摘要
特定形貌的金属以及合金类材料因具有独特的物理化学性质,在催化剂、光学、电学、电化学等方面有着广泛的应用价值。如何有效地制备特定形貌的金属类材料是研究者关注的热点,其中电沉积是较为便捷的方法。离子液体特殊的理化性质使其越来越广泛地用作电沉积的电解液。综述了离子液体电化学沉积的最新研究进展,从金属、合金、金属纳米材料三个方面进行归纳,总结了离子液体在制备不同类型及形貌材料时所起的作用,以及形貌调控的影响因素,并指出了离子液体电沉积存在的问题及未来的研究方向。
Metals and alloy materials with specific morphologies have a wide range of applications in petrochemical catalysts,optics,electricity and electrochemistry due to their unique physicochemical properties. How to effectively prepare metallic materials with specific morphology is a hot spot of attention and electrodeposition is a more convenient method for material preparation. The special physicochemical properties possessed by ionic liquids have led to their increasing use as electrolytes for electrodeposition. This paper reviews recent advances in the electrochemical deposition of ionic liquids,focuses on the three aspects of metals,alloys,and metal nanomaterials. Ionic liquids role in the preparation materials with different types and morphologies,and the modulation factors which effect on the morphology are summarized. Furthermore,the problems in the electrodeposition of ionic liquids and future research directions are presented.
引文
[1]胡德荣,张新位,赵景芝.离子液体简介[J].首都师范大学学报:自然科学版,2005,26(2):40-45.
[2]Wilkes J S,Zaworotko M J.Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids[J].J Chem Soc Chem Commun,1992,23(13):965-967.
[3]赵东滨,寇元.室温离子液体:合成、性质及应用[J].大学化学,2002,17(1):42-46.
[4]Galiński M,Lewandowski A,St?pniak I.Ionic liquids as electrolytes[J].Electrochim Acta,2006,51(26):5567-5580.
[5]Carmichael A J,Earle M J,Holbrey J D,et al.The Heck reaction in ionic liquids:A multiphasic catalyst system[J].Org Lett,2005,1(7):997-1000.
[6]王均凤,张锁江,陈慧萍,等.离子液体的性质及其在催化反应中的应用[J].过程工程学报,2003,3(2):177-185.
[7]朱海燕,曹祖宾,牟晓刚.室温离子液体的应用[J].化工生产与技术,2006,13(5):40-42.
[8]Lee C W.Diels-Alder reactions in chloroaluminate ionic liquids:Acceleration and selectivity enhancement[J].Tetrahedron Lett,1999,40(13):2461-2464.
[9]姜妲,尹振,翟玉春.离子液体及其研究进展[J].材料导报,2006,20(5):89-91.
[10]Wasserscheid P,Keim W.Ionic liquids-New“solutions”for transition metal catalysis[J].Angew Chem,Int Ed,2000,39(21):3772-3789.
[11]周雅文,邓宇,尚海萍,等.离子液体的性质及其应用[J].杭州化工,2009,39(3):7-10.
[12]刘艳升,严骏,徐春明,等.离子液体在电沉积金属和半导体材料中的应用[J].化学通报:网络版,2004,67(12):w105.
[13]Endres F,Bukowski M,Hempelmann R,et al.Electrodeposition of nanocrystalline metals and alloys from ionic liquids[J].Angew Chem,Int Ed,2003,42(29):3428-3430.
[14]李庆阳,安茂忠,刘安敏,等.离子液体中合金的电化学沉积研究进展[J].电镀与精饰,2013,35(8):26-32.
[15]Endres F,Abbott A P,MacFarlane D R.Electrodeposition from Ionic Liquids[M].Weinheim:Wiley-VCH,2008:182.
[16]Zhang Qinqin,Wang Qian,Zhang Suojiang,et al.Electrodeposition in ionic liquids[J].ChemPhysChem,2016,17(3):335-351.
[17]Zein A S,Endres F.Electrodeposition of metals and semiconductors in air-and water-stable ionic liquids[J].ChemPhysChem,2006,7(1):58-61.
[18]Hurley F H,Wier T P.Electrodeposition of metals from fused quaternary ammonium salts[J].J Electrochem Soc,1951,98(5):203-206.
[19]Bakkar A,Neubert V.A new method for practical electrodeposition of aluminium from ionic liquids[J].Electrochem Commun,2015,51:113-116.
