铈基氧化物在固体氧化物燃料电池中的应用
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摘要
综述了铈基氧化物在固体氧化物燃料电池(SOFCs)中应用的研究进展。基于SOFCs中的不同组件,铈基氧化物在SOFCs中的应用主要分为如下三个部分:铈基氧化物在电解质、阴极、阳极中的应用。通过不同元素的掺杂,铈基氧化物可以具有较高的离子电导率,作为电解质可以减少电池的欧姆电阻,同时也可以提高阴极的催化活性,以及改善阴极与电解质之间的界面性能,此外,还可以应用于阳极之中,能够改善阳极的抗积碳和抗硫中毒性能。为提高SOFCs中低温性能以及改善抗积碳、抗硫中毒性能提供了新的思路。
This paper reviewed recent advancement on applications of ceria-based oxides in solid oxide fuel cells( SOFCs). The applications were divided into three main categories based on different components of the SOFCs: electrolyte,cathode and anode. Higher ionic conductivity could be achieved for ceria-based oxides by doping with different elements and the ohmic resistances of SOFCs could be reduced,the catalytic activity and the cathode/electrolyte interface could be improved when the ceria-based material applied in cathode,in addition,ceria-based material could improve the ability of anti-carbon deposition and anti-sulfur poison used in anode. It provides a new avenue for increasing the performances at reduced or intermediate temperatures,and improving the ability of anti-carbon deposition and anti-sulfur poison for SOFCs.
This paper reviewed recent advancement on applications of ceria-based oxides in solid oxide fuel cells( SOFCs). The applications were divided into three main categories based on different components of the SOFCs: electrolyte,cathode and anode. Higher ionic conductivity could be achieved for ceria-based oxides by doping with different elements and the ohmic resistances of SOFCs could be reduced,the catalytic activity and the cathode/electrolyte interface could be improved when the ceria-based material applied in cathode,in addition,ceria-based material could improve the ability of anti-carbon deposition and anti-sulfur poison used in anode. It provides a new avenue for increasing the performances at reduced or intermediate temperatures,and improving the ability of anti-carbon deposition and anti-sulfur poison for SOFCs.
引文
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[5]Wachsman E D,Lee K T.Lowering the temperature of solid oxide fuel cells[J].Science,2011,334:935-939.
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[8]Campbell C T,Peden C H F.Oxygen vacancies and catalysis on ceria surfaces[J].Science,2005,309:713-714.
[9]Choi Y M,Abernathy H,Chen H,et al.Characterization of O2-Ce O2interactions using in situ raman spectroscopy and first-principle calculations[J].Chem Phys Chem,2006,7:1957-1963.
[10]Wang J,Liu M,Lin M.Oxygen reduction reactions in the SOFC cathode of Ag/Ce O2[J].Solid State Ionics,2006,177:939-947.
[11]周芬,翟纪敏,郜建全,等.Sm0.5-xGdxSr0.5Co O3-δ/30%Ce0.9Gd0.1O1.95复合阴极的制备及性能研究[J].稀土,2013,34(8):30-34.Zhou F,Zhai J M,Gao J Q,et al.Preparation and characterization of Sm0.5-xGdxSr0.5Co O3-δ/30%Ce0.9Gd0.1O1.95composite cathodes for intermediate temperature solid oxide fuel cells[J].Chinese Rare Earths,2013,34(8):30-34.
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[15]Steel B C H.Appraisal of Ce1-yGdyO2-y/2electrolytes for LT-SOFC operation at 500℃[J].Solid State Ionics,2000,129:95-110.
[16]Li B,Wei X,Pan W.Electrical properties of Mg-doped Gd0.1Ce0.9O1.95under different sintering conditions[J].Journal of Power Sources,2008,183(2):498-505.
[17]Li S,Ge L,Gu H,et al.Sinterability and electrical properties of Zn O-doped Ce0.8Y0.2O1.9electrolytes prepared by an EDTA citrate complexing method[J].Journal of Alloys and Compounds,2011,509:94-98.
