过硫酸盐活化技术降解污染物的研究进展
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摘要
简介了过硫酸盐的物理和化学性质,重点介绍了过硫酸盐的活化技术,如过渡金属离子活化、过渡金属活化、碳活化、热活化等,并对活化机理及活化过硫酸盐在有机物降解中的应用进行了简述,提出了过硫酸盐活化技术未来的主要研究方向以及技术改进方向。
We briefly introduce physical and chemical properties of persulfate( PS),and emphatically introduce the PS activation technology,including transition metal ions activation,transition metal activation,carbon activation,and thermal activation,etc.Meanwhile,we summarize the activation mechanism and the application of activated PS in the degradation of organic matter,and propose the main research directions and the technical improvement directions of PS activation technology in the future.
We briefly introduce physical and chemical properties of persulfate( PS),and emphatically introduce the PS activation technology,including transition metal ions activation,transition metal activation,carbon activation,and thermal activation,etc.Meanwhile,we summarize the activation mechanism and the application of activated PS in the degradation of organic matter,and propose the main research directions and the technical improvement directions of PS activation technology in the future.
引文
[1]PERA-TITUS M,GARCIA-MOLINA V,BAOS M A,et al.Degradation of chlorophenols by means of advanced oxidation processes:a general review[J].Applied Catalysis B:Environmental,2004,47(4):219-256.
[2]SONNTAG C V,GUNTEN U V,SONNTAG C V,et al.Chemistry of Ozone in Water and Wastewater Treatment:from Basic Principles to Applications[M].Iwa Publishing,2012:6-10.
[3]SPELLMAN F R.Choosing Disinfection Alternatives for Water/Wastewater Treatment Plants[M].CRC Press,1999:1256-1257.
[4]LUO C W,MA J,JIANG J,et al.Simulation and comparative study on the oxidation kinetics of atrazine by UV/H2O2,UV/HSO-5and UV/S2O2-8[J].Water Research,2015,80:99-108.
[5]FAN G P,CANG L,FANG G D,et al.Electrokinetic delivery of persulfate to remediate PCBs polluted soils:effect of injection spot[J].Chemosphere,2014,117(1):410-418.
[6]YEN C H,CHEN K F,KAO C M,et al.Application of persulfate to remediate petroleum hydrocarbon-contaminated soil:feasibility and comparison with common oxidants[J].Journal of Hazardous Materials,2011,186(2/3):2097-2102.
[7]SELVAM K,MURUGANANDHAM M,MUTHUVEL I,et al.The influence of inorganic oxidants and metal ions on semiconductor sensitized photodegradation of 4-fluorophenol[J].Chemical Engineering Journal,2007,128(1):51-57.
[8]SHAH N S,HE X X,KHAN H M,et al.Efficient removal of endosulfan from aqueous solution by UV-C/peroxides:a comparative study[J].Journal of Hazardous Materials,2013,263(Part 2):584-592.
[9]DENG Y,EZYSKE C M.Sulfate radical-advanced oxidation process(SR-AOP)for simultaneous removal of refractory organic contaminants and ammonia in landfill leachate[J].Water Research,2011,45(18):6189-6194.
[10]AHMED S,RASUL M G,MARTENS W N,et al.Heterogeneous photocatalytic degradation of phenols in wastewater:a review on current status and developments[J].Desalination,2010,261(1/2):3-18.
[11]ZHANG H,FU H,ZHANG D B.Degradation of C.I.Acid Orange 7 by ultrasound enhanced heterogeneous Fenton-like process[J].Journal of Hazardous Materials,2009,172(2/3):654-660.
[12]JI Y F,XIE W P,FAN Y,et al.Degradation of trimethoprim by thermo-activated persulfate oxidation:reaction kinetics and transformation mechanisms[J].Chemical Engineering Journal,2016,286:16-24.
[13]ZHANG R,SUN P,BOYER T H,et al.Degradation of pharmaceuticals and metabolite in synthetic human urine by UV,UV/H2O2,and UV/PDS[J].Environmental Science&Technology,2015,49(5):3056-3066.
[14]CHEN W S,SU Y C.Removal of dinitrotoluenes in wastewater by sono-activated persulfate[J].Ultrasonics Sonochemistry,2012,19(4):921-927.
[15]CRIQUET J,LEITNER N K V.Electron beam irradiation of aqueous solution of persulfate ions[J].Chemical Engineering Journal,2011,169(1/2/3):258-262.
[16]LEI Y,CHEN C S,TU Y J,et al.Heterogeneous degradation of organic pollutants by persulfate activated by Cu O-Fe3O4:mechanism,stability,and effects of p H and bicarbonate ions[J].Environmental Science&Technology,2015,49(11):6838-6845.
