水处理试剂高铁酸钾的研究进展
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摘要
主要概述了次氯酸盐法、电解法、化学-电解法、微波辅助湿式氧化法等制备方法.分析了高铁酸钾在饮用水处理、工业废水处理、生物污泥处理、新兴微污染处理等方面的应用现状.为了实现工业化生产,促进高铁酸钾的应用,应研究推进绿色安全、简便节能、低成本的高铁酸钾制备方法,而在诸多制备方法中,电解法最具发展潜力.高铁酸钾与氧化剂、絮凝剂、微波及超声等的联用技术能弥补单独应用高铁酸钾的不足,有助于对难降解有机物的处理.
Method of hypochlorite, electrolysis, chemical-electrolytic method, microwave-assisted wet oxidation and other potassium ferrate preparation methods were introduced. This study summed up the potassium ferrate in drinking water treatment, industrial wastewater treatment, sludge treatment, new micro-pollution treatment and other aspects of the application. In order to achieve industrial production and promote the application of potassium ferrate, it is necessary to promote green, safe, and simple energy-saving, low-cost method for preparation of potassium ferrate.Among many preparation methods, most potential one is electrolysis. Potassium ferrate and oxidizing agent,flocculant, microwave and ultrasound combined with technology can make up for lack of individual application of potassium ferrate, contribute to refractory organics processing.
Method of hypochlorite, electrolysis, chemical-electrolytic method, microwave-assisted wet oxidation and other potassium ferrate preparation methods were introduced. This study summed up the potassium ferrate in drinking water treatment, industrial wastewater treatment, sludge treatment, new micro-pollution treatment and other aspects of the application. In order to achieve industrial production and promote the application of potassium ferrate, it is necessary to promote green, safe, and simple energy-saving, low-cost method for preparation of potassium ferrate.Among many preparation methods, most potential one is electrolysis. Potassium ferrate and oxidizing agent,flocculant, microwave and ultrasound combined with technology can make up for lack of individual application of potassium ferrate, contribute to refractory organics processing.
引文
[1]吉青杰,吴耀国,张文存,等.高铁酸钾的电解法制备、表征及在水处理中的应用[J].工业水处理,2005(4):12-16.
[2]王颖馨,周雪婷,卜洪龙,等.高铁酸钾的制备及其对水中As(III)、Pb(II)的去除效能研究[J].华南师范大学学报,2015,47(4):80-87.
[3]蔡庄红,贺素姣.连续法电解制备高铁酸钾及工艺研究[J].无机盐工业,2016,48(7):51-54.
[4]刘汝锋,刘婷灵,尚小琴,等.高铁酸钾的制备工艺研究与表征[J].化工进展,2013,32(8):1 902-1 904.
[5]刘亚男,薛罡,董娟,等.高铁酸钾降解苯胺的效能与机理[J].东华大学学报(自然科学版),2010,36(3):288-293.
[6]JIANG J Q.Advances in the development and application of ferrate(VI)for water and wastewater treatment[J].Journal of Chemical Technology&Biotechnology,2014.89(2):165-177.
[7]郑雪琴,许俊鸽.电化学制备高铁酸钾用于强化电动修复苯酚污染[J].福建工程学院学报,2014(4):342-347.
[8]尚宏利,田志锋.高铁酸钾电化学合成及其机理研究[J].表面技术,2007,36(6):53-55.
[9]单润涛,李党生,王海芳.多功能净水剂高铁酸钾的研究进展[J].无机盐工业,2011,43(4):11-14.
[10]陈同云,古绪鹏.化学-电解氧化法制备高铁酸钾的研究[J].水处理技术,2003,29(1):53-55.
[11]何则强,滕瑶,胡文勇,等.高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果[J].环境工程学报,2016,10(2):551-558.
[12]SHARMA V K.Ferrate(VI)and ferrate(V)oxidation of organic compounds:kinetics and mechanism[J].Coordination Chemistry Reviews,2013,257(2):495-510.
[13]ZHOU S Q,SHAO Y S,GAO N Y,et al.Removal of microcystis aeruginosa by potassium ferrate(VI):impacts on cells integrity,intracellular organic matter release and disinfection by-products formation[J].Chemical Engineering Journal,2014,251(5):304-309.