[18]Zheng Y,Zhou M,Ge L,et al.Effect of Fe2O3on Smdoped ceria solid electrolyte for IT-SOFCs[J].Journal of Alloys and Compounds,2011,509:546-550.
[19]Hyund S,Dae W,Kyoo Y.Effect of Ti addition on the electric and ionic property of the oxide scale formed on the ferritic stainless steel for SOFC interconnect[J].International Journal of Hydrogen Energy,2012,37:16151-16160.
[20]Xu D,Liu X,Xu S,et al.Fabrication and performance of Ce0.85Sm0.15O1.925-Fe2O3electrolytes in IT-SOFCs[J].Solid State Ionics,2011,192:510-514.
[21]李柯慧,王世民,徐世峰,等.Ce0.8Gd0.2O1.9-Co3O4复合电解质的制备及性能研究[J].科技创新导报,2015,l30:128-132.Li K H,Wang S M,Xu S F,et al.Fabrication and performance of Ce0.8Gd0.2O1.9-Co3O4composite electrolytes[J].Science and Technology Innovation Herald,2015,l30:128-132.
[22]杨志宾,朱腾龙,项文龙,等.Li2O助烧的Gd0.1Ce0.9O1.95烧结过程及其电导性能研究[J].无机材料学报,2015,30(4):345-350.Yang Z B,Zhu T L,Xiang W L,et al.Sintering behavior and electrical conductivity of Gd0.1Ce0.9O1.95with Li2O additives[J].Journal of Inorganic Materials,2015,30(4):345-350.
[23]Lubke S,Wiemhofer H D.Electronic conductivity of Gddoped ceria with additional Pr-doping[J].Solid State Ionics,1999,117:229-243.
[24]Wu W,Wang X,Liu Z,et al.Influence of deposition temperature of GDC interlayer deposited by RF magnetron sputtering on anode-supported SOFC[J].Fuel Cells,2014,14:171-176.
[25]武卫明,刘中波,赵哲,等.通过溅射与退火制备的用于固体氧化物燃料电池的氧化钆掺杂氧化铈电解质隔层[J].催化学报,2014,35:1376-1384.Wu W M,Liu Z B,Zhao Z,et al.Gadolinia doped ceria barrier layer prepared by sputtering and annealing for anode-supported solid oxide fuel cell[J].Chinese Journal of Catalysis,2014,35:1376-1384.
[26]武卫明.溅射法制备GDC隔层的固体氧化物燃料电池研究[D].大连:中国科学院大连化学物理研究,2014.Wu W M.Study on GDC interlayer deposited by magnetron sputtering for solid oxide fuel cell[D].Dalian:Dalian Institute of Chemical Physics,2014.
[27]Fonseca F C,Uhlenbruck S,Nedelec R,et al.Properties of bias-assisted sputtered gadolinia-doped ceria interlayers for solid oxide fuel cells[J].Journal of Power Sources,2010,195:1599-1604.
[28]Liu W,Liu H,Pan W.Fabrication of Sm3+and Nd3+codoped Ce O2thin-film electrolytes by radio frequency magnetron sputtering[J].Electrochimica Acta,2011,56:8329-8333.
[29]Xia C,Rauch W,Chen F,Liu M.Sm0.5Sr0.5Co O3cathodes for low-temperature SOFCs[J].Solid State Ionics,2002,149:11-19.
[30]Bi Z,Cheng M,Dong Y,et al.Electrochemical evaluation of La0.6Sr0.4Co O3-La0.45Ce0.55O2composite cathodes for anode-supported La0.45Ce0.55O2–La0.9Sr0.1Ga0.8Mg0.2O2.85bilayer electrolyte solid oxide fuel cells[J].Solid State Ionics,2005,176:655-661.
[31]Liu L,Zhao Z,Zhang X,et al.A ternary cathode composed of LSM,YSZ and Ce0.9Mn0.1O2-δfor the intermediate temperature solid oxide fuel cells[J].Chemical Communications,2013,49:777-779.
[32]Liu L,Zhao Z,Zhang X,et al.Development of ternary cathodes using Ce1-x-yMnxMyO2-δ(M=La,Gd)as catalysts for oxygen reduction reactions[J].Fuel Cells,2014,14:364-371.
