木素制备石墨烯复合材料的应用进展
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摘要
木素来源广泛、储量丰富、碳含量高,可以作为制备石墨烯的碳源。木素含有诸多活性官能团,这些官能团在制备石墨烯复合材料过程中发挥重要作用。本文简要介绍了木素与石墨烯的性质,以及石墨烯复合材料的制备方法;主要阐述了木素作为碳源或基体制备石墨烯复合材料的研究进展,包括木素-石墨烯功能化复合材料、石墨烯储能材料、石墨烯量子点等;并展望了木素在石墨烯复合材料中的应用前景。
Lignin hasrich sources in the nature,and contains a large amount of carbon content,which can be used as a carbon source for the preparation of graphene. Lignin also contains many functional groups which can play an important role in the preparation of graphene composite materials. This article briefly described the properties of lignin and graphene,the preparation methods of graphene composite. The research progress of preparation of graphene composites using lignin as carbon source or matrix was mainly discussed,including lignin-graphene functional composite,graphene energy storage materials,graphene quantum dots,etc. The expectation for the applications of lignin in graphene composite materials was presented as well.
Lignin hasrich sources in the nature,and contains a large amount of carbon content,which can be used as a carbon source for the preparation of graphene. Lignin also contains many functional groups which can play an important role in the preparation of graphene composite materials. This article briefly described the properties of lignin and graphene,the preparation methods of graphene composite. The research progress of preparation of graphene composites using lignin as carbon source or matrix was mainly discussed,including lignin-graphene functional composite,graphene energy storage materials,graphene quantum dots,etc. The expectation for the applications of lignin in graphene composite materials was presented as well.
引文
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[13]Liu Jian.Moving toward the application and industrialization of graohene:Processes of graphite formation and graphitic crystal chemistry[D].Beijing:China University of Geosciences(Beijing),2017.刘剑.天然石墨的成因、晶体化学特征及对石墨烯产业化的约束[D].北京:中国地质大学(北京),2017.
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[19]Mishra P C,Yadav A.Enhanced Electron Density Edge Effect in Polycyclic Aromatic Hydrocarbons as Finite Size Models of Graphene and Graphene Nanoribbons[J].National Academy Science Letters,2012,35(1):53.
[20]Gao Hai-li,He Li-lie,Xia Tong-chi,et al.Recent Research Progress in Preparation Methods of Graphene[J].Guangdong Chemical Industry,2015(24):87.高海丽,何里烈,夏同驰,等.石墨烯制备技术最新研究进展[J].广东化工,2015(24):87.
[21]Wang C,Liu Y,Li L,et al.Anisotropic thermal conductivity of graphene wrinkles[J].Nanoscale,2014,6(11):5703.
[22]Singh V,Joung D,Lei Z,et al.Graphene based materials:Past,present and future[J].Progress in Materials Science,2011,56(8):1178.
[23]Bai H,Li C,Shi G.Functional composite materials based on chemically converted graphene[J].Advanced Materials,2015,23(9):1088.
[24]Cao A,Liu Z,Chu S,et al.A Facile One-step Method to Produce Graphene–Cd S Quantum Dot Nanocomposites as Promising Optoelectronic Materials[J].Advanced Materials,2010,22(1):103.
[25]Vivekchand S R C,Rout C S,Subrahmanyam K S,et al.Graphene-based electrochemical supercapacitors[J].Journal of Chemical Sciences,2008,120(1):9.
[26]Kou R,Shao Y,Wang D,et al.Enhanced activity and stability of Pt catalysts on functionalized graphene sheets for electrocatalytic oxygen reduction[J].Electrochemistry Communications,2009,11(5):954.
[27]Zhu L,Shen F,Smith R L,et al.Black liquor-derived porous carbons from rice straw for high-performance supercapacitors[J].Chemical Engineering Journal,2017,316:770.
[28]Popova O V,Serbinovskiy M Y,AbramovaАG.Development of technology for production and application of graphite from hydrolytic lignin[J].European Journal of Wood&Wood Products,2015,73(3):369.
[29]Xu Shi-hai.Studies on Catalytic Graphitization of Carbon Materials[D].Changsha:Hunan University,2010.徐世海.碳材料催化石墨化研究[D].长沙:湖南大学,2010.
