粮油产品质量安全检测技术的研究进展与发展趋势
|
摘要
我国粮油产品存在真菌毒素污染、重金属超标和非法添加有毒有害物质等主要质量安全问题。摄入受污染的粮食作物为原料加工而成的食品(饲料)会对人类和动物的身体健康造成极其严重的危害。为了满足粮油产品质量的安全监管,保障国民健康,加快建立健全粮油产品质量安全检测技术尤为重要。本研究从真菌毒素检测技术、重金属检测技术和粮油掺伪检测技术3个方面,综述了近10年来国内外的研究进展,讨论了各种技术的优点及限制因素,分析了存在的主要问题,并对其发展趋势进行了展望,以期为粮油产品质量安全检测提供参考。
There are some main quality and safety problems in China's grain and oil products, such as mycotoxin pollution, excessive heavy metals and illegal addition of toxic and harmful substances. The ingestion of food(feed) made from contaminated food crops is extremely harmful to the health of humans and animals. In order to meet the safety supervision of grain and oil product quality and ensure the national health, it is particularly important to accelerate the establishment and improvement of grain and oil product quality and safety inspection technology. This paper reviewed the research progress in recent 10 years at home and abroad of mycotoxin detection, heavy metal detection and grain and oil adulteration detection, discussed the advantages and limitations of various technologies, analyzed the main problems, and prospected the development trend, in order to provide reference for quality and safety inspection of grain and oil products.
There are some main quality and safety problems in China's grain and oil products, such as mycotoxin pollution, excessive heavy metals and illegal addition of toxic and harmful substances. The ingestion of food(feed) made from contaminated food crops is extremely harmful to the health of humans and animals. In order to meet the safety supervision of grain and oil product quality and ensure the national health, it is particularly important to accelerate the establishment and improvement of grain and oil product quality and safety inspection technology. This paper reviewed the research progress in recent 10 years at home and abroad of mycotoxin detection, heavy metal detection and grain and oil adulteration detection, discussed the advantages and limitations of various technologies, analyzed the main problems, and prospected the development trend, in order to provide reference for quality and safety inspection of grain and oil products.
引文
[1]李培武.粮油产品质量安全检测技术研究动态[J].食品安全质量检测学报,2014,5(8):2356-2357.Li PW.Research trends of quality and safety testing technology for grain and oil products[J].J Food Saf Qual,2014,5(8):2356-2357.
[2]白艺珍,李培武,丁小霞,等.我国粮油作物产品真菌毒素风险评估现状与对策探讨[J].农产品质量与安全,2015,(5):54-58.Bai YZ,Li PW,Ding XX,et al.Current situation and countermeasure of mycotoxin risk assessment of grain and oil crop products in China[J].Qual Saf Agro-Prod,2015,(5):54-58.
[3]杜政,唐瑞明.粮食中真菌毒素标准法规与检验[M].长沙:湖南科学技术出版社,2013.Du Z,Tang RM.Standard regulations and inspection of mycotoxins in grain[M].Changsha:Hunan Science and Technology Publishing House,2013.
[4]黄晓静,王少敏,毛丹.曲霉属真菌毒素的毒性研究进展[J].食品安全质量检测学报,2017,8(5):1679-1687.Huang XJ,Wang SM,Mao D.Advances in toxicity of aspergillus mycotoxins[J].J Food Saf Qual,2017,8(5):1679-1687.
[5]王瑞鑫,张微,李书国.免疫传感器在粮油中真菌毒素快速检测的应用研究进展[J].粮油食品科技,2015,23(4):83-87.Wang RX,Zhang H,Li SG.Progress in application of immunosensor in rapid detection of mycotoxins in grain and oil[J].Sci Technol Cere Oils Foods,2015,23(4):83-87.
[6]张思思,陆继伟,王少敏,等.国内外真菌毒素检测方法研究现状及进展[J].食品安全质量检测学报,2016,7(7):2575-2586.Zhang SS,Lu JW,Wang SM,et al.Current status and progress of detection methods for mycotoxins at home and abroad[J].J Food Saf Qual,2016,7(7):2575-2586.
[7]魏文忠,粱艳红,马红峰,等.粮食中真菌毒素检测技术研究进展[J].粮油食品科技,2012,20(2):37-39.Wei WZ,Liang YH,Ma HF,et al.Research progress in mycotoxin detection in grain[J].Sci Technol Cere Oils Foods,2012,20(2):37-39.
[8]陈慧菲,郁海菲,秦施奇,等.超高效液相色谱串联质谱法检测谷物中8种真菌毒素[J].粮食与油脂,2017,30(2):97-100.Chen HF,Yu HF,Qin SK,et al.Detection of eight mycotoxins in cereals by ultra-high performance liquid chromatography-tandem mass spectrometry[J].J Cere Oils,2017,30(2):97-100.
[9]郭建,尚艳娥,张燕,等.胶体金快速测试卡检测粮食中真菌毒素的应用[J].粮食科技与经济,2012,37(1):42-44.Guo J,Shang YE,Zhang Y,et al.Application of colloidal gold rapid test card in detecting mycotoxins in grain[J].Grain Sci Technol Econ,2012,37(1):42-44.
