶霞,周明,李健,等.从自然到仿生的超疏水表面的微观结构[J].纳米技术与精密工程,2009,7(5):381-386.
[17]TESCH S,GERHARDS C,SCHUBERT H.Stabilization of emulsions by OSA starches[J].Journal of food engineering,2002,54(2):167-174.
[18]SPARROW R L,HEALEY G,PATTON K A,et al.Distribution of octenyl succinate groups in octenyl succinic anhydride modified waxy maize starch[J].Starch-Starke,2000,52(6):196-204.
[19]WENZEL R N.Resistance of solid surfaces to wetting by water[J].Industrial&engineering chemistry,1936,28(8):988-994.
[20]CASSIE A B D.Wettability of porous surfaces[J].Transactions of the faraday society,1994,40:546-551.
[21]QIAN B,SHEN Z.Fabrication of superhydrophobic surfaces by dislocation-selective chemical etching on aluminum,copper,and zinc substrates[J].Langmuir,2005,21(20):9007-9009.
[22]XI W,QIAO Z,ZHU C,et al.The preparation of lotus-like super-hydrophobic copper surfaces by electroplating[J].Applied surface science,2009,255(9):4836-4839.
[23]SARKAR D K,SALEEMA N.One-step fabrication process of super-hydrophobic green coatings[J].Surface and coatings technology,2010,204(15):2483-2486.
[24]THIEME M,FRENZEL R,SCHMIDT S,et al.Generation of ultra-hydrophobic properties of aluminum-a first step to selfcleaning transparently coated metal surfaces[J].Advanced engineering materials,2001,3(9):691-695.
[25]RAO A V,LATTHE S S,MAHADIK S A,et al.Mechanically stable and corrosion resistant superhydrophobic sol-gel coatings on copper substrate[J].Applied surface science,2011,257(13):5772-5776.
[26]王景刚,王芳,罗和义,等.铜表面复合超疏水薄膜的制备与表征[J].精细化工,2011,28(2):108-110.
[27]曹凯,张谦,陈福明.酸性镀铜法制备黄铜基超疏水表面[J].电镀与涂饰,2014,33(4):137-141.
[28]张万强,陈新华,李大鹏,等.铜基底超疏水薄膜的制备[J].广东化工,2015,42(11):67-68.
[29]马福民,郝全勇,张燕,等.氧化还原法刻蚀制备铜基超疏水表面[J].科学技术与工程,2013,13(14):3960-3962.