[30]Demir M,Kahveci Z,Aksoy B,et al.Graphitic Biocarbon from Metal-Catalyzed Hydrothermal Carbonization of Lignin[J].Industrial&Engineering Chemistry Research,2015,54(43):10731.
[31]Popova O V,Serbinovskiy M Y,AbramovaАG.Development of technology for production and application of graphite from hydrolytic lignin[J].European Journal of Wood and Wood Products,2015,73(3):369.
[32]Vivekanandhan S,Misra M,Mohanty A K.Microscopic,structural,and electrical characterization of the carbonaceous materials synthesized from various lignin feedstocks[J].Journal of Applied Polymer Science,2015,132(15):9.
[33]Yan Q,Zhang X,Li J,et al.Catalytic conversion of Kraft lignin to bio-multilayer graphene materials under different atmospheres[J].Journal of Materials Science,2018(2):1.
[34]Leng W,Barnes H M,Yan Q,et al.Low temperature synthesis of graphene-encapsulated copper nanoparticles from kraft lignin[J].Materials Letters,2016,185:131.
[35]Yi X,He W,Zhang X,et al.Graphene-like carbon sheet/Fe3O4nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries[J].Electrochimica Acta,2017,232:550.
[36]Ye R,Chyan Y,Zhang J,et al.Laser-Induced Graphene Formation on Wood[J].Advanced Materials,2017,29(37):1702211.
[37]Chyan Y,Ye R,Li Y,et al.Laser-Induced Graphene by Multiple Lasing:Toward Electronics on Cloth,Paper,and Food[J].ACSNano,2018,12(3):2176.
[38]Yoon D,Hwang J,Chang W,et al.Carbon with Expanded and Well-Developed Graphene Planes Derived Directly from Condensed Lignin as a High-Performance Anode for Sodium-Ion Batteries[J].ACS Appl Mater Interfaces,2018,10(1):569.
[39]Zhu S,Song Y,Zhao X,et al.The photoluminescence mechanism in carbon dots(graphene quantum dots,carbon nanodots,and polymer dots):current state and future perspective[J].Nano Research,2015,8(2):355.
[40]Ding Z,Li F,Wen J,et al.Gram-scale synthesis of single-crystalline graphene quantum dots derived from lignin biomass[J].Green Chemistry,2018,20(6):1383.
[41]Chen C,Li F,Zhang Y,et al.Compressive,ultralight and fire-resistant lignin-modified graphene aerogels as recyclable absorbents for oil and organic solvents[J].Chemical Engineering Journal,2018,350:173.
[42]Zeng Z,Wang C,Zhang Y,et al.Ultralight and Highly Elastic Graphene/Lignin-Derived Carbon Nanocomposite Aerogels with Ultrahigh Electromagnetic Interference Shielding Performance[J].ACSApplied Materials&Interfaces,2018,10(9):8205.
[43]Lota G,Milczarek G.The effect of lignosulfonates as electrolyte additives on the electrochemical performance of supercapacitors[J].E-lectrochemistry Communications,2011,13(5):470.
[44]Li F,Wang X,Sun R.A metal-free and flexible supercapacitor based on redox-active lignosulfonate functionalized graphene hydrogels[J].Journal of Materials Chemistry A,2017,5(39).
[45]Wang M,Le D D,Ma Y,et al.A strategy to synthesize grapheneincorporated lignin polymer composite materials with uniform graphene dispersion and covalently bonded interface engineering[J].Korea-Australia Rheology Journal,2017,29(3):207.
[46]You Chuan-bei,Li Fa-chun.MDI Production Technology of NonPhosgene Process and Cost Comparison[J].Chemical Fertilizer Industry,2016,43(5):44.游川北,李发春.非光气法MDI生产技术及成本比较[J].化肥工业,2016,43(5):44.
[47]Oribayo O,Feng X,Rempel G L,et al.Synthesis of lignin-based polyurethane/graphene oxide foam and its application as an absorbent for oil spill clean-ups and recovery[J].Chemical Engineering Journal,2017,323:191.
[48]Chen C,Wang X,Li M,et al.Humidity sensor based on reduced graphene oxide/lignosulfonate composite thin-film[J].Sensors&Actuators B Chemical,2017,255.
[49]Yang J,Wu J,LüQ,et al.Facile Preparation of LignosulfonateGraphene Oxide-Polyaniline Ternary Nanocomposite as an Effective Adsorbent for Pb(Ⅱ)Ions[J].ACS Sustainable Chemistry&Engineering,2014,2(5):1203.
