高能钝感推进剂配方改性的研究进展
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摘要
分别从含能黏合剂、含能增塑剂、高能填料以及高能填料的物理及化学改性等方面,综述了高能钝感推进剂配方改性的研究进展。高能钝感推进剂的发展趋势表明,如何协调推进剂的高能量与低感度的矛盾是今后的研究重点。具体途径包括以下三点:新型钝感含能组分在推进剂中的应用研究、高能推进剂结构与感度的构效关系研究以及高能量密度材料的降感改性研究。
The progress of high energy insensitive solid propellant has been reviewed in respect of energetic binder,energetic plasticizer,energetic high energy filler and surface/interface modification technology of high energy fillers. The development tendency of high energy insensitive solid propellant indicated that,how to resolve the conflict between high energy and insensitive is vital for the future research of propellant. Three specific methods contains,applied research of novel energetic insensitive constituents for propellant,study on the structure function relationship of high energy propellant,and desensitization technology of high energy density materials.
The progress of high energy insensitive solid propellant has been reviewed in respect of energetic binder,energetic plasticizer,energetic high energy filler and surface/interface modification technology of high energy fillers. The development tendency of high energy insensitive solid propellant indicated that,how to resolve the conflict between high energy and insensitive is vital for the future research of propellant. Three specific methods contains,applied research of novel energetic insensitive constituents for propellant,study on the structure function relationship of high energy propellant,and desensitization technology of high energy density materials.
引文
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3侯林法.复合固体推进剂.北京:宇航出版社,1994Hou Linfa.Composite solid propellant.Beijing:Aerospace Press,1994
4 Sikder A,Sikder N,et al.A review of advanced high performance,insensitive and thermally stable energetic materials emerging for military and space applications.Journal of Hazardous Materials,2004;112(1):1-15
5 Badgujar D,Talawar M,Asthana S,et al.Advances in science and technology of modern energetic materials:An overview.Journal of Hazardous Materials,2008;151(2):289-305
6 Pagoria P,Lee G,Mitchell A,et al.A review of energetic materials synthesis.Thermochimica Acta,2002;384(1):187-204
7 Kadirech P,Sridhar B.Experimental study on ballistic behavior of an aluminized AP/HTPB propellant during accelerated aging.Journal of Thermal Analysis and Calorimetry,2010;100(1):331-335
8 Frankel M,Grant L,Flanagan J.Historical development of glycidyl azide polymer.Journal of Propulsion and Power,1992;8(3):560-563
9 Frankel M,Flanagan J.Energetic hydroxy-terminated azide polymer:US 4268450.1981-05-19
10 Kim C,Yoon J,Min B,et al.Insensitive propellant composition:US0227875.2012-09-13
11翟进贤,杨荣杰.BAMO-THF复合推进剂催化燃烧特性分析.推进技术,2010;31(2):226-229Zhai Jingxian,Yang Rongjie.Analysis on properties of catalytic combustion of composite BAMO-THF propellants.Journal of Propulsion Technology,2010;31(2):226-229
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14 Murray J,Politzer P.Structure-sensitivity relationships in energetic compounds.Berlin:Springer Netherlands,1990;309:157-173
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24尹华丽,李东峰,张纲要.丁羟推进剂粘接体系中的组分迁移.固体火箭技术,2007;30(5):416-419Yin Huali,Li Dongfeng,Zhang Gangyao.Ingredient migration in the bond system of HTPB propellant.Journal of Solid Rocket Technology,2007;30(5):416-419
25杨月诚,焦东明,强洪夫,等.HTPB推进剂组分溶度参数的分子模拟研究.含能材料,2008;16(2):191-195Yang Yuecheng,Jiao Dongming,Qiang Hongfu,et al.Molecular simulation of solubility parameter for HTPB solid propellants.Chinese Journal of Energetic Materials,2008;16(2):191-195
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31 Milton B F,Cunningham M A,Wilson E R.Glycidyl azide polymer azide:US 2285624 A,1995