[33]刘丽.中低温固体氧化物燃料电池LSM-YSZ阴极催化改性研究[D].大连:中国科学院大连化学物理研究,2014.Liu L.Study of modified LSM-YSZ cathode for intermediate and reduced temperature solid oxide fuel cells[D].Dalian:Dalian Institute of Chemical Physics,2014.
[34]Zhang M,Yang M,Liu B,et al.La0.4Ce0.6O1.8-La0.8Sr0.2Mn O3-8 mol%yttria-stabilized zirconia composite cathode for anode-supported solid oxide fuel cells[J].Journal of Power Sources,2008,175:739-748.
[35]Zhang M,Yang M,Hou Z,et al.A bi-layered composite cathode of La0.8Sr0.2Mn O3-YSZ and La0.8Sr0.2Mn O3-La0.4Ce0.6O1.8for IT-SOFCs[J].Electrochimica Acta,2008,53:4998-5006.
[36]Koh J,Yoo Y,Park J,et al.Carbon deposition and cell performance of Ni-YSZ anode support SOFC with methane fuel[J].Solid State Ionics,2002,149:157-166.
[37]Takeguchi T,Kikuchi R,Yano T,et al.Effect of precious metal addition to Ni-YSZ cermet on reforming of CH4and electrochemical activity as SOFC anode[J].Catalysis Today,2003,84:217-222.
[38]Koide H,Someya Y,Yoshida T,et al.Properties of Ni/YSZ cermet as anode for SOFC[J].Solid State Ionics,2000,132:253-260.
[39]Lussier A,Sofie S,Dvorak J,et al.Mechanism for SOFC anode degradation from hydrogen sulphide exposure[J].International Journal of Hydrogen Energy,2008,33:3945-3951.
[40]Badwal S P S,Ciacchi F T,Drennan J.Investigation of the stability of ceria-gadolinia electrolytes in solid oxide fuel cell environments[J].Solid State Ionics,1999,121:253-262.
[41]Marina O A,Bagger C,Primdahl S,et al.A solid oxide fuel cell with a gadolinia-doped ceria anode:preparation and performance[J].Solid State Ionics,1999,123:199-208.
[42]Mogensen M,Sammes N M,Tompsett G A.Physical,chemical and electrochemical properties of pure and doped ceria[J].Solid State Ionics,2000,129:63-94.
[43]Han J,Kim H,Yoon S,et al.Shape effect of ceria in Cu/ceria catalysts for preferential CO oxidation[J].Journal of Molecular Catalysis A:Chemical,2011,335:82-88.
[44]Park S,Vohs J M,Gorte R J.Direct oxidation of hydrocarbons in a solid-oxide fuel cell[J].Nature,2000,404:265-267.
[45]Kim H,Park S,Vohs J M,et al.Direct oxidation of liquid fuels in a solid oxide fuel cell[J].Journal of Electrochemistry Society,2001,148:A693-A695.
[46]Murray E P,Tsai T,Barnett S A.A direct-methane fuel cell with a ceria-based anode[J].Nature,1999,400:649-651.
[47]Chueh W C,Hao Y,Jung W,et al.High electrochemical activity of the oxide phase in model ceria-Pt and ceria-Ni composite anodes[J].Nature Materials,2012,11:155-161.
[48]Marina O A,Bagger C,Primdahl S,et al.A solid oxide fuel cell with a gadolinia-doped ceria anode:preparation and performance[J].Solid State Ionics,1999,123:199-208.
[49]Zhan Z,Scott A.Barnett,An octane-cueled solid oxide fuel cell[J].Science,2005,308:844-847.
[50]Shao Z,Haile S M,Ahn J,et al.A thermally self-sustained micro solid-oxide fuel-cell stack with high power density[J].Nature,2005,435(9):495-498.
[51]Stephanopoulos M F,Sakbodin M,Wang Z.Regenerative adsorption and removal of H2S from hot fuel gas streams by rare earth oxides[J].Science,2006,312:1508-1510.
