大气污染物二氧化硫的荧光检测技术研究进展
|
摘要
二氧化硫是目前含量较大、影响面较广的一种大气污染物,是酸雨形成的主要来源。很多国家都把空气中二氧化硫的含量作为衡量空气污染的主要指标。二氧化硫主要来源于含硫化石矿物燃料的燃烧、火山喷发、含硫矿物的冶炼和焙烧等。二氧化硫不仅会形成酸雨,腐蚀生产设备和建筑物,而且会对环境安全、动植物和人体健康造成严重危害,因此建立可靠、快捷、准确、高效的二氧化硫检测方法尤为重要。荧光分析法具有检出限低、灵敏度高、快速、仪器简单等优点,将其用于二氧化硫的实时检测,可以实现溶液乃至大气中二氧化硫的准确、快速、高效检测。对二氧化硫的荧光检测技术研究进展作了综述。
Currently, sulfur dioxide is one of the major air pollutants which have large content and wide impact, and it is the main source of formation of acid rain. Many countries have put the content of sulfur dioxide in the air as a key indicator of air pollution. There are a lot of sources of sulfur dioxide, such as burning of sulfur-containing fossil fuels,eruptions of volcanoes, smelting and roasting of sulfur-containing minerals. Sulfur dioxide not only causes acid rain,corrodes the production equipment and buildings, but also does serious harm to environmental safety, animals, plants and human health. Therefore, it is particularly important to develop a reliable, fast, accurate and efficient method for the detection of sulfur dioxide in the environment. Fluorescence analytical method has some advantages, such as low detection limits, high sensitivity, fast operation and simple instruments. If the method could be used for real-time detection of sulfur dioxide, the accurate, fast and efficient detection of sulfur dioxide in solutions and even in atmosphere would be achieved.This review summarizes the advances in the fluorescence detection technology of sulfur dioxide.
Currently, sulfur dioxide is one of the major air pollutants which have large content and wide impact, and it is the main source of formation of acid rain. Many countries have put the content of sulfur dioxide in the air as a key indicator of air pollution. There are a lot of sources of sulfur dioxide, such as burning of sulfur-containing fossil fuels,eruptions of volcanoes, smelting and roasting of sulfur-containing minerals. Sulfur dioxide not only causes acid rain,corrodes the production equipment and buildings, but also does serious harm to environmental safety, animals, plants and human health. Therefore, it is particularly important to develop a reliable, fast, accurate and efficient method for the detection of sulfur dioxide in the environment. Fluorescence analytical method has some advantages, such as low detection limits, high sensitivity, fast operation and simple instruments. If the method could be used for real-time detection of sulfur dioxide, the accurate, fast and efficient detection of sulfur dioxide in solutions and even in atmosphere would be achieved.This review summarizes the advances in the fluorescence detection technology of sulfur dioxide.
引文
[1]YULIARTO B,RAMADHANI M F,TAPRAN N,et al.Enhancement of SO2gas sensing performance using ZnOnanorod thin films:the role of deposition time[J].Journal of Materials Science,2016,52(8):4543-4554.
[2]SHAYMURAT T,TANG Q X,TONG Y H,et al.Gas dielectric transistor of CuPc single crystalline nanowire for SO2detection down to sub-ppm levels at room temperature[J].Advanced materials,2013,25(16):2269-2273.
[3]CRIDER W L.Hydrogen flame emission spectrophotometry in monitoring air for sulfur dioxide and sulfuric acid aerosol[J].Analytical Chemistry,1965,37(13):1770-1773.
[4]YOGENDRA K M S,GOWTHAM M D,MAHADEVA-IAH,et al.Simple spectrophotometric and titrimetric methods for the determination of sulfur dioxide[J].Analytical Sciences:the International Journal of the Japan Society for Analytical Chemistry,2006,22(5):757-761.
[5]SHI G Y,LUO M,XUE J,et al.The study of PVP/Pd/IrO2modified sensor for amperometric determination of sulfur dioxide[J].Talanta,2001,55(2):241-247.
[6]BRUNO P,CASELLI M,DI FANO A,et al.Fast and simple polarographic method for the determination of free and total sulphur dioxide in wines and other common beverages[J].The Analyst,1979(104):1083-1087.