32 Wang G,Ge Z,Luo Y J.Thermal decomposition kinetics of poly-(3,3'-bisazidomethyl oxetane-3-azidomethyl-3'-methyl oxetane).Journal of Thermal Analysis and Calorimetry,2015;122(3):1515-1523
33 Wang G,Ge Z,Luo Y J.Synthesis and characterization of poly(3-azido-methyl-3-methyl oxetane)by the azidation of poly(3-mesyloxymethyl-3-methyl oxetane).Propellants,Explosives,Pyrotechnics,2015;40(6):920-926
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35 Agarwal J P,Hodgson R D,Organic chemistry of explosives.New York:Wiley,2007
36 Provatas A.Energetic plasticizer migration studies.Journal of Energetic Materials,2003;21(4):237-245
37 Willer R W,Stearn A G,Day R S,Polyglycidyl nitrate plasticizers:US 5380777,1995
38 Kumari D,Singh H,Patil M,et al.Synthesis,characterization,thermal and computational studies of novel tetraeazido esters as energetic plasticizers.Thermochimca Acta,2013;562:96-104
39 Zhang M,Eaton P E,Gilardi R.Hepta-and octanitrocubanes.Angewandte Chemie International Edition,2000;39:401-404
40 Tao G H,Guo Y,Parrish D A,et al.Energetic 1,5-diamino-4H-tetrazolium nitro-substituted azolates.Journal of Materials Chemistry,2010;20(15):2999-3005
41 Lin Q H,Li Y C,Li Y Y,et al.Energetic salts based on 1-amino-1,2,3-triazole and 3-methyl-1-amino-1,2,3-triazole.Journal of Materials Chemistry,2012;22(2):666-674
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45 Thomas H,Heike P,Jasmin A,et al.Ammonium dinitramide(ADN)-prilling,coating,and characterization.Propellants,Explosives,Pyrotechnics,2009;34(3):231-238
46 Lan L.Advances in the evaluation of FOX-7.28th Proceedings of the International Pyrotechnics Seminar.Reston:American Institute of Aeronautics and Astronautics,2001:479-489
47陈中娥,李忠友,姚南,等.FOX-7及含FOX-7的HTPB推进剂安全性能.含能材料,2010;18(3):316-319Chen Zhonge,Li youzhong,Yao Nan.et al.Safety property of FOX-7 and HTPB propellants with FOX-7.Chinese Journal of Energetic Materials,2010;18(3):316-319
48王伯周,刘愆,张志忠,等.新型含能材料FOX-12性能研究.含能材料,2004;12(1):38-39Wang Bozhou,Liu Qian,Zhang Zhizhong,et al.Study on properties of FOX-12.Chinese Journal of Energetic Materials,2004;12(1):38-39
49杨通辉,何金选,张海林.N-脒基脲二硝酰胺盐(FOX-12)的合成与表征.含能材料,2004;12(1):36-37Yang Tonghui,He jinxuan,Zhang Hailin.Synthesis and characterization of FOX-12.Chinese Journal of Energetic Materials,2004;12(1):36-37
50 Agrawal J P,Walley S M,Field J E.A high speed photographic study of the impact initiation of NTO and CL-20.Combustion and Flame,1998;112(1-2):62-72
51 Sikder A K,Rao P C,Agrawal J P.Synthesis and characterization of some new acid salts of 8H-2,6,8,9,10-Pentaazabicyclo-(5.2.1)-Deca-2,5,9,10-Tetracene.Journal of Energetic Materials,2000;18(4):289-297
52 Agrawal J P,Mehilal N,Sikder,Sikder A.K.,A thermally stable insensitive high explosive.Indian Journal of Engineering and Materials Sciences,2004;11:516-520
53 Zheng S T,Wu T,Chou C T.Development of composite inorganic building blocks for MOFs.Journal of the American Chemical Society,2012;134(10):4517-4520
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2庞爱民,黎小平.固体推进剂技术的创新与发展规律.含能材料,2015;23(1):3-6Pang Aimin,Li Xiaoping.The innovation and development law of solid propellant technology.Chinese Journal of Energetic Materials,2015;23(1):3-6
3侯林法.复合固体推进剂.北京:宇航出版社,1994Hou Linfa.Composite solid propellant.Beijing:Aerospace Press,1994
4 Sikder A,Sikder N,et al.A review of advanced high performance,insensitive and thermally stable energetic materials emerging for military and space applications.Journal of Hazardous Materials,2004;112(1):1-15
5 Badgujar D,Talawar M,Asthana S,et al.Advances in science and technology of modern energetic materials:An overview.Journal of Hazardous Materials,2008;151(2):289-305
6 Pagoria P,Lee G,Mitchell A,et al.A review of energetic materials synthesis.Thermochimica Acta,2002;384(1):187-204