[2]衣宝廉.燃料电池-原理·技术·应用[M].北京:化学工业出版社,2003.5-515.Yi B L.Fuel Cells-Principle·Technology·Applications[M].Beijing:Chemical Industry Press,2003.5-515.
[3]韩建华,张瑞雪,吴冰,等.Ce O2基体掺杂材料及其在SOFC中的应用[J].电源技术,2014,38(11):2196-2204.Han J H,Zhang R X,Wu B,et al.Ce O2-based doping material and application in SOFC[J].Chinese Journal of Power Sources,2014,38(11):2196-2204)
[4]Nesaraj A S.Recent developments in solid oxide fuel cell technology-a review[J].Journal of Scientific&Industrial Research,2010,69(3):169-176.
[5]Wachsman E D,Lee K T.Lowering the temperature of solid oxide fuel cells[J].Science,2011,334:935-939.
[6]代安娜,许林峰,税安泽.固体氧化物燃料电池的研究与进展[J].硅酸盐通报,2015,34:234-238.Dai A N,Xu L F,Shui A Z.Research progress of solid oxide fuel cell[J].Bulletin of the Chinese Ceramic Society,2015,34:234-238.
[7]Yashima M.Invited Review:Some recent developments in the atomic-scale characterization of structural and transport properties of ceria-based catalysts and ionic conductors[J].Catalysis Today,2015,253:3-19.
[8]Campbell C T,Peden C H F.Oxygen vacancies and catalysis on ceria surfaces[J].Science,2005,309:713-714.
[9]Choi Y M,Abernathy H,Chen H,et al.Characterization of O2-Ce O2interactions using in situ raman spectroscopy and first-principle calculations[J].Chem Phys Chem,2006,7:1957-1963.
[10]Wang J,Liu M,Lin M.Oxygen reduction reactions in the SOFC cathode of Ag/Ce O2[J].Solid State Ionics,2006,177:939-947.
[11]周芬,翟纪敏,郜建全,等.Sm0.5-xGdxSr0.5Co O3-δ/30%Ce0.9Gd0.1O1.95复合阴极的制备及性能研究[J].稀土,2013,34(8):30-34.Zhou F,Zhai J M,Gao J Q,et al.Preparation and characterization of Sm0.5-xGdxSr0.5Co O3-δ/30%Ce0.9Gd0.1O1.95composite cathodes for intermediate temperature solid oxide fuel cells[J].Chinese Rare Earths,2013,34(8):30-34.
[12]田长安,王春阳,季必发,等.溶胶凝胶法制备Ce0.8Y0.2-xSrxO2-δ电解质材料及其性能研究[J].稀土,2016,37(2):9-14.Tian C A,Wang C Y,Ji B F,et al.Properties of Ce0.8Y0.2-xSrxO2-δelectrolyte prepared by sol-gel method[J].Chinese Rare Earths,2016,37(2):9-14.
[13]Panhans M A,Bluemental R N.A thermodynamic and electrical conductivity study of nonstoichiometric cerium dioxide[J].Solid State Ionics,1993,60:279-298.
[14]Yahiro H,Eguchi Y,Eguchi K,et al.Oxygen ion conductivity of the ceria-samarium oxide system with fluorite structure[J].Journal of Applied Electrochemistry,1988,18:527-531.
[15]Steel B C H.Appraisal of Ce1-yGdyO2-y/2electrolytes for LT-SOFC operation at 500℃[J].Solid State Ionics,2000,129:95-110.
[16]Li B,Wei X,Pan W.Electrical properties of Mg-doped Gd0.1Ce0.9O1.95under different sintering conditions[J].Journal of Power Sources,2008,183(2):498-505.
[17]Li S,Ge L,Gu H,et al.Sinterability and electrical properties of Zn O-doped Ce0.8Y0.2O1.9electrolytes prepared by an EDTA citrate complexing method[J].Journal of Alloys and Compounds,2011,509:94-98.