[7]YANG D Z,HOU M Q,NING H,et al.Efficient SO2capture by amine functionalized PEG[J].Physical chemistry chemical physics:PCCP,2013,15(41):18 123-18 127.
[8]MENG H,WU F W,HE Z K,et al.Chemiluminescence determination of sulfite in sugar and sulfur dioxide in air using Tris(2,2′-bipyridyl)ruthenium(II)-permanganate system[J].Talanta,1999,48(3):571-577.
[9]MANA H,SPOHN U.Sensitive and selective flow injection analysis of hydrogen sulfite/sulfur dioxide by fluorescence detection with and without membrane separation by gas diffusion[J].Analytical Chemistry,2001,73(13):3187-3192.
[10]KOCH M,KOPPEN R,SIEGEL D.Determination of total sulfite in wine by ion chromatography after in-sample oxidation[J].Journal of Agricultural and Food Chemistry,2010,58(17):9463-9467.
[11]AXELROD H D,BONELLI J E,LODGE J P.Fluorimetric determination of sulfur dioxide as sulfite[J].Analytical Chemistry,1970,42(4):512-515.
[12]RAJENDIRAN N,SANTHANALAKSHMI J.Interaction of sulfur dioxide with zinc(II)tetrasulfo phthalocyanine in aqueous medium:steady state fluorescence quenching studies[J].Polyhedron,2002,21(9-10):951-957.
[13]CHANG W,ONO Y,KUMEMURA M,et al.On-line determination of trace sulfur dioxide in air by integrated microchip coupled with fluorescence detection[J].Talanta,2005,67(3):646-650.
[14]SUN M T,YU H,ZHANG K,et al.Determination of gaseous sulfur dioxide and its derivatives via fluorescence enhancement based on cyanine dye functionalized carbon nanodots[J].Analytical Chemistry,2014,86(19):9381-9385.
[15]LI H H,ZHU H J,SUN M T,et al.Manipulating the surface chemistry of quantum dots for sensitive ratiometric fluorescence detection of sulfur dioxide[J].Langmuir:the ACS Journal of Surfaces ard Colloids,2015,31(31):8667-8671.
[16]OKABE H,SPLITSTONE P L,BALL J J.Ambient and source SO2detector based on a fluorescence method[J].Journal of the Air Pollution Control Association,1973,23(6):514-516.
[17]MATSUMI Y,SHIGEMORI H,TAKAHASHI K.Laser-induced fluorescence instrument for measuring atmospheric SO2[J].Atmospheric Environment,2005,39(17):3177-3185.
[18]RAZEK T M,MILLER M J,HASSAN S S,et al.Optical sensor for sulfur dioxide based on fluorescence quenching[J].Talanta,1999,50(3),491-498.
[19]CHE S Y,DAO R N,ZHANG W D,et al.Designing an anion-functionalized fluorescent ionic liquid as an efficient and reversible turn-off sensor for detecting SO2[J].Chemical Communications,2017,53(27):3862-3865
[20]ZHANG J,XIA T F,ZHAO D,et al.In situ secondary growth of Eu(III)-organic framework film for fluorescence sensing of sulfur dioxide[J].Sensors and Actuators B:Chemical,2018,260:63-69.
[21]YANG Y Q,WANG Z Z,NIU H,et al.One-pot synthesis of quantum dot-labeled hydrophilic molecularly imprinted polymer nanoparticles for direct optosensing of folic acid in real,undiluted biological samples[J].Biosensors and Bioelectronics 2016,86:580-587.
[22]NGUYER V T,KWON Y S,GU M B.Aptamer-based environmental biosensors for small molecule contaminants[J].Current Opinion in Biotechnology,2017,45:15-23.
[2]SHAYMURAT T,TANG Q X,TONG Y H,et al.Gas dielectric transistor of CuPc single crystalline nanowire for SO2detection down to sub-ppm levels at room temperature[J].Advanced materials,2013,25(16):2269-2273.
[3]CRIDER W L.Hydrogen flame emission spectrophotometry in monitoring air for sulfur dioxide and sulfuric acid aerosol[J].Analytical Chemistry,1965,37(13):1770-1773.
