导电织物的制备及应用研究进展
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摘要
导电织物是各种可穿戴电子设备的基础材料,除需具备良好的导电性能外,还要求具有良好的柔韧性、对弯曲伸展等大幅度变形持久稳定以及透气吸水等符合服装穿着需要的特点。近年来,导电织物的相关研究层出不穷,综合性能已经接近实用要求。文章首先对近五年的导电织物相关研究进行总结,根据导电填料种类,将导电织物归纳为聚合物基导电织物、金属基导电织物和碳基导电织物三类,并依此展开论述,指出导电织物研究中亟待解决的问题,主要包括提高导电织物的导电性、耐久性以及不破坏织物原有的特性等,最后对导电织物的应用进行了介绍,并对其前景进行展望。
The conductive fabrics are the basic material for the wearable devices.In addition to excellent conductivity,it's still necessary to possess the merits of flexibility,and stability for large amplitude deformation such as bending,breathability and water absorbability which meet the needs of clothing wearing.In recent years,the related researches on conductive fabrics have been developing quickly,and its comprehensive performance has been close to practical application requirements.In this article,the researches on conductive fabrics in recent 5 years were summarized.According to different types of conductive fillers,conductive fabrics can be classified into polymer-based conductive fabric,metalbased conductive fabric and carbon-based conductive fabric.These three types of conductive fabrics were mainly introduced and the problems in the research were pointed out such as improving conductivity and durability of conductive fabrics,and maintaining fabric properties.Finally,the application of conductive fabrics was introduced,and the application prospects of conductive fabrics were anticipated.
The conductive fabrics are the basic material for the wearable devices.In addition to excellent conductivity,it's still necessary to possess the merits of flexibility,and stability for large amplitude deformation such as bending,breathability and water absorbability which meet the needs of clothing wearing.In recent years,the related researches on conductive fabrics have been developing quickly,and its comprehensive performance has been close to practical application requirements.In this article,the researches on conductive fabrics in recent 5 years were summarized.According to different types of conductive fillers,conductive fabrics can be classified into polymer-based conductive fabric,metalbased conductive fabric and carbon-based conductive fabric.These three types of conductive fabrics were mainly introduced and the problems in the research were pointed out such as improving conductivity and durability of conductive fabrics,and maintaining fabric properties.Finally,the application of conductive fabrics was introduced,and the application prospects of conductive fabrics were anticipated.
引文
[1]Chen S,Liu S,Wang P,et al.Highly stretchable fibershaped e-textiles for strain/pressure sensing,full-range human motions detection,health monitoring,and 2Dforce mapping[J].Journal of Materials Science,2018,53(4):2995-3005.
[2]Maity S,Chatterjee A.Conductive polymer-based electro-conductive textile composites for electromagnetic interference shielding:A review[J].Journal of Industrial Textiles,2018,47(8):2228-2252.
[3]Ko J,Jee S,Lee J H,et al.High durability conductive textile using MWCNT for motion sensing[J].Sensors and Actuators a-Physical,2018,274(5):50-56.
[4]Zhang N,Chen J,Huang Y,et al.A wearable all-solid photovoltaic textile[J].Advanced Materials,2016,28(2):263-269.
[5]Kim M,Kim H,Park J,et al.Real-time sitting posture correction system based on highly durable and washable electronic textile pressure sensors[J].Sensors and Actuators A:Physical,2018,269(1):394-400.
[6]Wu H,Huang Y,Xu F,et al.Energy harvesters for wearable and stretchable electronics:From flexibility to stretchability[J].Advanced Materrials,2016,28(45):9881-9919.
[7]Zeng W,Shu L,Li Q,et al.Fiber-based wearable electronics:A review of materials,fabrication,devices,and applications[J].Advanced Materials,2014,26(31):5310-5336.
[8]Gong S,Cheng W.Toward soft skin-like wearable and implantable energy devices[J].Advanced Energy Materials,2017,7(23):1700648-1700680.
[9]Lee Y H,Kim J S,Noh J,et al.Wearable textile battery rechargeable by solar energy[J].Nano Letters,2013,13(11):5753-5761.