[10]张捷,陈广全,乐加昌,等.生物传感器在食源性致病菌检测中的应用[J].食品工业科技,2011,(10):453-456.Zhang J,Chen GQ,Le JC,et al.Application of biosensors in detection of foodborne pathogens[J].Food Ind Sci Technol,2011,(10):453-456.
[11]王坤,侯玉泽,胡骁飞,等.时间分辨荧光免疫分析技术在真菌毒素检测的应用[J].中国免疫学杂志,2013,29(2):197-201.Wang K,Hou YZ,Hu XF,et al.Application of time-resolved fluorescence immunoassay in detection of mycotoxins[J].Chin J Immunol,2013,29(2):197-201.
[12]黎睿,崔华,谢刚,等.几种菌毒素快速检测技术分析[J].粮食科技与经济,2013,38(1):21-23.Li R,Cui H,Xie G,et al.Analysis of rapid detection techniques for several bacteriotoxins[J].Grain Sci Technol Econ,2013,38(1):21-23.
[13]王茵,董颖超,陆成慧,等.脱氧雪腐镰刀菌烯醇胶体金检测试纸的研制及应用[J].粮食与食品工业,2014,21(5):85-90.Wang Y,Dong YC,Lu CH,et al.Development and application of deoxynivalenol colloidal gold test strip[J].Cere Food Ind,2014,21(5):85-90.
[14]李培武,张兆威,张奇,等.同步检测黄曲霉毒素、赭曲霉毒素A和玉米赤霉烯酮混合污染的免疫层析试纸条及制备方法:中国,CN201310115190.7[P].2014.Li PW,Zhang ZW,Zhang Q,et al.Simultaneous detection of aflatoxin,ochratoxin A and zearalenone by immunochromatographic test paper and preparation method:CN,CN 201310115190.7[P].2014.
[15]王文珺,刘磊,叶金,等.脱氧镰刀雪腐菌烯醇时间分辩荧光定量检测体系适用性评价[J].食品质量安全学报,2018,9(13):3490-3496.Wang WJ,Liu L,Ye J,et al.Applicability evaluation of time-resolved fluoro-immunoassay detection system for deoxynivalenol[J].J Food Saf Qual,2018,9(13):3490-3496.
[16]张兆威,李培武,张奇,等.农产品中黄曲霉毒素的时间分辨荧光免疫层析快速检测技术研究[J].中国农业科学,2014,47(18):3668-3674.Zhang ZW,Li PW,Zhang Q,et al.Study on time-resolved flurescence immunochromatography for aflatoxin determination in agricultural product[J].Sci Agric Sin,2014,47(18):3668-3674.
[17]王文珺,桑华春.真菌毒素免疫检测技术的研究进展[J].食品安全导刊,2017,6:24-26.Wang WJ,Sang HC.Advances in immunoassay of mycotoxins[J].Chin Food Saf Magaz,2017,6:24-26.
[18]李小明,银尧明,罗颖,等.粮食中真菌毒素快速定量检测方法应用比较研究[J].粮油食品科技,2017,25(1):54-57.Li XM,Yin XM,Luo Y,et al.Comparative study on rapid quantitative detection of mycotoxins in grain[J].Sci Technol Cere Oils Foods,2017,25(1):54-57.
[19]Tang XQ,Zhang ZW,Li PW,et al.Sample-pretreatment-free based high sensitive determination of aflatoxin M1 in raw milk using a time-resolved fluorescent competitive immunochromatographic assay[J].RSC Adv,2015,5(1):558-564.
[20]Zhang F,Liu B,Liu G,et al.Novel magnetic nanobeads-based fluoroimmunoassays for zearalenone detection in cereals using protein gas the recognition linker[J].Sensor Actuat B,2018,270:149-157.
[21]王文珺,叶金,孙双艳,等.粮食污染物的快速检测技术研究进展[J].食品安全质量检测学报,2018,9(21):5552-5557.Wang WJ,Ye J,Sun SY,et al.Research progress on rapid analytical methods for toxic and harmful substance in grains[J].J Food Saf Qual,2018,9(21):5552-5557.
[22]彭彦昆,张雷蕾.农畜产品品质安全光学无损检测技术的进展和趋势[J].食品安全质量检测学报,2012,3(6):561-568.Peng YK,Zhang LL.Progress and trend of optical nondestructive testing technology for quality and safety of agricultural and animal products[J].JFood Saf Qual,2012,3(6):561-568.
[23]沈飞,吴启芳,刘兵,等.粮食真菌毒素污染的无损检测方法研究进展[J].食品安全质量检测学报,2014,5(8):2372-2377.Shen F,Wu QF,Liu B,et al.Advances in nondestructive detection of food mycotoxin pollution[J].J Food Saf Qual,2014,5(8):2372-2377.
