新型有机硅壳聚糖两性表面活性剂对羊毛的低温染色性能研究
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摘要
为克服传统羊毛在高温沸染时存在羊毛天然品质破坏、纤维强力下降、能耗大、成本高等问题,采用有机硅对壳聚糖进行改性,制备了一种新型有机硅壳聚糖两性表面活性剂,并将其应用于羊毛低温染色,重点研究了染色过程中有机硅壳聚糖两性表面活性剂浓度、染色温度、染色时间对上染百分率和K/S值的影响.结果表明:经有机硅壳聚糖两性表面活性剂处理后的羊毛织物,能保持其品质的同时,一定程度上降低染色温度.预处理最优条件为:有机硅壳聚糖两性表面活性剂2g/L,预处理温度40℃,预处理时间30min;最佳染色工艺为:温度85℃,染色pH值为3,毛用活性翠蓝2.5%(owf),该条件下K/S均值为11.320,标准偏差仅为0.196.
In order to solve the problems of wool's natural quality destruction,fiber strength reduction,energy consumption and high cost in traditional wool dyeing at high temperature,a new type of organosilicon chitosan amphoteric surfactant is prepared by modification of chitosan with organosilicon and applied to low temperature dyeing of wool.The effects of the amount of organosilicon chitosan amphoteric surfactant,dyeing temperature and dyeing time on dyeing percentage and K/S value are studied.The results show that wool fabrics treated with the organosilicon chitosan amphoteric surfactants can hold natural properties of wool and reduce dyeing temperature to a certain extent.The optimal preconditioning conditions are as follows:the organosilicon chitosan amphoteric surfactant 2 g/L,the pretreatment temperature is 40℃,and the pretreatment time is 30 min.The optimum dying process is pH value of 3,85 ℃,Wool Reactive Turquoise Blue dye 2.5%(owf)of solution for wool fabr,Under this condition,the K/S value is 11.320,and the standard deviation is only 0.196.
In order to solve the problems of wool's natural quality destruction,fiber strength reduction,energy consumption and high cost in traditional wool dyeing at high temperature,a new type of organosilicon chitosan amphoteric surfactant is prepared by modification of chitosan with organosilicon and applied to low temperature dyeing of wool.The effects of the amount of organosilicon chitosan amphoteric surfactant,dyeing temperature and dyeing time on dyeing percentage and K/S value are studied.The results show that wool fabrics treated with the organosilicon chitosan amphoteric surfactants can hold natural properties of wool and reduce dyeing temperature to a certain extent.The optimal preconditioning conditions are as follows:the organosilicon chitosan amphoteric surfactant 2 g/L,the pretreatment temperature is 40℃,and the pretreatment time is 30 min.The optimum dying process is pH value of 3,85 ℃,Wool Reactive Turquoise Blue dye 2.5%(owf)of solution for wool fabr,Under this condition,the K/S value is 11.320,and the standard deviation is only 0.196.
引文
[1]郭璨.羊毛低温染色理论与实践研究[D].河南:中原工学院硕士学位论文,2015.
[2]孟祥玲,刀俊华.三羧乙基膦对羊毛织物低温染色性能的影响[J].针织工业,2016(6):58-61.
[3]丁彩玲,俞建勇,张瑞云.超细羊毛的低温低损伤染色性能[J].纺织学报,2016,37(6):72-75.
[4]董玲,胡啸林.羊绒纤维超声波低温染色[J].毛纺科技,2014,42(5):24-27.
[5]李贲,王强,袁久刚.羊毛角蛋白酶和蛋白酶二浴法防毡缩整理研究[J].毛纺科技,2013,41(6):1-5.
[6]张正宇.以尿素为基础的羊毛低温染色工艺初探[J].印染助剂,2008,25(1):38-40.
[7]张正宇,郑春玲.基于蚁酸的羊毛红外低温染色研究[J].毛纺科技,2011,39(4):10-14.
[8]Jock D,Vflchez S,Topalovic T,et al.Effect of Lowtemperature Plasma and Chitosan Treatment on Wool Dyeing with Acid Red 27[J].J Appl Poly Sci,2005(97):2204-2214.
[9]Ali N F,Ei-Khatib E M.Modification of Wool Fabric to Improve its Dye Ability[J].J Natural Fibers,2010,7(4):276-288.
[10]王兰兰,张辉,章德发.壳聚糖分子量对羊毛织物染色性能的影响[J].纺织科技进展,2008(3):69-70.
[11]刘雷艮,潘志娟,牛建涛.壳聚糖改性静电纺聚砜纤维膜对染料的过滤性能[J].纺织学报,2016,37(10):1-7.
