长江中下游典型火山盆地的水岩相互作用和金属矿床蚀变分带
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摘要
长江中下游火山岩盆地中金属矿床和蚀变分带的的地球化学研究表明,它们具有内带深色蚀变带和外带浅色蚀变带,形成于600℃到100℃范围。两类蚀变带分界温度大致是300℃。大金属矿床蚀变分带剖面显示出热液系统存在有明显的温度梯度。通过与背景岩石(玄武岩石)对比研究表明,自下而上的不同蚀变岩石中主要元素含量显著变化,交代作用中的代出和代入元素在空间上是演化的。25~400℃和23MPa下矿物(钠长石、阳起石、透辉石、钙铁辉石)-H2O、岩石(玄武岩)-H2O反应的化学动力学实验表明,金属元素释放速率是温度的函数。在恒压升温过程中,从20℃到400℃,硅酸盐矿物、玄武岩中Si溶解速率不断上升;在300~350℃时,Si、Al溶解速率到最大数值。随后,温度再上升导致溶解速率下降。在<300℃时,大部分矿物中Ca、Mg、Fe、Na溶解速率较高,溶液里的Ca/Si、Mg/Si、Fe/Si、Na/Si等都高于矿物中对应元素的计量比。矿物反应后的表面存在富集硅的淋失层,或有富硅铝矿物(粘土矿物)出现。在>300℃时,Si溶解快于其他金属元素,溶液中金属元素与硅摩尔浓度比(Ca/Si、Mg/Si、Fe/Si、Na/Si)等都低于矿物中的计量比。矿物反应后的表面缺少硅的淋失层,或者有贫硅矿物和铁氧化物出现。作者还进行23~35MPa、20~550℃玄武岩与水反应实验。上述高温高压下矿物在水溶液中的溶解反应动力学实验和流体-玄武岩相互作用实验,对于理解金属矿床及蚀变分带形成机制提供新的依据。
This paper reports kinetic experimental results of mineral in aqueous solutions and water rock interactions at high temperature and pressures.These results are used for us to understand metal-alteration zoning occurred in the volcanic basins in Middle-Lower Yangtze River Valley.Generally,studies on the metal-alteration zoning in the volcanic basins found that there are two sets of alteration zoning,one is melano-cratic alteration zoning at inner parts;the other is leuco-cratic alteration zoning at outer parts.The boundary between melano-cratic alteration zones and leuco-cratic alteration zones is at about 300℃ for their coexisting hydrothermal systems.In the alteration profile,there were temperature gradient occurred.Investigations indicated that the different minerals can precipitate in different zones in the whole profile.Or,different elements can be released in the different zones from deeper to shallow during water-rock interactions.Dissolution experiments of minerals(albite,actinolite,pyroxene,etc.) and rocks(basalts) in aqueous solutions were performed at temperatures from 20 to 435℃ and at pressures of 23 to 36 MPa.Experiments found that the maximum release rates of silica in mineral or in rocks always occur at 300℃.Generally,Ca,Mg,Fe,and Al dissolved more quickly than Si at temperatures in the range 25~300℃,but more slowly than Si in the range 300~400℃.All of the metal release rates varied with temperature.Non-congruent dissolutions occur in most cases.Release ratios Mi/Si,concentrations of dissolved metal vs.dissolved Si in the effluents,vary with temperature.As T<300℃,Ca/Si,Mg/Si,Fe/Si,Na/Si are higher than the stoichimetric numbers in solid.As T>300℃,Ca/Si,Mg/Si,Fe/Si,Na/Si are always lower than the stoichiometric number.Experiments found that a Si-rich,Mi-deficient layers is formed at the mineral surface at temperatures ≤300℃.As T>300℃,a Mi-rich,Si-deficient layers is present at the surface.Release rates for various metals of minerals vary with temperatures,which are different in the different temperatures.These results can be used to interpret the alteration zoning occurred in the present of temperature gradient,because,the release rates of various metals are different in different locations in the profile.