[4]YOGENDRA K M S,GOWTHAM M D,MAHADEVA-IAH,et al.Simple spectrophotometric and titrimetric methods for the determination of sulfur dioxide[J].Analytical Sciences:the International Journal of the Japan Society for Analytical Chemistry,2006,22(5):757-761.
[5]SHI G Y,LUO M,XUE J,et al.The study of PVP/Pd/IrO2modified sensor for amperometric determination of sulfur dioxide[J].Talanta,2001,55(2):241-247.
[6]BRUNO P,CASELLI M,DI FANO A,et al.Fast and simple polarographic method for the determination of free and total sulphur dioxide in wines and other common beverages[J].The Analyst,1979(104):1083-1087.
[7]YANG D Z,HOU M Q,NING H,et al.Efficient SO2capture by amine functionalized PEG[J].Physical chemistry chemical physics:PCCP,2013,15(41):18 123-18 127.
[8]MENG H,WU F W,HE Z K,et al.Chemiluminescence determination of sulfite in sugar and sulfur dioxide in air using Tris(2,2′-bipyridyl)ruthenium(II)-permanganate system[J].Talanta,1999,48(3):571-577.
[9]MANA H,SPOHN U.Sensitive and selective flow injection analysis of hydrogen sulfite/sulfur dioxide by fluorescence detection with and without membrane separation by gas diffusion[J].Analytical Chemistry,2001,73(13):3187-3192.
[10]KOCH M,KOPPEN R,SIEGEL D.Determination of total sulfite in wine by ion chromatography after in-sample oxidation[J].Journal of Agricultural and Food Chemistry,2010,58(17):9463-9467.
[11]AXELROD H D,BONELLI J E,LODGE J P.Fluorimetric determination of sulfur dioxide as sulfite[J].Analytical Chemistry,1970,42(4):512-515.
[12]RAJENDIRAN N,SANTHANALAKSHMI J.Interaction of sulfur dioxide with zinc(II)tetrasulfo phthalocyanine in aqueous medium:steady state fluorescence quenching studies[J].Polyhedron,2002,21(9-10):951-957.
[13]CHANG W,ONO Y,KUMEMURA M,et al.On-line determination of trace sulfur dioxide in air by integrated microchip coupled with fluorescence detection[J].Talanta,2005,67(3):646-650.
[14]SUN M T,YU H,ZHANG K,et al.Determination of gaseous sulfur dioxide and its derivatives via fluorescence enhancement based on cyanine dye functionalized carbon nanodots[J].Analytical Chemistry,2014,86(19):9381-9385.
[15]LI H H,ZHU H J,SUN M T,et al.Manipulating the surface chemistry of quantum dots for sensitive ratiometric fluorescence detection of sulfur dioxide[J].Langmuir:the ACS Journal of Surfaces ard Colloids,2015,31(31):8667-8671.
[16]OKABE H,SPLITSTONE P L,BALL J J.Ambient and source SO2detector based on a fluorescence method[J].Journal of the Air Pollution Control Association,1973,23(6):514-516.
[17]MATSUMI Y,SHIGEMORI H,TAKAHASHI K.Laser-induced fluorescence instrument for measuring atmospheric SO2[J].Atmospheric Environment,2005,39(17):3177-3185.
[18]RAZEK T M,MILLER M J,HASSAN S S,et al.Optical sensor for sulfur dioxide based on fluorescence quenching[J].Talanta,1999,50(3),491-498.
[19]CHE S Y,DAO R N,ZHANG W D,et al.Designing an anion-functionalized fluorescent ionic liquid as an efficient and reversible turn-off sensor for detecting SO2[J].Chemical Communications,2017,53(27):3862-3865
[20]ZHANG J,XIA T F,ZHAO D,et al.In situ secondary growth of Eu(III)-organic framework film for fluorescence sensing of sulfur dioxide[J].Sensors and Actuators B:Chemical,2018,260:63-69.
[21]YANG Y Q,WANG Z Z,NIU H,et al.One-pot synthesis of quantum dot-labeled hydrophilic molecularly imprinted polymer nanoparticles for direct optosensing of folic acid in real,undiluted biological samples[J].Biosensors and Bioelectronics 2016,86:580-587.
[22]NGUYER V T,KWON Y S,GU M B.Aptamer-based environmental biosensors for small molecule contaminants[J].Current Opinion in Biotechnology,2017,45:15-23.