[12]甄莉莉,付小蓉,程坚,等.经壳聚糖季铵盐整理的羊毛织物酸性染料染色性能[J].纺织学报,2014,35(8):59-63.
[13]龚真萍.芦木染料对壳聚糖处理羊毛织物的染色性能[J].毛纺科技,2017,45(2):17-20.
[14]Radetic M,Jocic D,Jovancic P,et al.Recycled Wool-based Nonwoven Material for So-rption of Acid Dyes[J].Indian J Fiber Text Res,2005,30(1):82-87.
[15]何雪梅,杜梅,沈雪柏.壳聚糖季铵盐/硅杂化膜对棉纤维的表面修饰[J].纺织学报,2016,37(2):97-102.
[16]Kumar M N V,Muzzarelli R A A,Muzzarelli C.Chitosan Chemistry and Pharmaceutical Per-spectives[J].Chemical Reviews,2004,104:6017-6084.
[17]颜东,邓继勇,汪南方.有机硅改性聚氨酯/丙烯酸酯共聚乳液对棉织物的抗皱整理[J].纺织学报,2018,39(1):89-93.
[18]GB/T 2391-2006,反应染料固色率的测定[S].中国标准出版社,2006.
[19]GB/T 3921-2008,纺织品色牢度实验耐皂洗色牢度[S].中国标准出版社,2008.
[20]GB/T 12490-2014,纺织品色牢度试验耐家庭和商业洗涤色牢度[S].中国标准出版社,2014.
[2]孟祥玲,刀俊华.三羧乙基膦对羊毛织物低温染色性能的影响[J].针织工业,2016(6):58-61.
[3]丁彩玲,俞建勇,张瑞云.超细羊毛的低温低损伤染色性能[J].纺织学报,2016,37(6):72-75.
[4]董玲,胡啸林.羊绒纤维超声波低温染色[J].毛纺科技,2014,42(5):24-27.
[5]李贲,王强,袁久刚.羊毛角蛋白酶和蛋白酶二浴法防毡缩整理研究[J].毛纺科技,2013,41(6):1-5.
[6]张正宇.以尿素为基础的羊毛低温染色工艺初探[J].印染助剂,2008,25(1):38-40.
[7]张正宇,郑春玲.基于蚁酸的羊毛红外低温染色研究[J].毛纺科技,2011,39(4):10-14.
[8]Jock D,Vflchez S,Topalovic T,et al.Effect of Lowtemperature Plasma and Chitosan Treatment on Wool Dyeing with Acid Red 27[J].J Appl Poly Sci,2005(97):2204-2214.
[9]Ali N F,Ei-Khatib E M.Modification of Wool Fabric to Improve its Dye Ability[J].J Natural Fibers,2010,7(4):276-288.
[10]王兰兰,张辉,章德发.壳聚糖分子量对羊毛织物染色性能的影响[J].纺织科技进展,2008(3):69-70.
[11]刘雷艮,潘志娟,牛建涛.壳聚糖改性静电纺聚砜纤维膜对染料的过滤性能[J].纺织学报,2016,37(10):1-7.
[12]甄莉莉,付小蓉,程坚,等.经壳聚糖季铵盐整理的羊毛织物酸性染料染色性能[J].纺织学报,2014,35(8):59-63.
[13]龚真萍.芦木染料对壳聚糖处理羊毛织物的染色性能[J].毛纺科技,2017,45(2):17-20.
[14]Radetic M,Jocic D,Jovancic P,et al.Recycled Wool-based Nonwoven Material for So-rption of Acid Dyes[J].Indian J Fiber Text Res,2005,30(1):82-87.
[15]何雪梅,杜梅,沈雪柏.壳聚糖季铵盐/硅杂化膜对棉纤维的表面修饰[J].纺织学报,2016,37(2):97-102.
[16]Kumar M N V,Muzzarelli R A A,Muzzarelli C.Chitosan Chemistry and Pharmaceutical Per-spectives[J].Chemical Reviews,2004,104:6017-6084.
[17]颜东,邓继勇,汪南方.有机硅改性聚氨酯/丙烯酸酯共聚乳液对棉织物的抗皱整理[J].纺织学报,2018,39(1):89-93.
[18]GB/T 2391-2006,反应染料固色率的测定[S].中国标准出版社,2006.
[19]GB/T 3921-2008,纺织品色牢度实验耐皂洗色牢度[S].中国标准出版社,2008.
[20]GB/T 12490-2014,纺织品色牢度试验耐家庭和商业洗涤色牢度[S].中国标准出版社,2014.