This paper reports kinetic experimental results of mineral in aqueous solutions and water rock interactions at high temperature and pressures.These results are used for us to understand metal-alteration zoning occurred in the volcanic basins in Middle-Lower Yangtze River Valley.Generally,studies on the metal-alteration zoning in the volcanic basins found that there are two sets of alteration zoning,one is melano-cratic alteration zoning at inner parts;the other is leuco-cratic alteration zoning at outer parts.The boundary between melano-cratic alteration zones and leuco-cratic alteration zones is at about 300℃ for their coexisting hydrothermal systems.In the alteration profile,there were temperature gradient occurred.Investigations indicated that the different minerals can precipitate in different zones in the whole profile.Or,different elements can be released in the different zones from deeper to shallow during water-rock interactions.Dissolution experiments of minerals(albite,actinolite,pyroxene,etc.) and rocks(basalts) in aqueous solutions were performed at temperatures from 20 to 435℃ and at pressures of 23 to 36 MPa.Experiments found that the maximum release rates of silica in mineral or in rocks always occur at 300℃.Generally,Ca,Mg,Fe,and Al dissolved more quickly than Si at temperatures in the range 25~300℃,but more slowly than Si in the range 300~400℃.All of the metal release rates varied with temperature.Non-congruent dissolutions occur in most cases.Release ratios Mi/Si,concentrations of dissolved metal vs.dissolved Si in the effluents,vary with temperature.As T<300℃,Ca/Si,Mg/Si,Fe/Si,Na/Si are higher than the stoichimetric numbers in solid.As T>300℃,Ca/Si,Mg/Si,Fe/Si,Na/Si are always lower than the stoichiometric number.Experiments found that a Si-rich,Mi-deficient layers is formed at the mineral surface at temperatures ≤300℃.As T>300℃,a Mi-rich,Si-deficient layers is present at the surface.Release rates for various metals of minerals vary with temperatures,which are different in the different temperatures.These results can be used to interpret the alteration zoning occurred in the present of temperature gradient,because,the release rates of various metals are different in different locations in the profile.
引文
Bischoff JL.1991.Densities of liquids and vapors in boiling Na Cl-H2Osolutions:A PVTx summary from 300 to 500℃.American Journal of Science,291(4):309-338
Dong SW,Gao R,Lv QT,Zhang JS,Zhang RH,Xue HM,Wu CL,Lu ZW and Ma LC.2009.Deep structure and ore-forming in LujiangZongyang ore concentrated area.Acta geoscientica Sinica,30(3):279-284(in Chinese with English abstract)
Dong SW,Xiang HS,Gao R,Lv QT,Li JS,Zhao SQ,Lu ZW and Ma LC.2010.Deep structure and ore formation with Lujiang-Zongyang volcanic ore concentrated area in Middle-Lower Yangtze River.Acta Petrologica Sinica,26(9):2529-2542(in Chinese with English abstract)
Helgeson HC.1969.Thermodynamics of hydrothermal systems at elevated temperatures and pressures.American Journal of Science,267(7):729-804
Hellmann R,Zhang RH and Crepar DA.1989.Albite feldspar hydrolysis to 300℃.Solid State Ionics,32-33:314-329
Hemley JJ and Jones WR.1964.Chemical Aspects of hydrothermal alteration with emphasis on hydrogen metasomatism.Economic Geology,59(4):538-569
Hu SM,Zhang RH and Zhang XT.2000.A study of near-and supercritical fluids using diamond anvil cell and in situ FT-IRspectroscopy.Acta Geologica Sinica,74(2):412-417