[24]沈飞,吴启芳,姜大峰,等.基于电子鼻技术的糙米黄曲霉毒素污染快速检测方法研究[J].中国粮油学报,2017,32(6):146-151.Shen F,Wu QF,Jiang DF,et al.Rapid detection of aflatoxin contamination in brown rice based on electronic nose technology[J].JChin Cere Oil Ass,2017,32(6):146-151.
[25]路子显.中国粮油重金属污染现状及防控对策[J].粮食科技与经济,2016,41(6):6-11.Lu ZX.Status of heavy metal pollution in cereals and oils in China and countermeasures for its prevention and control[J].Grain Sci Technol Econ,2016,41(6):6-11.
[26]蔡美芳,李开明,谢丹平,等.我国耕地土壤重金属污染现状与防治对策研究[J].环境科学与技术,2014,37(120):223-231.Cai MF,Li KM,Xie DP,et al.Status of heavy metal pollution in cultivated land soil and its control countermeasures in China[J].Environ Sci Technol,2014,37(120):223-231.
[27]王玉超.粮食中重金属检测技术研究进展[J].农业科学,2017,(8):46-47.Wang YC.Research progress of heavy metals detection technology in grain[J].Agric Sci,2017,(8):46-47.
[28]倪小英,许艳霞,梅广,等.主要重金属在污染稻谷籽粒中的分布规律研究[J].中国粮油学报,2017,32(1):7-11.Ni XY,Xu YX,Mei G,et al.Distribution of major heavy metals in rice grains[J].J Chin Cere Oil Ass,2017,32(1):7-11.
[29]王海慧,郇恒福,罗瑛,等.土壤重金属污染及植物修复技术[J].中国农学报,2009,25(11):210-214.Wang HH,Huan HF,Luo Y,et al.Heavy metal pollution in soil and phytoremediation techniques[J].Chin Agric Bull,2009,25(11):210-214.
[30]路子显.粮食重金属污染对粮食安全、人体健康的影响[J].粮食科技与经济,2011,36(4):14-17.Lu ZX.Effects of heavy metal pollution on food security and human health[J].Grain Sci Technol Econ,2011,36(4):14-17.
[31]冯亮,张珑,温丽英.重金属对农产品的影响及其检测方法[J].食品安全导刊,2011,3:46-48.Feng L,Zhang,Wen LY.Effects of heavy metals on agricultural products and their detection methods[J].China Food Saf Magaz,2011,3:46-48.
[32]李冉.重金属的危害及检测技术研究进展[J].农业与技术,2017,37(16):63-64.Li R.Research progress on hazard and detection technology of heavy metals[J].Agric Technol,2017,37(16):63-64.
[33]Wang YZ,Hong Y,Pschenitza M,et al.Highly sensitive and specific determination of mercury in water,food and cosmetic samples with an ELISA based on a novel monoclonal antibody[J].Anal Bioanal Chem,2012,403:2519-2528.
[34]朱旭东,赵小旭.粮食中重金属镉定量快速检测方法的建立[J].粮食科技与经济,2017,2(3):39-42.Zhu XD,Zhao XX.Establishment of rapid quantitative determination method for heavy metal cadmium in grain[J].Grain Sci Technol Econ,2017,42(3):39-42.
[35]Stozhko NY,Kolyadina LI.Electrochemical sample preparation for the voltammetric determination of heavy-metal ions in wine[J].J Anal Chem,2005,60(10):901-907.
[36]Abbasi S,Khodarahmiyan K,Abbasi F.Simultaneous determination of ultra trace amounts of lead and cadmium in food samples by adsorptive stripping voltammetry[J].Food Chem,2011,(128):254-257.
[37]刘燕德,万常斓,孙旭东,等.X射线荧光光谱技术在重金属检测中的应用[J].激光与红外,2011,41(6):605-611.Liu YD,Wan CL,Sun XD,et al.Application of X-ray fluorescence spectroscopy in the detection of heavy metals[J].Laser Infrared,2011,41(6):605-611.
[38]Shrivas K,Jarsval NK,Dispersive liquid-liquid microextraction for the determination of copperin cereals and vegetable food samples using flame atomic absorption spectrometry[J].Food Chem,2013,141(3):2263-2268.
[39]庞艳华,薛大方,田苗.微波消解-电感耦合等离子体质谱法测定食品中的18种元素现代科学仪器[J].现代科学仪器,2011,(3):78-80.Pang YH,Xue DF,Tian M.Determination of 18 kinds of trace elements in food by microwave digestion system and inductively coupled plasma mass spectrometry[J].Mod Sci Instrum,2011,(3):78-80.
[40]罗欢忠,刘俊武.微波消解-电感耦合等离子体质谱法测定大米中的铅、镉、汞和砷[J].光谱实验室,2012,29(1):470-473.Luo HZ,Liu JW.Determination of Pb,Cd,Hg ang As in rice by inductively coupled plasma mass spectrometry with microwave digestion[J].Chin J Spectrosc Lab,2012,29(1):470-473.