[50]Li F,Wang X,Yuan T,et al.A lignosulfonate-modified graphene hydrogel with ultrahigh adsorption capacity for Pb(ii)removal[J].Journal of Materials Chemistry A,2016,4(30):11888.
[51]Geng X,Zhang Y,Jiao L,et al.Bioinspired Ultrastable Lignin Cathode via Graphene Reconfiguration for Energy Storage[J].ACSSustainable Chemistry&Engineering,2017,5(4):3553.
[52]Xu Li-na,Huang Kun,Li Shou-hai,et al.Synthesis and properties of lignin/graphene quantum dots composites as fluorescent sensor[J].Chemical Industry and Engineering Progress,2016(11):3595.许利娜,黄坤,李守海,等.木质素磺酸钙-石墨烯复合量子点的制备及性能[J].化工进展,2016(11):3595.
[2]ZHANG Qingtong,WANG Shuangfei,LI Mingfu,et al.Progress on Preparation and Application of Lignin Nanoparticles[J].China Pulp&Paper,2018,37(9):43.张清桐,王双飞,李明富,等.木素纳米粒子的制备及应用研究进展[J].中国造纸,2018,37(9):43.
[3]He Zheng.Chemical modification of technical lignin from different sources and the dispersion performance in pesticide WP and WG formulation[D].Guangzhou:South China University of Technology,2015.贺政.不同来源工业木质素的化学改性及对农药WP和WG的分散作用研究[D].广州:华南理工大学,2015.
[4]Chang Zhen-zhen.Study on the preparation and the energy storage performance of pyrolyzed lignin[D].Tianjin:Tianjin University,2016.常珍珍.热解木质素的制备及储能性质的研究[D].天津:天津大学,2016.
[5]Thakur V K,Thakur M K,Raghavan P,et al.Progress in Green Polymer Composites from Lignin for Multifunctional Applications:A Review[J].Acs Sustainable Chemistry&Engineering,2014,2(5):1072.
[6]Laurichesse S,Avérous L.Chemical modification of lignins:Towards biobased polymers[J].Progress in Polymer Science,2014,39(7):1266.
[7]JIA Zhuan,WAN Guangcong,LI Mingfu,et al.Progress in Chemical Modification of Lignin and Its Application in Phenolic Resins Adhesive Preparation[J].China Pulp&Paper,2018,37(3):72.贾转,万广聪,李明富,等.化学改性在木素基酚醛树脂胶黏剂制备中的研究进展[J].中国造纸,2018,37(3):72.
[8]Zhang Hui,Zhou Wan-peng,Chen Fan-geng.Research Progress in Dispersion of Lignin and Lignin-based Dispersants[J].Paper Science&Technology,2016(4):22.张晖,周万鹏,谌凡更.木质素分散性的应用研究进展[J].造纸科学与技术,2016(4):22.
[9]GregorovA,Ko2íkovB,Moravík R.Stabilization effect of lignin in natural rubber[J].Polymer Degradation&Stability,2006,91(2):229.
[10]Yan R,Yang D,Zhang N,et al.Performance of UV curable lignin based epoxy acrylate coatings[J].Progress in Organic Coatings,2018,116:83.
[11]Qian Y,Qiu X,Zhong X,et al.Lignin Reverse Micelles for UV-Absorbing and High Mechanical Performance Thermoplastics[J].Industrial&Engineering Chemistry Research,2015,54(48):1202.
[12]Song P,Cao Z,Fu S,et al.Thermal degradation and flame retardancy properties of ABS/lignin:Effects of lignin content and reactive compatibilization[J].Thermochimica Acta,2011,518(1/2):59.
[13]Liu Jian.Moving toward the application and industrialization of graohene:Processes of graphite formation and graphitic crystal chemistry[D].Beijing:China University of Geosciences(Beijing),2017.刘剑.天然石墨的成因、晶体化学特征及对石墨烯产业化的约束[D].北京:中国地质大学(北京),2017.
[14]Xing Yue,Hao Si-jia,Chen Yu-bin,et al.A brief discussion on graphene properties and cutting-edge applications[J].Advanced Materials Industry,2016(10):24.邢悦,郝思嘉,陈宇滨,等.浅谈石墨烯性能及前沿应用[J].新材料产业,2016(10):24.