[18]Zheng Y,Zhou M,Ge L,et al.Effect of Fe2O3on Smdoped ceria solid electrolyte for IT-SOFCs[J].Journal of Alloys and Compounds,2011,509:546-550.
[19]Hyund S,Dae W,Kyoo Y.Effect of Ti addition on the electric and ionic property of the oxide scale formed on the ferritic stainless steel for SOFC interconnect[J].International Journal of Hydrogen Energy,2012,37:16151-16160.
[20]Xu D,Liu X,Xu S,et al.Fabrication and performance of Ce0.85Sm0.15O1.925-Fe2O3electrolytes in IT-SOFCs[J].Solid State Ionics,2011,192:510-514.
[21]李柯慧,王世民,徐世峰,等.Ce0.8Gd0.2O1.9-Co3O4复合电解质的制备及性能研究[J].科技创新导报,2015,l30:128-132.Li K H,Wang S M,Xu S F,et al.Fabrication and performance of Ce0.8Gd0.2O1.9-Co3O4composite electrolytes[J].Science and Technology Innovation Herald,2015,l30:128-132.
[22]杨志宾,朱腾龙,项文龙,等.Li2O助烧的Gd0.1Ce0.9O1.95烧结过程及其电导性能研究[J].无机材料学报,2015,30(4):345-350.Yang Z B,Zhu T L,Xiang W L,et al.Sintering behavior and electrical conductivity of Gd0.1Ce0.9O1.95with Li2O additives[J].Journal of Inorganic Materials,2015,30(4):345-350.
[23]Lubke S,Wiemhofer H D.Electronic conductivity of Gddoped ceria with additional Pr-doping[J].Solid State Ionics,1999,117:229-243.
[24]Wu W,Wang X,Liu Z,et al.Influence of deposition temperature of GDC interlayer deposited by RF magnetron sputtering on anode-supported SOFC[J].Fuel Cells,2014,14:171-176.
[25]武卫明,刘中波,赵哲,等.通过溅射与退火制备的用于固体氧化物燃料电池的氧化钆掺杂氧化铈电解质隔层[J].催化学报,2014,35:1376-1384.Wu W M,Liu Z B,Zhao Z,et al.Gadolinia doped ceria barrier layer prepared by sputtering and annealing for anode-supported solid oxide fuel cell[J].Chinese Journal of Catalysis,2014,35:1376-1384.
[26]武卫明.溅射法制备GDC隔层的固体氧化物燃料电池研究[D].大连:中国科学院大连化学物理研究,2014.Wu W M.Study on GDC interlayer deposited by magnetron sputtering for solid oxide fuel cell[D].Dalian:Dalian Institute of Chemical Physics,2014.
[27]Fonseca F C,Uhlenbruck S,Nedelec R,et al.Properties of bias-assisted sputtered gadolinia-doped ceria interlayers for solid oxide fuel cells[J].Journal of Power Sources,2010,195:1599-1604.
[28]Liu W,Liu H,Pan W.Fabrication of Sm3+and Nd3+codoped Ce O2thin-film electrolytes by radio frequency magnetron sputtering[J].Electrochimica Acta,2011,56:8329-8333.
[29]Xia C,Rauch W,Chen F,Liu M.Sm0.5Sr0.5Co O3cathodes for low-temperature SOFCs[J].Solid State Ionics,2002,149:11-19.
[30]Bi Z,Cheng M,Dong Y,et al.Electrochemical evaluation of La0.6Sr0.4Co O3-La0.45Ce0.55O2composite cathodes for anode-supported La0.45Ce0.55O2–La0.9Sr0.1Ga0.8Mg0.2O2.85bilayer electrolyte solid oxide fuel cells[J].Solid State Ionics,2005,176:655-661.
[31]Liu L,Zhao Z,Zhang X,et al.A ternary cathode composed of LSM,YSZ and Ce0.9Mn0.1O2-δfor the intermediate temperature solid oxide fuel cells[J].Chemical Communications,2013,49:777-779.
[32]Liu L,Zhao Z,Zhang X,et al.Development of ternary cathodes using Ce1-x-yMnxMyO2-δ(M=La,Gd)as catalysts for oxygen reduction reactions[J].Fuel Cells,2014,14:364-371.
