气泡静电纺丝工艺与装置研究进展
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摘要
介绍了气泡静电纺丝技术以及相关研究成果,为后续学习与研究提供了理论依据。综述了气泡静电纺丝技术的发展现状,主要包括气泡静电纺丝原理、纺丝参数(电压、接收距离、气流流量、浓度/黏度、聚合物相对分子质量、电导率和表面张力)对纺丝过程的影响以及各种气泡静电纺丝装置的纺丝原理与优势。特别是气流气泡纺丝技术,利用气流代替高压静电的作用进行纺丝,更安全,简便,节能。研究发现,气泡静电纺丝技术具有设备制作简单、操作方便、成本低廉、生产效率高、适用性广泛等优点,可推广应用于工业化生产。
This paper introduces a technology named bubble electrospinning and its development to provide theoretical basus for subsequent research. A complete review on bubble-electrospinning including its mechanism,influence of spinning parameters( including voltage,collector distance,flow rate,concentration /viscosity,polymer relative molecular weight,conductivity and surface tension) on the spinning process and the spinning principles and advantages of different set-ups is made to elucidate the main properties and advantages of the technology. A novel technology,blown bubble spinning,proposed to fabricate nanofibers by using blowing air instead of the high voltage electrostatic action,is safer,simpler and more energy saving. According to research,bubble electrospinning has advantages of simple equipment fabrication,easy operation,low cost,high production efficiency and wide application,and can be generalized and used for the industrial production.
This paper introduces a technology named bubble electrospinning and its development to provide theoretical basus for subsequent research. A complete review on bubble-electrospinning including its mechanism,influence of spinning parameters( including voltage,collector distance,flow rate,concentration /viscosity,polymer relative molecular weight,conductivity and surface tension) on the spinning process and the spinning principles and advantages of different set-ups is made to elucidate the main properties and advantages of the technology. A novel technology,blown bubble spinning,proposed to fabricate nanofibers by using blowing air instead of the high voltage electrostatic action,is safer,simpler and more energy saving. According to research,bubble electrospinning has advantages of simple equipment fabrication,easy operation,low cost,high production efficiency and wide application,and can be generalized and used for the industrial production.
引文
[1]LI J,GAO F,LIU L Q,et al.Needleless electro-spun nanofibers used for filtration of small particles[J].Express Polymer Letters,2013,7(8):683-689.
[2]THAVASI V,SINGH G,RAMAKRISHNA S.Electrospun nanofibers in energy and environmental applications[J].Energy&Environmental Science,2008,1(2):205-221.
[3]ARORA P,ZHANG Z M.Battery separators[J].Chemical Reviews,2004,104(10):4419-4462.
[4]徐阳,王肖娜,杜远之,等.静电和熔融纺对PET纤维表面结构的影响[J].纺织学报,2012,33(9):1-5.XU Yang,WANG Xiaona,DU Yuanzhi,et al.Effects of electrospinning and melt spinning on surface structure of PET fibers[J].Journal of Textile Research,2012,33(9):1-5.
[5]田龙,李杰,潘志娟.多射流静电纺技术的研究现状[J].纺织学报.2013,34(9):150-156.TIAN Long,LI Jie,PAN Zhijuan.Research status of multi-jet electrospinning technology[J].Journal of Textile Research,2013,34(9):150-156.
[6]HE J H.Nano bubble dynamics in spider spinning system[J].Journal of Animal and Veterinary Advances,2008,7(2):207-209.
[7]HE J H,LIU Y,XU L.Apparatus for preparing electrospun nanofibres:a comparative review[J].Materials Science and Technology,2010,26(11):1275-1287.
[8]LIU Y,HE J H,XU L,et al.The principle of bubble electrospinning and its experimental verification[J].Journal of Polymer Engineering,2008,28(1/2):55-65.
[9]HE J H,LIU Y,XU L,et al.Biomimic fabrication of electrospun nanofibers with high-throughput[J].Chaos Solitons&Fractals,2008,37(3):643-651.