[10]白林翠,沈勇,张惠芳,等.本征型导电高聚物织物的研究与应用[J].上海纺织科技,2011,39(8):1-5.
[11]Ghahremani Honarvar M,Latifi M.Overview of wearable electronics and smart textiles[J].The Journal of The Textile Institute,2016,108(4):631-652.
[12]Hansora D P,Shimpi N G,Mishra S.Performance of hybrid nanostructured conductive cotton materials as wearable devices:An overview of materials,fabrication,properties and applications[J].RSCAdvances,2015,5(130):107716-107770.
[13]Oliveira C R S D,Batistella M A,Souza A A U D,et al.Development of flexible sensors using knit fabrics with conductive polyaniline coating and graphite electrodes[J].Journal of Applied Polymer Science,2017,134(18):44785-44794.
[14]赵晓明,孙嘉瑞.导电聚苯胺的研究进展及其在纺织领域的应用[J].纺织科学与工程学报,2018,35(1):153-158.
[15]刘元军,武翔,钱学浩.氧化剂种类和浓度对聚苯胺/锦纶复合材料吸波性能的影响[J].纺织科学与工程学报,2018,35(1):56-60.
[16]Alamer F A.Structural and electrical properties of conductive cotton fabrics coated with the composite polyaniline/carbon black[J].Cellulose,2018,25(3):2075-2082.
[17]Tissera N D,Wijesena R N,Rathnayake S,et al.Heterogeneous in situ polymerization of polyaniline(PANI)nanofibers on cotton textiles:Improved electrical conductivity,electrical switching,and tuning properties[J].Carbohydrate Polymers,2018,186(4):35-44.
[18]Grancaric'A M,Jerkovic'I,Koncar V,et al.Conductive polymers for smart textile applications[J].Journal of Industrial Textiles,2018,48(3):612-642.
[19]Yang Q Q,Gao L F,Zhu Z Y,et al.Confinement effect of natural hollow fibers enhances flexible supercapacitor electrode performance[J].Electrochimica Acta,2018,260(1):204-211.
[20]武翔,刘元军,赵晓明,等.聚吡咯涂层尼龙导电织物的性能研究[J].成都纺织高等专科学校学报,2017,34(4):18-21.
[21]董猛,田俊莹.聚吡咯/银导电涤纶织物的开发[J].印染,2015,22(1):1-4.
[22]Hao D,Xu B,Cai Z.Polypyrrole coated knitted fabric for robust wearable sensor and heater[J].Journal of Materials Science:Materials in Electronics,2018,29(11):9218-9226.
[23]Kumar N,Ginting R T,Kang J-W.Flexible,largearea,all-solid-state supercapacitors using spray deposited PEDOT:PSS/reduced-graphene oxide[J].Electrochimica Acta,2018,270(2):37-47.
[24]Tadesse M G,Dumitrescu D,Loghin C,et al.3Dprinting of NinjaFlex filament onto PEDOT:PSS-coated textile fabrics for electroluminescence applications[J].Journal of Electronic Materials,2018,47(3):2082-2092.
[25]管应凯,王魁,马吉宏,等.PEDOT/尼龙复合织物的化学氧化聚合法制备[J].印染,2015,19(3):10-14.
[26]李昕,许英涛,郑一平,等.原位聚合制备PEDOT/PSS/PVA电磁波吸收功能复合导电织物[J].高分子学报,2017,5(4):661-668.
[27]Choi C M,Kwon S N,Na S I.Conductive PEDOT:PSS-coated poly-paraphenylene terephthalamide thread for highly durable electronic textiles[J].Journal of Industrial and Engineering Chemistry,2017,50(3):155-161.
[28]Ali A,Baheti V,Militky J,et al.Comparative performance of copper and silver coated stretchable fabrics[J].Fibers and Polymers,2018,19(3):607-619.
[29]Wu Y Y,Mechael S S,Chen Y T,et al.Solution deposition of conformal gold coatings on knitted fabric for E-textiles and electroluminescent clothing[J].Advanced Materials Technologies,2018,3(3):1700292-1700301.