[33]刘丽.中低温固体氧化物燃料电池LSM-YSZ阴极催化改性研究[D].大连:中国科学院大连化学物理研究,2014.Liu L.Study of modified LSM-YSZ cathode for intermediate and reduced temperature solid oxide fuel cells[D].Dalian:Dalian Institute of Chemical Physics,2014.
[34]Zhang M,Yang M,Liu B,et al.La0.4Ce0.6O1.8-La0.8Sr0.2Mn O3-8 mol%yttria-stabilized zirconia composite cathode for anode-supported solid oxide fuel cells[J].Journal of Power Sources,2008,175:739-748.
[35]Zhang M,Yang M,Hou Z,et al.A bi-layered composite cathode of La0.8Sr0.2Mn O3-YSZ and La0.8Sr0.2Mn O3-La0.4Ce0.6O1.8for IT-SOFCs[J].Electrochimica Acta,2008,53:4998-5006.
[36]Koh J,Yoo Y,Park J,et al.Carbon deposition and cell performance of Ni-YSZ anode support SOFC with methane fuel[J].Solid State Ionics,2002,149:157-166.
[37]Takeguchi T,Kikuchi R,Yano T,et al.Effect of precious metal addition to Ni-YSZ cermet on reforming of CH4and electrochemical activity as SOFC anode[J].Catalysis Today,2003,84:217-222.
[38]Koide H,Someya Y,Yoshida T,et al.Properties of Ni/YSZ cermet as anode for SOFC[J].Solid State Ionics,2000,132:253-260.
[39]Lussier A,Sofie S,Dvorak J,et al.Mechanism for SOFC anode degradation from hydrogen sulphide exposure[J].International Journal of Hydrogen Energy,2008,33:3945-3951.
[40]Badwal S P S,Ciacchi F T,Drennan J.Investigation of the stability of ceria-gadolinia electrolytes in solid oxide fuel cell environments[J].Solid State Ionics,1999,121:253-262.
[41]Marina O A,Bagger C,Primdahl S,et al.A solid oxide fuel cell with a gadolinia-doped ceria anode:preparation and performance[J].Solid State Ionics,1999,123:199-208.
[42]Mogensen M,Sammes N M,Tompsett G A.Physical,chemical and electrochemical properties of pure and doped ceria[J].Solid State Ionics,2000,129:63-94.
[43]Han J,Kim H,Yoon S,et al.Shape effect of ceria in Cu/ceria catalysts for preferential CO oxidation[J].Journal of Molecular Catalysis A:Chemical,2011,335:82-88.
[44]Park S,Vohs J M,Gorte R J.Direct oxidation of hydrocarbons in a solid-oxide fuel cell[J].Nature,2000,404:265-267.
[45]Kim H,Park S,Vohs J M,et al.Direct oxidation of liquid fuels in a solid oxide fuel cell[J].Journal of Electrochemistry Society,2001,148:A693-A695.
[46]Murray E P,Tsai T,Barnett S A.A direct-methane fuel cell with a ceria-based anode[J].Nature,1999,400:649-651.
[47]Chueh W C,Hao Y,Jung W,et al.High electrochemical activity of the oxide phase in model ceria-Pt and ceria-Ni composite anodes[J].Nature Materials,2012,11:155-161.
[48]Marina O A,Bagger C,Primdahl S,et al.A solid oxide fuel cell with a gadolinia-doped ceria anode:preparation and performance[J].Solid State Ionics,1999,123:199-208.
[49]Zhan Z,Scott A.Barnett,An octane-cueled solid oxide fuel cell[J].Science,2005,308:844-847.
[50]Shao Z,Haile S M,Ahn J,et al.A thermally self-sustained micro solid-oxide fuel-cell stack with high power density[J].Nature,2005,435(9):495-498.
[51]Stephanopoulos M F,Sakbodin M,Wang Z.Regenerative adsorption and removal of H2S from hot fuel gas streams by rare earth oxides[J].Science,2006,312:1508-1510.