电容去离子技术在水处理中的研究现状
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摘要
介绍了电容去离子技术(CDI)的研究现状和主要影响参数,分析了地浸采铀工艺水及废水的组成,以及活性炭电极对铀的吸附性能,认为CDI技术在浸出液中铀的富集、工艺废水脱盐及减量化等方向具有重要的研究意义。
The research status and the major influence parameters of Capacitive Deionization are introduced in this paper.The component of process water and industrial wastewater in in-situ leaching uranium are analyzed as well as the adsorbing capacity of uranium on activated carbon electrode.The study indicates that CDI process may accomplish value in the uranium enrichment and in the waste water desalination.
The research status and the major influence parameters of Capacitive Deionization are introduced in this paper.The component of process water and industrial wastewater in in-situ leaching uranium are analyzed as well as the adsorbing capacity of uranium on activated carbon electrode.The study indicates that CDI process may accomplish value in the uranium enrichment and in the waste water desalination.
引文
[1]苏学斌,张渤,汤庆四.地浸采铀工艺钻孔现状及发展趋势:中国核科学技术进展报告(第四卷)——中国核学会2015年学术年会论文集第1册(铀矿地质分卷、铀矿冶分卷)[C].北京:中国原子能出版社,2015:344-351.
[2]李兴亮,宋强,刘碧君,等.炭材料对铀的吸附[J].化学进展,2011,(7):1446-1453.
[3]黄宽,唐浩,刘丹阳,等.电容去离子技术综述(一):理论基础[J].环境工程,2016,34(S1):82-88.
[4]黄伟.电容去离子法电极材料脱盐特性及处理提钒高盐废水研究[D].武汉:武汉理工大学,2014.
[5]王璐.电吸附法去除水中重金属离子的研究[D].西安:西安建筑科技大学,2010.
[6] PORADA S,ZHAO R,WAL A VAN DER,et al.Review on the science and technology of water desalination by capacitive deionization[J].Progress in Materials Science,2013,58(8):1388-1442.
[7]黄宽,唐浩,刘丹阳,等.电容去离子技术综述(二):电极材料[J].环境工程,2016,34(S1):89-100.
[8]黄宽,唐浩,刘丹阳,等.电容去离子技术综述(三):影响因素[J].环境工程,2016,34(S1):101-106.
[9] LI H,ZOU L,PAN L,et al.Using grapheme nano-flakes as electrodes to remove ferric ions by capacitive deionization[J].Separation and Purification Technology,2010,75(1):8-14.
[10] SHARMA K,KIM Y H,GABITTO J,et al.Transport of ions in mesoporous carbon electrodes during capacitive deionization of high-salinity solutions[J].Langmuir:The ACS Journal of Surfaces and Colloids,2015,31(3):1038-1047.
[11] SHARMA K,BILHEUX H Z,WALKER L M H,et al.Neutron imaging of ion transport in mesoporous carbon materials[J].Physical Chemistry Chemical Physics,2013,15(28):11740-11747.
[12] JEON S I,PARK H R,YEO J G,et al.Desalination via a new membrane capacitive deionization process utilizing flow-electrodes[J].Energy&Environmental Science,2013,6(5):1471-1475.
[13] GABELICH C J,TRANSFER T D,SUFFET I H.Electrosorption of inorganic salts from aqueous solution using carbon[J].Environ Scithchnol,2002(36):2010-2019.
[14]韩寒,陈新春,尚海利.电吸附除盐技术的发展及应用[J].工业水处理,2010,30(2):20-23.
[15]陈天明,严金龙,陈艳虹,等.活性炭纤维对电镀废水中镍的电吸附性能研究[J].工业水处理,2014,34(11):36-39.
[16]徐芳草,王丹丹,许庆迪,等.电吸附法处理低浓度含铜废水研究[J].广东化工,2015,42(23):155-157.
[17]施周,靳兆祺,邓林,等.CNT/PANI电极吸附去除水中Cu2+的研究[J].中国环境科学,2016,36(12):3650-3656.
[18] AFKHAMI A,CONWAY B E.Investigation of removal of Cr(Ⅵ),Mo(Ⅵ),W(Ⅵ),V(Ⅳ)and V(Ⅴ)oxy-ions from industrial waste-waters by adsorption and electrosorption at high-area carbon cloth[J].Jounal of Colloid and Interface Science.2002,251(2):248-255.
[19]刘海静,张鸿涛,孙晓慰.电吸附法去除地下水中离子的试验研究[J].中国给水排水,2003,19(11):36-38.
[20]周贵忠,王兆丰,王绚,等.石墨-活性炭纤维复合电极电吸附处理含盐废水的研究[J].环境科学,2014,35(5):1832-1837.
[21]梁乾伟,胡承志,李永峰,等.ACF电吸附去除饮用水中的硝酸盐[J].环境工程学报,2016,10(7):3510-3514.
[22]马爱鹏,李福勤,王翠.活性炭纤维电极电吸附除盐的试验研究[J].中国新技术新产品,2011(5):8.
[23]李少华,潘涌璋.活性炭纤维电极的电容去离子脱盐试验研究[J].工业用水与废水,2014,45(1):36-39.
[24]陈榕,胡熙恩.电吸附技术的应用与研究[J].化学进展,2006,18(1):80-86.
[25] PLAISANCE H,MOCHO P,BONNECAZE G.Adsorption and electrosorption of benzene on granular activated carbon[J].Environmental Technology.1996,17(12):1313-1325.
[26]王永军.电吸附技术开辟第二廉价水源[J].齐鲁石油化工,2011(39):178.