[41]张鑫桐.微波消解-电感耦合等离子体质谱法同时测定小麦粉中的铅和镉[J].农业工程,2014,1(4):66-68.Zhang XT.Simultaneous detection of Pb ang Cd in wheat flour by using inductively coupled plasma mass spectrometry with microwave reaction[J].Agric Eng,2014,1(4):66-68.
[42]Nacano LR,De-Freitas R,Barbosa F.Evaluation of seasonal dietary exposure to arsenic,cadmium and lead in schoolchildren through the analysis of meals served by public schools of Ribeirao preto,Brazil[J].JToxicol Env Heal A,2014,77(7):367-374.
[43]吴娆,张良晓,李培武,等.粮食中重金属检测技术研究进展[J].食品安全质量检测学报,2014,5(8):2358-2365.Wu X,Zhang LX,Li PW,et al.Research progress on analytical methods for heavy metals in grains[J].J Food Saf Qual,2014,5(8):2358-2365.
[44]马海华,张元,甄彤,等.电化学生物传感器在黄曲霉毒素检测中的研究进展[J].中国粮油学报,2016,31(2):132-139.Ma HH,Zhang Y,Zhen T,et al.Research progress of electrochemical biosensor in aflatoxin detection[J].J Chin Cere Oil Ass,2016,31(2):132-139.
[45]Singh C,Srivastava S,Ali A,et al.Carboxylated multiwalled carbon nanotubes based biosensor for aflatoxin detection[J].Sensor Actuator B,2013,185(1):258-264.
[46]Masoomi L,Sadeghi O,Banitaba MH,et al.A non-enzy-malic nanomagnetic electro-immunosensor for determination of aflatoxin as a model antigen[J].Sensor Actuator B,2013,177(1):1122-1127.
[47]Li SC,Chen JH,Cao H,et al.Amperometric biosensor forflatoxin based on aflatoxin-oxidase immobilized on multiwalled carbon nanotubes[J].Food Control,2011,22(11):43-49.
[48]周维斌,袁艺婉,阮学香.粮食中重金属检测前处理方法的注意事项[J].食品安全导刊,2017,1(3):62.Zhou WB,Yuan YW,Ruan XX.Precautions for pretreatment of heavy metals in grain[J].China Food Saf Magaz,2017,1(3):62.
[49]白满英,张金诚.掺伪粮油食品鉴别检验[M].北京:中国标准出版社,1995.Bai MY,Zhang JC.Adulterated grain and oil food identification test[M].Beijing:China Standards Press,1995.
[50]彭珊珊.食品掺伪鉴别检验[M].北京:中国轻工业出版社,2014.Peng SS.Identification of food adulteration[M].Beijing:China Light Industry Press,2014.
[51]罗莫放,刘翠银.粮油新型检测方法研究综述[J].安徽农学通报,2016,22(17):152-155.Luo MF,Liu CY.Review of new detection methods for grain and oil[J].Anhui Agric Sci Bull,2016,22(17):152-155.
[52]刘伟,张敏,张然,等.植物油掺伪检验技术研究进展[J].食品安全质量检测学,2017,8(5):1533-1538.Liu W,Zhang M,Zhang R,et al.Research progress on determination of adulterated vegetable oil[J].J Food Saf Qual,2017,8(5):1533-1538.
[53]张萍,闫继红,朱志华,等.近红外光谱技术在食品品质鉴别中的应用研究[J].现代科学仪器,2006,1:60-62.Zhang P,Yan JH,Zhu ZH,et al.Application of near infrared spectroscopy in food quality identification[J].Mod Sci Instrum,2006,1:60-62.
[54]薛雅琳,王雪莲,张蕊,等.食用植物油掺伪鉴别快速检验方法研究[J].中国粮油学报,2010,25(10):116-118.Xue YL,Wang XL,Zhang R,et al.Study on rapid detection method for adulteration identification of edible vegetable oil[J].J Cere Oils Ass,2010,25(10):116-118.
[55]Lai YW,Kemsley EK,Wilson RH.Potentialof fourier transform infraredspectroscopy for the authentication of vegetable oils[J].J Agric Food Chem,1994,42(5):1154-1159.
[56]刘福莉,王志岚,郑驰原,等.食用调和油中花生油含量的近红外光谱分析[J].激光生物学报,2007,16(6):759-762.Liu FL,Wang ZL,Zheng CY,et al.Quantitative analysis of the peanut oil content in blended edible oilusing near infrared spectroscopy[J].Acta Laser Biol Sin,2007,16(6):759-762.
[57]张伟平.粮油品质检测评价新技术的探究[J].科技与企业,2014,(8):63.Zhang WP.Exploration on new technology of grain and oil quality detection and evaluation[J].Sci Technol Enterp,2014,(8):63.
[58]张檬达,鞠兴荣,石嘉怿.电子鼻在粮油品质检测中的应用进展[J].粮食与食品工业,2013,(5):34-38.Zhang MD,Ju XR,Shi JY.Application progress of electronic nose in grain and oil quality detection[J].Cere Food Ind,2013,(5):34-38.