[30]韦肖,柳岩,陈嘉毅.镀银导电织物的防辐射性能研究[J].上海纺织科技,2016,44(9):30-31.
[31]Huang Y,Ip W S,Lau Y Y,et al.Weavable,conductive yarn-based NiCo/Zn textile battery with high energy density and rate capability[J].ACS Nano,2017,11(9):8953-8961.
[32]Qin H,Li J,He B,et al.Novel wearable electrodes based on conductive chitosan fabrics and their application in smart garments[J].Materials(Basel),2018,11(3):370-379.
[33]周洲,许夏昕,杨树.碳纳米管/涤纶复合织物的电学性能研究[J].纺织科技进展,2016,15(10):1-4.
[34]Yang M,Fu C,Xia Z,et al.Conductive and durable CNT-cotton ring spun yarns[J].Cellulose,2018,25(7):4239-4249.
[35]Du D,Tang Z,Ouyang J.Highly washable e-textile prepared by ultrasonic nanosoldering of carbon nanotubes onto polymer fibers[J].Journal of Materials Chemistry C,2018,6(4):883-889.
[36]迟淑丽,田明伟,曲丽君.石墨烯纤维素复合纤维制备及导电导热性能研究[J].成都纺织高等专科学校学报,2017,34(2):22-25.
[37]Karim N,Afroj S,Tan S,et al.Scalable production of graphene-based wearable E-textiles[J].ACS Nano,2017,11(12):12266-12275.
[38]Cataldi P,Ceseracciu L,Athanassiou A,et al.Healable cotton-graphene nanocomposite conductor for wearable electronics[J].ACS Applied Materials Interfaces,2017,9(16):13825-13830.
[39]Vinisha Rani K,Sarma B,Sarma A.Plasma treatment on cotton fabrics to enhance the adhesion of reduced graphene oxide for electro-conductive properties[J].Diamond and Related Materials,2018,84(4):77-85.
[40]Mottaghitalab V,Haghi A K,Haghdoost F.Comfortable textile-based electrode for wearable electrocardiogram[J].Sensor Review,2015,35(1):20-29.
[41]Zhang M,Wang C,Liang X,et al.Weft-knitted fabric for a highly stretchable and low-voltage wearable heater[J].Advanced Electronic Materials,2017,3(9):1700193-1700199.
[42]Li Y,Zhang Z,Li X,et al.A smart,stretchable resistive heater textile[J].Journal of Materials Chemistry C,2017,5(1):41-46.
[43]Tian M,Du M,Qu L,et al.Electromagnetic interference shielding cotton fabrics with high electrical conductivity and electrical heating behavior via layer-by-layer selfassembly route[J].RSC Advances,2017,7(68):42641-42652.
[44]Wang C,Xiang C,Tan L,et al.Preparation of silver/reduced graphene oxide coated polyester fabric for electromagnetic interference shielding[J].RSCAdvances,2017,7(64):40452-40461.
[45]Seyedin S,Razal J M,Innis P C,et al.Knitted strain sensor textiles of highly conductive all-polymeric fibers[J].ACS Applied Materials&Interfaces,2015,7(38):21150-21158.
[46]常龙威,周炳海.聚苯胺电致变色织物的研究与开发[J].机械制造,2015,53(6):22-25.
[47]Weng W,Chen P,He S,et al.Smart electronic textiles[J].Angewandte Chemie,2016,55(21):6140-6169.
[2]Maity S,Chatterjee A.Conductive polymer-based electro-conductive textile composites for electromagnetic interference shielding:A review[J].Journal of Industrial Textiles,2018,47(8):2228-2252.
[3]Ko J,Jee S,Lee J H,et al.High durability conductive textile using MWCNT for motion sensing[J].Sensors and Actuators a-Physical,2018,274(5):50-56.
[4]Zhang N,Chen J,Huang Y,et al.A wearable all-solid photovoltaic textile[J].Advanced Materials,2016,28(2):263-269.
[5]Kim M,Kim H,Park J,et al.Real-time sitting posture correction system based on highly durable and washable electronic textile pressure sensors[J].Sensors and Actuators A:Physical,2018,269(1):394-400.