[17]ZHAO L,HOU H,FUJII A,et al.Degradation of 1,4-dioxane in water with heat-and Fe2+-activated persulfate oxidation[J].Environmental Science&Pollution Research,2014,21(12):7457-7465.
[18]KOLTHOFF I M,MILLER I K.The chemistry of persulfate.Ⅰ.the kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium[J].Journal of the American Chemical Society,1951,73(7):1-30.
[19]BEHRMAN E J,DEAN D H.Sodium peroxydisulfate is a stable and cheap substitute for ammonium peroxydisulfate(persulfate)in polyacrylamide gel electrophoresis[J].Journal of Chromatography B:Biomedical Sciences&Applications,1999,723(1/2):325-326.
[20]BAJPAI P.Chapter Seven:Peroxyacids Bleaching//Environmentally Benign Approaches for Pulp Bleaching[M].Elsevier Science Ltd.,2012:167-188.
[21]PEYTON G R.The free-radical chemistry of persulfate-based total organic carbon analyzers[J].Marine Chemistry,1993,41(1/2/3):91-103.
[22]XU X R,LI X Z.Degradation of azo Dye Orange G in aqueous solutions by persulfate with ferrous ion[J].Separation&Purification Technology,2010,72(1):105-111.
[23]LIANG C,BRUELL C J,MARLEY M C,et al.Persulfate oxidation for in situ remediation of TCE.Ⅱ.activated by chelated ferrous ion[J].Chemosphere,2004,55(9):1225-1233.
[24]RASTOGI A,AL-ABED S R,DIONYSIOU D D.Effect of inorganic,synthetic and naturally occurring chelating agents on Fe(Ⅱ)mediated advanced oxidation of chlorophenols[J].Water Research,2009,43(3):684-694.
[25]ZHANG J,CHEN M Y,ZHU L.Activation of persulfate by Co3O4nanoparticles for Orange G degradation[J].RSC Advances,2015,6(1):758-768.
[26]RHADFI T,PIQUEMAL J Y,SICARD L,et al.Polyol-made Mn3O4,nanocrystals as efficient Fenton-like catalysts[J].Applied Catalysis A:General,2010,386(1/2):132-139.
[27]LI Y,LIU L D,LU L,et al.Efficient oxidation of phenol by persulfate using manganite as a catalyst[J].Journal of Molecular Catalysis A:Chemical,2016,411:264-271.
[28]FURUKAWA Y,KIM J W,WATKINS J,et al.Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron[J].Environmental Science&Technology,2002,36(24):5469-5475.
[29]OH S Y,KIM H W,PARK J M,et al.Oxidation of polyvinyl alcohol by persulfate activated with heat,Fe2+,and zero-valent iron[J].Journal of Hazardous Materials,2009,168(1):346-351.
[30]FANG G D,DIONYSIOU D D,AL-ABED S R,et al.Superoxide radical driving the activation of persulfate by magnetite nanoparticles:implications for the degradation of PCBs[J].Applied Catalysis B:Environmental,2013,129:325-332.
[31]YAN J,LEI M,ZHU L,et al.Degradation of sulfamonomethoxine with Fe3O4magnetic nanoparticles as heterogeneous activator of persulfate[J].Journal of Hazardous Materials,2011,186(2/3):1398-1404.
[32]LEE H,LEE H J,JEONG J,et al.Activation of persulfates by carbon nanotubes:oxidation of organic compounds by nonradical mechanism[J].Chemical Engineering Journal,2015,266:28-33.
[33]DUAN X G,SUN H Q,KANG J,et al.Insights into heterogeneous catalysis of persulfate activation on dimensional-structured nanocarbons[J].ACS Catalysis,2015,5:4629-4636.
[34]史宸菲,李雨濛,冯瑞杰,等.蓝藻生物炭的制备及对过硫酸盐的活化效能[J].生态与农村环境学报,2017,33(12):1140-1145.SHI C F,LI Y M,FENG R J,et al.Preparation of biochar from cyanobacteria and function of the biochar for persulfate activation[J].Rural Eco-Environment,2017,33(12):1140-1145.
[35]刘子乐,曾泽泉,杨洁杨,等.表面改性活性炭活化过硫酸盐降解苯酚[J].高等学校化学学报,2017,38(7):1241-1248.LIU Z L,ZENG Z Q,YANG J Y,et al.Degradation of phenol with persulfate activated by surface modified activated carbon[J].Chemical Research in Chinese Universities,2017,38(7):1241-1248.
[36]荣亚运,师林丽,张晨,等.热活化过硫酸盐氧化去除木质素降解产物[J].化工学报,2016,67(6):2618-2624.RONG Y Y,SHI L L,ZHANG C,et al.Oxidation of lignin-degradation products by heat-activated persulfate[J].Journal of Chemical Industry and Engineering(China),2016,67(6):2618-2624.