[14]马艳,高乃云,李聪,等.高铁酸钾去除饮用水源中盐酸四环素试验研究[J].土木建筑与环境工程,2010(4):108-112.
[15]HUANG J L,LIU G G,WANG F L,et al.Kinetics of indomethacin degradation by potassium ferrate in simulated disinfection of drinking water[J].Environmental Chemistry,2016,35(10):1 985-1 993.
[16]SHARMA V K,ZBORIL R,VARMA R S.Ferrates:greener oxidants with multimodal action in water treatment technologies[J].Accounts of Chemical Research,2015,48(2):182-191.
[17]YU D N,LI S,HE Q,et al.Degradation of phenanthrene by potassium ferrate(Ⅵ)characterized by fluorescence and GC-MS[J].Environmental Chemistry,2015,34(1):117-122.
[18]WANG C J,KLAMERTH N,MESSELE S A,et al.Comparison of UV/hydrogen peroxide,potassium ferrate(VI),and ozone in oxidizing the organic fraction of oil sands processaffected water(OSPW)[J].Water Research,2016,100:476-485.
[19]彭明江,吴菊珍.高铁酸钾处理多晶硅废水影响因素研究[J].工业水处理,2016,30(8):48-51.
[20]HAN Q,DONG W Y,WANG H J,et al.Effects of coexisting on decolonization of azo dye X-3B by ferrate(VI)and a comparative study between ferrate(VI)and potassium permanganate[J].Separation and Purification Technology,2013,108(16):74-82.
[21]耿士文,贾亚婷,蓝惠霞,等.相转移催化剂对高铁酸钾深度处理制浆中段废水的影响[J].中国造纸,2016,35(2):37-40.
[22]周建红,李军,令玉林,等.高铁酸钾和次氯酸钠联用处理苯酚废水研究[J].工业水处理,2013,33(10):27-29.
[23]张雄军,彭书传,朱承驻,等.高铁酸钾/254nm紫外光氧化降解水体中双酚A[J].环境化学,2014,14(4):643-648.
[24]何文丽,桂和荣,苑志华,等.改性粉煤灰联合高铁酸钾处理造纸废水的试验研究[J].环境科学与技术,2010,33(5):154-158.
[25]苗宗成,王蕾,霍小平,等.高铁酸钾/聚合硫酸铁在制革废水处理中的应用[J].工业水处理,2013,45(2):45-47.
[26]LAN B Y,WANG Y X,WANG X,et al.Aqueous arsenic(As)and antimony(Sb)removal by potassium ferrate[J].Chemical Engineering Journal,2016,292:389-397.
[27]张海燕,张盼月,曾光明,等.高铁酸钾预氧化一三氯化铁混凝去除水中As3+[J].化工环保,2006,28(6):495-499.
[28]樊鹏跃,崔建国,李玲.p H对高铁酸钾辅助聚合氯化铝去除废水中Cu2+的影响研究[J].环境污染与防治,2014,36(3):78-81.
[29]ZHANG X H,LEI H Y,CHEN K,et al.Effect of potassium ferrate(K2Fe O4)on sludge dewaterability under different p Hconditions[J].Chemical Engineering Journal,2012,210:467-474.
[30]ZHANG W J,CAO B D,WANG D S,et al.Variations in distribution and composition of extracellular polymeric substances(EPS)of biological sludge under potassium ferrate conditioning:effects of p H and ferrate dosage[J].Biochemical Engineering Journal,2016,106:37-47.
[31]WU C,JIN L Y,ZHANG P Y,et al.Effects of potassium ferrate oxidation on sludge disintegration,dewaterability and anaerobic biodegradation[J].International Biodeterioration&Biodegradation,2015,102:137-142.
[32]林颐,宁寻安,温炜彬,等.高铁酸钾-微波耦合对印染污泥脱水性能的影响研究[J].环境科学学报,2014,34(7):1 776-1 780.
[33]冯银芳,宁寻安,巫俊楫,等.超声耦合高铁酸钾对印染污泥脱水性能的影响[J].环境工程学报,2016,10(7):3 787-3 792.
[34]马艳,高乃云,祝淑敏,等.高铁酸钾去除水中磺胺嘧啶[J].同济大学学报(自然科学版),2013,41(1):106-109.