[6]Wu H,Huang Y,Xu F,et al.Energy harvesters for wearable and stretchable electronics:From flexibility to stretchability[J].Advanced Materrials,2016,28(45):9881-9919.
[7]Zeng W,Shu L,Li Q,et al.Fiber-based wearable electronics:A review of materials,fabrication,devices,and applications[J].Advanced Materials,2014,26(31):5310-5336.
[8]Gong S,Cheng W.Toward soft skin-like wearable and implantable energy devices[J].Advanced Energy Materials,2017,7(23):1700648-1700680.
[9]Lee Y H,Kim J S,Noh J,et al.Wearable textile battery rechargeable by solar energy[J].Nano Letters,2013,13(11):5753-5761.
[10]白林翠,沈勇,张惠芳,等.本征型导电高聚物织物的研究与应用[J].上海纺织科技,2011,39(8):1-5.
[11]Ghahremani Honarvar M,Latifi M.Overview of wearable electronics and smart textiles[J].The Journal of The Textile Institute,2016,108(4):631-652.
[12]Hansora D P,Shimpi N G,Mishra S.Performance of hybrid nanostructured conductive cotton materials as wearable devices:An overview of materials,fabrication,properties and applications[J].RSCAdvances,2015,5(130):107716-107770.
[13]Oliveira C R S D,Batistella M A,Souza A A U D,et al.Development of flexible sensors using knit fabrics with conductive polyaniline coating and graphite electrodes[J].Journal of Applied Polymer Science,2017,134(18):44785-44794.
[14]赵晓明,孙嘉瑞.导电聚苯胺的研究进展及其在纺织领域的应用[J].纺织科学与工程学报,2018,35(1):153-158.
[15]刘元军,武翔,钱学浩.氧化剂种类和浓度对聚苯胺/锦纶复合材料吸波性能的影响[J].纺织科学与工程学报,2018,35(1):56-60.
[16]Alamer F A.Structural and electrical properties of conductive cotton fabrics coated with the composite polyaniline/carbon black[J].Cellulose,2018,25(3):2075-2082.
[17]Tissera N D,Wijesena R N,Rathnayake S,et al.Heterogeneous in situ polymerization of polyaniline(PANI)nanofibers on cotton textiles:Improved electrical conductivity,electrical switching,and tuning properties[J].Carbohydrate Polymers,2018,186(4):35-44.
[18]Grancaric'A M,Jerkovic'I,Koncar V,et al.Conductive polymers for smart textile applications[J].Journal of Industrial Textiles,2018,48(3):612-642.
[19]Yang Q Q,Gao L F,Zhu Z Y,et al.Confinement effect of natural hollow fibers enhances flexible supercapacitor electrode performance[J].Electrochimica Acta,2018,260(1):204-211.
[20]武翔,刘元军,赵晓明,等.聚吡咯涂层尼龙导电织物的性能研究[J].成都纺织高等专科学校学报,2017,34(4):18-21.
[21]董猛,田俊莹.聚吡咯/银导电涤纶织物的开发[J].印染,2015,22(1):1-4.
[22]Hao D,Xu B,Cai Z.Polypyrrole coated knitted fabric for robust wearable sensor and heater[J].Journal of Materials Science:Materials in Electronics,2018,29(11):9218-9226.
[23]Kumar N,Ginting R T,Kang J-W.Flexible,largearea,all-solid-state supercapacitors using spray deposited PEDOT:PSS/reduced-graphene oxide[J].Electrochimica Acta,2018,270(2):37-47.
[24]Tadesse M G,Dumitrescu D,Loghin C,et al.3Dprinting of NinjaFlex filament onto PEDOT:PSS-coated textile fabrics for electroluminescence applications[J].Journal of Electronic Materials,2018,47(3):2082-2092.
[25]管应凯,王魁,马吉宏,等.PEDOT/尼龙复合织物的化学氧化聚合法制备[J].印染,2015,19(3):10-14.
[26]李昕,许英涛,郑一平,等.原位聚合制备PEDOT/PSS/PVA电磁波吸收功能复合导电织物[J].高分子学报,2017,5(4):661-668.
