纳米技术在石膏中的应用研究进展
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摘要
纳米技术是当前科学研究领域的热门,将纳米技术应用到石膏中,可以制备出性能更好的材料。对纳米技术在石膏中的应用研究进展做了介绍,发现纳米材料能使石膏具备光催化性、相变储能性,提高石膏的力学性能、生物耐久性等,与此同时,还可以制备纳米CaSO_4及其他纳米材料。指出了目前纳米技术在石膏中应用研究存在的问题,并对其发展前景做了展望。
Nano-technology is a hot topic in the field of scientific research.The application of nano-technology in gypsum can produce better materials.In order to promote the development of application of nano-technology in gypsum,the current research on application of nano-technology in gypsum was introduced.It also was discovered that nano-materials made gypsum possess the photocatalytic property and phase change energy storage performance,while the mechanical property and biological durability of gypsum were both improved as well.Besides,the nano-CaSO_4 and other nano-materials can also be prepared by gypsum.At last,the prospects were discussed based on the existing problems of the application of nano-technology in gypsum.
Nano-technology is a hot topic in the field of scientific research.The application of nano-technology in gypsum can produce better materials.In order to promote the development of application of nano-technology in gypsum,the current research on application of nano-technology in gypsum was introduced.It also was discovered that nano-materials made gypsum possess the photocatalytic property and phase change energy storage performance,while the mechanical property and biological durability of gypsum were both improved as well.Besides,the nano-CaSO_4 and other nano-materials can also be prepared by gypsum.At last,the prospects were discussed based on the existing problems of the application of nano-technology in gypsum.
引文
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[20]Huang H L,Lin C C,Hsu K N.Comparison of resistance improvement to fungal growth on green and conventional building materials by nano-metal impregnation[J].Building&Environment,2015,93:119-127.
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[22]尚雷,高翔,胡宗超,等.以磷石膏为原料制备纳米羟基磷灰石的研究[J].贵州化工,2011,36(2):3-6.
[23]兰培强.磷石膏反应结晶制备纳米Ca CO3及其用作CO2捕集[D].杭州:浙江大学,2014.
[24]Wu S F,Lan P Q.Method for preparing a nano-calcium carbonate slurry from waste gypsum as calcium source,the product and use thereof:US,8846562[P].2014-09-30.
[25]朱玲,毛大厦,范文娟,等.以磷石膏为原料制备纳米碳酸钙[J].广州化工,2016,44(12):55-57.
[26]周静,邹洪涛,邢焰,等.磷石膏制备纳米氧化钙基二氧化碳吸附剂工艺的优化[J].无机盐工业,2016,48(10):73-76.
[27]Sawant P D,Niranjane A.Formation of nanoparticles of sparingly soluble salts(Ca SO4and Ca SO4:Dy)using liquid-liquid separation method and application for detection ofα-radiations[J].Micro&Nano Letters,2006,1(2):108-111.
[28]Osterwalder N,Loher S,Grass R N,et al.Preparation of nano-gypsum from anhydrite nanoparticles:strongly increased vickers hardness and formation of calcium sulfate nano-needles[J].Journal of Nanoparticle Research,2007,9(2):275-281.
[29]Chen D,Szostak P,Wei Z S,et al.Reduction of orthophosphates loss in agricultural soil by nano calcium sulfate[J].Science of the Total Environment,2016,539(4):381-387.
[2]栾云博.纳米Ti O2光催化剂无机酸改性及有机污染物降解效能机制[D].哈尔滨:哈尔滨工业大学,2014.
[3]彭丽.以石膏板为载体的掺氮Ti O2粉末光催化降解室内甲醛污染的实验研究[D].重庆:重庆大学,2009.
[4]Janus M,Bubacz K,Zatorska J,et al.NOxphotocatalytic degradation on gypsum plates modified by Ti O2-N,C photocatalysts[J].Polish Journal of Chemical Technology,2015,17(3):8-12.
[5]张静,丁益民,陈念贻.相变储能材料的研究及应用[J].盐湖研究,2005,13(3):52-57.
[6]黄昭雯.Li NO3-KCl/膨胀石墨烯复合相变材料的制备及性能研究[D].广州:华南理工大学,2015.