[59]李元元,吴亚君,张海亮,等.电子鼻在食用油鉴伪中的应用进展[J].中国油脂,2011,10:60-63.Li YY,Wu YJ,Zhang HL,et al.Progress on the application of electronicnose for edible oil adulteration[J].China Oils Fats,2011,10:60-63.
[60]谢刚,叶金,王松雪.食品安全快速检测方法评价技术研究进展[J].食品科学,2016,37(17):270-274.Xie G,Ye J,Wang SX.Research progress on evaluation technology of food safety rapid detection methods[J].Food Sci,2016,37(17):270-274.
[61]李培武,丁小霞.我国粮油质量安全防控技术研究与发展对策[J].中国农业科技导报,2011,13(5):54-58.Li PW,Ding XX.Studies on control technology for grain and oil quality and safety in China and development countermeasure[J].J Agric Sci Technol,2011,13(5):54-58.
[62]孙启鹏.我国粮油质量安全防控技术研究与发展对策[J].食品安全导刊,2018,(18):17.Sun QP.Research and development countermeasure of grain and oil quality and safety preventi on and control technology in China[J].China Food Saf Magaz,2018,(18):17.
[2]白艺珍,李培武,丁小霞,等.我国粮油作物产品真菌毒素风险评估现状与对策探讨[J].农产品质量与安全,2015,(5):54-58.Bai YZ,Li PW,Ding XX,et al.Current situation and countermeasure of mycotoxin risk assessment of grain and oil crop products in China[J].Qual Saf Agro-Prod,2015,(5):54-58.
[3]杜政,唐瑞明.粮食中真菌毒素标准法规与检验[M].长沙:湖南科学技术出版社,2013.Du Z,Tang RM.Standard regulations and inspection of mycotoxins in grain[M].Changsha:Hunan Science and Technology Publishing House,2013.
[4]黄晓静,王少敏,毛丹.曲霉属真菌毒素的毒性研究进展[J].食品安全质量检测学报,2017,8(5):1679-1687.Huang XJ,Wang SM,Mao D.Advances in toxicity of aspergillus mycotoxins[J].J Food Saf Qual,2017,8(5):1679-1687.
[5]王瑞鑫,张微,李书国.免疫传感器在粮油中真菌毒素快速检测的应用研究进展[J].粮油食品科技,2015,23(4):83-87.Wang RX,Zhang H,Li SG.Progress in application of immunosensor in rapid detection of mycotoxins in grain and oil[J].Sci Technol Cere Oils Foods,2015,23(4):83-87.
[6]张思思,陆继伟,王少敏,等.国内外真菌毒素检测方法研究现状及进展[J].食品安全质量检测学报,2016,7(7):2575-2586.Zhang SS,Lu JW,Wang SM,et al.Current status and progress of detection methods for mycotoxins at home and abroad[J].J Food Saf Qual,2016,7(7):2575-2586.
[7]魏文忠,粱艳红,马红峰,等.粮食中真菌毒素检测技术研究进展[J].粮油食品科技,2012,20(2):37-39.Wei WZ,Liang YH,Ma HF,et al.Research progress in mycotoxin detection in grain[J].Sci Technol Cere Oils Foods,2012,20(2):37-39.
[8]陈慧菲,郁海菲,秦施奇,等.超高效液相色谱串联质谱法检测谷物中8种真菌毒素[J].粮食与油脂,2017,30(2):97-100.Chen HF,Yu HF,Qin SK,et al.Detection of eight mycotoxins in cereals by ultra-high performance liquid chromatography-tandem mass spectrometry[J].J Cere Oils,2017,30(2):97-100.
[9]郭建,尚艳娥,张燕,等.胶体金快速测试卡检测粮食中真菌毒素的应用[J].粮食科技与经济,2012,37(1):42-44.Guo J,Shang YE,Zhang Y,et al.Application of colloidal gold rapid test card in detecting mycotoxins in grain[J].Grain Sci Technol Econ,2012,37(1):42-44.
[10]张捷,陈广全,乐加昌,等.生物传感器在食源性致病菌检测中的应用[J].食品工业科技,2011,(10):453-456.Zhang J,Chen GQ,Le JC,et al.Application of biosensors in detection of foodborne pathogens[J].Food Ind Sci Technol,2011,(10):453-456.
[11]王坤,侯玉泽,胡骁飞,等.时间分辨荧光免疫分析技术在真菌毒素检测的应用[J].中国免疫学杂志,2013,29(2):197-201.Wang K,Hou YZ,Hu XF,et al.Application of time-resolved fluorescence immunoassay in detection of mycotoxins[J].Chin J Immunol,2013,29(2):197-201.
[12]黎睿,崔华,谢刚,等.几种菌毒素快速检测技术分析[J].粮食科技与经济,2013,38(1):21-23.Li R,Cui H,Xie G,et al.Analysis of rapid detection techniques for several bacteriotoxins[J].Grain Sci Technol Econ,2013,38(1):21-23.
