钠基固体电解质及其在能源上的应用
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摘要
由于以钠基固体电解质为核心的新型钠电池体系具有低成本和高安全性,在能源领域应用潜力巨大。高离子电导率和稳定性是钠基固体电解质应用于新型钠电池体系的前提。近年来,人们通过对制备方法改进和掺杂改性等方面的研究显著提高了钠基固体电解质的离子电导率和稳定性。此外,新型钠电池体系亟需解决固体电解质与电极间的界面接触性差和界面稳定性差等问题。本文首先总结了β″-Al_2O_3、NASICON型、硫化物类和聚合物类钠基固体电解质的研究进展,然后介绍了钠基固体电解质在以钠-硫电池,有机/水混合系钠-空气电池和全固态钠离子电池为代表的新型钠电池体系中的应用情况,并对界面问题和采取的解决策略进行系统论述。基于固体电解质的新型钠电池体系在能源上的大规模应用还需要电池材料、界面和电池设计等多方面的研究同时突破。
Due to the low cost and high safety of the new sodium battery system using sodium-based solid electrolyte, the new sodium battery system has great potential for its applications in energy storage field. High ionic conductivity and stability of sodium-based solid electrolytes are prerequisites for its applications in new sodium battery systems. In recent years, people have significantly improved the ionic conductivity and stability of sodium-based solid electrolytes by improving preparation methods and doping modifications. In addition, the new sodium battery system needs to solve the interface problems such as poor interface contact and poor interface stability between the solid state electrolyte and the electrode. In this paper, we firstly summarize the research progress in ionic conductivity and stability of β-Al_2O_3, NASICON, sulfides, and polymer of sodium-based solid electrolytes. Then the applications of sodium-based solid electrolytes in sodium-sulfur batteries, hybrid sodium-air batteries, and all-solid-state sodium-ion batteries are introduced. In view of the interface problems, the solving strategies are systematically discussed. The future large-scale applications in energy of the new sodium battery system based on solid state electrolytes need breakthroughs in many aspects such as battery materials, interfaces, and battery design.
Due to the low cost and high safety of the new sodium battery system using sodium-based solid electrolyte, the new sodium battery system has great potential for its applications in energy storage field. High ionic conductivity and stability of sodium-based solid electrolytes are prerequisites for its applications in new sodium battery systems. In recent years, people have significantly improved the ionic conductivity and stability of sodium-based solid electrolytes by improving preparation methods and doping modifications. In addition, the new sodium battery system needs to solve the interface problems such as poor interface contact and poor interface stability between the solid state electrolyte and the electrode. In this paper, we firstly summarize the research progress in ionic conductivity and stability of β-Al_2O_3, NASICON, sulfides, and polymer of sodium-based solid electrolytes. Then the applications of sodium-based solid electrolytes in sodium-sulfur batteries, hybrid sodium-air batteries, and all-solid-state sodium-ion batteries are introduced. In view of the interface problems, the solving strategies are systematically discussed. The future large-scale applications in energy of the new sodium battery system based on solid state electrolytes need breakthroughs in many aspects such as battery materials, interfaces, and battery design.
引文
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[2] 刘丽露(Liu L L), 戚兴国(Qi X G), 邵元骏(Shao Y J), 潘都(Pan D),白莹(Bai Y),胡勇胜(Hu Y S), 李泓(Li H), 陈立泉(Chen L Q). 储能科学与技术(Energy Storage Science and Technology), 2017, 6(5): 961.
[3] Lee D H, Lee S T, Kim J S, Lim S K. Materials Research Bulletin, 2017, 96: 143.
[4] Samiee M, Radhakrishnan B, Rice Z, Deng Z, Meng Y S, Ong S P, Luo J. Journal of Power Sources, 2017, 347: 229.
[5] Chu I H, Kompella C S, Nguyen H, Zhu Z, Hy S, Deng Z, Meng Y S, Ong Scientific Reports, 2016, 6: 33733.
[6] Min J K, Stackpool M, Shin C H, Lee C H. Journal of Power Sources, 2015, 293(3): 835.
[7] 林祖纕(Lin Z X), 郭祝崑(Guo Z K), 孙成文(Sun W C), 李世椿(Li S C), 陈昆刚(Chen K G), 田顺宝(Tian S B), 严冬生(Yang D S). 快离子导体(Fast Ion Conductor). 上海:上海科学技术出版社(Shanghai: Shanghai Scientific Technology Press), 1983.141.
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[12] Zhang G X, Wen Z Y, Wu X W, Zhang J C, Ma G Q, Jin J. Journal of Alloys and Compounds, 2014, 613(1): 80.
[13] Wei X L, Xia Y, Liu X M, Yang H, Shen X D. Electrochimica Acta, 2014, 136: 250.
[14] Xu D, Jiang H, Li Y, Li L, Li M, Hai O. European Physical Journal Applied Physics, 2016, 74(1): 250.
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[22] Guin M, Tietz F. Journal of Power Sources, 2015, 273: 1056.
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[28] Fuentes R O, Figueiredo F, Marques F M B, Franco J I. Solid State Ionics, 2001, 139(3/4): 309.
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[35] Hayashi A, Noi K, Tanibata N, Nagao M, Tatsumisago M. Journal of Power Sources, 2014, 258(14): 420.
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[40] Aobing D U, Chai J, Zhang J, Liu Z, Cui G. Energy Storage Science and Technology, 2016, 6: 627.
