有机-无机离子纳米粒子的合成及在聚合物中的应用研究进展
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摘要
有机-无机离子纳米粒子在无溶剂的条件下具备类似于液体的流动性、导电性能和耐热性能好、粒子自组装有序排列、呈现单分散核-壳粒子、结构稳定及具有绿色环保性等优点,能在纳米材料领域广泛应用。重点介绍了有机-无机离子纳米粒子的制备方法、分类、原理及在高分子复合材料领域的应用前景,并指出其在实际应用中遇到的瓶颈。
Organic-inorganic ionic nanoparticle exhibit unique properties due to its liquid-like rheological behavior without solvent,such as electrical conductivity and heat resistance,self-assembly arrangement orderly,mono-dispersion and structural stability of nanoparticle,green environmental protection and so on.It has widely been applied in the field of nano-materials.Its preparation method,classification,principle and its application prospect in the field of polymer composites are summarized,and the difficulty in the practical application is pointed out.
Organic-inorganic ionic nanoparticle exhibit unique properties due to its liquid-like rheological behavior without solvent,such as electrical conductivity and heat resistance,self-assembly arrangement orderly,mono-dispersion and structural stability of nanoparticle,green environmental protection and so on.It has widely been applied in the field of nano-materials.Its preparation method,classification,principle and its application prospect in the field of polymer composites are summarized,and the difficulty in the practical application is pointed out.
引文
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2 Li Q,et al.The effect of the addition of carbon nanotube fluids to a polymeric matrix to produce simultaneous reinforcement and plasticization[J].Carbon,2012,50:2045
3 Yin X Z,Tan Y Q,Gao Y,et al.Viscoelasticity of shellcrosslinked core-shell nanoparticles filled in polystyrene melt[J].Polymer,2012,53(14):3968
4 Livi S,Bugatti V,Estevez L,et al.Synthesis and physical properties of new layered double hydroxides based on ionic liquids:Application to apolylactide matrix[J].J Colloid Interf Sci,2012,388(1):123
5 Yang Y K,Yu L J,Peng R G,et al.Incorporation of liquid-like multiwalled carbon nanotubes into an epoxy matrix by solvent-free processing[J].Nanotechnology,2012,23(22):225701
6 Ma H Y,et al.Improving toughness of ultra-high molecular weight polyethylene with ionic liquid modified carbon nanofiber[J].Polymer,2014,55(1):160
7 李琦,吴晓彦,董丽杰,等.SiO2纳米类流体及其复合材料的电性能研究[J].武汉理工大学学报,2011,33(1):22
8 Rodriguez R,Herrera R,Archer L A,et al.Nanoscale ionic materials[J].Adv Mater,2008,20(22):4353
9 Bourlinos A B,et al.Functionalized ZnO nanoparticles with liquid like behavior and their photoluminescence properties[J].Small,2006,2(4):513
10 Bourlinos A B,Herrera R,Chalkias N,et al.Surface-functionalized nanoparticles with liquid-like behavior[J].Adv Mater,2005,17(2):234
11 Bourlinos A B,Ray Chowdhury S,Herrera R,et al.Functionalized nanostructures with liquid-like behavior:Expanding the gallery of available nanostructures[J].Adv Funct Mater,2005,15(8):1285
12 Zheng Y P,et al.Sepiolite nanofluids with liquid-like behavior[J].Appl Surf Sci,2011,257(14):6171
13 Jespersen M L,et al.Canopy dynamics in nanoscale ionic materials[J].ACS Nano,2010,4(7):3735
14 Rodriguez R,Herrera R,Bourlinos A B,et al.The synthesis and properties of nanoscale ionic materials[J].Appl Organomet Chem,2010,24(8):581
15 Bourlinos A B,Georgakilas V,Tzitzios V,et al.Functionalized carbon nanotubes:Synthesis of meltable and amphiphilic derivatives[J].Small,2006,2(10):1188
16 Fukushima T,Kosaka A,Ishimura Y,et al.Molecular ordering of organic molten salts triggered by single-walled carbon nanotubes[J].Science,2003,300(5628):2072
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19 Zhang J X,Zheng Y P,Lan L,et al.Direct synthesis of solvent-free multiwall carbon nanotubes/silica nonionic nanofluid hybrid material[J].ACS Nano,2009,3(8):2185
20 Zhang Y,Shen Y,Li J,et al.Electrochemical functionalization of single-walled carbon nanotubes in large quantities at a room-temperature ionic liquid supported three-dimensional network electrode[J].Langmuir,2005,21(11):4797
21 Fernandes N,Dallas P,Rodriguez R,et al.Fullerol ionic fluids[J].Nanoscale,2010,2(9):1653
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23 Zheng Y,Zhang J,Lan L,et al.Preparation of solvent-free gold nanofluids with facile self-assembly technique[J].Chem Phys Chem,2010,11(1):61
24 李琦.纳米类流体制备技术、结构与形成机制[D].武汉:武汉理工大学,2010
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28 Zhang J X,Zheng Y P,Yu P Y,et al.The synthesis of functionalized carbon nanotubes by hyperbranched poly(amine-ester)with liquid-like behavior at room temperature[J].Polymer,2009,50(13):2953
29 李琦,杜欣,黄静,等.低聚物离子液体修饰石墨烯的性能研究[C]//2011年全国高分子学术论文报告会论文集.大连,2011
30 Tang Z,Zeng C,Lei Y,et al.Fluorescent whitening agent stabilized graphene and its composites with chitosan[J].J Mater Chem,2011,21(43):17111
31 Wu L S,Zhang B Q,Lu H,et al.Nanoscale ionic materials based on hydroxyl-functionalized graphene[J].J Mater Chem A,2014,5(5):1409
32 Wu F,Zheng Y,Qu P,et al.A liquid-like multiwalled carbon nanotube derivative and its epoxy nanocomposites[J].J Appl Polym Sci,2013,130(3):2217
33 Texter J,Qiu Z,Crombez R,et al.Nanofluid acrylate composite resins-initial preparation and characterization[J].Polym Chem,2011,2(8):1778
34 Rogers R,Seddon K.Ionic liquids-solvents of the future[J].Science,2003,302(5646):792
35 Matsumoto K,Talukdar B,Endo T.Synthesis and properties of methacrylate-based ionic networked polymers containing ionic liquids:Comparison of ionic and nonionic networked polymers[J].Polym Bull,2011,66(6):771