[20]Pulletikurthi G,Decker B,Borodin A,et al.Electrodeposition of Al from a 1-butylpyrrolidine-AlCl3 ionic liquid[J].Prog Nat Sci Mater Int,2015,25(6):603-611.
[21]郑勇,郑永军,武卫明,等.乙酰胺型离子液体在铝电沉积中的应用研究[J].有色金属:冶炼部分,2017(9):15-18.
[22]钱建刚,李鑫,栾海静,等.1-丁基-3-甲基咪唑四氟硼酸盐离子液体电沉积制备Ir研究[J].稀有金属材料与工程,2017,46(7):1756-1761.
[23]He Wencai,Liu Aimin,Guan Jinzhao,et al.Pb electrodeposition from PbO in the urea/1-ethyl-3-methylimidazolium chloride at room temperature[J].Rsc Adv,2017,7(12):6902-6910.
[24]Carlos I A,Malaquias M A,Oizumi M M,et al.Study of the influence of glycerol on the cathodic process of lead electrodeposition and on its morphology[J].J Power Sources,2001,92(1/2):56-64.
[25]Wong S M,Abrantes L M.Lead electrodeposition from very alkaline media[J].Electrochim Acta,2006,51(4):619-626.
[26]Carlos I A,Siqueira J L P,Finazzi G A,et al.Voltammetric study of lead electrodeposition in the presence of sorbitol and morphological characterization[J].J Power Sources,2003,117(1/2):179-186.
[27]Gu Yingying,Zhou Qionghua,Yang Tianzu,et al.Lead electrodeposition from alkaline solutions containing xylitol[J].中国有色金属学报:英文版,2011,21(6):1407-1413.
[28]Neboj?a D N,Goran B,Uro??L.Formation of twodimensional(2D)lead dendrites by application of different regimes of electrolysis[J].J Solid State Electrochem,2012,16(6):2121-2126.
[29]Neboj?a D N,Konstantin I P,Predrag M?,et al.A new insight into the mechanism of lead electrodeposition:Ohmicdiffusion control of the electrodeposition process[J].J Electroanal Chem,2013,691(5):66-76.
[30]Mostany J,Parra J,Scharifker B R.The nucleation of lead from halide-containing solutions[J].J Appl Electrochem,1986,16(3):333-338.
[31]Neboj?a D N,Djendji D V,Predrag M?,et al.Influence of the complex formation on the morphology of lead powder particles produced by the electrodeposition processes[J].Adv Powder Technol,2013,24(3):674-682.
[32]Wong S M,Abrantes L M.Lead electrodeposition from very alkaline media[J].Electrochim Acta,2006,51(4):619-626.
[33]Chen Zhongyao,Liu Meng,Zhang Peng,et al.Tuning the architectures of lead deposits on metal substrates by electrodeposition[J].Electrochim Acta,2008,54(2):247-253.
[34]Ispas A,Adolphi B,Bund A,et al.On the electrodeposition of tantalum from three different ionic liquids with the bis(trifluoromethyl sulfonyl)amide anion[J].Phys Chem Chem Phys,2010,12(8):1793-1803.
[35]Atkin R,Abedin S Z E,Hayes R,et al.AFM and STMstudies on the surface interaction of[BMP]TFSA and[EMIm]TFSA ionic liquids with Au(111)[J].J Phys Chem C,2009,113(30):13266-13272.
[36]Giridhar P,Abedin S Z E,Bund A,et al.Electrodeposition of niobium from 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide ionic liquid[J].Electrochim Acta,2014,129(6):312-317.
[37]Endres F,Bukowski M,Hempelmann R,et al.Electrodeposition of nanocrystalline metals and alloys from ionic liquids[J].Angew Chem,Int Ed,2003,42(29):3428-3430.
[38]Barchi L,Bardi U,Caporali S,et al.Electroplated bright aluminium coatings for anticorrosion and decorative purposes[J].Prog Org Coat,2010,67(2):146-151.
[39]Liu Lian,Lu Xingmei,Cai Yingjun,et al.Influence of additives on the speciation,morphology,and nanocrystallinity of aluminium electrodeposition[J].Aust J Chem,2012,65(11):1523-1528.
[40]Abbott A P,Qiu F,Abood H M,et al.Double layer,diluent and anode effects upon the electrodeposition of aluminium from chloroaluminate based ionic liquids[J].Phys Chem Chem Phys,2010,12(8):1862-1872.
[41]Wang Qian,Zhang Qinqin,Chen Bin,et al.Electrodeposition of bright Al coatings from 1-butyl-3-methylimidazolium chloroaluminate ionic liquids with specific additives[J].JElectrochem Soc,2015,162(8):320-324.
