酸岩反应动力学关键问题及其进展
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摘要
酸岩反应动力学研究是酸化酸压设计的基础,目前多以旋转岩盘动态模拟方法为主。现有旋转岩盘装置酸岩反应的溶蚀形态是面溶蚀,而实际酸化过程中常产生蚓孔溶蚀。采用面溶蚀下测得的酸岩反应动力学参数用于蚓孔溶蚀下的酸化工艺设计,是导致酸化设计不合理的重要原因之一,也是酸岩反应动力学研究中亟待解决的关键问题。通过对国内外酸岩反应动力学研究进展进行了系统的总结,分析了酸岩反应动力学研究中存在的问题,例如CO_2等反应产物、面容比、氢离子浓度分布等因素对酸岩反应动力学参数的准确测定带来的影响,并针对关键问题指出了酸岩反应动力学研究的发展趋势。
The study of acid-rock reaction kinetics is the basis of acidizing design. At present,rotating rock disk is mainly used. The dissolution form of the acid-rock is surface dissolution,but worm-hole often occurs in actual acidizing process. The acid-rock reaction kinetics under surface erosion are used to acidification process design,which is one of reasons for the unreasonable acidification design. It is also a key issue to be solved. By summarizing kinetics of acid rock reaction at home and abroad,the problems in kinetics of acid rock reaction are analyzed,such as the influence of factors,CO_2 reaction products,the ratio of face volume and the distribution of hydrogen ion concentration to the determination of parameters. The development trend of acid-rock reaction kinetics was pointed out.
The study of acid-rock reaction kinetics is the basis of acidizing design. At present,rotating rock disk is mainly used. The dissolution form of the acid-rock is surface dissolution,but worm-hole often occurs in actual acidizing process. The acid-rock reaction kinetics under surface erosion are used to acidification process design,which is one of reasons for the unreasonable acidification design. It is also a key issue to be solved. By summarizing kinetics of acid rock reaction at home and abroad,the problems in kinetics of acid rock reaction are analyzed,such as the influence of factors,CO_2 reaction products,the ratio of face volume and the distribution of hydrogen ion concentration to the determination of parameters. The development trend of acid-rock reaction kinetics was pointed out.
引文
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2赵立强.碳酸盐岩和盐酸反应动力学的试验研究[J].西南石油学院报,1988,10(1):34-41Zhao Liqiang.Experimental study on reaction kinetics of carbonate rocks and hydrochloric acid[J].Journal of Southwest Petroleum Institute,1988,10(1):34-41
3任书泉,李联奎,袁子光,等.旋转岩盘试验仪的研制和应用[J].石油钻采工艺,1983(5):69-75Ren Shuquan,Li Liankui,Yuan Ziguang,et al.Development and application of rotary disk tester[J].Petroleum Drilling and Production Technology,1983(5):69-75
4 Mumallah N A.Hydrochric acid diffusion coefficients at acid-fracturing conditions[J].Journal of Petroleum Science And Engineering,1996,15:361-374
5罗平,张静,刘伟,等.中国海相碳酸盐岩油气储层基本特征[J].地学前缘,2008(1):36-50Luo Ping,Zhang Jing,Liu Wei,et al.Basic characteristics of marine carbonate reservoirs in China[J].Geological Front,2008(1):36-50
6任书泉,袁子光,李联奎,等.酸岩反应的旋转模拟试验[J].石油钻采工艺,1983(6):61-67Ren Shuquan,Yuan Ziguang,Li Liankui,et al.Rotational simulation test of acid rock reaction[J].Petroleum Drilling and Production Technology,1983(6):61-67
7张智勇,蒋廷学,梁冲,等.胶凝酸反应动力学试验研究[J].钻井液与完井液,2005(5):28-30Zhang Zhiyong,Jiang Tingxue,Liang Chong,et al.Kinetics of gelling acid reaction[J].Drilling Fluid and Completion Fluid,2005(5):28-30
8张建利,孙忠杰,张泽兰.碳酸盐岩油藏酸岩反应动力学实验研究[J].油田化学,2003,20(3):216-219Zhang Jianli,Sun Zhongjie,Zhang Zelan.Experimental study on acid-rock reaction kinetics in carbonate reservoirs[J].Oilfield Chemistry,2003,20(3):216-219
9何春明,陈红军,刘岚,等.VES自转向酸反应动力学研究[J].石油化工与天然气化工,2010,33(9):246-253He Chunming,Chen Hongjun,Liu Lan,et al.Study on kinetics of VES self-turning acid reaction[J].Petrochemical and Natural Gas Chemical,2010,33(9):246-253