Hu SM,Zhang RH,Zhang XT and Huang WB.2010.Basalt-fluid interaction in Luzong volcanic basin.Acta Petrologica Sinica,26(9):2681-2693(in Chinese with English abstract)
Johnson JW and Norton D.1991.Critical phenomena in hydrothermal systems:State,thermodynamic,electrostatic,and transport properties of H2O in the critical region.American Journal of Science,291(6):541-648
Johnson JW,Oelkers EH and Helgeson C.1992.Supcrt92:A software package for calculating the standard molal thermodynamic properties of minerals,gases,aqueous species,and reactions from 1 to 5000bar and 0 to 1000℃.Computers&Geosciences,18(7):899-947
Meyer C and Hemley JJ.1967.Wall rock alteration.In:Barnes(ed.).Geochemistry of hydrothermal Ore Deposits.New York:Holt,Rinehart and Winston,166-235
Mogollon JL,Ganor J,Soler JM and Lasaga AC.1996.Column experiments and the full dissolution rate law of gibbsite.American Journal of Science,296(7):729-765
Mogollón JL,Pérez-Dial A and Monaco SL.2000.The effects of ion identity and ionic strength on the dissolution rate of a gibbsitic bauxite.Geochimica et Cosmochimica Acta,64(5):781-795
Murphy WM and Helgeson HC.1989.Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions.IV.Retrieval of rate constants and activation parameters for the hydrolysis of pyroxene,wollastonite,olivine,andalusite,quartz,and nepheline.American Journal of Science,289(1):17-101
Oelkers E,Bénézeth P and Pokrovski GS.2009.Thermodynamic databases for water-rock interaction.Reviews in Mineralogy and Geochemistry,70(1):1-46
Zhang RH.1974.On the zoning of country rock alteration and its genesis of an iron deposit.Acta Geologica Sinica,48(1):53-90(in Chinese with English abstract)
Zhang RH.1979.Geochemical zoning of altered country rocks of perphyrite iron deposits,Yangtze River Valley.Acta Geologica Sinica,53(2):137-153(in Chinese with English abstract)
Zhang RH.1980.Geochemical zoning and its mechanism of altered country rocks of perphyrite iron deposits,Yangtze River Valley.Acta Geologica Sinica,54(1):70-85(in Chinese with English abstract)
Zhang RH and Lu CQ.1981.On the mineralization,altercation of iron deposits located at a volcanic basin in the Middle-Lower Yangtze Valley.Bulletin of Chinese Academy of Geological Sciences,Series3,1:83-103(in Chinese with English abstract)
Zhang RH,Sheng JF and Lu CQ.1982.The mineralizing alteration and the sources of ore-forming materials at Lu-Zong volcanic basin.In:Bulletin of Institute of Mineral Deposits,Chinese Academy of Geological Sciences(4).Beijing:Geological Publishing House,51-64(in Chinese with English abstract)
Zhang RH.1986.Sulfur isotopes and pyrite-anhydrite equilibria in a volcanic basin hydrothermal system of the Middle to Lower Yangtze River Valley.Economic Geology,81(1):32-45
Zhang RH,Posey-Dowty J,Hellmann R,Borcsik M,Crerar D and Hu SM.1990.Kinetics studies of mineral-water reactions in hydrothermal flow systems at elevated temperatures and pressures.Science in China(Series B),33(9):1136-1152
Zhang RH,Hu SM,Hellmann R and Crerar D.1992.Chemical Kinetics of Minerals in Hydrothermal Systems and Mass Transfer.Beijing:Science Press,1-158(in Chinese)
Zhang RH and Hu SM.1996.Reaction kinetics of fluorite in flow systems and surface chemistry.Science in China(Series D),39(6):561-575
Zhang RH,Hu SM,Tong JC and Jiang L.1998.Mineral-Fluid Reaction Kinetics in Open Systems.Beijing:Science Press,1-252(in Chinese)
Zhang RH and Hu SM.1999.Experimental observation of deep crust fluid-Na Cl aqueous solution at elevated temperatures and pressures and its significance.Chinese Science Bulletin,44(7):654-660