[37]朱思瑞,高乃云,鲁仙,等.热激活过硫酸盐氧化降解水中双酚A[J].中国环境科学,2017,37(1):188-194.ZHU S R,GAO N Y,LU X,et al.Degradation of bisphenol A in aqueous solution by thermally activated sulfate oxidation[J].China Environmental Science,2017,37(1):188-194.
[38]马京帅,吕文英,刘国光,等.热活化过硫酸盐降解水中的普萘洛尔[J].环境化学,2017,36(2):221-228.MA J S,LV W Y,LIU G G,et al.Degradation of propranolol in aqueous solution by heat-activated persulfate[J].Environmental Chemistry,2017,36(2):221-228.
[2]SONNTAG C V,GUNTEN U V,SONNTAG C V,et al.Chemistry of Ozone in Water and Wastewater Treatment:from Basic Principles to Applications[M].Iwa Publishing,2012:6-10.
[3]SPELLMAN F R.Choosing Disinfection Alternatives for Water/Wastewater Treatment Plants[M].CRC Press,1999:1256-1257.
[4]LUO C W,MA J,JIANG J,et al.Simulation and comparative study on the oxidation kinetics of atrazine by UV/H2O2,UV/HSO-5and UV/S2O2-8[J].Water Research,2015,80:99-108.
[5]FAN G P,CANG L,FANG G D,et al.Electrokinetic delivery of persulfate to remediate PCBs polluted soils:effect of injection spot[J].Chemosphere,2014,117(1):410-418.
[6]YEN C H,CHEN K F,KAO C M,et al.Application of persulfate to remediate petroleum hydrocarbon-contaminated soil:feasibility and comparison with common oxidants[J].Journal of Hazardous Materials,2011,186(2/3):2097-2102.
[7]SELVAM K,MURUGANANDHAM M,MUTHUVEL I,et al.The influence of inorganic oxidants and metal ions on semiconductor sensitized photodegradation of 4-fluorophenol[J].Chemical Engineering Journal,2007,128(1):51-57.
[8]SHAH N S,HE X X,KHAN H M,et al.Efficient removal of endosulfan from aqueous solution by UV-C/peroxides:a comparative study[J].Journal of Hazardous Materials,2013,263(Part 2):584-592.
[9]DENG Y,EZYSKE C M.Sulfate radical-advanced oxidation process(SR-AOP)for simultaneous removal of refractory organic contaminants and ammonia in landfill leachate[J].Water Research,2011,45(18):6189-6194.
[10]AHMED S,RASUL M G,MARTENS W N,et al.Heterogeneous photocatalytic degradation of phenols in wastewater:a review on current status and developments[J].Desalination,2010,261(1/2):3-18.
[11]ZHANG H,FU H,ZHANG D B.Degradation of C.I.Acid Orange 7 by ultrasound enhanced heterogeneous Fenton-like process[J].Journal of Hazardous Materials,2009,172(2/3):654-660.
[12]JI Y F,XIE W P,FAN Y,et al.Degradation of trimethoprim by thermo-activated persulfate oxidation:reaction kinetics and transformation mechanisms[J].Chemical Engineering Journal,2016,286:16-24.
[13]ZHANG R,SUN P,BOYER T H,et al.Degradation of pharmaceuticals and metabolite in synthetic human urine by UV,UV/H2O2,and UV/PDS[J].Environmental Science&Technology,2015,49(5):3056-3066.
[14]CHEN W S,SU Y C.Removal of dinitrotoluenes in wastewater by sono-activated persulfate[J].Ultrasonics Sonochemistry,2012,19(4):921-927.
[15]CRIQUET J,LEITNER N K V.Electron beam irradiation of aqueous solution of persulfate ions[J].Chemical Engineering Journal,2011,169(1/2/3):258-262.
[16]LEI Y,CHEN C S,TU Y J,et al.Heterogeneous degradation of organic pollutants by persulfate activated by Cu O-Fe3O4:mechanism,stability,and effects of p H and bicarbonate ions[J].Environmental Science&Technology,2015,49(11):6838-6845.
[17]ZHAO L,HOU H,FUJII A,et al.Degradation of 1,4-dioxane in water with heat-and Fe2+-activated persulfate oxidation[J].Environmental Science&Pollution Research,2014,21(12):7457-7465.
[18]KOLTHOFF I M,MILLER I K.The chemistry of persulfate.Ⅰ.the kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium[J].Journal of the American Chemical Society,1951,73(7):1-30.
[19]BEHRMAN E J,DEAN D H.Sodium peroxydisulfate is a stable and cheap substitute for ammonium peroxydisulfate(persulfate)in polyacrylamide gel electrophoresis[J].Journal of Chromatography B:Biomedical Sciences&Applications,1999,723(1/2):325-326.