10伊向艺,卢渊,李沁,等.不同黏度酸液体系酸岩反应动力学参数测定装置:中国,ZL 200910058898.7.[P].2012-08-08Yi Xiangyi,Lu Yuan,Li Qin,et al.Kinetic parameters of acidrock reaction in acid-liquid systems with different viscosities:ZL200910058898.7[P].2012-08-08
11李小刚,杨兆中,胡学明,等.酸压裂缝中酸液流动反应行为研究综述[J].钻井液与完并液,2008,25(6):70-73Li Xiaogang,Yang Zhaozhong,Hu Xueming,et al.A review of acid flow reaction behavior in acid fracturing[J].Drilling Fluid and Completion Fluid,2008,25(6):70-73
12陈赓良,黄瑛.碳酸盐岩酸化反应机理分析[J].天然气工业,2006,26(1):104-108Chen Gengliang,Huang Ying.Mechanism analysis of carbonate rock acidification reaction[J].Natural Gas Industry,2006,26(1):104-108
13孙连环.塔里木盆地塔中碳酸盐岩储层酸岩反应动力学实验研究[J].石油与天然气化工,2006,35(1):51-53Sun Lianhuan.Experimental study on acid-rock reaction kinetics of carbonate reservoirs in Tazhong Tarim Basin[J].Petroleum and Natural Gas Chemical Industry,2006,35(1):51-53
14孙大权.南堡奥陶系碳酸盐岩储层酸化改造技术研究[D].成都:西南石油大学,2017Sun Daquan.Study on the acidizing technology of Ordovician carbonate reservoir in Nanpu[D].Chengdu:Southwest Petroleum University,2017
15任书泉,熊宏杰.同离子效应和温度场对裂缝中酸液有效作用距离的影响[J].西南石油学院学报,1986(4):23-35Ren Shuquan,Xiong Hongjie.Effect of the same ion effect and temperature field on the effective distance of acid solution in fracture.Journal of Southwest Petroleum Institute,1986(4):23-35
16李沁.高黏度酸液酸岩反应模拟实验新方法探索[D].成都:成都理工大学,2010Li Qin.A new method for simulating acid rock reaction of high viscosity acid[D].Chengdu:Chengdu University of Technology,2010
17李小刚,陈雨松,邓庄,等.碳酸盐岩基质酸化中酸蚀蚓孔模拟回顾与展望[J].新疆石油地质,2017,38(4):492-497Li Xiaogang,Chen Yusong,Dengzhuang,et al.Review and Prospect of acid-etching wormhole simulation in carbonate matrix acidification[J].Petroleum Geology of Xinjiang,2017,38(4):492-497
18 Lund K,Fogler H S,Mc Cune C C,et al.Acidization-ll.The dissolution of calcite in hydrochloric acid[J].Chemical Engineer Science,1975,30:825-835
19赵立强,陈冀眉,任书泉.酸岩反应动力学的试验研究[J〗.西南石油学院学报,1984(2):14-30Zhao Liqiang,Chen Jimei,Ren Shuquan.Experimental study on reaction kinetics of acid rocks[J].Journal of Southwest Petroleum Institute,1984(2):14-30
20 Hansford G S,Litt M.Mass transport from a rotating disk into power-law liquids[J].Chemical Engineering Science,1968,23:849-864
21 de Rozieres J.Measuring diffusion coefficients in acid fracturing fluids and their application to gelled and emulsified acids.SPE Annual Technical Conference and Exhibition.Society of Petroleum Engineers,1994,15(4):361-374
22 Lund K,Fogler H S,Mc Cune C C.Acidization-I.the dissolution of dolomite in hydrochloric acid[J].Chemical Engineer Science,1973,28:691-700
23 Taylor K C,Al-Ghamdi A M,Nasr-El-Din H A.Measurement of acid reaction rates of a deep dolomitic gas reservoir[J].Journal of Canadian Petroleum Technology,2003,43(10):49-56
24张继周,蒋晓敏,韩晓强,等.RDA100高温高压动态腐蚀测定仪在酸岩反应研究中的应用[J].新疆石油科技,2003,13(4):39-42Zhang Jizhou,Jiang Xiaomin,Han Xiaoqiang,et al.Application of RDA100 high temperature and high pressure dynamic corrosion analyzer in the study of acid rock reaction[J].Xinjiang Petroleum Science and Technology,2003,13(4):39-42
25张黎明,任书泉.酸岩反应动力学方式与酸溶蚀行为关系的理论判别[J].油田化学,1996(1):48-52Zhang Liming,Ren Shuquan.Theoretical discrimination of the relationship between acid-rock reaction kinetics and acid dissolution behavior[J].Oilfield Chemistry,1996(1):48-52
26祝琦.清洁转向酸H+表面传质行为实验研究[J].石油化工应用,2014,33(9):9-13Zhu Qi.Experimental study on mass transfer behavior of clean turning acid H+surface[J].Petrochemical Applications,2014,33(9):9-13
27 Mohammad T,Fariborz R.A qualitative simulation of a face dissolution pattern in acidizing process using rotating disk apparatus for a carbonate gas reservoir[J].Journal of Natural Gas Science and Engineering,2015,26:1460-1469
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