Zhang RH,Hu SM and Zhang XT.2000.Kinetics of hydrothermal reactions of minerals in near-critical and supercritical water.Acta Geologica Sinica,74(2):400-405
Zhang RH and Hu SM.2001.The evolution of deep earth fluids and ore genesis.Earth Science Frontiers,8(4):297-310(in Chinese with English abstract)
Zhang RH,Hu SM and Su YF.2002.Hydrothermal alteration zoning and kinetic process of mineral-water interactions.Acta Geologica Sinica,76(3):351-366
Zhang RH,Hu SM,Wang J and Xu LM.2002.Water-Rock Interactions of Typical Volcanic Area in Middle-Lower Yangtze River Valley.Beijing:China Land Press,175(in Chinese)
Zhang RH and Hu SM.2004.Hydrothermal study using a new diamond anvil cell with in situ IR spectroscopy under high temperatures and high pressures.The Journal of Supercritical fluids,29(1-2):185-202
Zhang RH,Hu SM,Zhang XT and Su YF.2005.Origin-TransportationDeposition of the Important Metals and their Chemical Kinetics.Beijing:Science Press,1-232(in Chinese)
Zhang RH,Hu SM and Zhang XT.2006.Experimental study of dissolution rates of fluorite in HCl-H2O solutions.Aquatic Geochemistry,12(2):123-159
Zhang RH,Hu SM and Zhang XT.2006.Geochemical kinetics in middle crust and ore geneses.Acta Geosciemtica Sinica,27(5):460-470(in Chinese with English abstract)
Zhang RH,Zhang XT,Hu SM and Su YF.2007.Kinetic experiments of water rock interactions at high temperatures and high pressures corresponding to the middle crust conditions.Acta Petrologica Sinica,23(11):2933-2942(in Chinese with English abstract)
Zhang RH,Zhang XT,Guy B,Hu SM,De Ligny D and Moutte J.2013.Experimental study of dissolution rates of hedenbergitic clinopyroxene at high temperatures:Dissolution in water from 25℃to 374℃.European Journal of Mineralogy,25(13):353-372
Zhang XT and Zhang RH.2005.Kinetics study of zeolite in hydrothermal solutions.Acta Physico-Chimica Sinica,21(6):616-621(in Chinese with English abstract)
董树文,高锐,吕庆田,张季生,张荣华,薛怀民,吴才来,卢占武,马立成.2009.庐江-枞阳矿集区深部结构与成矿.地球学报,30(3):279-284
董树文,项怀顺,高锐,吕庆田,李建设,卢占武,马立成.2010.长江中下游火山岩矿集区深部结构和成矿作用.岩石学报,26(9):2529-2542
胡书敏,张荣华,张雪彤,黄文斌.2010.庐枞火山盆地玄武岩与流体相互作用.岩石学报,26(9):2681-2693
张荣华.1974.一个铁矿床的围岩蚀变和成因探讨.地质学报,48(1):53-90
张荣华.1979.长江中下游玢岩铁矿围岩蚀变的地球化学分带.地质学报,53(2):137-153
张荣华.1980.长江中下游玢岩铁矿围岩蚀变的地球化学分带形成机理.地质学报,54(1):70-85
张荣华,陆成庆.1981.长江中下游火山岩盆地的矿化蚀变.中国地质科学院院刊,1:83-103
张荣华,盛继福,陆成庆.1982.庐枞火山岩盆地的矿化蚀变与矿质来源.见:中国地质科学院矿床地质研究所文集(4).北京:地质出版社,51-64
张荣华,胡书敏,Hellmann R,Crerar D.1992.矿物在热液内化学动力学和物质迁移.北京:科学出版社,1-158
张荣华,胡书敏,童建昌,姜路.1998.开放体系矿物流体反应动力学.北京:科学出版社,1-252
张荣华,胡书敏.2001.地球深部流体演化与矿石成因.地学前缘,8(4):297-310
张荣华,胡书敏,王军,徐磊明.2002.长江中下游典型火山岩区水-岩相互作用.北京:中国大地出版社,1-175
张荣华,胡书敏,张雪彤,苏艳丰.2005.重要金属矿来源迁移堆积过程和化学动力学.北京:科学出版社,1-233
张荣华,胡书敏,张雪彤.2006.中地壳的地球化学动力学和矿石成因.地球学报,27(5):460-470
张荣华,张雪彤,胡书敏,苏艳丰.2007.中地壳温度压力条件下的水-岩作用化学动力学实验.岩石学报,23(11):2933-2942
张雪彤,张荣华.2005.沸石与酸性水溶液反应的动力学机制.物理化学学报,21(6):616-621
(1)张荣华,胡书敏,童建昌,姜路.1996.长江中下游典型火山岩区水-岩相互作用.地矿部重要基础项目(8502215)科研报告
(1)张荣华,胡书敏,张雪彤,王勇.2004.地球化学动力学:地球深部物质进入地壳的化学动力学.国土资源部重点基础项目(20010302)研究报告
Dong SW,Gao R,Lv QT,Zhang JS,Zhang RH,Xue HM,Wu CL,Lu ZW and Ma LC.2009.Deep structure and ore-forming in LujiangZongyang ore concentrated area.Acta geoscientica Sinica,30(3):279-284(in Chinese with English abstract)
Dong SW,Xiang HS,Gao R,Lv QT,Li JS,Zhao SQ,Lu ZW and Ma LC.2010.Deep structure and ore formation with Lujiang-Zongyang volcanic ore concentrated area in Middle-Lower Yangtze River.Acta Petrologica Sinica,26(9):2529-2542(in Chinese with English abstract)
Helgeson HC.1969.Thermodynamics of hydrothermal systems at elevated temperatures and pressures.American Journal of Science,267(7):729-804
