二氧化碳加氢制烯烃催化剂的制备和性能
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摘要
对CO2加氢制烯烃催化剂的制备方法、反应机理以及不同的助剂和载体对于催化剂结构的影响进行了综述。阐述了当前CO2加氢制烯烃催化剂研究中存在的问题和难点。提出了结合相关原位光谱表征技术手段、构建催化剂结构和性能高效可控的构-效关系是今后研究的方向。
The preparation methods and reaction mechanism of catalysts for carbon dioxide hydrogenation are reviewed,and the influence of various auxiliaries and supports on the structure of catalysts is investigated.The problems and difficulties in the study of catalysts for carbon dioxide hydrogenation to olefin are discussed.It is proposed that the elaborating of the relationship between structure and performance of catalyst under working conditions by using operando techniques is the direction of future research.
The preparation methods and reaction mechanism of catalysts for carbon dioxide hydrogenation are reviewed,and the influence of various auxiliaries and supports on the structure of catalysts is investigated.The problems and difficulties in the study of catalysts for carbon dioxide hydrogenation to olefin are discussed.It is proposed that the elaborating of the relationship between structure and performance of catalyst under working conditions by using operando techniques is the direction of future research.
引文
[1]Olah G A,Goeppert A,Prakash G S.Chemical recycling of carbon dioxide to methanol and dimethyl ether:From greenhouse gas to renewable,environmentally carbon neutral fuels and synthetic hydrocarbons[J].Journal of Organic Chemistry,2008,74(2):487-498.
[2]Jiang Z,Xiao T,Kuznetsov V.Turning carbon dioxide into fuel[J].Philosophical Transactions of the Royal Society A:Mathematical,Physical and Engineering Sciences,2010,368(1923):3343-3364.
[3]柏明星,贺凯,段永伟,等.CO2在能源开发中的应用进展[J].现代化工,2018,38(1):26-29,31.
[4]Wang W,Wang S P,Ma X B,et al.Recent advances in catalytic hydrogenation of carbon dioxide[J].Chemical Society Reviews,2011,40:3703-3727.
[5]Cao F H,Liu D H,Hou Q S,et al.Thermodynamic analysis of CO2direct hydrogenation reactions[J]. Journal of Natural Gas Chemistry,2001,10(1):24-33.
[6]刘业奎,王黎,侯栋,等.二氧化碳加氢合成低碳烯烃反应平衡体系热力学研究[J].催化学报,2004,25(3):210-218.
[7]刘业奎,侯栋,王黎,等.二氧化碳加氢合成低碳烯烃的研究进展[J].石油与天然气化工,2003,32(6):343-348.
[8]Visconti C G,Martinelli M,Falbo L,et al.CO2hydrogenation to hydrocarbons over Co and Fe-based Fischer-Tropsch catalysts[J].Catalysis Today,2016,277:161-170.
[9]Wang J,You Z,Zhang Q,et al.Synthesis of lower olefins by hydrogenation of carbon dioxide over supported iron catalysts[J].Catalysis Today,2013,215:186-193.
[10]Yang C,Zhao H,Hou Y,et al. Fe5C2nanoparticles:A facile bromide-induced synthesis and as an active phase for Fischer-Tropsch synthesis[J]. Journal of American Chemical Society,2012,134:15814-15821.
[11]Satthawong R,Koizumi N,Song C,et al.Bimetallic Fe-Co catalysts for CO2hydrogenation to higher hydrocarbons[J]. Journal of CO2Utilization,2013,3/4:102-106.
[12]Herranz T,Rojas S,Perez-Alonso F J,et al.Carbon oxide hydrogenation over silica-supported iron-based catalysts[J]. Applied Catalysis A:General,2006,308:19-30.
[13]Gogate R J.Comparative study of CO and CO2hydrogenation over supported Rh-Fe catalysts[J].Catalysis Communications,2010,11:901-906.
[14]Hu S,Liu M,Ding F,et al.Hydrothermally stable MOFs for CO2hydrogenation over iron-based catalyst to light olefins[J]. Journal of CO2Utilization,2016,15:89-95.
[15]Satthawong R,Koizumi N,Song C,et al.Light olefin synthesis from CO2hydrogenation over K-promoted Fe-Co bimetallic catalysts[J].Catalysis Today,2015,251:34-40.
