双相不锈钢成分、性能及析出相分析
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摘要
叙述了常用的超级双相不锈钢的成分、耐蚀性和应用,分析了不同种析出相、有害相、点蚀当量值(PRE)及焊接对双相不锈钢组织和性能的影响,得出通过控制合金化成分,调整点蚀当量值,编制合理的热处理工艺,严格控制有害相析出,使两相比含量比值接近1,可获得良好耐蚀性、高强度和耐磨性的双相不锈钢。
The composition, corrosion resistance and application of normal and super duplex stainless steels have been summarized, and different kinds of precipitated phases, harmful phases, pitting resistant equivalent( PRE) and effect of welding on structure and properties of duplex stainless steel are analyzed.It is obtained that with controlling alloy chemical composition adjusting pitting resistant equivalent value; scheduling reasonable heat treatment process to control the precipitation of harmful phases and the ratio of dual phase content near to 1, it is able to get better corrosion, higher strength and wear-resistant duplex stainless steel.
The composition, corrosion resistance and application of normal and super duplex stainless steels have been summarized, and different kinds of precipitated phases, harmful phases, pitting resistant equivalent( PRE) and effect of welding on structure and properties of duplex stainless steel are analyzed.It is obtained that with controlling alloy chemical composition adjusting pitting resistant equivalent value; scheduling reasonable heat treatment process to control the precipitation of harmful phases and the ratio of dual phase content near to 1, it is able to get better corrosion, higher strength and wear-resistant duplex stainless steel.
引文
[1]吴玖.双相不锈钢[M].北京:冶金工业出版社,2000.
[2]孙长庆.双相不锈钢的发展、性能与应用(二)[J].化工设备设计,1998(6):48-51.
[3]J Charles,P Chemelle,胡锦程,等.双相不锈钢的发展现状及未来市场趋势[J].世界钢铁,2011,11(6):1-22.
[4]吴玖,刘尔华.国内外双相不锈钢材料和应用的发展[C].2009年第三届中国国际双相不锈钢大会论文集,太原,2009.
[5]高娃,罗建民,杨建君.双相不锈钢的研究进展及其应用[J].兵器材料科学与工程,2005(3):61-64.
[6]王兰喜.国产超级双相不锈钢应用浅析[J].石油化工设备技术,2017,38(2):54-58
[7]仇潞.热输人对超低碳双相不锈钢焊缝性能的影响[J].焊接技术,2018,47(7):27-29.
[8]张鹏,陈晓秋,尚峰,等.双相不锈钢成形技术研究进展[J].热加工工艺,2018,47(15):14-17.
[9]曾路,吴腾,吴润,等.冷轧高强双相钢中残留奥氏体的作用[J].金属热处理,2018,43(10)1-4.
[10]蔡珍,汪水泽,徐进桥,等.短流程热轧双相钢的生产现状及发展趋势[J].轧钢,2018,35(2):59-64.
[11]SA-240/SA-240M,ASME BPVC-II A 2015 Ferrous Material Specifications[M]. New York. The American Society of Mechanical Engineers. 2015:373.
[12]SA-789/SA-789M,ASME BPVC-II A 2015 Ferrous Material Specifications[M]. New York. The American Society of Mechanical Engineers. 2015:1417.
[13]晃代义.核电用2205双相不锈钢组织与性能的研究[D].烟台:烟台大学(硕士学位论文),2013:5,10-15.
[14]胡育瑞.特级双相不锈钢耐冲刷腐蚀性能的研究[D].福州:福州大学(硕士学位论文),2016:6-13.
[15] Nilsson J 0. Super Duplex Stainless Steels[J]. Materials Science and Technology, 1992,8(8):685-700.
[16]李均.新型资源节约型高Mn-N双相不锈钢的制备、结构及性能研究[D].上海:上海大学(博士学位论文),2010:12-16.
[17]吴天海.2205双相不锈钢中σ相的析出及其对组织性能的影响[D].沈阳:东北大学(硕士学位论文),2013:17-19.
[18]杨银辉,严彪,郑鑫.双相不锈钢高温时效σ相析出行为研究进展[J].材料导报,2011,25(19):105-109.
[19]Sieurin H,Sandstrom R. Engineering Fracture Mechanics[M],2006,377-390.
[20]Wiesner C S. Proceedings of the Duplex Stainless Steel.[C] 1997-Fifth World Conference Maastricht. Netherlands,1997.10.979-990.
[21] Han Y S and Hong S H. The Effects of Thermo-mechanical Treatments on Superplasticity of Fe-24Cr-7Ni-3Mo-0.14N Duplex Stainless Steel[J]. Scripta Materialia,1997,36:557-63.
[22]Sagradi M, Pulino-Sagradi D and Medrano R E. The Effect of the Microstructure on the Superplasticity of a Duplex Stainless Steel[J]. Acto Materialia, 1998,46:3857-3862.
[23]Lu-X C,Li S and Jiang X. Effects ofσPhase in Stainless Steels on Corrosive Wear Dehavior in Sulfuric acid[J]. Wear.2001,251:1234-8.