[41] Chandra A. Indian Journal of Pure and Applied Physics, 2016, 54(9): 583.
[42] Anantha P S, Hariharan K. Solid State Ionics, 2005, 176(1/2): 155.
[43] Qi X, Ma Q, Liu L, Hu Y S, Li H, Zhou Z, Huang X, Chen L. ChemElectroChem, 2016, 3(11): 1741.
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[46] Ni'Mah Y L, Cheng M Y, Cheng J H, Rick J, Hwang B J. Journal of Power Sources, 2015, 278: 375.
[47] Zhang Z, Zhang Q, Ren C, Luo F, Ma Q, Hu Y S, Li H, Zhou Z, Huang X, Chen L. Journal of Materials Chemistry A, 2016, 4: 15823.
[48] Reddy M J, Sreekanth T, Rao U V S. Solid State Ionics, 1999, 126(1): 55.
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[51] Song S, Kotobuki M, Zheng F, Xu C, Savilov S V, Hu N, Lu L, Wang Y, Li W D Z. Journal of Materials Chemistry A, 2017, 5: 6424.
[52] Lee S, Park S J, Kim S. Res Chem Intermed, 2017, 43: 5403.
[53] Reddy M J, Sreekanth T, Chandrashekar M, Rao U V S. Journal of Materials Science, 2000, 35(11): 2841.
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[55] Aziz S B, Abdullah O G, Rasheed M A. Journal of Materials Science Materials in Electronics, 2017, 28(17): 12873.
[56] Bhargav P B, Mohan V M, Sharma A K, Rao V R. Journal of Applied Polymer Science, 2008, 108(1): 510.
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[59] Jyothi N K, Kumar K V, Sundari G S, Murthy P N. Indian Journal of Physics, 2015, 90(3): 1.
[60] Yang Y Q, Chang Z, Li M X, Wang X W, Wu Y P. Solid State Ionics, 2015, 269: 1.
[61] Badr S, Sheha E, Bayomi R M, Shaarawy M G E. Ionics, 2010, 16(3): 269.
[62] Vignarooban K, Badami P, Dissanayake M A K L, Ravirajan P, Kanan AM. Ionics, 2017, 23: 2817.
[63] Wang F, Wang X, Chang Z, Wu X, Liu X, Fu L, Zhu Y, Wu Y, Huang W. Advanced Materials, 2015, 27: 6962.
[64] 温兆银(Wen Z Y), 俞国勤(Yu G Q), 顾中华(Gu Z H), 何维国(He W G), 韩金铎(Han J D), 张宇(Zhang Y), 刘宇(Liu Y), 楼晓东(Lou X D). 供用电(Distribution and Utilization), 2010, 27(6): 25.
[65] 胡英瑛(Hu Y Y), 温兆银(Wen Z Y), 芮琨(Rui K), 吴相伟(Wu X W). 储能科学与技术(Energy Storage Science and Technology), 2013, 2(2): 81.
[66] Jung K, Colker J P, Cao Y, Kim G, Park Y C, Kim C S. Journal of Power Sources, 2016, 324: 665.
[67] Kim I, Kim C H, Choi S, Ahn J P, Ahn J H, Kim K W, Cairns E J, Ahn H J. Journal of Power Sources, 2016, 307: 31.
[68] Wei S, Xu S, Agrawral A, Choudhury S, Lu Y, Tu Z, Ma L, Archer L. Nature Communications, 2016, 7: 11722.
[69] Tanibata N, Deguchi M, Hayashi A, Tatsumisago M. Chemistry of Materials, 2017, 29: 5232.
[70] Kim I, Park J Y, Kim C H, Park J W, Ahn J P, Ahn J H, Kim K W, Ahn H J. Journal of the Electrochemical Society, 2016, 163(5): A611.
[71] Wenzel S, Metelmann H, Rai? C, Dürr A K, Janek J, Adelhelm P. Journal of Power Sources, 2013, 243(6): 758.
[72] Lu X, Kirby B W, Xu W, Li G, Kim J Y, Lemmon J P, Sprenkle V L, Yang Z. Energy and Environmental Science, 2012, 6(1): 299.
[73] Luo W, Lin C, Zhao O, Noked M, Zhang Y, Rubloff G W, Hu L. Advanced Energy Materials, 2017, 7: 1601526.
[74] Kohl M, Borrmann F, Althues H, Kaskel S. Advanced Energy Materials, 2016, 6: 1.
[75] Song J, Jeong G, AhJung Lee, Park J H, Kim H, Kim Y J. ACS Applied Materials and Interfaces, 2015, 7(49): 27206.
[76] Hayashi K, Shima K, Sugiyama F. Journal of the Electrochemical Society, 2013, 160(9): A1467.
[77] Yao K, Feng L, Hayashi K. Electrochimica Acta, 2016, 218: 119.
[78] Tian Y, Shi T, Richards W D, Li J, Kim J C, Bo S H, Ceder G. Energy and Environmental Sci., 2017, 10: 1150.
[79] Rao R P, Chen H, Wong L, Adams S. Journal of Materials Chemistry A, 2017, 5: 3377.
[80] Yubuchi S, Hayashi A, Tatsumisago M. Chemistry Letters, 2015, 44(47): 884.
[81] Zhu Y S, Li L L, Li C Y, Zhou L, Wu Y P. Solid State Ionics, 2016, 289: 113.
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