[13]王茵,董颖超,陆成慧,等.脱氧雪腐镰刀菌烯醇胶体金检测试纸的研制及应用[J].粮食与食品工业,2014,21(5):85-90.Wang Y,Dong YC,Lu CH,et al.Development and application of deoxynivalenol colloidal gold test strip[J].Cere Food Ind,2014,21(5):85-90.
[14]李培武,张兆威,张奇,等.同步检测黄曲霉毒素、赭曲霉毒素A和玉米赤霉烯酮混合污染的免疫层析试纸条及制备方法:中国,CN201310115190.7[P].2014.Li PW,Zhang ZW,Zhang Q,et al.Simultaneous detection of aflatoxin,ochratoxin A and zearalenone by immunochromatographic test paper and preparation method:CN,CN 201310115190.7[P].2014.
[15]王文珺,刘磊,叶金,等.脱氧镰刀雪腐菌烯醇时间分辩荧光定量检测体系适用性评价[J].食品质量安全学报,2018,9(13):3490-3496.Wang WJ,Liu L,Ye J,et al.Applicability evaluation of time-resolved fluoro-immunoassay detection system for deoxynivalenol[J].J Food Saf Qual,2018,9(13):3490-3496.
[16]张兆威,李培武,张奇,等.农产品中黄曲霉毒素的时间分辨荧光免疫层析快速检测技术研究[J].中国农业科学,2014,47(18):3668-3674.Zhang ZW,Li PW,Zhang Q,et al.Study on time-resolved flurescence immunochromatography for aflatoxin determination in agricultural product[J].Sci Agric Sin,2014,47(18):3668-3674.
[17]王文珺,桑华春.真菌毒素免疫检测技术的研究进展[J].食品安全导刊,2017,6:24-26.Wang WJ,Sang HC.Advances in immunoassay of mycotoxins[J].Chin Food Saf Magaz,2017,6:24-26.
[18]李小明,银尧明,罗颖,等.粮食中真菌毒素快速定量检测方法应用比较研究[J].粮油食品科技,2017,25(1):54-57.Li XM,Yin XM,Luo Y,et al.Comparative study on rapid quantitative detection of mycotoxins in grain[J].Sci Technol Cere Oils Foods,2017,25(1):54-57.
[19]Tang XQ,Zhang ZW,Li PW,et al.Sample-pretreatment-free based high sensitive determination of aflatoxin M1 in raw milk using a time-resolved fluorescent competitive immunochromatographic assay[J].RSC Adv,2015,5(1):558-564.
[20]Zhang F,Liu B,Liu G,et al.Novel magnetic nanobeads-based fluoroimmunoassays for zearalenone detection in cereals using protein gas the recognition linker[J].Sensor Actuat B,2018,270:149-157.
[21]王文珺,叶金,孙双艳,等.粮食污染物的快速检测技术研究进展[J].食品安全质量检测学报,2018,9(21):5552-5557.Wang WJ,Ye J,Sun SY,et al.Research progress on rapid analytical methods for toxic and harmful substance in grains[J].J Food Saf Qual,2018,9(21):5552-5557.
[22]彭彦昆,张雷蕾.农畜产品品质安全光学无损检测技术的进展和趋势[J].食品安全质量检测学报,2012,3(6):561-568.Peng YK,Zhang LL.Progress and trend of optical nondestructive testing technology for quality and safety of agricultural and animal products[J].JFood Saf Qual,2012,3(6):561-568.
[23]沈飞,吴启芳,刘兵,等.粮食真菌毒素污染的无损检测方法研究进展[J].食品安全质量检测学报,2014,5(8):2372-2377.Shen F,Wu QF,Liu B,et al.Advances in nondestructive detection of food mycotoxin pollution[J].J Food Saf Qual,2014,5(8):2372-2377.
[24]沈飞,吴启芳,姜大峰,等.基于电子鼻技术的糙米黄曲霉毒素污染快速检测方法研究[J].中国粮油学报,2017,32(6):146-151.Shen F,Wu QF,Jiang DF,et al.Rapid detection of aflatoxin contamination in brown rice based on electronic nose technology[J].JChin Cere Oil Ass,2017,32(6):146-151.
[25]路子显.中国粮油重金属污染现状及防控对策[J].粮食科技与经济,2016,41(6):6-11.Lu ZX.Status of heavy metal pollution in cereals and oils in China and countermeasures for its prevention and control[J].Grain Sci Technol Econ,2016,41(6):6-11.
[26]蔡美芳,李开明,谢丹平,等.我国耕地土壤重金属污染现状与防治对策研究[J].环境科学与技术,2014,37(120):223-231.Cai MF,Li KM,Xie DP,et al.Status of heavy metal pollution in cultivated land soil and its control countermeasures in China[J].Environ Sci Technol,2014,37(120):223-231.
[27]王玉超.粮食中重金属检测技术研究进展[J].农业科学,2017,(8):46-47.Wang YC.Research progress of heavy metals detection technology in grain[J].Agric Sci,2017,(8):46-47.