[16]刘蓉,王鹏飞,查飞,等.稀土改性SAPO-34分子筛的制备及其在CO2加氢合成低碳烯烃中的催化性能[J].精细化工,2016,33(4):413-418.
[17]Li Z L,Wang J J,Li C. Highly selective conversion of carbon dioxide to Lower olefins[J].ACS Catalysis,2017,7:8544-8548.
[18]Liu X L,Wang M H,Wang Y.Selective transformation of carbon dioxide into lower olefins with a bifunctional catalyst composed of ZnGa2O4and SAPO-34[J]. Chemical Communications,2018,54:140-143.
[19]Zhang J L,Lu S P,Zhao T S. Selective formation of light olefins from CO2hydrogenation over Fe-Zn-K catalysts[J].Journal of CO2Utilization,2015,1912:95-100.
[20]Li Z J,Zhong L S.Effects of sodium on the catalytic performance of CoMn catalysts for Fischer-Tropsch to olefin reactions[J].ACS Catalysis,2017,7:3622-3631.
[21]Dorner R W,Hardy D R,Williams F W,et al.C2-C5+olefin production from CO2hydrogenation using ceria modified Fe/Mn/K catalysts[J].Catalysis Communications,2011,15:88-92.
[22]王迪.新型Fe基费托合成制低碳烯烃催化剂的精细调控与机理研究[D].上海:华东理工大学,2017.
[23]Fischer F,Tropsch H. The synthesis of petroleum at atmospheric pressures from gasification products of coal[J].Brennstoff-Chemie,1926,7:97-104.
[24]Pichler H,Schultz H. New insights in the area of the synthesis of hydrocarbons from CO and H2[J]. Chemie Ingenieur Technik,1970,12(18):1160-1174.
[25]Stroch H,Golumbic N,Anderson R. The Fischer-Tropsch and Related synthesis[M].New Jersy:John Wiley&Sons,1951.
[26]Zhang Y,Fu D,Han Y F.Application of operando spectroscopy on catalytic reactions[J]. Current Opinion in Chemical Engineering,2016,12:1-7.
[27]Chan H Y,Nguyen V H,Wu J C S,et al.Real-time Raman monitoring during photocatalytic epoxidation of cyclohexene over V-Ti/MCM-41 catalysts[J].Catalysts,2015,5:518-533.
[28]Jin S,Feng Z,Fan F,et al. UV Raman spectroscopic characterization of catalysts and catalytic active sites[J]. Catalysis Letters,2015,145:468-481.
[29]Lin L,Tian X,Hong S,et al. A bioorthogonal Raman reporter strategy for SERS detection of glycans on live cells[J].Angewandte Chemie,2013,125:7407-7412.
[30]Fu D,Dai W,Xu X,et al.Probing the structure evolution of ironbased Fischer-Tropsch to produce olefins by operando Raman spectroscopy[J].Chem Cat Chem,2015,7:752-756.
[2]Jiang Z,Xiao T,Kuznetsov V.Turning carbon dioxide into fuel[J].Philosophical Transactions of the Royal Society A:Mathematical,Physical and Engineering Sciences,2010,368(1923):3343-3364.
[3]柏明星,贺凯,段永伟,等.CO2在能源开发中的应用进展[J].现代化工,2018,38(1):26-29,31.
[4]Wang W,Wang S P,Ma X B,et al.Recent advances in catalytic hydrogenation of carbon dioxide[J].Chemical Society Reviews,2011,40:3703-3727.
[5]Cao F H,Liu D H,Hou Q S,et al.Thermodynamic analysis of CO2direct hydrogenation reactions[J]. Journal of Natural Gas Chemistry,2001,10(1):24-33.
[6]刘业奎,王黎,侯栋,等.二氧化碳加氢合成低碳烯烃反应平衡体系热力学研究[J].催化学报,2004,25(3):210-218.
[7]刘业奎,侯栋,王黎,等.二氧化碳加氢合成低碳烯烃的研究进展[J].石油与天然气化工,2003,32(6):343-348.
[8]Visconti C G,Martinelli M,Falbo L,et al.CO2hydrogenation to hydrocarbons over Co and Fe-based Fischer-Tropsch catalysts[J].Catalysis Today,2016,277:161-170.
