微米二氧化硅微球的制备研究进展
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摘要
以聚合诱导胶体凝聚法、种子生长法、模板法和反相乳液法等制备方法为主线,综述制备微米二氧化硅微球的最新研究进展,同时以所得微球的性能为考察重点,对各种方法进行评价与展望;提出通过硅酸钠等低成本硅原料取代硅酸酯制备高性能硅微球是未来研究重点;改变种子生长法中溶剂的种类、制备粒径更大的单分散微球并进行理论探究成为种子生长法的研究方向;采用模板法对聚合诱导胶体凝聚法制备的微球孔结构进行重组完善,得到纯度较高、机械强度和比表面积较大的微米有序介孔二氧化硅微球,进而用于高性能色谱柱的制备以及生物催化等领域,发展前景可观。
The preparation methods of micron-sized silica microspheres which include polymerization induced colloid aggregation, seeded growth, templating method, reverse emulsion and some other methods were reviewed. The preparation methods were evaluated through the performance of silica microspheres, and its development direction were also presented.It is put forward that the high performance silica microspheres prepared by sodium silicate and other cheap silicon feedstock instead of silicate ester are the research priorities in the future,uniform microspheres with bigger particle size can be prepared by adjusting the categories of solvent from seed growth method which will become the emphasis in the further study, and the porous structure of microspheres prepared by polymerization induced colloid aggregation can be adjusted by templating method in order to obtain well-ordered mesoporous microspheres with high mechanical strength, high purity, as well as high specific surface area, which can be used in high-performance chromatographic column, biocatalysis and other fields.
The preparation methods of micron-sized silica microspheres which include polymerization induced colloid aggregation, seeded growth, templating method, reverse emulsion and some other methods were reviewed. The preparation methods were evaluated through the performance of silica microspheres, and its development direction were also presented.It is put forward that the high performance silica microspheres prepared by sodium silicate and other cheap silicon feedstock instead of silicate ester are the research priorities in the future,uniform microspheres with bigger particle size can be prepared by adjusting the categories of solvent from seed growth method which will become the emphasis in the further study, and the porous structure of microspheres prepared by polymerization induced colloid aggregation can be adjusted by templating method in order to obtain well-ordered mesoporous microspheres with high mechanical strength, high purity, as well as high specific surface area, which can be used in high-performance chromatographic column, biocatalysis and other fields.
引文
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[32]HE J L,CHEN X H,ZHU W J,et al.Synthesis of mesoporous silica microspheres by PICA and pseudomorphic transformation using silica fume as silica source[J].Materials Science Forum,2015,809:207-212.
[33]ST BER W,FINK A,BOHN E.Controlled growth of monodisperse silica spheres in the micron size range[J].J Colloid Interf Sci,1968,26(1):62-69.
[34]WATANABE R,YOKOI T,KOBAYASHI E,et al.Extension of size of monodisperse silica nanospheres and their well-ordered assembly[J].J Colloid Interf Sci,2011,360(1):1-7.
[35]CHANG S M,LEE M,KIM W S.Preparation of large monodispersed spherical silica particles using seed particle growth[J].J Colloid Interf Sci,2005,286(2):536-542.
[36]ZHAO B,TIAN C,ZHANG Y,et al.Size control of monodisperse nonporous silica particles by seed particle growth[J].Particuology,2011,9(3):314-317.
[37]CHEN S L,YUAN G,HU C T.Preparation and size determination of monodisperse silica microspheres for particle size certified reference materials[J].Powder Technol,2011,207(1):232-237.
[38]鲍艳,杨永强,马建中,等.氧化锌为模板制备中空二氧化硅微球及其对聚丙烯酸酯薄膜性能的影响[J].硅酸盐学报,2014,42(7):914-919.
[39]钱家盛,王旭华,章于川.介孔材料的制备及表征[J].中国粉体技术,2005,11(1):36-38.
[40]王吉会,董青.Si O2空心微球的制备与表征[J].材料开发与应用,2009,24(4):42-47.
[41]TUNGKANANURAK K,KERDSIRI S,JADSADAPATTARAKUL D,et al.Semi-micro preparation and characterization of mesoporous silica microspheres from rice husk sodium silicate using a non-ionic surfactant as a template:application in normal phase HPLC columns[J].Microchim Acta,2007,159(3/4):217-222.
[42]潘恩磊.反相悬浮聚合诱导微米级多孔Si O2微球的制备[J].中国陶瓷,2012(4):27-30.
[43]SMITHA S,SHAJESH P,MUKUNDAN P,et al.Synthesis of mesoporous hydrophobic silica microspheres through a modified sol-emulsion-gel process[J].J Sol-Gel Sci Techn,2008,48(3):356-361.