[42]饶帅.离子液体中电沉积Al-Mn系合金的研究[D].昆明:昆明理工大学,2013.
[43]Catrangiu A S,Beregoi M,Cojocaru A,et al.Electrochemical deposition of zinc telluride thin films from ethaline ionic liquid[J].Chalcogenide Lett,2016,13(5):187-199.
[44]王宏智,张晓振,黄波,等.碳毡基体上电沉积Ni-Mo合金及其催化析氢性能[J].化学工业与工程,2017,34(1):53-59.
[45]章志铖,郭嘉成,徐文彬,等.室温离子液体中电沉积高耐蚀性Ni-Mn薄膜[J].表面技术,2017,46(3):66-71.
[46]肖娜,高德峰,张国锋.离子液体中电沉积钴-银软磁薄膜[J].电镀与环保,2017,37(4):29-31.
[47]张创.离子液体电沉积镍-铬合金工艺的研究[J].广州化工,2017,45(2):77-79.
[48]Fashu S,Khan R.Studies on electrochemical deposition of novel Zn-Mn-Ni ternary alloys from an ionic liquid based on choline chloride[J].Prot Met Phys Chem Surf,2017,53(1):118-126.
[49]Fashu S,Khan R,Zulfiqar S.Ternary Zn-Mn-Sn alloy electrodeposition from an ionic liquid based on choline chloride[J].Trans Inst Met Finish,2017,95(4):217-225.
[50]Tsuda T,Hussey C L,Stafford G R.Electrodeposition of AlMo-Mn ternary alloys from the Lewis acidic AlCl3-EtMeImCl molten salt[J].J Electrochem Soc,2005,152(152):620-625.
[51]Tsuda T,Ikeda Y,Imanishi A,et al.Electrodeposition of Al-W-Mn ternary alloys from the Lewis acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride ionic liquid[J].JElectrochem Soc,2015,162(9):405-411.
[52]Chaudret B.Synthesis and Surface Reactivity of Organometallic Nanoparticles[M]//Surface and Interfacial Organometallic Chemistry and Catalysis.Berlin:Springer,2005:233-259.
[53]Chaudret B,Philippot K.Organometallic nanoparticles of metals or metal oxides[J].Oil Gas Sci Technol-Revue de l'IFP,2007,62(6):799-817.
[54]Prechtl M H,Scholten J D,Dupont J.Carbon-carbon cross coupling reactions in ionic liquids catalysed by palladium metal nanoparticles[J].Molecules,2010,15(5):3441-3461.
[55]Sultana S,Tachikawa N,Yoshii K,et al.Electrochemical preparation of platinum nanoparticles from bis(acetylacetonato)platinum(Ⅱ)in some aprotic amide-type ionic liquids[J].Electrochim Acta,2017,249:263-270.
[56]Essig S,Behrens S.Ionic liquids as size-and shape-regulating solvents for the synthesis of cobalt nanoparticles[J].Chem Ingenieur Technik,2016,87(12):1741-1747.
[57]Darwich W,Gedig C,Srour H,et al.Single step synthesis of metallic nanoparticles using dihydroxyl functionalized ionic liquids as reductive agent[J].Rsc Adv,2013,3(43):20324-20331.
[58]Thiebaud L,Legeai S,Ghanbaja J,et al.Synthesis of TeBi core-shell nanowires by two-step electrodeposition in ionic liquids[J].Electrochem Commun,2018,86:30-33.
[59]Szymczak J,Legeai S,Diliberto S,et al.Template-free electrodeposition of tellurium nanostructures in a room-temperature ionic liquid[J].Electrochem Commun,2012,24(1):57-60.
[60]Zoubi M A,Endres F.Electrochemical synthesis of poly(pphenylene)and poly(p-phenylene)/TiO2 nanowires in an ionic liquid[J].Electrochim Acta,2011,56(17):5872-5876.
[61]Mazierski P,?uczak J,Lisowski W,et al.The ILs-assisted electrochemical synthesis of TiO2,nanotubes:The effect of ionic liquids on morphology and photoactivity[J].Appl Catal,B,2017,214:100-113.
[62]Su Chung-Jui,Hsieh Y T,Chen Chi-Chang,et al.Electrodeposition of aluminum wires from the Lewis acidic AlCl3/trimethylamine hydrochloride ionic liquid without using a template[J].Electrochem Commun,2013,34(5):170-173.