[10]LIU F J,DOU H.Modified yang-laplace equation for the bubble electrospinning considering the effect of humidity[J].Thermal Science,2013(17):629-630.
[11]HE J H.Effect of temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication[J].Thermal Science,2012,16(1):327-330.
[12]HE J H,KONG H Y,YANG R R,et al.Review on fiber morphology obtained by bubble electrospinning and blown bubble spinning[J].Thermal Science,2012,16(5):1263-1279.
[13]LIU Y,DONG L,FAN J,et al.Effect of applied voltage on diameter and morphology of ultrafine fibers in bubble electrospinning[J].Journal of Applied Polymer Science,2011(120):592-598.
[14]杨芹.气泡静电纺工艺及机理研究[D].上海:东华大学,2010:11-30.YANG Qin.Experimental characterization and mechanism of bubble-electrospinning[D].Shanghai:Donghua University,2010:11-30.
[15]杨瑞瑞.气泡静电纺产品成形机理及增韧应用研究[D].上海:东华大学,2012:25-55.YANG Ruirui.Formation mechanism and application in interfacial toughening of bubble-electrospun nanofibers[D].Shanghai:Donghua University,2012:25-55.
[16]刘雍.气泡静电纺丝技术及其机理研究[D].上海:东华大学,2008:35-50.LIU Yong.A new technology,bubble electrospinning,for production nanofibers[D].Shanghai:Donghua University,2008:35-55.
[17]HE J H,WAN Y Q.Effect of concentration on electrospun polyacrylonitrile(PAN)nanofibers[J].Fibers and Polymers,2008,9(2):140-142.
[18]XU L.A mathematical model for electro spinning process under coupled field forces[J].Chaos,Solitons&Fractals.2009,42(3):1463-1465.
[19]YANG R R,HE J H,XU L,et al.Effect of solution concentration on diameter and morphology of PVA nanofibres in bubble electro spinning process[J].Materials Science and Technology,2010,26(11):1313-1316.
[20]刘雍,何吉欢,俞建勇,等.一种可用于大批量生产纳米纤维的喷气式静电纺丝装置:中国,CN200710036447.4[P].2007-07-25.LIU Yong,HE Jihuan,YU Jianyong,et al.A jetpropelled electrospinning set-up for mass production of nanofibers:China,CN200710036447.4[P].2007-07-25.
[21]刘雍,俞建勇,何吉欢,等.一种纳米纤维的静电纺丝装置:中国,CN200710040316.3[P].2007-10-10.LIU Yong,YU Jianyong,HE Jihuan,et al.An electrospinning set-up for fabrication of nanofibers:China,CN200710040316.3[P].2007-10-10.
[22]何吉欢,杨瑞瑞,任忠夫.一种可便携制备纳米纤维的喷气静电纺丝装置:中国,CN200910056750.X[P].2010-01-27.HE Jihuan,YANG Ruirui,REN Zhongfu.A portable jet-propelled electrospinning set-up for fabrication of nanofibers:China,CN200910056750.X[P].2010-01-27.
[23]YANG R R,HE J H,XU L,et al.Bubbleelectrospinning for fabricating nanofibers[J].Polymer,2009,24(16):5846-5850.
[24]KONG H Y,HE J H.Superthin combined pva-graphene film[J].Thermal Science,2012,16(5):1560-1561.
[25]HE J H,WAN Y Q,XU L.Nano-effects,quantum-like properties in electrospun nanofibers[J].Chaos Solitons&Fractals,2007,33(1):26-37.
[26]HSIAO H Y,HUANG C M,LIU Y Y,et al.Effect of air blowing on the morphology and nanofiber properties of blowing-assisted Electrospun polycarbonates[J].Journal of Applied Polymer Science,2012(124):4904-4914.
[27]SINHA-RAY S,YARIN A L,POURDEYHIMI B.The production of 100/400 nm inner/outer diameter carbon tubes by solution blowing and carbonization of coreshell nanofibers[J].Carbon,2010(48):3575-3578.