[44]刘帅,陈磊.以廉价硅源制备多孔二氧化硅微球及其孔结构的控制[J].硅酸盐通报,2012,31(3):669-674.
[45]刘世鹏.反相悬浮体系制备高纯多孔二氧化硅微球[J].硅酸盐通报,2014(9):2370-2374.
[46]ZHOKHOV A A,MASALOV V M,SUKHININA N S,et al.Photonic crystal microspheres[J].Opt Mater,2015,49:208-212.
[47]KARMAKAR B,DE G,GANGULI D.Dense silica microspheres from organic and inorganic acid hydrolysis of TEOS[J].J Non-cryst Solids,2000,272(2/3):119-126.
[2]YUAN H,YU B,CONG H,et al.The fabrication and application of bio-functional microspheres[J].Curr Org Chem,2014,18(17):2270-2279.
[3]施阳和,郑华.球形粉体的制备方法及应用[J].中国粉体技术,2015,21(4):71-75.
[4]陈朝霞,张玉红,殷俊,等.有机-无机纳米复合微球研究进展[J].高分子通报,2013,11:005.
[5]OZER O,INCE A,KARAGOZ B,et al.Crosslinked PS-DVB microspheres with sulfonated polystyrene brushes as new generation of ion exchange resins[J].Desalination,2013,309:141-147.
[6]郭春芳.水热法合成Zn O纳米微球及其光吸收特性[J].中国粉体技术,2014,20(2):64-67.
[7]邵承伟,魏荣卿,张婷婷,等.聚(苯乙烯-二乙烯基苯)反相高效液相色谱填料在胸腺素α-1分离中的应用[J].分析化学,2007,35(10):1491-1494.
[8]XU Y,LIU X,ZHOU J,et al.Simultaneous determination ofβ-methyl-β-nitrostyrolene and its related substances by PS-DVB chromatographic column and structural analysis of its photo-isomerization product[J].Anal Methods-UK,2014,6(20):8284-8290.
[9]王丹.球形硅胶的制备和孔结构研究[D].北京:北京化工大学,2008.
[10]P REZ-QUINTANILLA D,MORANTE-ZARCERO S,SIERRA I.Preparation and characterization of mesoporous silicas modified with chiral selectors as stationary phase for high-performance liquid chromatography[J].J Colloid Interf Sci,2014,414(4):14-23.
[11]敦惠娟,祝馨怡,李文智,等.球形氧化锆液相色谱柱填料的制备和评价[J].色谱,2003,21(5):490-493.
[12]杨俊佼,张硕.单分散高纯硅胶色谱柱填料的制备[J].高等学校化学学报,2012,33(4):689-694.
[13]POPOVA M D,SZEGEDI,KOLEV I N,et al.Carboxylic modified spherical mesoporous silicasаs drug delivery carriers[J].Int J Pharmaceut,2012,436(1):778-785.
[14]邹涛,周素红,陈萦.两种二氧化硅吸附性能比较[J].中国粉体技术,2005(增刊1):208-210.
[15]MACHIDA M,FOTOOHI B,AMAMO Y,et al.Cadmium(II)adsorption using functional mesoporous silica and activated carbon[J].J Hazard Mater,2012,s221/222(4):220-227.
[16]王俊丽,孟双明,赵强,等.二氧化硅负载纳米Cu2O的制备及其光催化反应[J].实验技术与管理,2016(2):45-47.
[17]HAN L,XIONG P,BAI J,et al.Spontaneous formation and characterization of silica mesoporous crystal spheres with reverse multiply twinned polyhedral hollows[J].J Am Chem Soc,2011,133(16):6106-6109.
[18]LIN P L,ECKERSLEY R J,HALL E A H.Ultrabubble:a laminated ultrasound contrast agent with narrow size range[J].Adv Mater,2009,21(38/39):3949-3952.
[19]HU H,ZHOU H,LIANG J,et al.Facile synthesis of amino-functionalized hollow silica microspheres and their potential application for ultrasound imaging[J].J Colloid Interf Sci,2011,358(2):392-398.
[20]ZHAO B,ZHANG Y,TANG T,et al.Preparation of high-purity monodisperse silica microspheres by the sol-gel method coupled with polymerization-induced colloid aggregation[J].Particuology,2014,22(5):177-184.
[21]GALARNEAU A,IAPOCHELLA J,BONHOMME K,et al.Controlling the morphology of mesostructured silicas by pseudomorphic transformation:a route towards applications[J].Adv Funct Mater,2006,16(13):1657-1667.
[22]QI G,WANG Y,ESTEVEZ L,et al.Facile and scalable synthesis of monodispersed spherical capsules with a mesoporous shell[J].Chem Mater,2010,22(9):2693-2695.