[15]Xiao Yong,Ma Wei-dong,Sun Zhi-yong,et al.Research progress on preparation and application of graphene[J].Journal of Functional Materials and Devices,2017(5):125.肖勇,马卫东,孙志勇,等.石墨烯制备与应用研究进展[J].功能材料与器件学报,2017(5):125.
[16]Dervishi E,Li Z,Watanabe F,et al.Large-scale graphene production by RF-c CVD method[J].Chemical Communications,2009,27(27):4061.
[17]Reina A,Jia X,Ho J,et al.Large area,few-layer graphene films on arbitrary substrates by chemical vapor deposition[J].Nano Letters,2009,9(1):30.
[18]Hass J,Feng R,Milln-Otoya J E,et al.The structural properties of the multi-layer graphene/4H-Si C(000-1)system as determined by Surface X-ray Diffraction[J].Phys.Rev.B,2007,75(21):4109.
[19]Mishra P C,Yadav A.Enhanced Electron Density Edge Effect in Polycyclic Aromatic Hydrocarbons as Finite Size Models of Graphene and Graphene Nanoribbons[J].National Academy Science Letters,2012,35(1):53.
[20]Gao Hai-li,He Li-lie,Xia Tong-chi,et al.Recent Research Progress in Preparation Methods of Graphene[J].Guangdong Chemical Industry,2015(24):87.高海丽,何里烈,夏同驰,等.石墨烯制备技术最新研究进展[J].广东化工,2015(24):87.
[21]Wang C,Liu Y,Li L,et al.Anisotropic thermal conductivity of graphene wrinkles[J].Nanoscale,2014,6(11):5703.
[22]Singh V,Joung D,Lei Z,et al.Graphene based materials:Past,present and future[J].Progress in Materials Science,2011,56(8):1178.
[23]Bai H,Li C,Shi G.Functional composite materials based on chemically converted graphene[J].Advanced Materials,2015,23(9):1088.
[24]Cao A,Liu Z,Chu S,et al.A Facile One-step Method to Produce Graphene–Cd S Quantum Dot Nanocomposites as Promising Optoelectronic Materials[J].Advanced Materials,2010,22(1):103.
[25]Vivekchand S R C,Rout C S,Subrahmanyam K S,et al.Graphene-based electrochemical supercapacitors[J].Journal of Chemical Sciences,2008,120(1):9.
[26]Kou R,Shao Y,Wang D,et al.Enhanced activity and stability of Pt catalysts on functionalized graphene sheets for electrocatalytic oxygen reduction[J].Electrochemistry Communications,2009,11(5):954.
[27]Zhu L,Shen F,Smith R L,et al.Black liquor-derived porous carbons from rice straw for high-performance supercapacitors[J].Chemical Engineering Journal,2017,316:770.
[28]Popova O V,Serbinovskiy M Y,AbramovaАG.Development of technology for production and application of graphite from hydrolytic lignin[J].European Journal of Wood&Wood Products,2015,73(3):369.
[29]Xu Shi-hai.Studies on Catalytic Graphitization of Carbon Materials[D].Changsha:Hunan University,2010.徐世海.碳材料催化石墨化研究[D].长沙:湖南大学,2010.
[30]Demir M,Kahveci Z,Aksoy B,et al.Graphitic Biocarbon from Metal-Catalyzed Hydrothermal Carbonization of Lignin[J].Industrial&Engineering Chemistry Research,2015,54(43):10731.
[31]Popova O V,Serbinovskiy M Y,AbramovaАG.Development of technology for production and application of graphite from hydrolytic lignin[J].European Journal of Wood and Wood Products,2015,73(3):369.
[32]Vivekanandhan S,Misra M,Mohanty A K.Microscopic,structural,and electrical characterization of the carbonaceous materials synthesized from various lignin feedstocks[J].Journal of Applied Polymer Science,2015,132(15):9.
[33]Yan Q,Zhang X,Li J,et al.Catalytic conversion of Kraft lignin to bio-multilayer graphene materials under different atmospheres[J].Journal of Materials Science,2018(2):1.
[34]Leng W,Barnes H M,Yan Q,et al.Low temperature synthesis of graphene-encapsulated copper nanoparticles from kraft lignin[J].Materials Letters,2016,185:131.