[9]Wang J,You Z,Zhang Q,et al.Synthesis of lower olefins by hydrogenation of carbon dioxide over supported iron catalysts[J].Catalysis Today,2013,215:186-193.
[10]Yang C,Zhao H,Hou Y,et al. Fe5C2nanoparticles:A facile bromide-induced synthesis and as an active phase for Fischer-Tropsch synthesis[J]. Journal of American Chemical Society,2012,134:15814-15821.
[11]Satthawong R,Koizumi N,Song C,et al.Bimetallic Fe-Co catalysts for CO2hydrogenation to higher hydrocarbons[J]. Journal of CO2Utilization,2013,3/4:102-106.
[12]Herranz T,Rojas S,Perez-Alonso F J,et al.Carbon oxide hydrogenation over silica-supported iron-based catalysts[J]. Applied Catalysis A:General,2006,308:19-30.
[13]Gogate R J.Comparative study of CO and CO2hydrogenation over supported Rh-Fe catalysts[J].Catalysis Communications,2010,11:901-906.
[14]Hu S,Liu M,Ding F,et al.Hydrothermally stable MOFs for CO2hydrogenation over iron-based catalyst to light olefins[J]. Journal of CO2Utilization,2016,15:89-95.
[15]Satthawong R,Koizumi N,Song C,et al.Light olefin synthesis from CO2hydrogenation over K-promoted Fe-Co bimetallic catalysts[J].Catalysis Today,2015,251:34-40.
[16]刘蓉,王鹏飞,查飞,等.稀土改性SAPO-34分子筛的制备及其在CO2加氢合成低碳烯烃中的催化性能[J].精细化工,2016,33(4):413-418.
[17]Li Z L,Wang J J,Li C. Highly selective conversion of carbon dioxide to Lower olefins[J].ACS Catalysis,2017,7:8544-8548.
[18]Liu X L,Wang M H,Wang Y.Selective transformation of carbon dioxide into lower olefins with a bifunctional catalyst composed of ZnGa2O4and SAPO-34[J]. Chemical Communications,2018,54:140-143.
[19]Zhang J L,Lu S P,Zhao T S. Selective formation of light olefins from CO2hydrogenation over Fe-Zn-K catalysts[J].Journal of CO2Utilization,2015,1912:95-100.
[20]Li Z J,Zhong L S.Effects of sodium on the catalytic performance of CoMn catalysts for Fischer-Tropsch to olefin reactions[J].ACS Catalysis,2017,7:3622-3631.
[21]Dorner R W,Hardy D R,Williams F W,et al.C2-C5+olefin production from CO2hydrogenation using ceria modified Fe/Mn/K catalysts[J].Catalysis Communications,2011,15:88-92.
[22]王迪.新型Fe基费托合成制低碳烯烃催化剂的精细调控与机理研究[D].上海:华东理工大学,2017.
[23]Fischer F,Tropsch H. The synthesis of petroleum at atmospheric pressures from gasification products of coal[J].Brennstoff-Chemie,1926,7:97-104.
[24]Pichler H,Schultz H. New insights in the area of the synthesis of hydrocarbons from CO and H2[J]. Chemie Ingenieur Technik,1970,12(18):1160-1174.
[25]Stroch H,Golumbic N,Anderson R. The Fischer-Tropsch and Related synthesis[M].New Jersy:John Wiley&Sons,1951.
[26]Zhang Y,Fu D,Han Y F.Application of operando spectroscopy on catalytic reactions[J]. Current Opinion in Chemical Engineering,2016,12:1-7.
[27]Chan H Y,Nguyen V H,Wu J C S,et al.Real-time Raman monitoring during photocatalytic epoxidation of cyclohexene over V-Ti/MCM-41 catalysts[J].Catalysts,2015,5:518-533.
[28]Jin S,Feng Z,Fan F,et al. UV Raman spectroscopic characterization of catalysts and catalytic active sites[J]. Catalysis Letters,2015,145:468-481.
[29]Lin L,Tian X,Hong S,et al. A bioorthogonal Raman reporter strategy for SERS detection of glycans on live cells[J].Angewandte Chemie,2013,125:7407-7412.
[30]Fu D,Dai W,Xu X,et al.Probing the structure evolution of ironbased Fischer-Tropsch to produce olefins by operando Raman spectroscopy[J].Chem Cat Chem,2015,7:752-756.