[28]何吉欢,孔海燕,周丽霞.涡流式气泡纺丝装置:中国,CN201210548273.0[P].2013-03-20.HE Jihuan,KONG Haiyan,ZHOU Lixia.Eddy bubbleelectrospinning set-up:China,CN201210548273.0[P].2013-03-20.
[29]SANTOS L P,DUCATI T R D,BALESTRIN L B S,et al.Water with excess electric charge[J].The Journal of Physical Chemistry C,2011,115(22):1-14.
[30]何吉欢,孔海燕,周丽霞.气泡纺丝装置:中国,CN201210407119.1[P].2013-01-09.HE Jihuan,KONG Haiyan,ZHOU Lixia.Bubbleelectrospinning set-up:China,CN201210407119.1[P].2013-01-09.
[31]DOU H,ZUO B Q,HE J H.Blown bubble-spinning for fabrication of superfine fibers[J].Thermal Science,2012,16(5):1465-1466.
[32]何吉欢,孔海燕,周丽霞.静电纺丝装置:中国,CN201210422932.6[P].2013-01-16.HE Jihuan,KONG Haiyan,ZHOU Lixia.Electrospinning set-up:China,CN201210422932.6[P].2013-01-16.
[2]THAVASI V,SINGH G,RAMAKRISHNA S.Electrospun nanofibers in energy and environmental applications[J].Energy&Environmental Science,2008,1(2):205-221.
[3]ARORA P,ZHANG Z M.Battery separators[J].Chemical Reviews,2004,104(10):4419-4462.
[4]徐阳,王肖娜,杜远之,等.静电和熔融纺对PET纤维表面结构的影响[J].纺织学报,2012,33(9):1-5.XU Yang,WANG Xiaona,DU Yuanzhi,et al.Effects of electrospinning and melt spinning on surface structure of PET fibers[J].Journal of Textile Research,2012,33(9):1-5.
[5]田龙,李杰,潘志娟.多射流静电纺技术的研究现状[J].纺织学报.2013,34(9):150-156.TIAN Long,LI Jie,PAN Zhijuan.Research status of multi-jet electrospinning technology[J].Journal of Textile Research,2013,34(9):150-156.
[6]HE J H.Nano bubble dynamics in spider spinning system[J].Journal of Animal and Veterinary Advances,2008,7(2):207-209.
[7]HE J H,LIU Y,XU L.Apparatus for preparing electrospun nanofibres:a comparative review[J].Materials Science and Technology,2010,26(11):1275-1287.
[8]LIU Y,HE J H,XU L,et al.The principle of bubble electrospinning and its experimental verification[J].Journal of Polymer Engineering,2008,28(1/2):55-65.
[9]HE J H,LIU Y,XU L,et al.Biomimic fabrication of electrospun nanofibers with high-throughput[J].Chaos Solitons&Fractals,2008,37(3):643-651.
[10]LIU F J,DOU H.Modified yang-laplace equation for the bubble electrospinning considering the effect of humidity[J].Thermal Science,2013(17):629-630.
[11]HE J H.Effect of temperature on surface tension of a bubble and hierarchical ruptured bubbles for nanofiber fabrication[J].Thermal Science,2012,16(1):327-330.
[12]HE J H,KONG H Y,YANG R R,et al.Review on fiber morphology obtained by bubble electrospinning and blown bubble spinning[J].Thermal Science,2012,16(5):1263-1279.
[13]LIU Y,DONG L,FAN J,et al.Effect of applied voltage on diameter and morphology of ultrafine fibers in bubble electrospinning[J].Journal of Applied Polymer Science,2011(120):592-598.
[14]杨芹.气泡静电纺工艺及机理研究[D].上海:东华大学,2010:11-30.YANG Qin.Experimental characterization and mechanism of bubble-electrospinning[D].Shanghai:Donghua University,2010:11-30.
[15]杨瑞瑞.气泡静电纺产品成形机理及增韧应用研究[D].上海:东华大学,2012:25-55.YANG Ruirui.Formation mechanism and application in interfacial toughening of bubble-electrospun nanofibers[D].Shanghai:Donghua University,2012:25-55.