Hellmann R,Zhang RH and Crepar DA.1989.Albite feldspar hydrolysis to 300℃.Solid State Ionics,32-33:314-329
Hemley JJ and Jones WR.1964.Chemical Aspects of hydrothermal alteration with emphasis on hydrogen metasomatism.Economic Geology,59(4):538-569
Hu SM,Zhang RH and Zhang XT.2000.A study of near-and supercritical fluids using diamond anvil cell and in situ FT-IRspectroscopy.Acta Geologica Sinica,74(2):412-417
Hu SM,Zhang RH,Zhang XT and Huang WB.2010.Basalt-fluid interaction in Luzong volcanic basin.Acta Petrologica Sinica,26(9):2681-2693(in Chinese with English abstract)
Johnson JW and Norton D.1991.Critical phenomena in hydrothermal systems:State,thermodynamic,electrostatic,and transport properties of H2O in the critical region.American Journal of Science,291(6):541-648
Johnson JW,Oelkers EH and Helgeson C.1992.Supcrt92:A software package for calculating the standard molal thermodynamic properties of minerals,gases,aqueous species,and reactions from 1 to 5000bar and 0 to 1000℃.Computers&Geosciences,18(7):899-947
Meyer C and Hemley JJ.1967.Wall rock alteration.In:Barnes(ed.).Geochemistry of hydrothermal Ore Deposits.New York:Holt,Rinehart and Winston,166-235
Mogollon JL,Ganor J,Soler JM and Lasaga AC.1996.Column experiments and the full dissolution rate law of gibbsite.American Journal of Science,296(7):729-765
Mogollón JL,Pérez-Dial A and Monaco SL.2000.The effects of ion identity and ionic strength on the dissolution rate of a gibbsitic bauxite.Geochimica et Cosmochimica Acta,64(5):781-795
Murphy WM and Helgeson HC.1989.Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions.IV.Retrieval of rate constants and activation parameters for the hydrolysis of pyroxene,wollastonite,olivine,andalusite,quartz,and nepheline.American Journal of Science,289(1):17-101
Oelkers E,Bénézeth P and Pokrovski GS.2009.Thermodynamic databases for water-rock interaction.Reviews in Mineralogy and Geochemistry,70(1):1-46
Zhang RH.1974.On the zoning of country rock alteration and its genesis of an iron deposit.Acta Geologica Sinica,48(1):53-90(in Chinese with English abstract)
Zhang RH.1979.Geochemical zoning of altered country rocks of perphyrite iron deposits,Yangtze River Valley.Acta Geologica Sinica,53(2):137-153(in Chinese with English abstract)
Zhang RH.1980.Geochemical zoning and its mechanism of altered country rocks of perphyrite iron deposits,Yangtze River Valley.Acta Geologica Sinica,54(1):70-85(in Chinese with English abstract)
Zhang RH and Lu CQ.1981.On the mineralization,altercation of iron deposits located at a volcanic basin in the Middle-Lower Yangtze Valley.Bulletin of Chinese Academy of Geological Sciences,Series3,1:83-103(in Chinese with English abstract)
Zhang RH,Sheng JF and Lu CQ.1982.The mineralizing alteration and the sources of ore-forming materials at Lu-Zong volcanic basin.In:Bulletin of Institute of Mineral Deposits,Chinese Academy of Geological Sciences(4).Beijing:Geological Publishing House,51-64(in Chinese with English abstract)
Zhang RH.1986.Sulfur isotopes and pyrite-anhydrite equilibria in a volcanic basin hydrothermal system of the Middle to Lower Yangtze River Valley.Economic Geology,81(1):32-45
Zhang RH,Posey-Dowty J,Hellmann R,Borcsik M,Crerar D and Hu SM.1990.Kinetics studies of mineral-water reactions in hydrothermal flow systems at elevated temperatures and pressures.Science in China(Series B),33(9):1136-1152