[7]李琳,李东旭,张毅,等.脂肪酸/膨胀珍珠岩复合相变材料的制备与性能表征[J].南京工业大学学报:自然科学版,2016,38(4):11-16.
[8]Sayyar M,Weerasiri R R,Soroushiana P,et al.Experimental and numerical study of shape-stable phase-change nanocomposite toward energy-efficient building constructions[J].Energy&Buildings,2014,75(27):249-255.
[9]Biswas K,Lu J,Soroushian P,et al.Combined experimental and numerical evaluation of a prototype nano-PCM enhanced wallboard[J].Applied Energy,2014,131(9):517-529.
[10]尚建丽,张浩,董莉.双壳微纳米相变胶囊/石膏复合材料等温吸放湿特性及机理研究[J].功能材料,2015,46(2):2084-2088.
[11]尚建丽,张浩,熊磊.相变储湿模拟墙板在自然通风条件下的特性研究[J].功能材料,2015,46(18):18083-18087.
[12]尚建丽,张浩,董莉.石膏基双壳微纳米相变胶囊复合材料制备及调温调湿性能研究[J].太阳能学报,2016,37(6):1481-1487.
[13]Khadiran T,Hussein M Z,Syamsi H W,et al.Laboratory-scale studies on smart gypsum composite boards incorporated with nanoencapsulated organic phase change material for thermal comfort building application[J].Journal of Materials in Civil Engineering,2016,28(3).
[14]雷文,邓玉和,周梅,等.超声波及纳米Si O2填充改善石膏刨花板的性能[J].上海建材,2007(2):9-11.
[15]Lei W,Deng Y H,Zhou M,et al.Mechanical properties of nano Si O2filled gypsum particleboard[J].Transactions of Nonferrous Metals Society of China,2006,16(s1):361-364.
[16]D′Armada P,Hirst E.Nano-lime for consolidation of plaster and stone[J].Journal of Architectural Conservation,2012,18(1):63-80.
[17]钱觉时.建筑材料学[M].武汉:武汉理工大学出版社,2007.
[18]彭小芹.土木工程材料[M].3版.重庆:重庆大学出版社,2013.
[19]Garkavi M S,Nekrasova S A,Troshkina E A.Kinetics of contact formation in nano-modified gypsum materials[J].СтроительныеМатериалы,2013(2):38-40.
[20]Huang H L,Lin C C,Hsu K N.Comparison of resistance improvement to fungal growth on green and conventional building materials by nano-metal impregnation[J].Building&Environment,2015,93:119-127.
[21]Tyumentsev V A,Fazlitdinova A G,Dozhdikova D V,et al.Effect of nanoadditives on the kinetics of Ca SO4·2H2O formation and the mosaic structure of crystals[J].Inorganic Materials,2015,51(1):68-70.
[22]尚雷,高翔,胡宗超,等.以磷石膏为原料制备纳米羟基磷灰石的研究[J].贵州化工,2011,36(2):3-6.
[23]兰培强.磷石膏反应结晶制备纳米Ca CO3及其用作CO2捕集[D].杭州:浙江大学,2014.
[24]Wu S F,Lan P Q.Method for preparing a nano-calcium carbonate slurry from waste gypsum as calcium source,the product and use thereof:US,8846562[P].2014-09-30.
[25]朱玲,毛大厦,范文娟,等.以磷石膏为原料制备纳米碳酸钙[J].广州化工,2016,44(12):55-57.
[26]周静,邹洪涛,邢焰,等.磷石膏制备纳米氧化钙基二氧化碳吸附剂工艺的优化[J].无机盐工业,2016,48(10):73-76.
[27]Sawant P D,Niranjane A.Formation of nanoparticles of sparingly soluble salts(Ca SO4and Ca SO4:Dy)using liquid-liquid separation method and application for detection ofα-radiations[J].Micro&Nano Letters,2006,1(2):108-111.
[28]Osterwalder N,Loher S,Grass R N,et al.Preparation of nano-gypsum from anhydrite nanoparticles:strongly increased vickers hardness and formation of calcium sulfate nano-needles[J].Journal of Nanoparticle Research,2007,9(2):275-281.
[29]Chen D,Szostak P,Wei Z S,et al.Reduction of orthophosphates loss in agricultural soil by nano calcium sulfate[J].Science of the Total Environment,2016,539(4):381-387.