[27]莫剑雄.电容吸附去离子方法的研究[J].水处理技术,2007,33(8):20-22.
[28]杜志明,刘乃忠,李建华,等.地浸采铀废水减量与循环利用:“中国核科学技术进展报告(第三卷)——中国核学会2013年学术年会论文集第2册”[C].北京:中国原子能出版社,2013:24-29.
[29]苏学斌,王海峰,刘乃忠.CO2+O2原地浸出采铀工艺[M].北京:中国原子能出版社,2016:194.
[30]杨伯和.铀矿加工工艺学[Z].[出版地不详]:[出版者不详],2002:250.
[2]李兴亮,宋强,刘碧君,等.炭材料对铀的吸附[J].化学进展,2011,(7):1446-1453.
[3]黄宽,唐浩,刘丹阳,等.电容去离子技术综述(一):理论基础[J].环境工程,2016,34(S1):82-88.
[4]黄伟.电容去离子法电极材料脱盐特性及处理提钒高盐废水研究[D].武汉:武汉理工大学,2014.
[5]王璐.电吸附法去除水中重金属离子的研究[D].西安:西安建筑科技大学,2010.
[6] PORADA S,ZHAO R,WAL A VAN DER,et al.Review on the science and technology of water desalination by capacitive deionization[J].Progress in Materials Science,2013,58(8):1388-1442.
[7]黄宽,唐浩,刘丹阳,等.电容去离子技术综述(二):电极材料[J].环境工程,2016,34(S1):89-100.
[8]黄宽,唐浩,刘丹阳,等.电容去离子技术综述(三):影响因素[J].环境工程,2016,34(S1):101-106.
[9] LI H,ZOU L,PAN L,et al.Using grapheme nano-flakes as electrodes to remove ferric ions by capacitive deionization[J].Separation and Purification Technology,2010,75(1):8-14.
[10] SHARMA K,KIM Y H,GABITTO J,et al.Transport of ions in mesoporous carbon electrodes during capacitive deionization of high-salinity solutions[J].Langmuir:The ACS Journal of Surfaces and Colloids,2015,31(3):1038-1047.
[11] SHARMA K,BILHEUX H Z,WALKER L M H,et al.Neutron imaging of ion transport in mesoporous carbon materials[J].Physical Chemistry Chemical Physics,2013,15(28):11740-11747.
[12] JEON S I,PARK H R,YEO J G,et al.Desalination via a new membrane capacitive deionization process utilizing flow-electrodes[J].Energy&Environmental Science,2013,6(5):1471-1475.
[13] GABELICH C J,TRANSFER T D,SUFFET I H.Electrosorption of inorganic salts from aqueous solution using carbon[J].Environ Scithchnol,2002(36):2010-2019.
[14]韩寒,陈新春,尚海利.电吸附除盐技术的发展及应用[J].工业水处理,2010,30(2):20-23.
[15]陈天明,严金龙,陈艳虹,等.活性炭纤维对电镀废水中镍的电吸附性能研究[J].工业水处理,2014,34(11):36-39.
[16]徐芳草,王丹丹,许庆迪,等.电吸附法处理低浓度含铜废水研究[J].广东化工,2015,42(23):155-157.
[17]施周,靳兆祺,邓林,等.CNT/PANI电极吸附去除水中Cu2+的研究[J].中国环境科学,2016,36(12):3650-3656.
[18] AFKHAMI A,CONWAY B E.Investigation of removal of Cr(Ⅵ),Mo(Ⅵ),W(Ⅵ),V(Ⅳ)and V(Ⅴ)oxy-ions from industrial waste-waters by adsorption and electrosorption at high-area carbon cloth[J].Jounal of Colloid and Interface Science.2002,251(2):248-255.
[19]刘海静,张鸿涛,孙晓慰.电吸附法去除地下水中离子的试验研究[J].中国给水排水,2003,19(11):36-38.
[20]周贵忠,王兆丰,王绚,等.石墨-活性炭纤维复合电极电吸附处理含盐废水的研究[J].环境科学,2014,35(5):1832-1837.
[21]梁乾伟,胡承志,李永峰,等.ACF电吸附去除饮用水中的硝酸盐[J].环境工程学报,2016,10(7):3510-3514.
[22]马爱鹏,李福勤,王翠.活性炭纤维电极电吸附除盐的试验研究[J].中国新技术新产品,2011(5):8.
[23]李少华,潘涌璋.活性炭纤维电极的电容去离子脱盐试验研究[J].工业用水与废水,2014,45(1):36-39.
[24]陈榕,胡熙恩.电吸附技术的应用与研究[J].化学进展,2006,18(1):80-86.
[25] PLAISANCE H,MOCHO P,BONNECAZE G.Adsorption and electrosorption of benzene on granular activated carbon[J].Environmental Technology.1996,17(12):1313-1325.
[26]王永军.电吸附技术开辟第二廉价水源[J].齐鲁石油化工,2011(39):178.
[27]莫剑雄.电容吸附去离子方法的研究[J].水处理技术,2007,33(8):20-22.
[28]杜志明,刘乃忠,李建华,等.地浸采铀废水减量与循环利用:“中国核科学技术进展报告(第三卷)——中国核学会2013年学术年会论文集第2册”[C].北京:中国原子能出版社,2013:24-29.
[29]苏学斌,王海峰,刘乃忠.CO2+O2原地浸出采铀工艺[M].北京:中国原子能出版社,2016:194.
[30]杨伯和.铀矿加工工艺学[Z].[出版地不详]:[出版者不详],2002:250.