[28]倪小英,许艳霞,梅广,等.主要重金属在污染稻谷籽粒中的分布规律研究[J].中国粮油学报,2017,32(1):7-11.Ni XY,Xu YX,Mei G,et al.Distribution of major heavy metals in rice grains[J].J Chin Cere Oil Ass,2017,32(1):7-11.
[29]王海慧,郇恒福,罗瑛,等.土壤重金属污染及植物修复技术[J].中国农学报,2009,25(11):210-214.Wang HH,Huan HF,Luo Y,et al.Heavy metal pollution in soil and phytoremediation techniques[J].Chin Agric Bull,2009,25(11):210-214.
[30]路子显.粮食重金属污染对粮食安全、人体健康的影响[J].粮食科技与经济,2011,36(4):14-17.Lu ZX.Effects of heavy metal pollution on food security and human health[J].Grain Sci Technol Econ,2011,36(4):14-17.
[31]冯亮,张珑,温丽英.重金属对农产品的影响及其检测方法[J].食品安全导刊,2011,3:46-48.Feng L,Zhang,Wen LY.Effects of heavy metals on agricultural products and their detection methods[J].China Food Saf Magaz,2011,3:46-48.
[32]李冉.重金属的危害及检测技术研究进展[J].农业与技术,2017,37(16):63-64.Li R.Research progress on hazard and detection technology of heavy metals[J].Agric Technol,2017,37(16):63-64.
[33]Wang YZ,Hong Y,Pschenitza M,et al.Highly sensitive and specific determination of mercury in water,food and cosmetic samples with an ELISA based on a novel monoclonal antibody[J].Anal Bioanal Chem,2012,403:2519-2528.
[34]朱旭东,赵小旭.粮食中重金属镉定量快速检测方法的建立[J].粮食科技与经济,2017,2(3):39-42.Zhu XD,Zhao XX.Establishment of rapid quantitative determination method for heavy metal cadmium in grain[J].Grain Sci Technol Econ,2017,42(3):39-42.
[35]Stozhko NY,Kolyadina LI.Electrochemical sample preparation for the voltammetric determination of heavy-metal ions in wine[J].J Anal Chem,2005,60(10):901-907.
[36]Abbasi S,Khodarahmiyan K,Abbasi F.Simultaneous determination of ultra trace amounts of lead and cadmium in food samples by adsorptive stripping voltammetry[J].Food Chem,2011,(128):254-257.
[37]刘燕德,万常斓,孙旭东,等.X射线荧光光谱技术在重金属检测中的应用[J].激光与红外,2011,41(6):605-611.Liu YD,Wan CL,Sun XD,et al.Application of X-ray fluorescence spectroscopy in the detection of heavy metals[J].Laser Infrared,2011,41(6):605-611.
[38]Shrivas K,Jarsval NK,Dispersive liquid-liquid microextraction for the determination of copperin cereals and vegetable food samples using flame atomic absorption spectrometry[J].Food Chem,2013,141(3):2263-2268.
[39]庞艳华,薛大方,田苗.微波消解-电感耦合等离子体质谱法测定食品中的18种元素现代科学仪器[J].现代科学仪器,2011,(3):78-80.Pang YH,Xue DF,Tian M.Determination of 18 kinds of trace elements in food by microwave digestion system and inductively coupled plasma mass spectrometry[J].Mod Sci Instrum,2011,(3):78-80.
[40]罗欢忠,刘俊武.微波消解-电感耦合等离子体质谱法测定大米中的铅、镉、汞和砷[J].光谱实验室,2012,29(1):470-473.Luo HZ,Liu JW.Determination of Pb,Cd,Hg ang As in rice by inductively coupled plasma mass spectrometry with microwave digestion[J].Chin J Spectrosc Lab,2012,29(1):470-473.
[41]张鑫桐.微波消解-电感耦合等离子体质谱法同时测定小麦粉中的铅和镉[J].农业工程,2014,1(4):66-68.Zhang XT.Simultaneous detection of Pb ang Cd in wheat flour by using inductively coupled plasma mass spectrometry with microwave reaction[J].Agric Eng,2014,1(4):66-68.
[42]Nacano LR,De-Freitas R,Barbosa F.Evaluation of seasonal dietary exposure to arsenic,cadmium and lead in schoolchildren through the analysis of meals served by public schools of Ribeirao preto,Brazil[J].JToxicol Env Heal A,2014,77(7):367-374.
[43]吴娆,张良晓,李培武,等.粮食中重金属检测技术研究进展[J].食品安全质量检测学报,2014,5(8):2358-2365.Wu X,Zhang LX,Li PW,et al.Research progress on analytical methods for heavy metals in grains[J].J Food Saf Qual,2014,5(8):2358-2365.
[44]马海华,张元,甄彤,等.电化学生物传感器在黄曲霉毒素检测中的研究进展[J].中国粮油学报,2016,31(2):132-139.Ma HH,Zhang Y,Zhen T,et al.Research progress of electrochemical biosensor in aflatoxin detection[J].J Chin Cere Oil Ass,2016,31(2):132-139.