[16]刘雍.气泡静电纺丝技术及其机理研究[D].上海:东华大学,2008:35-50.LIU Yong.A new technology,bubble electrospinning,for production nanofibers[D].Shanghai:Donghua University,2008:35-55.
[17]HE J H,WAN Y Q.Effect of concentration on electrospun polyacrylonitrile(PAN)nanofibers[J].Fibers and Polymers,2008,9(2):140-142.
[18]XU L.A mathematical model for electro spinning process under coupled field forces[J].Chaos,Solitons&Fractals.2009,42(3):1463-1465.
[19]YANG R R,HE J H,XU L,et al.Effect of solution concentration on diameter and morphology of PVA nanofibres in bubble electro spinning process[J].Materials Science and Technology,2010,26(11):1313-1316.
[20]刘雍,何吉欢,俞建勇,等.一种可用于大批量生产纳米纤维的喷气式静电纺丝装置:中国,CN200710036447.4[P].2007-07-25.LIU Yong,HE Jihuan,YU Jianyong,et al.A jetpropelled electrospinning set-up for mass production of nanofibers:China,CN200710036447.4[P].2007-07-25.
[21]刘雍,俞建勇,何吉欢,等.一种纳米纤维的静电纺丝装置:中国,CN200710040316.3[P].2007-10-10.LIU Yong,YU Jianyong,HE Jihuan,et al.An electrospinning set-up for fabrication of nanofibers:China,CN200710040316.3[P].2007-10-10.
[22]何吉欢,杨瑞瑞,任忠夫.一种可便携制备纳米纤维的喷气静电纺丝装置:中国,CN200910056750.X[P].2010-01-27.HE Jihuan,YANG Ruirui,REN Zhongfu.A portable jet-propelled electrospinning set-up for fabrication of nanofibers:China,CN200910056750.X[P].2010-01-27.
[23]YANG R R,HE J H,XU L,et al.Bubbleelectrospinning for fabricating nanofibers[J].Polymer,2009,24(16):5846-5850.
[24]KONG H Y,HE J H.Superthin combined pva-graphene film[J].Thermal Science,2012,16(5):1560-1561.
[25]HE J H,WAN Y Q,XU L.Nano-effects,quantum-like properties in electrospun nanofibers[J].Chaos Solitons&Fractals,2007,33(1):26-37.
[26]HSIAO H Y,HUANG C M,LIU Y Y,et al.Effect of air blowing on the morphology and nanofiber properties of blowing-assisted Electrospun polycarbonates[J].Journal of Applied Polymer Science,2012(124):4904-4914.
[27]SINHA-RAY S,YARIN A L,POURDEYHIMI B.The production of 100/400 nm inner/outer diameter carbon tubes by solution blowing and carbonization of coreshell nanofibers[J].Carbon,2010(48):3575-3578.
[28]何吉欢,孔海燕,周丽霞.涡流式气泡纺丝装置:中国,CN201210548273.0[P].2013-03-20.HE Jihuan,KONG Haiyan,ZHOU Lixia.Eddy bubbleelectrospinning set-up:China,CN201210548273.0[P].2013-03-20.
[29]SANTOS L P,DUCATI T R D,BALESTRIN L B S,et al.Water with excess electric charge[J].The Journal of Physical Chemistry C,2011,115(22):1-14.
[30]何吉欢,孔海燕,周丽霞.气泡纺丝装置:中国,CN201210407119.1[P].2013-01-09.HE Jihuan,KONG Haiyan,ZHOU Lixia.Bubbleelectrospinning set-up:China,CN201210407119.1[P].2013-01-09.
[31]DOU H,ZUO B Q,HE J H.Blown bubble-spinning for fabrication of superfine fibers[J].Thermal Science,2012,16(5):1465-1466.
[32]何吉欢,孔海燕,周丽霞.静电纺丝装置:中国,CN201210422932.6[P].2013-01-16.HE Jihuan,KONG Haiyan,ZHOU Lixia.Electrospinning set-up:China,CN201210422932.6[P].2013-01-16.