7 Kadirech P,Sridhar B.Experimental study on ballistic behavior of an aluminized AP/HTPB propellant during accelerated aging.Journal of Thermal Analysis and Calorimetry,2010;100(1):331-335
8 Frankel M,Grant L,Flanagan J.Historical development of glycidyl azide polymer.Journal of Propulsion and Power,1992;8(3):560-563
9 Frankel M,Flanagan J.Energetic hydroxy-terminated azide polymer:US 4268450.1981-05-19
10 Kim C,Yoon J,Min B,et al.Insensitive propellant composition:US0227875.2012-09-13
11翟进贤,杨荣杰.BAMO-THF复合推进剂催化燃烧特性分析.推进技术,2010;31(2):226-229Zhai Jingxian,Yang Rongjie.Analysis on properties of catalytic combustion of composite BAMO-THF propellants.Journal of Propulsion Technology,2010;31(2):226-229
12李辰芳.含能BAMO/AMMO粘合剂及其在固体推进剂中的应用研究.飞航导弹,1997;(1):42-45Li Chenfang.Research on application of energetic binder of BAMO/AMMO in solid propellant.Aerodynamic Missile Journal,1997;(1):42-45
13 Frankel M,Grant L,Flanagan J.Historical development of GAP.25th Joint Propulsion Conference.Reston:AIAA,1989:80-2307
14 Murray J,Politzer P.Structure-sensitivity relationships in energetic compounds.Berlin:Springer Netherlands,1990;309:157-173
15 Mathew S,Manu S,Varghese T.Thermomechanical and morphological characteristics of cross-linked GAP and GAP-HTPB networks with different diisocyanates.Propellants,Explosives,Pyrotechnics,2008;33(2):146-152
16宋晓庆,周集义,王文浩,等.HTPE推进剂研究进展.含能材料,2008;16(3):349-352Song Xiaoqing,Zhou Jiyi,Wang Wenhao,et al.Review on HTPEpropellants.Chinese Journal of Energetic Materials,2008;16(3):349-352
17汪存东,罗运军,夏敏,等.端羟基PTHF-PEO-PTHF嵌段共聚醚的合成与表征.固体火箭技术,2011;34(2):202-206Wang Cundong,Luo Yunjun,Xia Min,et al.Synthesis and characterization of hydroxyl-terminated block copolyether of PTHF-PEO-PTHF.Journal of Solid Rocket Technology,2011;34(2):202-206
18毛科铸,夏敏,罗运军,等.固化剂类型对HTPE型聚氨酯弹性体胶片性能的影响.火炸药学报,2012;35(1):55-58Mao Kezhu,Xia Min,Luo Yunjun,et al.Effect of curing agent types on properties of HTPE polyurethane elastomer films.Chinese Journal of Explosives and Propellants,2012;35(1):55-58
19杨冲冲.HTPE改性GAP粘合剂体系性能及应用研究.北京:北京理工大学,2016Yang Chongchong.Study on properties and application of GAP binder systems modified by HTPE.Beijing:Beijing Institute of Technology,2016
20谢五喜,蔚红建,张伟,等.含CL-20的BAMO/THF固体推进剂能量特性及低特征信号.兵器装备工程学报,2012;33(9):109-112Xie Wuxi,Wei Hongjian,Zhang Wei,et al.BAMO/THF solid propellant with CL-20 and low characteristic signal.Journal of Ordnance Equipment Engineering,2012;33(9):109-112
21 Kimura E,Oyumi Y,Effects of polymerization ratio of BAMO/NMMO and catalyst on sensitivity and burning rate of HMX propellant.Propellants,Explosives,Pyrotechnics,1995;20(4):215-221
22 Willer R L,Day R S,Stern A G.Process for producing improved poly(glycidyl nitrate):US Patent,5120827.1992
23 Cho J.R.,Kim J.S.,Cheun Y.G.,An improved synthetic method of Poly(NIMMO)and PGN prepolymers.Joint International Symposium on Energetic Materials Technology.Phoenix:American Defence Preparedness Association,1995:61-65
24尹华丽,李东峰,张纲要.丁羟推进剂粘接体系中的组分迁移.固体火箭技术,2007;30(5):416-419Yin Huali,Li Dongfeng,Zhang Gangyao.Ingredient migration in the bond system of HTPB propellant.Journal of Solid Rocket Technology,2007;30(5):416-419
25杨月诚,焦东明,强洪夫,等.HTPB推进剂组分溶度参数的分子模拟研究.含能材料,2008;16(2):191-195Yang Yuecheng,Jiao Dongming,Qiang Hongfu,et al.Molecular simulation of solubility parameter for HTPB solid propellants.Chinese Journal of Energetic Materials,2008;16(2):191-195
26 John R,James A.Solid propellant with non-crystalline polyether/energetic plasticizer binder:US 5783769.1998-07-21
27 Chan M L,Reed R,Turner A,et al.Properties of ADN propellants.The Fifth International Symposium on Special Topics in Chemical Propulsion(Combustion of Energetic Material).Stresa,2000:492-502
28 Junichi S,Miki S.Explosive properties of urethane-based PBXs containing HMX and BDNPA/F I.Effects of HMX contents and its particle size.Kogyo Kayaku,1992;53(2):59-66