[24]Escriba D M,Materna-Morris E,Plaut R L. Chi-phas Precipitation in a Duplex Stainless Steel, Materials Charaterization[J]. 2009,60:1214-1219.
[25] Joanna Michalska,Maria Sozariska. Qualitative and Quantitative Analysis ofσandχPhases in 2205 Duplex Stainless Steel[J]. Materials Characterization,2006,56:355-362.
[26] Dominguez-Aguilar M A,Newman R C. Detection of Deleterious Phases in Duplex Stainless Steel by Weak Galvanostatic Polarization in Alkaline Solution[J]. Corrosion Science,2006,48:2560-2576.
[27]Akisanya A R,Obi U and Neill C. Renton,Effect of Ageing on Phase Evolution and Mechanical Properties of a High Tungsten Super-duplex Stainless Ssteel[J]. Materials Science and Engineering. A 2012,535:281-289.
[28] Hochmann J A, Desestret P and Jolly, et al. Properties of Ductile Ferritic Stainless Steels with high Chromium Content and Duplex Stainless Steel[J]. Metal Corrosion Industries. 1974,49(591):390-414.
[29]陆卫东,乐平,刘雪燕,等.00Cr22Ni5Mo3N双相不锈钢的组织分析[J].热处理,2008(1):37-46.
[30]Kuroda T,Matsuda F. Role of Secondary Austenite on Corrosion and Stress Corrosion Cracking of Sensitized Duplex Stainless Steel Weldments[J]. Transactions of JWRI,1994,23(2):205-211.
[31]Hertzman S,Roberts W,Lindenmo M. Micro Structure and Properties of Nitrogen Alloyed Duplex Stainless Steel Weld Metal[J]. Duplex Stainless Steels. The Hague. Netherlands, 1986:257-267.
[32]张丽华.经济型双相不锈钢2101的腐蚀行为研究[D].上海:复旦大学(博士学位论文),2010.
[33]Newman R C,Shahrabi T. The Effect of Alloyed Nitrogen or Dissolved Nitrateions on the Anodic Behaviour of Austenitic Stainless Steel in Hydroelectric Acid[J]. Corrosion Science, 1987,27(8):827-838.
[34]Nilsson J 0,Kangas P. Mechanical Properties. Micro Structural Stability and Kinetics of(alpha)-phase Formation in 29Cr-6Ni-2Mo-0.38N Super-duplex Stainless Steel[J]. Metall Urgicaland Materials-transactions A,2000;31A(1):35-45.
[35]Bhattacharya A,Singh P M. Role of Micro-structure on the Corrosion Susceptibility of UNS S32101 Duplex Stainless Steel[J]. Corrosion,2008,64(6):532-540.
[36]刘秀晨,安成强.金属腐蚀学[M].北京:国防工业出版社,2002.
[37]谭华.双相不锈钢焊缝组织演变与腐蚀行为研究[D].上海:复旦大学(博士学位论文),2012.
[38] Lopes B L S. Nfluence of MIG/MAG Welding Process on Mechanical and Pitting Corrosion Behaviors on the Super-Duplex Stainless Steel SAF 2507 Welded Joints[J]. Materials Sciences and Applications.2018.9,228-245.
[2]孙长庆.双相不锈钢的发展、性能与应用(二)[J].化工设备设计,1998(6):48-51.
[3]J Charles,P Chemelle,胡锦程,等.双相不锈钢的发展现状及未来市场趋势[J].世界钢铁,2011,11(6):1-22.
[4]吴玖,刘尔华.国内外双相不锈钢材料和应用的发展[C].2009年第三届中国国际双相不锈钢大会论文集,太原,2009.
[5]高娃,罗建民,杨建君.双相不锈钢的研究进展及其应用[J].兵器材料科学与工程,2005(3):61-64.
[6]王兰喜.国产超级双相不锈钢应用浅析[J].石油化工设备技术,2017,38(2):54-58
[7]仇潞.热输人对超低碳双相不锈钢焊缝性能的影响[J].焊接技术,2018,47(7):27-29.
[8]张鹏,陈晓秋,尚峰,等.双相不锈钢成形技术研究进展[J].热加工工艺,2018,47(15):14-17.
[9]曾路,吴腾,吴润,等.冷轧高强双相钢中残留奥氏体的作用[J].金属热处理,2018,43(10)1-4.
[10]蔡珍,汪水泽,徐进桥,等.短流程热轧双相钢的生产现状及发展趋势[J].轧钢,2018,35(2):59-64.
[11]SA-240/SA-240M,ASME BPVC-II A 2015 Ferrous Material Specifications[M]. New York. The American Society of Mechanical Engineers. 2015:373.
[12]SA-789/SA-789M,ASME BPVC-II A 2015 Ferrous Material Specifications[M]. New York. The American Society of Mechanical Engineers. 2015:1417.