[35]Yi X,He W,Zhang X,et al.Graphene-like carbon sheet/Fe3O4nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries[J].Electrochimica Acta,2017,232:550.
[36]Ye R,Chyan Y,Zhang J,et al.Laser-Induced Graphene Formation on Wood[J].Advanced Materials,2017,29(37):1702211.
[37]Chyan Y,Ye R,Li Y,et al.Laser-Induced Graphene by Multiple Lasing:Toward Electronics on Cloth,Paper,and Food[J].ACSNano,2018,12(3):2176.
[38]Yoon D,Hwang J,Chang W,et al.Carbon with Expanded and Well-Developed Graphene Planes Derived Directly from Condensed Lignin as a High-Performance Anode for Sodium-Ion Batteries[J].ACS Appl Mater Interfaces,2018,10(1):569.
[39]Zhu S,Song Y,Zhao X,et al.The photoluminescence mechanism in carbon dots(graphene quantum dots,carbon nanodots,and polymer dots):current state and future perspective[J].Nano Research,2015,8(2):355.
[40]Ding Z,Li F,Wen J,et al.Gram-scale synthesis of single-crystalline graphene quantum dots derived from lignin biomass[J].Green Chemistry,2018,20(6):1383.
[41]Chen C,Li F,Zhang Y,et al.Compressive,ultralight and fire-resistant lignin-modified graphene aerogels as recyclable absorbents for oil and organic solvents[J].Chemical Engineering Journal,2018,350:173.
[42]Zeng Z,Wang C,Zhang Y,et al.Ultralight and Highly Elastic Graphene/Lignin-Derived Carbon Nanocomposite Aerogels with Ultrahigh Electromagnetic Interference Shielding Performance[J].ACSApplied Materials&Interfaces,2018,10(9):8205.
[43]Lota G,Milczarek G.The effect of lignosulfonates as electrolyte additives on the electrochemical performance of supercapacitors[J].E-lectrochemistry Communications,2011,13(5):470.
[44]Li F,Wang X,Sun R.A metal-free and flexible supercapacitor based on redox-active lignosulfonate functionalized graphene hydrogels[J].Journal of Materials Chemistry A,2017,5(39).
[45]Wang M,Le D D,Ma Y,et al.A strategy to synthesize grapheneincorporated lignin polymer composite materials with uniform graphene dispersion and covalently bonded interface engineering[J].Korea-Australia Rheology Journal,2017,29(3):207.
[46]You Chuan-bei,Li Fa-chun.MDI Production Technology of NonPhosgene Process and Cost Comparison[J].Chemical Fertilizer Industry,2016,43(5):44.游川北,李发春.非光气法MDI生产技术及成本比较[J].化肥工业,2016,43(5):44.
[47]Oribayo O,Feng X,Rempel G L,et al.Synthesis of lignin-based polyurethane/graphene oxide foam and its application as an absorbent for oil spill clean-ups and recovery[J].Chemical Engineering Journal,2017,323:191.
[48]Chen C,Wang X,Li M,et al.Humidity sensor based on reduced graphene oxide/lignosulfonate composite thin-film[J].Sensors&Actuators B Chemical,2017,255.
[49]Yang J,Wu J,LüQ,et al.Facile Preparation of LignosulfonateGraphene Oxide-Polyaniline Ternary Nanocomposite as an Effective Adsorbent for Pb(Ⅱ)Ions[J].ACS Sustainable Chemistry&Engineering,2014,2(5):1203.
[50]Li F,Wang X,Yuan T,et al.A lignosulfonate-modified graphene hydrogel with ultrahigh adsorption capacity for Pb(ii)removal[J].Journal of Materials Chemistry A,2016,4(30):11888.
[51]Geng X,Zhang Y,Jiao L,et al.Bioinspired Ultrastable Lignin Cathode via Graphene Reconfiguration for Energy Storage[J].ACSSustainable Chemistry&Engineering,2017,5(4):3553.
[52]Xu Li-na,Huang Kun,Li Shou-hai,et al.Synthesis and properties of lignin/graphene quantum dots composites as fluorescent sensor[J].Chemical Industry and Engineering Progress,2016(11):3595.许利娜,黄坤,李守海,等.木质素磺酸钙-石墨烯复合量子点的制备及性能[J].化工进展,2016(11):3595.