Zhang RH,Hu SM,Hellmann R and Crerar D.1992.Chemical Kinetics of Minerals in Hydrothermal Systems and Mass Transfer.Beijing:Science Press,1-158(in Chinese)
Zhang RH and Hu SM.1996.Reaction kinetics of fluorite in flow systems and surface chemistry.Science in China(Series D),39(6):561-575
Zhang RH,Hu SM,Tong JC and Jiang L.1998.Mineral-Fluid Reaction Kinetics in Open Systems.Beijing:Science Press,1-252(in Chinese)
Zhang RH and Hu SM.1999.Experimental observation of deep crust fluid-Na Cl aqueous solution at elevated temperatures and pressures and its significance.Chinese Science Bulletin,44(7):654-660
Zhang RH,Hu SM and Zhang XT.2000.Kinetics of hydrothermal reactions of minerals in near-critical and supercritical water.Acta Geologica Sinica,74(2):400-405
Zhang RH and Hu SM.2001.The evolution of deep earth fluids and ore genesis.Earth Science Frontiers,8(4):297-310(in Chinese with English abstract)
Zhang RH,Hu SM and Su YF.2002.Hydrothermal alteration zoning and kinetic process of mineral-water interactions.Acta Geologica Sinica,76(3):351-366
Zhang RH,Hu SM,Wang J and Xu LM.2002.Water-Rock Interactions of Typical Volcanic Area in Middle-Lower Yangtze River Valley.Beijing:China Land Press,175(in Chinese)
Zhang RH and Hu SM.2004.Hydrothermal study using a new diamond anvil cell with in situ IR spectroscopy under high temperatures and high pressures.The Journal of Supercritical fluids,29(1-2):185-202
Zhang RH,Hu SM,Zhang XT and Su YF.2005.Origin-TransportationDeposition of the Important Metals and their Chemical Kinetics.Beijing:Science Press,1-232(in Chinese)
Zhang RH,Hu SM and Zhang XT.2006.Experimental study of dissolution rates of fluorite in HCl-H2O solutions.Aquatic Geochemistry,12(2):123-159
Zhang RH,Hu SM and Zhang XT.2006.Geochemical kinetics in middle crust and ore geneses.Acta Geosciemtica Sinica,27(5):460-470(in Chinese with English abstract)
Zhang RH,Zhang XT,Hu SM and Su YF.2007.Kinetic experiments of water rock interactions at high temperatures and high pressures corresponding to the middle crust conditions.Acta Petrologica Sinica,23(11):2933-2942(in Chinese with English abstract)
Zhang RH,Zhang XT,Guy B,Hu SM,De Ligny D and Moutte J.2013.Experimental study of dissolution rates of hedenbergitic clinopyroxene at high temperatures:Dissolution in water from 25℃to 374℃.European Journal of Mineralogy,25(13):353-372
Zhang XT and Zhang RH.2005.Kinetics study of zeolite in hydrothermal solutions.Acta Physico-Chimica Sinica,21(6):616-621(in Chinese with English abstract)
董树文,高锐,吕庆田,张季生,张荣华,薛怀民,吴才来,卢占武,马立成.2009.庐江-枞阳矿集区深部结构与成矿.地球学报,30(3):279-284
董树文,项怀顺,高锐,吕庆田,李建设,卢占武,马立成.2010.长江中下游火山岩矿集区深部结构和成矿作用.岩石学报,26(9):2529-2542
胡书敏,张荣华,张雪彤,黄文斌.2010.庐枞火山盆地玄武岩与流体相互作用.岩石学报,26(9):2681-2693
张荣华.1974.一个铁矿床的围岩蚀变和成因探讨.地质学报,48(1):53-90
张荣华.1979.长江中下游玢岩铁矿围岩蚀变的地球化学分带.地质学报,53(2):137-153
张荣华.1980.长江中下游玢岩铁矿围岩蚀变的地球化学分带形成机理.地质学报,54(1):70-85
张荣华,陆成庆.1981.长江中下游火山岩盆地的矿化蚀变.中国地质科学院院刊,1:83-103
张荣华,盛继福,陆成庆.1982.庐枞火山岩盆地的矿化蚀变与矿质来源.见:中国地质科学院矿床地质研究所文集(4).北京:地质出版社,51-64
张荣华,胡书敏,Hellmann R,Crerar D.1992.矿物在热液内化学动力学和物质迁移.北京:科学出版社,1-158
张荣华,胡书敏,童建昌,姜路.1998.开放体系矿物流体反应动力学.北京:科学出版社,1-252
张荣华,胡书敏.2001.地球深部流体演化与矿石成因.地学前缘,8(4):297-310
张荣华,胡书敏,王军,徐磊明.2002.长江中下游典型火山岩区水-岩相互作用.北京:中国大地出版社,1-175
张荣华,胡书敏,张雪彤,苏艳丰.2005.重要金属矿来源迁移堆积过程和化学动力学.北京:科学出版社,1-233
张荣华,胡书敏,张雪彤.2006.中地壳的地球化学动力学和矿石成因.地球学报,27(5):460-470
张荣华,张雪彤,胡书敏,苏艳丰.2007.中地壳温度压力条件下的水-岩作用化学动力学实验.岩石学报,23(11):2933-2942
张雪彤,张荣华.2005.沸石与酸性水溶液反应的动力学机制.物理化学学报,21(6):616-621
(1)张荣华,胡书敏,童建昌,姜路.1996.长江中下游典型火山岩区水-岩相互作用.地矿部重要基础项目(8502215)科研报告
(1)张荣华,胡书敏,张雪彤,王勇.2004.地球化学动力学:地球深部物质进入地壳的化学动力学.国土资源部重点基础项目(20010302)研究报告