[13]晃代义.核电用2205双相不锈钢组织与性能的研究[D].烟台:烟台大学(硕士学位论文),2013:5,10-15.
[14]胡育瑞.特级双相不锈钢耐冲刷腐蚀性能的研究[D].福州:福州大学(硕士学位论文),2016:6-13.
[15] Nilsson J 0. Super Duplex Stainless Steels[J]. Materials Science and Technology, 1992,8(8):685-700.
[16]李均.新型资源节约型高Mn-N双相不锈钢的制备、结构及性能研究[D].上海:上海大学(博士学位论文),2010:12-16.
[17]吴天海.2205双相不锈钢中σ相的析出及其对组织性能的影响[D].沈阳:东北大学(硕士学位论文),2013:17-19.
[18]杨银辉,严彪,郑鑫.双相不锈钢高温时效σ相析出行为研究进展[J].材料导报,2011,25(19):105-109.
[19]Sieurin H,Sandstrom R. Engineering Fracture Mechanics[M],2006,377-390.
[20]Wiesner C S. Proceedings of the Duplex Stainless Steel.[C] 1997-Fifth World Conference Maastricht. Netherlands,1997.10.979-990.
[21] Han Y S and Hong S H. The Effects of Thermo-mechanical Treatments on Superplasticity of Fe-24Cr-7Ni-3Mo-0.14N Duplex Stainless Steel[J]. Scripta Materialia,1997,36:557-63.
[22]Sagradi M, Pulino-Sagradi D and Medrano R E. The Effect of the Microstructure on the Superplasticity of a Duplex Stainless Steel[J]. Acto Materialia, 1998,46:3857-3862.
[23]Lu-X C,Li S and Jiang X. Effects ofσPhase in Stainless Steels on Corrosive Wear Dehavior in Sulfuric acid[J]. Wear.2001,251:1234-8.
[24]Escriba D M,Materna-Morris E,Plaut R L. Chi-phas Precipitation in a Duplex Stainless Steel, Materials Charaterization[J]. 2009,60:1214-1219.
[25] Joanna Michalska,Maria Sozariska. Qualitative and Quantitative Analysis ofσandχPhases in 2205 Duplex Stainless Steel[J]. Materials Characterization,2006,56:355-362.
[26] Dominguez-Aguilar M A,Newman R C. Detection of Deleterious Phases in Duplex Stainless Steel by Weak Galvanostatic Polarization in Alkaline Solution[J]. Corrosion Science,2006,48:2560-2576.
[27]Akisanya A R,Obi U and Neill C. Renton,Effect of Ageing on Phase Evolution and Mechanical Properties of a High Tungsten Super-duplex Stainless Ssteel[J]. Materials Science and Engineering. A 2012,535:281-289.
[28] Hochmann J A, Desestret P and Jolly, et al. Properties of Ductile Ferritic Stainless Steels with high Chromium Content and Duplex Stainless Steel[J]. Metal Corrosion Industries. 1974,49(591):390-414.
[29]陆卫东,乐平,刘雪燕,等.00Cr22Ni5Mo3N双相不锈钢的组织分析[J].热处理,2008(1):37-46.
[30]Kuroda T,Matsuda F. Role of Secondary Austenite on Corrosion and Stress Corrosion Cracking of Sensitized Duplex Stainless Steel Weldments[J]. Transactions of JWRI,1994,23(2):205-211.
[31]Hertzman S,Roberts W,Lindenmo M. Micro Structure and Properties of Nitrogen Alloyed Duplex Stainless Steel Weld Metal[J]. Duplex Stainless Steels. The Hague. Netherlands, 1986:257-267.
[32]张丽华.经济型双相不锈钢2101的腐蚀行为研究[D].上海:复旦大学(博士学位论文),2010.
[33]Newman R C,Shahrabi T. The Effect of Alloyed Nitrogen or Dissolved Nitrateions on the Anodic Behaviour of Austenitic Stainless Steel in Hydroelectric Acid[J]. Corrosion Science, 1987,27(8):827-838.
[34]Nilsson J 0,Kangas P. Mechanical Properties. Micro Structural Stability and Kinetics of(alpha)-phase Formation in 29Cr-6Ni-2Mo-0.38N Super-duplex Stainless Steel[J]. Metall Urgicaland Materials-transactions A,2000;31A(1):35-45.
[35]Bhattacharya A,Singh P M. Role of Micro-structure on the Corrosion Susceptibility of UNS S32101 Duplex Stainless Steel[J]. Corrosion,2008,64(6):532-540.
[36]刘秀晨,安成强.金属腐蚀学[M].北京:国防工业出版社,2002.
[37]谭华.双相不锈钢焊缝组织演变与腐蚀行为研究[D].上海:复旦大学(博士学位论文),2012.
[38] Lopes B L S. Nfluence of MIG/MAG Welding Process on Mechanical and Pitting Corrosion Behaviors on the Super-Duplex Stainless Steel SAF 2507 Welded Joints[J]. Materials Sciences and Applications.2018.9,228-245.