[35]JIANG J Q,ZHOU Z W,PAHL O.Preliminary study of ciprofloxacin(cip)removal by potassium ferrate(VI)[J].Separation and Purification Technology,2012,88(2):95-98.
[36]WANG Y L,LIU H J,LIU G G,et al.Oxidation of diclofenac by potassium ferrate(VI):reaction kinetics and toxicity evaluation[J].Science of The Total Environment,2015,506:252-258.
[37]吴小倩,汪永辉,刘振鸿,等.高铁酸钾深度处理垃圾渗滤液的试验研究[J].中国给水排水,2008,24(5):57-60.
[38]张洋,罗志勇,屈勇军,等.高铁酸钾预处理垃圾渗滤液[J].环境工程学报,2014,8(6):2 451-2 455.
[39]肖瑜,章波,苏诚,等.高铁酸钾氧化-沸石吸附联合处理垃圾渗滤液[J].桂林理工大学学报,2011,31(1):123-127.
[2]王颖馨,周雪婷,卜洪龙,等.高铁酸钾的制备及其对水中As(III)、Pb(II)的去除效能研究[J].华南师范大学学报,2015,47(4):80-87.
[3]蔡庄红,贺素姣.连续法电解制备高铁酸钾及工艺研究[J].无机盐工业,2016,48(7):51-54.
[4]刘汝锋,刘婷灵,尚小琴,等.高铁酸钾的制备工艺研究与表征[J].化工进展,2013,32(8):1 902-1 904.
[5]刘亚男,薛罡,董娟,等.高铁酸钾降解苯胺的效能与机理[J].东华大学学报(自然科学版),2010,36(3):288-293.
[6]JIANG J Q.Advances in the development and application of ferrate(VI)for water and wastewater treatment[J].Journal of Chemical Technology&Biotechnology,2014.89(2):165-177.
[7]郑雪琴,许俊鸽.电化学制备高铁酸钾用于强化电动修复苯酚污染[J].福建工程学院学报,2014(4):342-347.
[8]尚宏利,田志锋.高铁酸钾电化学合成及其机理研究[J].表面技术,2007,36(6):53-55.
[9]单润涛,李党生,王海芳.多功能净水剂高铁酸钾的研究进展[J].无机盐工业,2011,43(4):11-14.
[10]陈同云,古绪鹏.化学-电解氧化法制备高铁酸钾的研究[J].水处理技术,2003,29(1):53-55.
[11]何则强,滕瑶,胡文勇,等.高铁酸钾的超声辅助化学合成及其对餐厨垃圾渗滤液的处理效果[J].环境工程学报,2016,10(2):551-558.
[12]SHARMA V K.Ferrate(VI)and ferrate(V)oxidation of organic compounds:kinetics and mechanism[J].Coordination Chemistry Reviews,2013,257(2):495-510.
[13]ZHOU S Q,SHAO Y S,GAO N Y,et al.Removal of microcystis aeruginosa by potassium ferrate(VI):impacts on cells integrity,intracellular organic matter release and disinfection by-products formation[J].Chemical Engineering Journal,2014,251(5):304-309.
[14]马艳,高乃云,李聪,等.高铁酸钾去除饮用水源中盐酸四环素试验研究[J].土木建筑与环境工程,2010(4):108-112.
[15]HUANG J L,LIU G G,WANG F L,et al.Kinetics of indomethacin degradation by potassium ferrate in simulated disinfection of drinking water[J].Environmental Chemistry,2016,35(10):1 985-1 993.
[16]SHARMA V K,ZBORIL R,VARMA R S.Ferrates:greener oxidants with multimodal action in water treatment technologies[J].Accounts of Chemical Research,2015,48(2):182-191.
[17]YU D N,LI S,HE Q,et al.Degradation of phenanthrene by potassium ferrate(Ⅵ)characterized by fluorescence and GC-MS[J].Environmental Chemistry,2015,34(1):117-122.
[18]WANG C J,KLAMERTH N,MESSELE S A,et al.Comparison of UV/hydrogen peroxide,potassium ferrate(VI),and ozone in oxidizing the organic fraction of oil sands processaffected water(OSPW)[J].Water Research,2016,100:476-485.