29 Gore G M.BDNPA/F as energetic plasticizer in propellant formulations.29th International Annual Conference of the ICT.Karlsruhe:ICT,1998,136:1-12
30 Wilson E R,Frankel M B.Azide-terminated azido compound:US4781861:1988-02-07
31 Milton B F,Cunningham M A,Wilson E R.Glycidyl azide polymer azide:US 2285624 A,1995
32 Wang G,Ge Z,Luo Y J.Thermal decomposition kinetics of poly-(3,3'-bisazidomethyl oxetane-3-azidomethyl-3'-methyl oxetane).Journal of Thermal Analysis and Calorimetry,2015;122(3):1515-1523
33 Wang G,Ge Z,Luo Y J.Synthesis and characterization of poly(3-azido-methyl-3-methyl oxetane)by the azidation of poly(3-mesyloxymethyl-3-methyl oxetane).Propellants,Explosives,Pyrotechnics,2015;40(6):920-926
34王刚.PBA含能热塑性弹性体的合成、表征及在固体推进剂中的应用研究.北京:北京理工大学,2015Wang Gang.Synthetic of energetic thermoplastic elastomer PBA.Beijing:Beijing Institute of Technology,2015
35 Agarwal J P,Hodgson R D,Organic chemistry of explosives.New York:Wiley,2007
36 Provatas A.Energetic plasticizer migration studies.Journal of Energetic Materials,2003;21(4):237-245
37 Willer R W,Stearn A G,Day R S,Polyglycidyl nitrate plasticizers:US 5380777,1995
38 Kumari D,Singh H,Patil M,et al.Synthesis,characterization,thermal and computational studies of novel tetraeazido esters as energetic plasticizers.Thermochimca Acta,2013;562:96-104
39 Zhang M,Eaton P E,Gilardi R.Hepta-and octanitrocubanes.Angewandte Chemie International Edition,2000;39:401-404
40 Tao G H,Guo Y,Parrish D A,et al.Energetic 1,5-diamino-4H-tetrazolium nitro-substituted azolates.Journal of Materials Chemistry,2010;20(15):2999-3005
41 Lin Q H,Li Y C,Li Y Y,et al.Energetic salts based on 1-amino-1,2,3-triazole and 3-methyl-1-amino-1,2,3-triazole.Journal of Materials Chemistry,2012;22(2):666-674
42 Boniuk H,Cudzi O S.Synthesis and properties of salts of dinitroamide(ADN)with various amines.The Proceeding of 31st ICT.Karlsruhe:Institute of Chemical and Technology of Fraunhofer Society,2000:39-41
43 Zenin A,Valentin P,Sergej F.Physics of ADN combustion.37th Aerospace Sciences Meeting and Exhibit.Reston:American Institute of Aeronautics and Astronautics,1999:595
44 Korobeinichev O P,Paletsky A A,Tereshenko A.Study of combustion characteristics of the ADN-base propellants.The Proceeding of32nd ICT.Karlsruhem:Institute of Chemical and Technology of Fraunhofer Society,2001:1-14
45 Thomas H,Heike P,Jasmin A,et al.Ammonium dinitramide(ADN)-prilling,coating,and characterization.Propellants,Explosives,Pyrotechnics,2009;34(3):231-238
46 Lan L.Advances in the evaluation of FOX-7.28th Proceedings of the International Pyrotechnics Seminar.Reston:American Institute of Aeronautics and Astronautics,2001:479-489
47陈中娥,李忠友,姚南,等.FOX-7及含FOX-7的HTPB推进剂安全性能.含能材料,2010;18(3):316-319Chen Zhonge,Li youzhong,Yao Nan.et al.Safety property of FOX-7 and HTPB propellants with FOX-7.Chinese Journal of Energetic Materials,2010;18(3):316-319
48王伯周,刘愆,张志忠,等.新型含能材料FOX-12性能研究.含能材料,2004;12(1):38-39Wang Bozhou,Liu Qian,Zhang Zhizhong,et al.Study on properties of FOX-12.Chinese Journal of Energetic Materials,2004;12(1):38-39
49杨通辉,何金选,张海林.N-脒基脲二硝酰胺盐(FOX-12)的合成与表征.含能材料,2004;12(1):36-37Yang Tonghui,He jinxuan,Zhang Hailin.Synthesis and characterization of FOX-12.Chinese Journal of Energetic Materials,2004;12(1):36-37
50 Agrawal J P,Walley S M,Field J E.A high speed photographic study of the impact initiation of NTO and CL-20.Combustion and Flame,1998;112(1-2):62-72
51 Sikder A K,Rao P C,Agrawal J P.Synthesis and characterization of some new acid salts of 8H-2,6,8,9,10-Pentaazabicyclo-(5.2.1)-Deca-2,5,9,10-Tetracene.Journal of Energetic Materials,2000;18(4):289-297
52 Agrawal J P,Mehilal N,Sikder,Sikder A.K.,A thermally stable insensitive high explosive.Indian Journal of Engineering and Materials Sciences,2004;11:516-520
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