[20]BAJPAI P.Chapter Seven:Peroxyacids Bleaching//Environmentally Benign Approaches for Pulp Bleaching[M].Elsevier Science Ltd.,2012:167-188.
[21]PEYTON G R.The free-radical chemistry of persulfate-based total organic carbon analyzers[J].Marine Chemistry,1993,41(1/2/3):91-103.
[22]XU X R,LI X Z.Degradation of azo Dye Orange G in aqueous solutions by persulfate with ferrous ion[J].Separation&Purification Technology,2010,72(1):105-111.
[23]LIANG C,BRUELL C J,MARLEY M C,et al.Persulfate oxidation for in situ remediation of TCE.Ⅱ.activated by chelated ferrous ion[J].Chemosphere,2004,55(9):1225-1233.
[24]RASTOGI A,AL-ABED S R,DIONYSIOU D D.Effect of inorganic,synthetic and naturally occurring chelating agents on Fe(Ⅱ)mediated advanced oxidation of chlorophenols[J].Water Research,2009,43(3):684-694.
[25]ZHANG J,CHEN M Y,ZHU L.Activation of persulfate by Co3O4nanoparticles for Orange G degradation[J].RSC Advances,2015,6(1):758-768.
[26]RHADFI T,PIQUEMAL J Y,SICARD L,et al.Polyol-made Mn3O4,nanocrystals as efficient Fenton-like catalysts[J].Applied Catalysis A:General,2010,386(1/2):132-139.
[27]LI Y,LIU L D,LU L,et al.Efficient oxidation of phenol by persulfate using manganite as a catalyst[J].Journal of Molecular Catalysis A:Chemical,2016,411:264-271.
[28]FURUKAWA Y,KIM J W,WATKINS J,et al.Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron[J].Environmental Science&Technology,2002,36(24):5469-5475.
[29]OH S Y,KIM H W,PARK J M,et al.Oxidation of polyvinyl alcohol by persulfate activated with heat,Fe2+,and zero-valent iron[J].Journal of Hazardous Materials,2009,168(1):346-351.
[30]FANG G D,DIONYSIOU D D,AL-ABED S R,et al.Superoxide radical driving the activation of persulfate by magnetite nanoparticles:implications for the degradation of PCBs[J].Applied Catalysis B:Environmental,2013,129:325-332.
[31]YAN J,LEI M,ZHU L,et al.Degradation of sulfamonomethoxine with Fe3O4magnetic nanoparticles as heterogeneous activator of persulfate[J].Journal of Hazardous Materials,2011,186(2/3):1398-1404.
[32]LEE H,LEE H J,JEONG J,et al.Activation of persulfates by carbon nanotubes:oxidation of organic compounds by nonradical mechanism[J].Chemical Engineering Journal,2015,266:28-33.
[33]DUAN X G,SUN H Q,KANG J,et al.Insights into heterogeneous catalysis of persulfate activation on dimensional-structured nanocarbons[J].ACS Catalysis,2015,5:4629-4636.
[34]史宸菲,李雨濛,冯瑞杰,等.蓝藻生物炭的制备及对过硫酸盐的活化效能[J].生态与农村环境学报,2017,33(12):1140-1145.SHI C F,LI Y M,FENG R J,et al.Preparation of biochar from cyanobacteria and function of the biochar for persulfate activation[J].Rural Eco-Environment,2017,33(12):1140-1145.
[35]刘子乐,曾泽泉,杨洁杨,等.表面改性活性炭活化过硫酸盐降解苯酚[J].高等学校化学学报,2017,38(7):1241-1248.LIU Z L,ZENG Z Q,YANG J Y,et al.Degradation of phenol with persulfate activated by surface modified activated carbon[J].Chemical Research in Chinese Universities,2017,38(7):1241-1248.
[36]荣亚运,师林丽,张晨,等.热活化过硫酸盐氧化去除木质素降解产物[J].化工学报,2016,67(6):2618-2624.RONG Y Y,SHI L L,ZHANG C,et al.Oxidation of lignin-degradation products by heat-activated persulfate[J].Journal of Chemical Industry and Engineering(China),2016,67(6):2618-2624.
[37]朱思瑞,高乃云,鲁仙,等.热激活过硫酸盐氧化降解水中双酚A[J].中国环境科学,2017,37(1):188-194.ZHU S R,GAO N Y,LU X,et al.Degradation of bisphenol A in aqueous solution by thermally activated sulfate oxidation[J].China Environmental Science,2017,37(1):188-194.
[38]马京帅,吕文英,刘国光,等.热活化过硫酸盐降解水中的普萘洛尔[J].环境化学,2017,36(2):221-228.MA J S,LV W Y,LIU G G,et al.Degradation of propranolol in aqueous solution by heat-activated persulfate[J].Environmental Chemistry,2017,36(2):221-228.