[19]彭明江,吴菊珍.高铁酸钾处理多晶硅废水影响因素研究[J].工业水处理,2016,30(8):48-51.
[20]HAN Q,DONG W Y,WANG H J,et al.Effects of coexisting on decolonization of azo dye X-3B by ferrate(VI)and a comparative study between ferrate(VI)and potassium permanganate[J].Separation and Purification Technology,2013,108(16):74-82.
[21]耿士文,贾亚婷,蓝惠霞,等.相转移催化剂对高铁酸钾深度处理制浆中段废水的影响[J].中国造纸,2016,35(2):37-40.
[22]周建红,李军,令玉林,等.高铁酸钾和次氯酸钠联用处理苯酚废水研究[J].工业水处理,2013,33(10):27-29.
[23]张雄军,彭书传,朱承驻,等.高铁酸钾/254nm紫外光氧化降解水体中双酚A[J].环境化学,2014,14(4):643-648.
[24]何文丽,桂和荣,苑志华,等.改性粉煤灰联合高铁酸钾处理造纸废水的试验研究[J].环境科学与技术,2010,33(5):154-158.
[25]苗宗成,王蕾,霍小平,等.高铁酸钾/聚合硫酸铁在制革废水处理中的应用[J].工业水处理,2013,45(2):45-47.
[26]LAN B Y,WANG Y X,WANG X,et al.Aqueous arsenic(As)and antimony(Sb)removal by potassium ferrate[J].Chemical Engineering Journal,2016,292:389-397.
[27]张海燕,张盼月,曾光明,等.高铁酸钾预氧化一三氯化铁混凝去除水中As3+[J].化工环保,2006,28(6):495-499.
[28]樊鹏跃,崔建国,李玲.p H对高铁酸钾辅助聚合氯化铝去除废水中Cu2+的影响研究[J].环境污染与防治,2014,36(3):78-81.
[29]ZHANG X H,LEI H Y,CHEN K,et al.Effect of potassium ferrate(K2Fe O4)on sludge dewaterability under different p Hconditions[J].Chemical Engineering Journal,2012,210:467-474.
[30]ZHANG W J,CAO B D,WANG D S,et al.Variations in distribution and composition of extracellular polymeric substances(EPS)of biological sludge under potassium ferrate conditioning:effects of p H and ferrate dosage[J].Biochemical Engineering Journal,2016,106:37-47.
[31]WU C,JIN L Y,ZHANG P Y,et al.Effects of potassium ferrate oxidation on sludge disintegration,dewaterability and anaerobic biodegradation[J].International Biodeterioration&Biodegradation,2015,102:137-142.
[32]林颐,宁寻安,温炜彬,等.高铁酸钾-微波耦合对印染污泥脱水性能的影响研究[J].环境科学学报,2014,34(7):1 776-1 780.
[33]冯银芳,宁寻安,巫俊楫,等.超声耦合高铁酸钾对印染污泥脱水性能的影响[J].环境工程学报,2016,10(7):3 787-3 792.
[34]马艳,高乃云,祝淑敏,等.高铁酸钾去除水中磺胺嘧啶[J].同济大学学报(自然科学版),2013,41(1):106-109.
[35]JIANG J Q,ZHOU Z W,PAHL O.Preliminary study of ciprofloxacin(cip)removal by potassium ferrate(VI)[J].Separation and Purification Technology,2012,88(2):95-98.
[36]WANG Y L,LIU H J,LIU G G,et al.Oxidation of diclofenac by potassium ferrate(VI):reaction kinetics and toxicity evaluation[J].Science of The Total Environment,2015,506:252-258.
[37]吴小倩,汪永辉,刘振鸿,等.高铁酸钾深度处理垃圾渗滤液的试验研究[J].中国给水排水,2008,24(5):57-60.
[38]张洋,罗志勇,屈勇军,等.高铁酸钾预处理垃圾渗滤液[J].环境工程学报,2014,8(6):2 451-2 455.
[39]肖瑜,章波,苏诚,等.高铁酸钾氧化-沸石吸附联合处理垃圾渗滤液[J].桂林理工大学学报,2011,31(1):123-127.