[27]Choi C M,Kwon S N,Na S I.Conductive PEDOT:PSS-coated poly-paraphenylene terephthalamide thread for highly durable electronic textiles[J].Journal of Industrial and Engineering Chemistry,2017,50(3):155-161.
[28]Ali A,Baheti V,Militky J,et al.Comparative performance of copper and silver coated stretchable fabrics[J].Fibers and Polymers,2018,19(3):607-619.
[29]Wu Y Y,Mechael S S,Chen Y T,et al.Solution deposition of conformal gold coatings on knitted fabric for E-textiles and electroluminescent clothing[J].Advanced Materials Technologies,2018,3(3):1700292-1700301.
[30]韦肖,柳岩,陈嘉毅.镀银导电织物的防辐射性能研究[J].上海纺织科技,2016,44(9):30-31.
[31]Huang Y,Ip W S,Lau Y Y,et al.Weavable,conductive yarn-based NiCo/Zn textile battery with high energy density and rate capability[J].ACS Nano,2017,11(9):8953-8961.
[32]Qin H,Li J,He B,et al.Novel wearable electrodes based on conductive chitosan fabrics and their application in smart garments[J].Materials(Basel),2018,11(3):370-379.
[33]周洲,许夏昕,杨树.碳纳米管/涤纶复合织物的电学性能研究[J].纺织科技进展,2016,15(10):1-4.
[34]Yang M,Fu C,Xia Z,et al.Conductive and durable CNT-cotton ring spun yarns[J].Cellulose,2018,25(7):4239-4249.
[35]Du D,Tang Z,Ouyang J.Highly washable e-textile prepared by ultrasonic nanosoldering of carbon nanotubes onto polymer fibers[J].Journal of Materials Chemistry C,2018,6(4):883-889.
[36]迟淑丽,田明伟,曲丽君.石墨烯纤维素复合纤维制备及导电导热性能研究[J].成都纺织高等专科学校学报,2017,34(2):22-25.
[37]Karim N,Afroj S,Tan S,et al.Scalable production of graphene-based wearable E-textiles[J].ACS Nano,2017,11(12):12266-12275.
[38]Cataldi P,Ceseracciu L,Athanassiou A,et al.Healable cotton-graphene nanocomposite conductor for wearable electronics[J].ACS Applied Materials Interfaces,2017,9(16):13825-13830.
[39]Vinisha Rani K,Sarma B,Sarma A.Plasma treatment on cotton fabrics to enhance the adhesion of reduced graphene oxide for electro-conductive properties[J].Diamond and Related Materials,2018,84(4):77-85.
[40]Mottaghitalab V,Haghi A K,Haghdoost F.Comfortable textile-based electrode for wearable electrocardiogram[J].Sensor Review,2015,35(1):20-29.
[41]Zhang M,Wang C,Liang X,et al.Weft-knitted fabric for a highly stretchable and low-voltage wearable heater[J].Advanced Electronic Materials,2017,3(9):1700193-1700199.
[42]Li Y,Zhang Z,Li X,et al.A smart,stretchable resistive heater textile[J].Journal of Materials Chemistry C,2017,5(1):41-46.
[43]Tian M,Du M,Qu L,et al.Electromagnetic interference shielding cotton fabrics with high electrical conductivity and electrical heating behavior via layer-by-layer selfassembly route[J].RSC Advances,2017,7(68):42641-42652.
[44]Wang C,Xiang C,Tan L,et al.Preparation of silver/reduced graphene oxide coated polyester fabric for electromagnetic interference shielding[J].RSCAdvances,2017,7(64):40452-40461.
[45]Seyedin S,Razal J M,Innis P C,et al.Knitted strain sensor textiles of highly conductive all-polymeric fibers[J].ACS Applied Materials&Interfaces,2015,7(38):21150-21158.
[46]常龙威,周炳海.聚苯胺电致变色织物的研究与开发[J].机械制造,2015,53(6):22-25.
[47]Weng W,Chen P,He S,et al.Smart electronic textiles[J].Angewandte Chemie,2016,55(21):6140-6169.