[23]张以梅,周倩,陈胜利,等.单分散Si O2无孔微球比表面积标准物质的研制[J].化工学报,2009,60(5):1327-1331.
[24]LEE E P,CHEN J,YIN Y,et al.Pd-catalyzed growth of Pt nanoparticles or nanowires as dense coatings on polymeric and ceramic particulate supports[J].Adv Mater,2006,18(24):3271-3274.
[25]SUN L,ANNEN M J,LORENZANO-PORRAS F,et al.Synthesis of porous zirconia spheres for HPLC by polymerization-induced colloid aggregation(PICA)[J].J Colloid Interf Sci,1994,163(2):464-473.
[26]LI W,CHEN D,LI Z,et al.Nitrogen enriched mesoporous carbon spheres obtained by a facile method and its application for electrochemical capacitor[J].Electrochem Commun,2007,9(4):569-573.
[27]KIRKLAND J.Completely porous microspheres for chromatographic uses:US 3782075A[P].1974-1-1.
[28]ZHAO L,YU J G,GUO R,et al.Preparation and formation mechanisms of monodispersed mesoporous Si O2microspheres by the PICA method[J].Key Engineering Materials,2007,280-283:1153-1156.
[29]郭彬,刘辉,郝志显,等.原位合成的活性脲醛树脂作为模板剂制备二氧化硅介孔材料[J].化学学报,2006,64(8):756-760.
[30]HE J L,CHEN X H,ZHU W J,et al.Preparation of porous silica microspheres by polymerization-induced colloid aggregation method[J].Adv Mater Res,2014,898:132-135.
[31]盛凤军,林保平.PICA法合成介孔二氧化硅研究[J].化工时刊,2007,21(10):1-3.
[32]HE J L,CHEN X H,ZHU W J,et al.Synthesis of mesoporous silica microspheres by PICA and pseudomorphic transformation using silica fume as silica source[J].Materials Science Forum,2015,809:207-212.
[33]ST BER W,FINK A,BOHN E.Controlled growth of monodisperse silica spheres in the micron size range[J].J Colloid Interf Sci,1968,26(1):62-69.
[34]WATANABE R,YOKOI T,KOBAYASHI E,et al.Extension of size of monodisperse silica nanospheres and their well-ordered assembly[J].J Colloid Interf Sci,2011,360(1):1-7.
[35]CHANG S M,LEE M,KIM W S.Preparation of large monodispersed spherical silica particles using seed particle growth[J].J Colloid Interf Sci,2005,286(2):536-542.
[36]ZHAO B,TIAN C,ZHANG Y,et al.Size control of monodisperse nonporous silica particles by seed particle growth[J].Particuology,2011,9(3):314-317.
[37]CHEN S L,YUAN G,HU C T.Preparation and size determination of monodisperse silica microspheres for particle size certified reference materials[J].Powder Technol,2011,207(1):232-237.
[38]鲍艳,杨永强,马建中,等.氧化锌为模板制备中空二氧化硅微球及其对聚丙烯酸酯薄膜性能的影响[J].硅酸盐学报,2014,42(7):914-919.
[39]钱家盛,王旭华,章于川.介孔材料的制备及表征[J].中国粉体技术,2005,11(1):36-38.
[40]王吉会,董青.Si O2空心微球的制备与表征[J].材料开发与应用,2009,24(4):42-47.
[41]TUNGKANANURAK K,KERDSIRI S,JADSADAPATTARAKUL D,et al.Semi-micro preparation and characterization of mesoporous silica microspheres from rice husk sodium silicate using a non-ionic surfactant as a template:application in normal phase HPLC columns[J].Microchim Acta,2007,159(3/4):217-222.
[42]潘恩磊.反相悬浮聚合诱导微米级多孔Si O2微球的制备[J].中国陶瓷,2012(4):27-30.
[43]SMITHA S,SHAJESH P,MUKUNDAN P,et al.Synthesis of mesoporous hydrophobic silica microspheres through a modified sol-emulsion-gel process[J].J Sol-Gel Sci Techn,2008,48(3):356-361.
[44]刘帅,陈磊.以廉价硅源制备多孔二氧化硅微球及其孔结构的控制[J].硅酸盐通报,2012,31(3):669-674.
[45]刘世鹏.反相悬浮体系制备高纯多孔二氧化硅微球[J].硅酸盐通报,2014(9):2370-2374.
[46]ZHOKHOV A A,MASALOV V M,SUKHININA N S,et al.Photonic crystal microspheres[J].Opt Mater,2015,49:208-212.
[47]KARMAKAR B,DE G,GANGULI D.Dense silica microspheres from organic and inorganic acid hydrolysis of TEOS[J].J Non-cryst Solids,2000,272(2/3):119-126.