[45]Singh C,Srivastava S,Ali A,et al.Carboxylated multiwalled carbon nanotubes based biosensor for aflatoxin detection[J].Sensor Actuator B,2013,185(1):258-264.
[46]Masoomi L,Sadeghi O,Banitaba MH,et al.A non-enzy-malic nanomagnetic electro-immunosensor for determination of aflatoxin as a model antigen[J].Sensor Actuator B,2013,177(1):1122-1127.
[47]Li SC,Chen JH,Cao H,et al.Amperometric biosensor forflatoxin based on aflatoxin-oxidase immobilized on multiwalled carbon nanotubes[J].Food Control,2011,22(11):43-49.
[48]周维斌,袁艺婉,阮学香.粮食中重金属检测前处理方法的注意事项[J].食品安全导刊,2017,1(3):62.Zhou WB,Yuan YW,Ruan XX.Precautions for pretreatment of heavy metals in grain[J].China Food Saf Magaz,2017,1(3):62.
[49]白满英,张金诚.掺伪粮油食品鉴别检验[M].北京:中国标准出版社,1995.Bai MY,Zhang JC.Adulterated grain and oil food identification test[M].Beijing:China Standards Press,1995.
[50]彭珊珊.食品掺伪鉴别检验[M].北京:中国轻工业出版社,2014.Peng SS.Identification of food adulteration[M].Beijing:China Light Industry Press,2014.
[51]罗莫放,刘翠银.粮油新型检测方法研究综述[J].安徽农学通报,2016,22(17):152-155.Luo MF,Liu CY.Review of new detection methods for grain and oil[J].Anhui Agric Sci Bull,2016,22(17):152-155.
[52]刘伟,张敏,张然,等.植物油掺伪检验技术研究进展[J].食品安全质量检测学,2017,8(5):1533-1538.Liu W,Zhang M,Zhang R,et al.Research progress on determination of adulterated vegetable oil[J].J Food Saf Qual,2017,8(5):1533-1538.
[53]张萍,闫继红,朱志华,等.近红外光谱技术在食品品质鉴别中的应用研究[J].现代科学仪器,2006,1:60-62.Zhang P,Yan JH,Zhu ZH,et al.Application of near infrared spectroscopy in food quality identification[J].Mod Sci Instrum,2006,1:60-62.
[54]薛雅琳,王雪莲,张蕊,等.食用植物油掺伪鉴别快速检验方法研究[J].中国粮油学报,2010,25(10):116-118.Xue YL,Wang XL,Zhang R,et al.Study on rapid detection method for adulteration identification of edible vegetable oil[J].J Cere Oils Ass,2010,25(10):116-118.
[55]Lai YW,Kemsley EK,Wilson RH.Potentialof fourier transform infraredspectroscopy for the authentication of vegetable oils[J].J Agric Food Chem,1994,42(5):1154-1159.
[56]刘福莉,王志岚,郑驰原,等.食用调和油中花生油含量的近红外光谱分析[J].激光生物学报,2007,16(6):759-762.Liu FL,Wang ZL,Zheng CY,et al.Quantitative analysis of the peanut oil content in blended edible oilusing near infrared spectroscopy[J].Acta Laser Biol Sin,2007,16(6):759-762.
[57]张伟平.粮油品质检测评价新技术的探究[J].科技与企业,2014,(8):63.Zhang WP.Exploration on new technology of grain and oil quality detection and evaluation[J].Sci Technol Enterp,2014,(8):63.
[58]张檬达,鞠兴荣,石嘉怿.电子鼻在粮油品质检测中的应用进展[J].粮食与食品工业,2013,(5):34-38.Zhang MD,Ju XR,Shi JY.Application progress of electronic nose in grain and oil quality detection[J].Cere Food Ind,2013,(5):34-38.
[59]李元元,吴亚君,张海亮,等.电子鼻在食用油鉴伪中的应用进展[J].中国油脂,2011,10:60-63.Li YY,Wu YJ,Zhang HL,et al.Progress on the application of electronicnose for edible oil adulteration[J].China Oils Fats,2011,10:60-63.
[60]谢刚,叶金,王松雪.食品安全快速检测方法评价技术研究进展[J].食品科学,2016,37(17):270-274.Xie G,Ye J,Wang SX.Research progress on evaluation technology of food safety rapid detection methods[J].Food Sci,2016,37(17):270-274.
[61]李培武,丁小霞.我国粮油质量安全防控技术研究与发展对策[J].中国农业科技导报,2011,13(5):54-58.Li PW,Ding XX.Studies on control technology for grain and oil quality and safety in China and development countermeasure[J].J Agric Sci Technol,2011,13(5):54-58.
[62]孙启鹏.我国粮油质量安全防控技术研究与发展对策[J].食品安全导刊,2018,(18):17.Sun QP.Research and development countermeasure of grain and oil quality and safety preventi on and control technology in China[J].China Food Saf Magaz,2018,(18):17.